An algorithm for the simulation of three-dimensi onal hypersonic flows in chemical nonequilibrium is presented. The basic flow solver is based on a quasiconservative formulation of the Euler or Navier-Stokes equations. The Jacobi matrices are split according to the sign of their eigenvalues. The derivatives of the conservative variables are split accordingly. A third-order upwind space discretization is used in conjunction with an optimized three-stage Runge-Kutta explicit time stepping scheme. The chemistry source terms are treated point-implicitly. For inviscid flow, the code is applied to the complete HERMES 1.0 configuration. The influence of mesh resolution is studied by comparing a fine grid with a coarse grid solution. The coarse grid solution is usually sufficient to describe global flow phenomena. The analysis of local flow details requires refined meshes. For viscous flow, the flow about generic configurations (double-ellipse, hemisphere-cylinder-flare, hyperbola-flare) is investigated by performing grid sensitivity studies as well as by comparing different transport models. UE to the initiation of the HERMES program, large research efforts have been directed to the development of space vehicles in Europe. The re-entry trajectories for space vehicles include large regions where the airflow is in chemical and thermal nonequilibrium. Nonequilibrium effects are important when the time scale for chemical reactions or energy exchange tchcm is comparable to a characteristic time scale for global flow changes fnow. If r chem « f flow, the process is in equilibrium, and if fchem » £now, the process is frozen. Since the density of air is low and the vehicle velocity on the reentry trajectory is high in the upper atmosphere, nonequilibrium effects have to be considered for altitudes larger than about 50 km. It is important to take nonequilibrium influences into account in order to be able to correctly simulate the aerodynamic behavior (pitching moment, c.p.), as well as heat-loads on the surface of the space vehicle (recombination, wall catalycity, radiation) at high altitudes. Although thermal nonequilibrium may be important near the vehicle nose and may influence the subsequent flowfield by convection, it is neglected here. Especially for the heat loads, a viscous flow simulation is necessary because the flow in the immediate vicinity of the vehicle surface is viscosity dominated. The numerical simulation of nonequilibriu m real gas flows requires very specialized and detailed physical models and numerical methods. Due to the complicated numerical formulation, code implementation, and due to the excessive computational requirements for numerical calculations, only recently nonequilibrium reacting flow computations have been undertaken. Numerical methods implemented so far use a full-conservative flux-splitting approach for the convective fluxes (either flux-vector or flux-differen ce).1-6 The intention of the work described in this article was to develop a solution method and computer code for the numerical simulation of nonequilibrium real gas flows about the complete HERMES configuration based on earlier developments for perfect gas flows7-8 and equilibrium real gas flows.9-10 In contrast to other solution methods, we employ the quasiconservative formulation with matrix splitting originally developed by Weiland7 and the shockfitting technique implemented by Pfitzner, 11 which is a postcorrection technique based on the ideas of Pandolfi. 12 The quasiconservative matrix splitting technique allows an accurate flow description in both inviscid and viscosity dominated regions. Using the shock-fitting technique, the location of the bow shock is given precisely. This is especially important for local bow shock—structure interactions (e.g., bow shock— winglet interaction). Additionally, the shock-fitting procedure enhances the efficiency of the method by limiting the computational domain automatically to the region where flow changes occur. In the near future, the solution method will be extended to include thermal nonequilibrium as well as advanced wall catalycity models and models for the transport terms. This work will be performed in the frame of the HERMES technology program in cooperation with international partners. In Sec. II we describe the physical model for viscous flows in chemical nonequilibrium (equation of state, chemistry terms, transport terms). In Sec. Ill we present the solution method (mixed quasi-/full-conservative formulation, matrix splitting, and discretization). Results are shown in Sec. IV for inviscid flows about the complete HERMES configuration and for viscous flows over generic configurations. A general conclusion is given in Sec. V.
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