Columnar Structure Research Articles

Different Heat-Exposure Temperatures on the Microstructure and Properties of Dissimilar GH4169/IC10 Superalloy Vacuum Electron Beam Welded Joint

Vacuum electron-beam welding (EBW) was used to join the precipitation-strengthened GH4169 superalloy and a new nickel-based superalloy IC10 to fabricate the turbine blade discs. In this study, a solid solution (1050 °C/2 h for GH4169 and 1150 °C/2 h for IC10) and different heat-exposure temperatures (650 °C, 750 °C, 950 °C and 1050 °C/200 h, respectively) were used to study the high-temperature tensile properties and microstructure evolution of welded joints; meanwhile, the formation and evolution of the second phases of the joints were analyzed. After EBW, the welded joint exhibited a typical nail morphology, and the fusion zone (FZ) consisted of columnar and cellular structures. During the solidification process of the molten pool, Mo elements are enriched in the dendrites and inter-dendrites, and that of Nb and Ti elements was enriched in the dendrites, which lead to forming a non-uniform distribution of Laves eutectic and MC carbides in the FZ. The microhardness of the FZ gradually increased during thermal exposure at 650 °C and reached 300–320 HV, and the γ′ and γ″ phases were gradually precipitated with size of about 50 nm. Meanwhile, the microhardness of the FZ decreased to 260–280 HV at 750 °C, and the higher temperature resulted in the coarsening of the γ″ phase (with a final size of about 100 nm) and the formation of the acicular δ-phase. At 950 °C and 1050 °C, the microhardness of FZ decreased sharply, reaching up to 170~190 HV and 160~180 HV, respectively. Moreover, the Laves eutectic and MC carbides are dissolved to a greater extent without the formation of γ″ and δ phases; as a result, the absent of γ″ and δ phases are attributed to the significant improvement of segregation at higher temperatures.

Investigation on microstructure and high-temperature wear properties of high-speed laser cladding Inconel 625 alloy

Inconel 625 alloy cladding layer was prepared by high-speed laser cladding (HLC) on Q245R steel substrate to improve the service performance of the structural components in the power industry in this work. A comprehensive study on the HLC Inconel 625 coating with different scanning speeds was conducted utilizing Scanning Electron Microscope (SEM), Transmission Electron Microscope (TEM), Laser Scanning Confocal Microscope (LSCM), X-Ray Diffraction (XRD), a microhardness tester, and an SRV-4 high-temperature friction and wear testing machine. The results show that the cladding layer's thickness and surface roughness decrease with the scanning speed increase. The cladding layers with different scanning speeds contain different microstructures. The phases mainly consist of γ-Ni and NbC. The microhardness of HLC coatings is generally higher than that of substrate, but decreased as the scanning speed increased. After the friction wear test at 500 °C, the cladding layer at the scanning speed of 2 m/min showed the best high-temperature wear resistance. The grain boundary area increases due to the formation of small-sized equiaxed dendrites, which resists dislocation slip and crack propagation, thereby enhancing high-temperature wear resistance. For the cladding layers at the higher scanning speed, the abrasive wear and the fatigue wear occur due to the precipitation of solid soluble elements such as Nb and Mo and the columnar crystal structures prone to deformation.

Effects of TiB Volume Fraction on the Microstructure and Mechanical Properties of TiBw/TA15 Composites with Novel Columnar Structure

Effects of TiB Volume Fraction on the Microstructure and Mechanical Properties of TiBw/TA15 Composites with Novel Columnar Structure

Mg incorporation induced microstructural evolution of reactively sputtered GaN epitaxial films to Mg-doped GaN nanorods

