Coarse-grained Quartz Research Articles

The complexity of luminescence dating of tidal sand body revealed by the discrepancy of paired quartz OSL ages

Optically stimulated luminescence (OSL) dating is becoming a useful technique to yield absolute age of organic-poor sandy deposits. The buried tidal sand body (BTSB) in the coastal zone of northern Jiangsu Province, China, has been suggested to have the same origin as the offshore radial sand ridge in the Yellow Sea. However, chronological constrain of the BSTB is still quite limited. In this study, OSL measurements were conducted using silt-sized multi-grain and coarse-grained single-grain quartz to constrain the depositional history of a 25.6 m core from the BTSB. A low luminescence sensitivity of quartz was observed, and only ∼1.04% of the grains passed the standard rejection criterion for single-grain measurement. Analysis of paired OSL ages from two grain-size fractions using different protocols showed that silt-sized quartz ages were underestimated of 0.14–1.35 ka in comparison to coarse-grained quartz in the depth interval of 5.8–22.4 m. We interpret such an age discrepancy as the effects of lateral infiltration of fine-grained sediment into the sand body due to dynamic feature of channel-ridge system on the shelf. As far as we know, it is the first time that such infiltration is demonstrated through OSL dating. Our OSL data indicated that there is a significant hiatus between the Late Pleistocene stiff clay layer (50–18 ka) and the Holocene sequence. Holocene deposits only occurred in the last 2 ka, with rapid accumulation of ∼17 m-thick sediments at ∼2–1 ka, a slower accumulation between ∼1 and 0.1 ka and rapid land emergence through an accretion of ∼4 m-thick sediment over the past ∼0.1 ka. This study highlights the complexity of OSL dating in highly dynamic sedimentary environments. Therefore, examining different grain size fractions and comparing different measurement protocols are highly deserved in carrying out OSL dating in such environments. • We compared multi-grain silt-sized quartz and single-grain coarse-grained quartz ages for a tidal sand body. • Silt-sized quartz underestimated ages due to ‘younger’ sediment infiltration into tidal sand body. • The buried tidal sand body in the northern Jiangsu Province of China was formed in the last 2 ka.

Radiocarbon and luminescence dating of the Wulanmulun site in Ordos, and its implication for the chronology of Paleolithic sites in China

After the Salawusu and Shuidonggou sites, the Wulanmulun site found in 2011 is another important Paleolithic site in Ordos, China, due to its numerous stone artifacts and animal fossils. Here, we carry out a combined luminescence and radiocarbon dating of the site. The luminescence dating was done on coarse-grained quartz from 24 sediment samples using a single-aliquot regenerative-dose (SAR) protocol. The radiocarbon dating was performed on ten charcoal samples and one bone sample using acid-base-acid (ABA) and acid–base-wet oxidation-stepped combustion (ABOx-SC) pretreatments. The results showed that: (i) although some samples show relative large (>20%) overdispersion in De distribution (small aliquots), the quartz grains are considered to be sufficiently bleached before burial; (ii) the quartz OSL ages of ∼4–65 ka obtained for the samples are generally stratigraphically consistent and reliable; (iii) the radiocarbon ages obtained using the ABA pretreatment procedure are much younger than the corresponding OSL ages, and the radiocarbon ages obtained using the ABOx-SC method are beyond or close to the laboratory background. The radiocarbon ages obtained using the ABA treatment were considered to be underestimated. This implication is that caution must be taken for dating Chinese Paleolithic (>25 ka) using the ABA pretreatment procedure on carbon samples. Finally, the cultural layers from the Wulanmulun site are deduced to be between 50 and 65 ka. • Wulanmulun is a newly excavated Paleolithic site in Ordos in north China. • A total of 24 sediment samples were luminescence dated using the SAR protocol on quartz grains. • Ten charcoal and bone samples were radiocarbon dated using different pretreatment procedures. • The radiocarbon ages are underestimated when using the acid-base-acid pretreatment. • The cultural layers of the site are dated to 65–50 ka.

