In this experimental investigation, wall surface temperatures have been measured during mixing of three water streams in the annular gap between two coaxial stainless-steel tubes. The inner tube, with an outer diameter of 35mm and a thickness of 5mm, holds six K-type, ungrounded thermocouples with a diameter of 0.5mm, which measured surface temperatures with a sampling rate of either 100Hz or 1000Hz. The tube was rotated from 0 to 360° and moved in a range of 387mm in the axial direction to allow measurements of surface temperatures in the whole mixing region. The outer tube has an inner diameter of 80mm and a thickness of 10mm to withstand a water pressure of 9MPa. A water stream at a temperature of either 333K or 423K and a Reynolds number between 1657 and 8410 rose vertically in the annular gap and mixed with two water streams at a temperature of 549K and a Reynolds number between 3.56×105 and 7.11×105. These two water streams entered the annulus radially on the same axial level, 180° apart. Water pressure was kept at 7.2MPa. Temperature recordings were performed at five axial and eight azimuthal locations, for each set of boundary conditions. Each recording lasted 120s to provide reliable data on the variance, intermittency and frequency of the surface temperature time series at hand. Thorough calculations indicate that the uncertainty in the measured temperature is of 1.58K. The mixing region extends up to 0.2m downward of the hot inlets. In most cases, measurements indicate non-uniform mixing in the azimuthal direction, because of asymmetries in either geometry or mass flow rates at the hot inlets. Due to the measurement accuracy and a relatively simple geometry, an experimental database has been obtained for validation of computational methods to predict thermal mixing and fatigue. Furthermore, these data can provide new insight into turbulent mixing at BWR operating conditions and, more generally, into mixing coupled to the dynamics, also termed level-2 mixing.