Mg-doped GaN films/nanorods were grown epitaxially on c-sapphire by reactive co-sputtering of GaAs and Mg at different N2 percentages in Ar–N2 sputtering atmosphere. Energy dispersive x-ray spectroscopy revealed that the Mg incorporation increases with increase of Mg area coverage of GaAs target, but does not depend on N2 percentage. In comparison to undoped GaN films, Mg-doped GaN displayed substantial decrease of lateral conductivity and electron concentration with the initial incorporation of Mg, indicating p-type doping, but revealed insulating behaviour at larger Mg content. Morphological investigations by scanning electron microscopy have shown that the films grown with 2%–4% Mg area coverages displayed substantially improved columnar structure, compared to undoped GaN films, along with rough and voided surface features at lower N2 percentages. With increase of Mg area coverage to 6%, the growth of vertically aligned and well-separated nanorods, terminating with smooth hexagonal faces was observed in the range of 50%–75% N2 in sputtering atmosphere. High-resolution x-ray diffraction studies confirmed the epitaxial character of Mg-doped GaN films and nanorods, which displayed complete c-axis orientation of crystallites and a mosaic structure, aligned laterally with the c-sapphire lattice. The catalyst-free growth of self-assembled Mg-doped GaN nanorods is attributed to increase of surface energy anisotropy due to the incorporation of Mg. However, with further increase of Mg area coverage to 8%, the nanorods revealed lateral merger, suggesting enhanced radial growth at larger Mg content.

A new method for refinement of Ti-6Al-4 V prior-β grain structure in the alternating magnetic field assisted narrow gap gas tungsten arc welding (AMF-GTAW) via filler wire oscillation

This study presents a new method for refining Ti-6Al-4 V prior-β grain in the alternating magnetic field assisted narrow gap gas tungsten arc welding (AMF-GTAW) process by stirring the molten pool, which is accomplished directly through the use of an oscillating filler wire. The wire feed rate can be increased from 1.8 m/min to 2.2 m/min by filler wire oscillation in the traditional AMF-GTAW process with minimal heat input. This method greatly increases welding efficiency by efficiently utilizing the energy of the arc and molten pool. Using a high-speed camera, the flow behavior of the molten pool was investigated under different filler wire oscillating amplitudes. The results showed that the oscillation of the filler wire can cause a violent stir in the molten pool. By increasing the oscillating amplitude of filler wire, one can refine the columnar prior-β grain structure and attain a morphology of the upper layer of the welded joint that is nearly equiaxed with crystallographic texture, all while maintaining a fixed heat input. This is because the wire's insertion into the molten pool also creates a negative thermal gradient and the filler wire's high-frequency and high-amplitude oscillation creates an intense convection that prevents randomly oriented nuclei and/or dendrite fragments from remelting and promotes nucleation activation. The oscillating amplitude of 6 mm and the oscillating frequency of 100 Hz are the ideal values for this effect.

Guinea fowl eggshell structural analysis at different scales reveals how organic matrix induces microstructural shifts that enhance its mechanical properties

Guinea fowl eggshells have an unusual structural arrangement that is different from that of most birds, consisting of two distinct layers with different microstructures. This bilayered organization, and distinct microstructural characteristics, provides it with exceptional mechanical properties. The inner layer, constituting about one third of the eggshell thickness, contains columnar calcite crystal units arranged vertically as in most bird shells. However, the thicker outer layer has a more complex microstructural arrangement formed by a switch to smaller calcite domains with diffuse/interlocking boundaries, partly resembling the interfaces seen in mollusk shell nacre. The switching process that leads to this remarkable second-layer microstructure is unknown. Our results indicate that the microstructural switching is triggered by changes in the inter- and intracrystalline organic matrix. During production of the outer microcrystalline layer in the later stages of eggshell formation, the interactions of organic matter with mineral induce an accumulation of defects that increase crystal mosaicity, instill anisotropic lattice distortions in the calcite structure, interrupt epitaxial growth, reduce crystallite size, and induce nucleation events which increase crystal misorientation. These structural changes, together with the transition between the layers and each layer having different microstructures, enhance the overall mechanical strength of the Guinea fowl eggshell. Additionally, our findings provide new insights into how biogenic calcite growth may be regulated to impart unique functional properties. Statement of significanceAvian eggshells are mineralized to protect the embryo and to provide calcium for embryonic chick skeletal development. Their thickness, structure and mechanical properties have evolved to resist external forces throughout brooding, yet ultimately allow them to crack open during chick hatching. One particular eggshell, that of the Guinea fowl, has structural features very different from other galliform birds – it is bilayered, with an inner columnar mineral structure (like in most birds), but it also has an outer layer with a complex microstructure which contributes to its superior mechanical properties. This work provides novel and new fundamental information about the processes and mechanisms that control and change crystal growth during the switch to microcrystalline domains when the second outer layer forms.