MET-post-IR IRSL luminescence dating of cobbles buried in fluvial terraces in the Northern Chinese Tian Shan

Cobbles can be used as an alternative to the conventionally employed sand-sized mineral luminescence dating. In piedmont environments, cobbles are much more abundant than sand-sized material. The IRSL 50 signal has been widely used in previous studies due to its greater sensitivity to exposure events. However, it is well known that the low temperature IRSL signal is more prone to fade than elevated temperature post-IR IRSL signal. In this study, to test the reliability and applicability of cobble sub-surface elevated temperature IRSL luminescence dating, six light-color granite cobbles and two sand-sized samples from silty sand lens were collected from a high terrace of Manas River on the northern piedmont of Chinese Tian Shan. A modified multi-elevated-temperature post-infrared infrared stimulated luminescence (MET-post-IR IRSL) protocol was applied. The age-temperature (A-T) plateau of MET-post-IR IRSL measurement was combined with the conventional age-depth (A-D) plateau in luminescence-depth profile to evaluate the resetting and fading of MET-post-IR IRSL signals. Uncertainties of grain-sizes of K-feldspar within solidified slices were also explored by μ-XRF mapping of potassium content. The A-T plateau was identified between MET-post-IR IRSL 170 and MET-post-IR IRSL 225 signals of one cobble, which suggested completeness of bleaching before burial and negligible anomalous fading during burial. This cobble yielded MET-post-IR IRSL 225 ages of 15.8 ± 2.6 ka and 19.0 ± 3.2 ka for top and bottom side, respectively. These MET-post-IR IRSL 225 ages were consistent with independent coarse-grained quartz MAM OSL ages (15.7 ± 3.6 ka and 14.8 ± 2.6 ka) of two sand-sized samples. The MET-post-IR IRSL 225 age of 16.0 ± 1.2 ka for the bottom side of another cobble was also consistent with the independent age, even without the A-T plateau. It was inferred to be caused by anomalous fading of MET-post-IR IRSL signals other than that stimulated at 225 °C by refering to the A-D plateau observed. Our results show that MET-post-IR IRSL measurement can be employed to determine the burial ages of cobbles. The A-T plateau, complemented with the A-D plateau, could be used to assess the reliability of burial ages of cobble luminescence dating from the view of bleaching and fading. • MET-post-IR IRSL measurement has advantages in judgement of fading and bleaching of rock slices. • Constraining the terrace ages using fluvial cobbles has great potential and prospects. • Evaluating the uncertainty of internal dose related to grain sizes variation of K-feldspar.

OSL Dating of Paleo-Shorelines at Dagze Co, Central Tibetan Plateau

Well-preserved paleo-shoreline systems suggest lake shrinkage occurred in a vast region of the Tibetan Plateau, indicating dramatic paleo-environmental changes that linked closely to variations in Asian monsoon precipitation, glacial meltwater, and evaporation. The elevation and chronology of these shoreline features can be used to reconstruct lake level fluctuation history and regional paleo-climate. Here, we report optically stimulated luminescence (OSL) dating of 14 sediment samples from three of seven paleo-shorelines at south of Dagze Co, central Tibetan Plateau, using coarse-grained quartz and K-feldspar. Two fine grain silt samples were also measured. The results suggest the following: 1) The highest paleo-shoreline for Dagze Co has an elevation around 4,525 m (+55 m above modern lake). Its age is estimated to be 9.1 ± 0.5 to 9.6 ± 0.6 ka, suggesting a relative humid condition in the early Holocene. 2) After that, the lake level dropped ∼20 m and remained relatively stable (+35 m) from ∼8 to 5 ka, implying a dry condition with reduced runoff. Lake level further declined for ∼40 m since about 5 ka. 3) The general trend of shrinkage for Dagze Co broadly matches studies from adjacent lakes, suggesting a common pattern of lake’s evolution on the south/central plateau in the late Quaternary. The long-term decreasing trend of Asian monsoon precipitation should be the main reason.

