Flux switching motors (FSMs) with conventional stator slots have a relatively low copper slot filling factor. In this article, a new octane modular stator with pentagon-shaped slot electrically excited FSM (EEFSM) that has a comparatively higher copper slot filling factor is analyzed analytically to reduce computational complexity, high computational time, and high drive storage. The analytical results of the proposed EEFSM are validated via the finite element method. Furthermore, the initial design is optimized to improve the electromagnetic performance, and finally the prototype is fabricated and tested experimentally. There is good agreement among the analytical, finite element analysis (FEA), and experimental results with variations of 3%–5%. The average torque of the optimized design has improved by 30%, cogging torque is suppressed by 36%, and torque ripples have reduced by 38%, which have improved the performance of EEFSM in terms of low acoustic noise, low vibration, and longer motor lifetime. The proposed octane modular stator can be easily unfolded for windings maintenance, coils placement, and motor transportation in case of large-size applications.