Corrosion Degradation Mechanism of Cr-Coated Zr-4 Alloy under Simulated Nuclear Conditions for Accident-Tolerant Fuel.

Cr coatings with a thickness of about 19 μm were synthesized on Zr-4 cladding using plasma-enhanced arc ion plating. A Zr-Cr micro-diffusion layer was formed via Cr ion cleaning before deposition to enhance the interface bonding strength. Cr coatings exhibit an obvious columnar crystal structure with an average grain size of 1.26 μm using SEM (scanning electron microscopy) and EBSD (electron backscatter diffraction) with a small amount of nanoscale pores on the surface. A long-term aqueous test at 420 ± 3 °C, 10.3 ± 0.7 MPa and isothermal oxidation tests at 900~1300 °C in air were conducted to evaluate the Cr-coated Zr-4 cladding. All the results showed that the Cr coatings had a significant protective effect to the Zr-4 alloy. However, the corrosion deterioration mechanism is different. A gradual thinning of the Cr coating was observed in a long-term aqueous test, but a cyclic corrosion mechanism of void initiation-propagation-cracking at the oxide film interface is the main corrosion characteristic of the Cr coating in isothermal oxidation. Different corrosion models are constructed to explain the corrosion mechanism.

Thermochemical convection in a slowly rotating spherical shell: a transition between prograde and retrograde flows

We numerically investigate thermochemically-driven convection in a spherical shell at a high Ekman number for a range of Rayleigh numbers, Prandtl numbers and buoyancy ratios. Rotating convection displays a nearly axisymmetric large-scale structure and appears mostly unaffected by the nature (thermal or chemical) of the driving buoyancy source. We observe both precession directions, prograde and retrograde, of convection structures and identify a snap-through transition between the prograde and retrograde flows in the parameter space spanned by the Rayleigh and Prandtl numbers. Equatorially wall-attached and spiralling columnar convection structures, which typically emerge in rapidly rotating shells, are not observed.

Facile preparation of KNN thin film with high purity phase and excellent electrical properties

Obtaining high purity alkali niobate (K x Na1-x NbO3) thin films without secondary phase on metal coated traditional silicon (Si) substrates via sol–gel technique has remained great challenges until now. Herein, we report K0.5Na0.5NbO3 (KNN) thin films successfully deposited on Pt/Ti/SiO2/Si(100) substrates by a simply effective sol–gel process. A comprehensive and systematic investigation of processing conditions on the microstructures and electrical properties of spin-coated KNN films was presented. We have found that phase purity and microstructures of KNN films are strongly influenced by content of alkali excess and the annealing temperature. Thin films with an equal excess amount of 10% mol K and Na (KNN1) sintered at 650 °C show high crystallinity with a preferred (100)-orientation degree of 78%, and homogeneous and dense surface with columnar structure and large grain size up to 254 nm. The result of quantitative XPS analysis has proved that the composition of the film is close to the chemical stoichiometry. As a consequence, the obtained KNN1 films exhibit a large dielectric constant of 775 and low dielectric loss of ∼2% in the wide frequency range from 1kHz up to 10MHz as well as the best shape of P−E loops. Furthermore, leakage current density of the film is about 9.45 × 10−5 A cm−2 at E ≈100 kV cm−1.