Research on Metallogenic System and Deposit Genesis: With Zhacun Goldmine in Weishan County of Yunnan as an Example

This paper mainly takes Zhacun goldmine as the research object and carries out research on the metallogenic system and genesis of the deposit in the area. The research methods are as follows: according to the geological characteristics of the metallogenic mining area in the Zhacun goldmine, combined with the comparative analysis of the metallogenic age, alteration characteristics and lithology between the Zhacun goldmine and the Lianhuashan alkali rich rock mass, and the analysis of the isotopic data in the Zhacun goldmine, this paper demonstrates that the magmatic activity of the Lianhuashan quartz monzonite porphyry plays an important role in the mineralization of this area, which is both an important ore source and fluid source. It is also the main heat source driving the circulation of ore-forming fluid. On this basis, through the analysis of the metallogenic elements in the area, the metallogenic system model of Zhacun goldmine is constructed. It is considered that under the action of long-term horizontal compressive stress, the atmospheric precipitation infiltrated into the formation continued to penetrate along the fractures and fissures to deep crust and finally mixed with the magmatic water sealed in the thick formation. During this period, a series of shallow and ultrashallow porphyry mass intruded, providing heat source and part of the ore-forming materials and resulting in incomplete homogenization under high temperature and high pressure, which formed highly mineralized mixed water. Under the combined action of long-term compressive stress and various deep thermal dynamics, these mineral fluids migrated along the buried deep faults near the core of the duplex anticline to the upper part of the crust. When the metal elements in these ore fluids migrated over long distances to the nappe fault zone of the gold-bearing fracture zone, the gold began to precipitate, and the native gold and the coarse-grained pyrite and quartz formed at the same time or earlier started to fill the fracture zone along the fissures and accumulate into minerals. Then, through the analysis of metallogenic conditions, gold mineralization process, and genetic mechanism of the deposit, it is proposed that the genetic type of the ore deposit in this area is magmatic mesothermal-epithermal gold deposit. The establishment of metallogenic system model in Zhacun goldmine will provide theoretical and practical guidance for deep and peripheral prospecting prediction in the area, carry out targeted and reasonable prediction, and improve prospecting effectiveness.

Lake level changes of Nam Co since 25 ka as revealed by OSL dating of paleo-shorelines

Many lakes in the Tibetan Plateau (TP) experienced dramatic lake level changes in the late Quaternary, as suggested by well-preserved paleo-shorelines up to ∼200 m above present lake levels. These relic shorelines provide direct geomorphic record to reconstruct past lake level fluctuation history and water volume changes, linked closely to variations in paleo-climatic controls including Asian monsoon, westerlies and glacial meltwater. In this study, 27 near-shore sediment samples from three of eight paleo-shorelines at north of Nam Co were dated by Optically Stimulated Luminescence (OSL) technique, using coarse grains of quartz and potassium feldspar. Our results indicate that: 1) S1 is the highest/most developed shoreline (+26 m). Sediment from upper part of S1 has a consistent age of ∼25 ka (nine samples from 3 gullies), suggesting a high lake level of Nam Co occurred around 25 ka. An overflow point west of Nam Co has a close elevation to that of S1 and thus limits the presence of higher lake levels; 2) sediment profile from the slightly lower S2 (+22 m) contains two parts, silty sand (6.9–8.9 ka) at the bottom and shoreline deposits atop (∼2.3 ka), suggesting Nam Co maintained a relative high lake level in the early Holocene and such lake level occurred again at about 3.0–2.0 ka; 3) In contrast to the swift variations of monsoon precipitation and glacial meltwater in the late Quaternary, water level of Nam Co remained relatively stable during the period from ∼25 ka to about early Holocene (from +26 m to +22 m), implying a continuous outflowing stage and lake infill constantly exceeds evaporation; 4) S5 (+11 m) has an age of 0.7–1.4 ka. Nam Co showed a much accelerated pace of shrinkage since about 2.0 ka in the late Holocene in roughly two steps: it dropped from +22 m to +11 m from ∼2.0 ka to 1.4 ka, and subsequently dropped another 11 m after 0.7 ka.

