Two end members of passive margin types are present on the Namibia margin: volcanic and non-volcanic. The central and southern parts of the Namibia margin feature characteristic volcanic margin elements such as thickened initial oceanic crust, seaward dipping reflectors, and high-velocity/density lower crust that extends beneath the rift zone that was formed during initial seafloor spreading in Early Cretaceous. The margin north of the Walvis FZ is non-volcanic in character and probably formed as a result of a ridge jump that occurred after cessation of the initial magmatic activity. The Walvis Ridge forms the boundary between the two margin types and resulted from the persistent magmatism associated with the Tristan plume. MCS data in conjunction with gravity modeling reveal a Paleozoic rift zone beneath the Namibia margin south of the Walvis FZ. The Paleozoic rift zone partly overlaps the Jurassic/Early Cretaceous rift zone which produced the breakup between Africa and South America. We calculate an average stretching value of β=1.4 for the Paleozoic rift, based on subsidence modeling. The rift is partly bounded by low-angle faults, related to the orogenic collapse of the Pan-African fold belt, which provided a major Paleozoic sediment source. The offshore continuity of onshore ophiolitic complexes is suggested by the coast parallel high-amplitude magnetic anomaly ’G‘, and low-angle detachment faults along the southern part of the margin. The average stretching value for the Jurassic/Early Cretaceous rift is β=1.7, which implies a syn-rift displacement on this margin of ∼70 km. The minimum igneous volume of the South Atlantic LIP was found to be in excess of 3.62×106 km3.