Improving the processability and grain structures of additively manufactured Al-Fe-Cu-xZr alloy: Experiment and high-fidelity simulation

Additive manufacturing (AM) offers significant advantages over conventional manufacturing techniques in processing Al alloys, however, high-strength Al alloys produced by AM commonly encounter a few challenges including poor processability and undesirable microstructures with coarse columnar grains and even micro-cracks, leading to poor mechanical properties of the resultant Al alloys. Here, we demonstrate that these issues can be largely resolved by micro-alloying of Zr element in the Al-based alloys. In this study, a series of novel Al-1Fe-0.6Cu-xZr alloys with different content of Zr (x=0.3, 0.6, 0.8, 1.3 at%) are designed and then subjected to laser powder bed fusion (LPBF). It is found that, with increasing Zr content, the processability of Al alloys is significantly improved, as evidenced by the gradual reduction of melt splashing and defects (including pores, balling, necking and discontinuity) during LPBF, which eventually leads to decrease of surface roughness and improvement of processability. High-fidelity simulation reveals that the processability is closely related to the melt velocity gradient (MVG) in melt pools. Increasing Zr content results in a more uniform distribution of MVG and decreased Marangoni convection, which favors the stability of melt pool and good processability. On the other hand, Zr content also plays an important role in microstructure. Although the four LPBF Al alloys all exhibit notably heterogeneous structures with alternate distribution of coarse grain zones (CGZs) and fine grain zones (FGZs) in the whole samples, with increasing Zr content, the coarse columnar grain structure in CGZs is suppressed and transforms to the fine equiaxial grain structure. The occurrence of columnar-to-equiaxed transition (CET) is attributed to the decreased ratio between temperature gradient (G) and solidification rate (R) at the solid-liquid interface with increasing Zr content. In addition, the increase in Zr content also leads to a gradual refinement of the grain size in both CGZs and FGZs due to the increased cooling rate. Beneficial from the good processability and fully refined equiaxial gain structure, nearly full-dense and high-strength Al alloys with 0.8 and 1.3 at% Zr are successfully fabricated, which show a good combination of high strength and ductility. The findings in this work provide a guild for design of novel Al alloys with good processability and advanced mechanical properties for additive manufacturing.

Characterization of Microstructural and Mechanical Properties of 17-4 PH Stainless Steel by Cold Rolled and Machining vs. DMLS Additive Manufacturing

The 17-4 PH stainless steel is widely used in the aerospace, petrochemical, chemical, food, and general metallurgical industries. The present study was conducted to analyze the mechanical properties of two types of 17-4 PH stainless steel—commercial cold-rolled and direct metal laser sintering (DMLS) manufactured. This study employed linear and nonlinear tensile FEM simulations, combined with various materials characterization techniques such as tensile testing and nanoindentation. Moreover, microstructural analysis was performed using metallographic techniques, optical microscopy, scanning electron microscopy (SEM) with energy dispersive spectroscopy (EDS), and X-ray diffraction (XRD). The results on the microstructure for 17-4 PH DMLS stainless steel reveal the layers of melting due to the laser process characterized by complex directional columnar structures parallel to the DMLS build direction. The mechanical properties obtained from the simple tension test decreased by 17% for the elastic modulus, 7.8% for the yield strength, and 7% for the ultimate strength for 17-4 PH DMLS compared with rolled 17-4 PH stainless steel. The FEM simulation using the experimental tension test data revealed that the 17-4 PH DMLS stainless steel experienced a decrease in the yield strength of ~8% and in the ultimate strength of ~11%. A reduction of the yield strength of the material was obtained as the grain size increased.