Dating Sediments by EPR Using Al-h Centre: A Comparison between the Properties of Fine (4−11 µm) and Coarse (>63 µm) Quartz Grains

The possibility of EPR dating for sediments using Al-h signals of fine (4–11 μm) grains of quartz has not been previously discussed. Here, the Al-h and peroxy EPR spectra of fine (4–11 μm) and coarse (63–90, 125–180 μm) sedimentary quartz from thoroughly investigated loess sites in Eastern Europe were examined. By comparing experimental spectra with a simulated signal, we evaluated the overestimation observed when using the standard approach established by Toyoda and Falguères to measure Al-h intensity for different doses of radiation, up to 40,000 Gy. This overestimation, caused by the presence of peroxy signals, was much more pronounced for fine grains. Fine grains exhibited some additional dose-dependent signals, which, for some samples, caused a complete distortion of the Al-h spectra at high doses, making it impossible to measure the standard amplitude. We propose a new approach to measuring Al-h signal intensity, focusing on the peak-to-baseline amplitude of the part of the signal at g ≈ 2.0603, which is not affected by the peroxy signals and therefore has the potential of providing more accurate results. The shapes of dose response curves constructed for coarse and fine grains using the new approach show considerable similarity, suggesting that Al-h centre formation in fine and coarse grains upon artificial radiation at room temperature follows the same pattern.

Evolved components in the eucrite parent body: Records in the layered eucrite Northwest Africa 8021

AbstractIn this study, we report the petrography and mineralogy of a brecciated eucrite Northwest Africa (NWA) 8021, which shows a locally layered texture with one layer containing graphic clasts and Si,Ti‐rich regions. The graphic clasts contain rod‐like grains of silica phases, augite, K‐feldspar, and Ca‐phosphate minerals included in anorthite. Some of the clasts contain relatively coarse grains of quartz, K‐feldspar, and augite, which are chemically different from the rod‐like phases, indicating different origins. All of the augite grains in the graphic clasts have rare earth element (REE) concentrations higher than those in typical eucrites. The bulk Na2O+K2O contents of the graphic clasts are higher than typical eucrites. All of these chemical features indicate that the graphic clasts were probably derived from an evolved parent rock. Low‐degree partial melting of the eucritic crust (<10%) is required to generate a melt equilibrated with the REE‐rich rod‐like pyroxene from the graphic clasts. The Si,Ti‐rich regions contain high abundances of silica phases (~52 vol%) and ilmenite (~9 vol%), probably derived from an evolved Si,Ti‐rich rock (dacite). The evolved components observed in NWA 8021 are different from other evolved components observed in howardites and indicate more diverse evolution in the eucrite parent body than previously thought.

Dating sediments by EPR using Al-h centre: a comparison be-tween the properties of fine (4-11 μm) and coarse (> 63 μm) quartz grains

Dating sediments by EPR using Al-h centre: a comparison be-tween the properties of fine (4-11 μm) and coarse (> 63 μm) quartz grains

Quartz age extension applied to SE Asian cover sands

A significant feature of the surface sediments of southeast Asia is a regionally extensive layer of distinctive red, quartz-rich, cover sand observed throughout Vietnam, Cambodia, Laos and Thailand, and further afield. In many locations, these cover sands immediately overlay a laterite layer containing tektites, known as the Muong Nong type, associated with a large meteorite impact between 750 and 800ka in Indochina. Sections of these cover sands at sites in Thailand, Laos and Vietnam have been investigated using field and laboratory profiling, and quartz SAR procedures. In some locations the sections consist of a layer of low-sensitivity quartz with saturated signals overlain by a visibly indistinguishable layer of high-sensitivity quartz with ages less than c. 35ka. Further work has been undertaken to attempt to extend quartz luminescence dating for the older materials, including samples associated with the tektites, using thermally stimulated or transferred luminescence to access traps that are expected to saturate at higher doses. Luminescence was recorded during sample heating and hold, giving thermoluminescence (TL-ramp) and isothermal decay (ID) data, in addition to optically stimulated luminescence after the transfer (Thermally Transferred Optically Stimulated Luminescence, TT-OSL) measurements. These measurements have produced equivalent dose values of up to 250Gy, and ages of 70–125ka, for these older materials, which is significantly younger than would be expected from the association with the tektites. Investigation of the traps associated with these signals has produced properties consistent with prior investigations, suggesting that these are not sufficiently stable at environmental temperatures above 25 °C to permit age extension using these methods. • TT-OSL applied to coarse quartz grains from SE Asia. • Ages obtained significantly less than assumed age of associated tektites. • Thermal stability of TT-OSL traps assessed. • Thermal stability limits age range to less than 800ka at temperatures above 25 °C.

