ABSTRACT The relatively poor oxygen barrier property limits broad application of polypropylene (PP) as packaging materials, pipes, etc. while incorporation of nanoparticles, EVOH etc. faces problems of poor compatibility and dispersion, and high price. In this work, in light of polyvinyl alcohol (PVA) with polyhydroxy structure and excellent barrier properties, PP was blended with PVA through reactive compatibilization by using polypropylene grafted maleic anhydride (PgM) as compatibilizer. A strong intermolecular interaction and entanglement between the two phases formed, leading to an increase of interfacial transition area, and the phase size decreased, changing from “sea-island” to “co-continuous” structure, while a relatively high PVA polymerization degree would lead to a decrease of intermolecular entanglement. In addition, the hydrogen bonding in the system was enhanced, although the crystallinity of the two phases decreased by blending. As a result, the oxygen transmission coefficient of the PP/PVA/PgM blends reached as low as 6.48 × 10−14 cm3·cm/(cm2·s·Pa), which was 48.1% lower than that of PP, while the impact toughness was improved by 56.5%. This work provides a feasible and economic method for enhancing the oxygen barrier ability of PP.
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