New nanoscale multilayer magnetron sputtered Ti-DLC/DLC coatings with improved mechanical properties

Two sets of nanoscale multilayer Ti-DLC/DLC coatings, with similar chemical composition but different periods between consecutive layers (0.4 and 5.5 nm), were deposited by non-reactive direct current magnetron sputtering using different rotational speeds of the substrate holder (12 and 1 rpm, respectively) in this work. The results show that the overall Ti content in the coatings varied from ≈ 2.9 to ≈ 8.2 at. % in both cases. Significant fluctuations in the Ti concentration between the middle points of the DLC and Ti-DLC layers were observed for the coatings deposited at 1 rpm. All the coatings deposited were mainly amorphous, presenting a columnar structure and a cauliflower-like granular surface morphology. The sp2/sp3 ratio increased as the concentration of Ti rose. The coatings deposited at 1 rpm demonstrated better mechanical properties (up to 33 % improvement in hardness and up to 25 % improvement in the elastic modulus) when compared to the equivalent coatings deposited at 12 rpm. The multilayer titanium doped coating (deposited at 1 rpm) with 5.9 at. % Ti presented the most significant improvement in mechanical properties when compared to pure DLC and monolayer coatings deposited at 12 rpm. The results confirmed that it is possible to tune the performance of this type of coatings by depositing alternating layers of pure DLC and Ti-doped DLC.

Effect of Mn addition on microstructure and corrosion behavior of AlCoCrFeNi high-entropy alloy

In this study, the effects of Mn content on the microstructure and corrosion resistance of AlCoCrFeNiMnx (x = 0, 0.25, 0.5, 0.75, and 1) high-entropy alloys were investigated. The results indicate that with increasing Mn content, the HEAs consistently comprise nanophase BCC geometry with different shapes embedded in the ordered B2-phase matrix, and the morphology of the microstructure changes from a coarse dendritic structure to a fine dendritic structure, then to a completely columnar dendrite structure. The microhardness of the HEAs increases gradually to 620 HV0.2 when x = 1, owing to the solid-solution and fine-grain strengthening. The corrosion resistance of the HEAs in 3.5 wt% NaCl solution first increases and then decreases, reaching a maximum with the lowest self-corrosion current density of 2.869 × 10−8 A∙cm−2 when x = 0.5. Improvement in corrosion resistance is related to a reduction in degree of composition segregation in the microstructure of HEAs, which leads to the formation of a dense and complete passivation film on the surface of the alloys. However, when the Mn content is in the range of 0–0.5, the pitting potential of the HEAs gradually decreases, although the passivation current density also gradually decreases. Higher Mn content (x > 0.5) leads to a transition of the HEAs from passivation to active dissolution. This indicates that the stability of the passivation film on the HEAs decreases with higher Mn content. XPS analysis revealed a gradual decline in the relative content of Cr2O3 and a gradual increase in the presence of unstable oxides such as MnO and Mn2O3 in the passivation film, leading to this phenomenon. The present work reveals that the addition of Mn in the AlCoCrFeNi HEA affects not only the microstructure and composition segregation but also the composition and stability of the passivation film, leading to a non-monotonic variation in the corrosion performance of the present HEAs with respect to the Mn content.

A high-voltage and low-solvating electrolyte towards promising micro-Si/Ni-rich NMC full cells

A full cell via pairing high-capacity silicon anode with high-voltage NMC cathode (Li(Ni0.83Co0.12Mn0.05)O2) holds great promise as a high-energy battery system for practical applications. Nevertheless, this potential has been hindered by challenges in terms of the pulverization of Si particles, unstable electrode/electrolyte interface, and severe dissolution of transition metals at high voltage. Herein, we present a novel high-voltage and weakly solvating electrolyte, consisted of lithium bis(fluorosulfonyl)imide in mixed solvent of diethyl carbonate and 1,1,2,2-tetrafluoroethyl-2,2,3,3-tetrafluoropropyl ether, which effectively enables the remarkable cycling stability of both micron silicon anode (a high reversible capacity of 1667 mAh g−1 after 200 cycles) and Ni-rich cathode (a notable capacity retention of 83% after 140 cycles at an ultrahigh cut-off voltage of 4.9 V). It is revealed that the tailored electrolyte leads to the formation of a robust and reinforced concrete-like solid electrolyte interphase, characterized by a distinctive vertical side-by-side columnar structure comprised of LiF and sulfide on the micro-silicon anode. Meanwhile, a uniform and thin cathode-electrolyte interphase is observed on the surface of NMC particles when cycled in the designed electrolyte. Furthermore, coupled with high-capacity micro-Si and high-voltage NMC, this designed electrolyte endows a remarkable full-cell with high energy density (475 Wh kg−1), excellent rate capability, and high-voltage cycling stability. This research contributes a pioneering approach to enabling the utilization of micron-sized silicon anodes and Ni-rich cathodes for next-generation high-energy lithium-ion batteries.

