In this study, Leibniz algebras and the derivations and properties of Leibniz algebras were given, respectively. The stable automorphism group of explicit splitting extension was calculated via the stable automorphism group of Abelian extension of finite group splitting. Based on the stable automorphism group of the splitting extension studied, the non-Abelian extension and the second order non-Abelian co-homology group of Leibniz algebra were investigated in detail according to the stable automorphism group of the splitting extension.