Green vehicles, particularly Fuel Cell Vehicles (FCVs), offer a promising solution to environmental challenges. One of the major obstacles for FCVs is starting the Polymer Electrolyte Membrane (PEM) fuel cell stacks in subfreezing temperatures, where the water produced by chemical reactions can freeze and hinder the cold-start process. Preheating the inlet air to the stack up to 80 °C is an effective approach to overcome this issue. However, conventional heating systems, such as electric heaters, are unable to heat the air quickly enough. This paper introduces a novel heating method to enhance the cold-start capability of FCVs. The proposed solution involves integrating vortex tubes, which are simple and cost-effective, with the vehicle’s existing compressor. This system not only preheats the inlet air to the stacks but also provides warm air for the passengers simultaneously. By developing a 3D-CFD model of the vortex tube, the results demonstrate that the system can preheat the inlet air to the stacks from −30 °C to 80 °C and the air entering the passenger compartment from −30 °C to nearly 37 °C in just about 5 s. In comparison, conventional heating systems require over 600 s (10 min) to achieve the same temperature rise.