Tubular Nanoclay-Enhanced Calcium Phosphate Mineralization and Assembly to Impart High Stiffness and Antimicrobial Properties.

Achieving superior mechanical properties of composite materials in artificially engineered materials is a great challenge due to technical bottlenecks in the size and morphological modulation of inorganic nanominerals. Hence, a "bioprocess-inspired fabrication" is proposed to create multilayered organic-inorganic columnar structures. The sequential assembly of halloysite nanotubes (HNTs), polyelectrolytes (PAAs), and calcium phosphates (CaPs) results in organic-inorganic structures. PAA plays a crucial role in controlling the formation of CaP, guiding it into amorphous particles with smaller nanosizes. The introduction of HNT induces the assembly and maturation of CaP-PAA, leading to the formation of a highly crystalline hydroxyapatite. Poly(vinyl alcohol) was then woven into HNT-encapsulated hydroxyapatite nanorods, resulting in composite materials with basic hierarchical structures across multiple scales. The fabricated composite exhibits exceptional hardness (4.27 ± 0.33 GPa) and flexural strength (101.25 ± 1.72 MPa), surpassing those of most previously developed biological hard tissue materials. Additionally, the composite demonstrates effective antibacterial properties and corrosion resistance, attributed to the dense crystalline phase of CaP. This innovative approach showcases the potential of clay minerals, particularly HNT, in the advancement of biomaterial design. The outstanding mechanical and antimicrobial properties of clay-based composites make them a promising candidate for applications in hard tissue repair, offering versatility in biomedicine and engineering.

Microstructure evolution and mechanical properties of friction welded IN713LC and AISI 4140

The microstructure and mechanical behavior of rotary friction-welded IN713LC nickel-base superalloy with AISI 4140 steel have been investigated. The microstructure of IN713LC changed from a columnar dendritic structure to equiaxed grains due to dynamic recrystallization with considerable change in in-grain misorientation, morphology, and volume fraction of gamma prime (γ′) precipitates. The observations indicate a counteracting effect of heat input and degree of deformation which resulted in achieving minimum grain size at an intermediate friction pressure. Phase transformation was observed in the weld interface/thermomechanically affected zone region of AISI 4140 steel. These changes in microstructure contribute to the variation in the microhardness across the weld joint. Furthermore, a maximum weld joint tensile strength of 922 MPa was observed at an intermediate friction pressure of 110 MPa.

Fabrication and characterization of thermal barrier coatings for internal combustion engines via suspension plasma spray with high solid loading

Suspension plasma spraying (SPS) technique producing thermal barrier coatings (TBCs) with high porosity and good thermal shock resistance has great potential to improve the thermal efficiency of internal combustion (IC) engines. However, its wide usage is limited by the immature fabrication technology and low spraying efficiency. Therefore, this study optimized the SPS process with high solid loading and characterized the properties of the coating to obtain TBCs suitable for IC engines. Suspension composition optimization revealed that polyethylenimide (PEI) has the best dispersion effect, and a suspension with high solid loading of 35 wt% was obtained. Furthermore, the effects of the spraying distance, feeding speed and spraying power on the coating microstructure were investigated, and the porosity and thermal shock resistance of the coatings were characterized to determine the optimal spraying process. Thermal shock failure of SPS coatings primarily arises from the propagation of horizontal cracks originating from vertical intercolumn cracks. The SPS coating with a feathery columnar structure has the best thermal shock resistance. By optimizing the spraying process, a coating with porosity up to 24.16 %, bonding strength of 41.69 MPa, and good thermal shock resistance is successfully achieved.

