Radiofrequency (RF) transmitter and receiver coils are employed in in magnetic resonance (MR) applications to, respectively, excite the nuclei in the object to be imaged and to pick up the signals emitted by the nuclei with a high signal-to-noise ratio (SNR). The ability to obtain high-quality images and spectra in MR strongly depends on the RF coil's efficiency. Local coil efficiency can be estimated with magnetic field mapping methods evaluated at a fixed point in space. Different methods have been described in the literature, divided into electromagnetic bench tests and MR techniques. In this paper, we review our experience in designing and testing RF coils for MR in our electromagnetic laboratory with the use of the perturbing sphere method, which permits coil efficiency and magnetic field mapping to be estimated with great accuracy and in a short space of time, which is useful for periodic coil quality control checks. The method's accuracy has been verified with simulations and workbench tests performed on RF coils with different surfaces and of different volumes. Furthermore, all the precautions taken to improve the measurement sensitivity are also included in this review, in addition to the various applications of the method that have been described over the last twenty years of research in our electromagnetic laboratory.