Chronostratigraphic and geomorphologic challenges of last glacial loess in Poland in the light of new luminescence ages

Abstract. The aim of this study is to check the validity of luminescence ages obtained from last glacial–interglacial Polish loess palaeosol sequences (LPSs) by several established current protocols, with respect to sound geomorphological and chronostratigraphic interpretations. We report 38 new optically stimulated luminescence (OSL) ages from fine-grained (4–11 µm) quartz separates extracted from four loess palaeosol sequences in Poland, measured in the Bayreuth Luminescence Laboratory, Germany. The investigated sections are situated in Lower Silesia in the southwest (Zaprężyn, Trzebnica Hills, and Biały Kościół, Strzelin Hills), the Sandomierz Upland (Złota) in central Poland, and the Volhynian Upland (Tyszowce) in the east, allowing for regional comparison. From one Silesian section (Biały Kościół) 12 new post-infrared infrared stimulated luminescence (pIRIR) ages are presented in addition to the quartz ages of identical sample material. The obtained ages are compared to already published independently elaborated middle-grain (45–63 µm) and coarse-grain (90–125 µm) quartz ages and pIRIR ages from fine grains produced in the Gliwice Luminescence Laboratory (Poland). This comparison shows that in many cases the middle- and coarse-grain quartz ages underestimate the fine-grain quartz ages, but a general rule has not been able to be established so far, likely due to different geological origin of the quartz grains. Even fine-grain quartz ages ≥∼ 50 ka may be underestimated with respect to lithostratigraphic expectations. For pIRIR ages, however, no evidence for age underestimates has been found in the studied sections, but they are more easily prone to age overestimates due to unknown residual doses at deposition in a periglacial environment. Basic agreement between the luminescence-based chronologies elaborated in the two involved laboratories can be stated for the first time in contrast to other previous studies. The observed age differences are, however, critical for the accurate time bracketing of geomorphologic and pedostratigraphic features such as ice wedging, thermokarst erosion events, and interstadial soil formations and for their attribution to marine isotope stages. Alternative interpretations are discussed including possible periglacial mirroring of pre-LGM ice advances (Ristinge and Klintholm advances) in the southwestern Baltic Sea area. The uncertainty in luminescence ages from pre-Holocene loess due to fossil ice during permafrost conditions is the major systematic error source which will be addressed but at present is far from an unambiguous solution. The present study focuses on a complex of interstadial soils now labelled L1SS1 and on harsh periglacial climate afterwards and before, yielding some unexpected results for the timing of ice wedging and thermokarst processes. In order not to leave the users alone with the decision about the most credible dating, the suggested way forwards is to simultaneously apply various luminescence dating protocols including different quartz grain sizes and pIRIR from fine polymineral grains, as an honest approach to reliable time bracketing of geomorphological processes and stratigraphic events under debate. A refinement of this approach remains challenging as far as the sole reliable dating protocol is not ensured.

Lithology Classification and Porosity Estimation of Tight Gas Reservoirs With Well Logs Based on an Equivalent Multi-Component Model

Tight gas makes up a significant portion of the natural gas resources. There are tight gas reservoirs with great reserve and economic potential in the west Sichuan Basin, China. Due to the complex mineral component and heterogeneity of the thick tight sand formations, the reservoir parameters are challenging to evaluate from well logs using conventional methods, even the fundamental porosity. The mineral components must be considered. In this study, based on the analysis of different logging responses of varying lithologies, we introduced the complex reservoir analysis (CRA) method. CRA is always used in the carbonate reservoirs to calculate the different rock component volume fractions and can be used to classify the lithology and calculate the porosity simultaneously. By analyzing the component, a new equivalent component method (CRAE) is proposed based on the CRA method in this paper. In this method, the AC-CNL equation-calculated porosity is calibrated according to the core porosity data to set the rock components’ physical parameters. After calibration, the rock component fractions and porosity can be calculated accurately. Also, according to the relationship between the grain size and natural gamma-ray, a granularity median model was established. Six lithology types, including coarse-grained quartz sandstone and coarse-grained lithic sandstone, are distinguished, and the porosity is estimated in the study area. The identification results are compared with the mud logging data and other methods. It shows that this method is very well adequate in the tight sandstone gas reservoirs in the study area.