Preparing ribbons with core@shell columnar structures and high magnetization using phase transition decomposition mechanism

A new way to prepare soft magnetic materials with high magnetization was proposed using the phase transition decomposition theory, and the saturated magnetic polarization intensity of the ribbons designed based on the composition of FeCo-type α1 phase reaches 1.88 T after melt-spinning at 40 m/s. The ingots and as-spun ribbons comprise FeCo-type main and AlNi-type minor phases. During melt-spinning, the main phase grows into columnar grains along the thickness direction of the as-spun ribbons. AlNi phase distributes at the grain boundaries of the columnar grains, and its content reduces from 38.8 wt% to 22.0 wt%, thus forming a novel core@shell columnar structure. The micromagnetic simulation results revealed that the soft magnetic properties of as-spun ribbons with AlNi phase at the grain boundaries are superior to that of the nonmagnetic grain boundary phase and grain boundary-free models. The weakly magnetic AlNi phase promotes the coordinated rotation of the magnetic moments of the ferromagnetic FeCo phase within the grains, thus reducing the coercivity of the ribbons; the columnar grain structure improves the remanence of the as-spun ribbons. This FeCo@AlNi core-shell columnar structure provides a new idea for preparing soft magnetic materials with high magnetization.

The performance and stability of NiTi photoactuator utilizing photothermal effect of TiN films with tilted columnar structure

Owing to the shape-memory effect, NiTi shape-memory alloys are widely used in microelectromechanical systems and aerospace as actuators. However, external heating units sometimes limit the application of NiTi actuators. In this study, a new type of wireless actuator that utilizes the photothermal effect of TiN films to drive the shape recovery of NiTi alloys was designed and manufactured. TiN films with columnar structure were deposited via magnetron sputtering at different oblique incident angles of plasma flux. The porosity of the TiN films and tilt angle of the columnar structure increased with the deposition angle. Owing to the formation of the light-trapping structure, the light-absorption ratio and intensity of the photothermal effect improved with the increase in the porosity and tilt angle of the columnar structure in the films. The ratio of shape recovery of the photoactuators also increased with the increase in the tilt angle of the columnar structure and porosity of the TiN film, and the performance stability of the TiN/NiTi photoactuators also improved owing to the tilted structure. The TiN/NiTi photoactuators have the potential to be used in microelectromechanical systems and aerospace applications.

On the Metastable Ferrite Hot Rolling of Low‐Grade Electrical Steels: Its Microstructure, Texture and Low‐Temperature Annealed Structure

The hot‐rolled sheets of low‐grade electrical steels undergo complete austenite‐ferrite phase transformation, resulting in fine equiaxed grains in the sheets. These fine initial grains eventually lead to a strong detrimental {111} texture in the final product after cold‐rolling and annealing process. This work, based on the phase transformation delay of columnar grain structure in cast slabs, proposes a novel approach called metastable ferrite hot rolling, namely, a two‐stage heating at 900 °C and then at 1100 °C shortly and hot rolling, to avoid complete transformation and to retain original {100} oriented regions. In addition, low‐temperature annealing is employed to increase grain sizes of hot‐rolled sheets thereby improving the final texture and magnetic properties after cold‐rolling and annealing. The results indicate that metastable ferritic columnar grains can be maintained during the two‐stage heating process at 1100 °C and primarily undergoes subgrain growth. The transformation from ferrite to austenite at 1100 °C is very slow. During the hot rolling with a high 86% reduction by two passes, the notable grain refinement is mainly caused by dynamic recrystallization rather than dynamic phase transformation as evidenced by the observation from the rolling plane.