The article discusses the effect of Plasma Electrolytic Oxidation (PEO) on the tribological properties of oxidelayers produced on the AZ31B magnesium alloy. The layers were formed using PEO (AC+DC) in an alkalineelectrolyte with a current density of 10 A/dm. The oxidation parameters (process time, cathodic voltage) wereselected based on a research plan. The tribological properties of the samples were tested on a T-17 tester in apin-on-plate test under technically dry friction conditions, using a pin made of PEEK-HPV polymer. The testsallowed the determination of the coefficient of friction, linear wear, and changes in the mass of the sampleand pin. Profilometric measurements were also made before and after the friction process. An increase in theoxidation time and cathodic voltage led to an increase in the thickness and roughness of the oxide layer. Thesample oxidized under the highest parameters exhibited the greatest thickness, as well as the highest amplitudeand Abbott–Firestone bearing ratio parameters. It was found that with increasing process time and cathodicvoltage, the coefficient of friction (μ) and polymer pin wear increased. Sample C, which had the highestprocessing parameters, showed the best tribological properties, with a coefficient of friction of 0.253 and a linearwear of 0.057 mm. Due to friction, a significant amount of opaque tribofilm was deposited on sample C, resultingin the highest mass wear of the pin (5.33 mg) and an increase in the mass of the sample by 0.74 mg.
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