The sintering mechanisms and temperature dependence of coalescence of colliding cubic boron nitride (c-BN) nanoparticles are investigated using classical molecular dynamics (MD) simulation. Particle-particle collisions of 2.55-nm octahedral c-BN nanoparticles, consisting solely of the most stable {111} facets, with half of the surface terminations being boron and the other half nitrogen, are analyzed statistically and evaluated to assess the initial temperature range (2500 K – 3100 K) for sintering and its effect on grain growth. At these temperatures, the collision process maximizes contact surface area through interfacial sliding, thereby minimizing free energy and accommodating dangling bonds. Moreover, the exothermic formation of bonds of the coalescing nanoparticles increases the temperature. The alignment of the {111} orientation of the two collided nanoparticles occurs at a temperature slightly above the melting point, and rapid grain growth happens when the temperature is a few hundred degrees higher than that. However, phase separation also takes place at the corners away from the collision plane of the merging nanoparticles. Between 3100 K and 3250 K, crystalline alignment occurs, which aids the sintering process and allows for the formation of a well-structured nanocluster. However, above 3300 K, phase separation dominates and drives the melting of the entire sintered nanocluster.