Investigating the applicability of a standardised growth curve approach on Middle Pleistocene sediments from northern Switzerland

The introduction of the Single Aliquot Regenerative Dose (SAR) protocol established luminescence dating as an indispensable tool in Quaternary research. A major impediment of this technique is the time required for measurements, since the protocol is repeated for various aliquots of each sample to establish a sound statistical basis. To reduce the demand on machine time, Standardised Growth Curve (SGC) approaches have been developed and successfully applied for samples from some regions. However, differences in luminescence properties require careful testing of this techniques when applied to samples with other geological background. In this study, the application of the SGC approach of Li et al. (2016) is successfully verified for multi-grain aliquots of coarse-grained quartz and feldspar samples from three sites in northern Switzerland. In-depth quality control measures ensure the reproducibility of equivalent dose (D e ) values obtained by the common SAR protocol and sample-specific SGCs. For both minerals little sensitivity was found to the re-normalisation dose and the sample-specific SGCs performed well. In contrast to other studies, no different types of dose response curve shape were observed for quartz. A minimum number of full SAR measurements of eight and six aliquots per sample has been found appropriate for quartz and feldspar, respectively. For the fading corrected feldspar signals, site-specific SGC worked well and D e values of up to 800 Gy were consistently replicated. In summary, sample-specific SGCs for samples from northern Switzerland perform well and their application reduces measurement times by up to 70%. The construction of a regional SGC may well be beneficial, however, caution regarding the choice of given doses and curve fitting is recommended and a thorough verification of SGC results is needed before the technique is widely applied. • Application of the standardised growth curve approach (SGC). • Sample- and site-specific SGCs successful for feldspar and quartz. • Application of a regional SGC for fading corrected feldspar signals with caution.

Standardized Dose–Response Curve (sDRC) Construction for OSL Dating of Quartz from Bohai Coast, NE China

The optically stimulated luminescence (OSL) dating method promises to provide reliable ages for various Quaternary archives. Coastal sedimentation in the Bohai Sea (northeastern China) since the Middle Pleistocene has been influenced by paleoenvironmental and sea-level change, of which dating has been restricted using the OSL dating approach in multiple investigations. In this study, to establish a robust OSL chronological framework of the Bohai coastal sediments more effectively, the regional standardized dose–response curve (sDRC) was constructed for quartz OSL dating in the Bohai Coast (NE China) using two existing approaches. The sDRC-determined equivalent doses are broadly in agreement with those using the individual DRC for each sample. Data used for DRC construction of the fine-grained (FG) quartz samples are less scattered than those of the coarse-grained (CG) quartz samples, probably due to the signal-averaging effect for the FG samples, while the OSL signal of the CG quartz samples might document provenance information that yield relatively scattered distribution. The two approaches used in this study yield identical sDRCs, indicating that both the methods are applicable for sDRC construction in the Bohai Sea.

Increasing sulfur and chlorine contents in ore-forming magmas: The key to Pulang porphyry Cu-Au formation, SW China

The giant Pulang porphyry Cu-Au district (446.8 million tonnes at 0.52% Cu and 0.18 g/t Au) is located in the southern Yidun terrane of the Sanjiang (Three-river) region, southwest China. It has six phases of porphyry intrusions: premineralized fine-grained quartz diorite (FQD) and coarse-grained quartz diorite porphyry (CQD), the main synmineralized quartz monzonite porphyry (QMP), and late synmineralized granodiorite porphyry (GP), diorite porphyry (DP), and aplite. New zircon U-Pb ages for the premineralized FQD and late synmineralized GP, DP, and aplite are 226.3 ± 2.6 Ma (MSWD = 1.9), 216.4 ± 1.0 Ma (MSWD = 2.0), 216.0 ± 1.1 Ma (MSWD = 1.7), and 216.0 ± 1.5 Ma (MSWD = 1.7), respectively. All Pulang porphyry rocks have high whole-rock Sr/Y ratios (37.8–184) with minor or no negative Eu anomalies (0.73–1.04), and are characterized by high large-ion-lithophile-element (LILE: Th, U, Ba, Rb) abundances and low high-field-strength-element (HFSE: Nb, Ta, Ti, Zr, Hf).Zircons from premineralized FQD and synmineralized GP, DP, and aplite rocks have consistently high EuN/EuN* ratios (mostly > 0.4). The magmatic oxygen fugacity calculated from zircon compositions, show that the FQD (ΔFMQ = 1.59 ± 0.43), GP (ΔFMQ = 1.52 ± 0.18), DP (ΔFMQ = 1.52 ± 0.30), and aplite (ΔFMQ = 1.75 ± 0.60) were all derived from moderately oxidized magmas. Magmatic water contents estimated from amphibole compositions and the extensive presence of amphibole phenocrysts suggest that H2O contents are >4 wt%. Together with the published results for premineralized CQD and main synmineralized QMP, it is concluded the causative magmas for the six porphyry phases at Pulang were all relatively oxidized and hydrous.The difference between premineralized FQD and CQD and synmineralized QMP, GP, and DP are reflected in magmatic chlorine and sulfur contents. To minimize the effect of hydrothermal alteration, the apatite microphenocrysts enclosed by least altered phenocrysts were selected for analyses. The Cl contents of magmatic apatite microphenocrysts from the synmineralized QMP (avg = 0.340 ± 0.192, n = 26), GP (avg = 0.317 ± 0.151, n = 21), and DP (avg = 0.179 ± 0.112, n = 18) are significantly higher than those from the premineralized FQD (avg = 0.046 ± 0.032, n = 9) and CQD (avg = 0.043 ± 0.034, n = 13). Similarly, the SO3 contents of igneous apatite microphenocrysts from the synmineralized QMP (avg = 0.259 ± 0.156, n = 25), GP (avg = 0.203 ± 0.163, n = 20), and DP (avg = 0.306 ± 0.173, n = 18) are higher than those from the premineralized FQD (avg = 0.181 ± 0.136, n = 10) and CQD (avg = 0.085 ± 0.068, n = 6). The S-Cl contents of synmineralized melts estimated from apatite S-Cl compositions are higher than those of premineralized magmas, suggesting that the elevated magmatic S-Cl contents in the synmineralized porphyries might have been important for Cu-Au mineralization. This was likely due to S-Cl rich mafic magma recharge, supported by the presence of abundant mafic magmatic enclaves in the synmineralized QMP.

Melt volatile budgets and magma evolution revealed by diverse apatite halogen and trace elements compositions: A case study at Pulang porphyry Cu-Au deposit, China

Apatites those shielded as inclusions in igneous minerals are avoided of diffusion effects associated with evolving melts and can record the original volatile and trace element evolutions of the magma. Volatile and trace element compositions of apatites enclosed in high-Al, medium-Al, low-Al amphibole, magmatic biotite, plagioclase, and groundmass from ores, quartz monzonite porphyry (QMP) and its mafic microgranular enclaves (MMEs), and pre-ore coarse-grained quartz diorite porphyry (CQD) were present to evaluate the magmatic processes in the formation of Pulang porphyry Cu-Au deposit. All apatite inclusions are magmatic fluorapatites and occur as early-crystallization phases (940–980 °C), followed by the crystallization sequence of high-Al amphibole, medium-Al amphibole, magmatic biotite, plagioclase, low-Al amphibole (altered medium-Al amphibole) with fluctuating ƒO2 conditions. Compared to the low SO3 (<0.27 wt%) concentrations of other apatites inclusions in fertile QMP, the biotite-hosted apatites retain an abnormal SO3 (0.15–1.01 wt%) and Cl (0.08–0.71 wt%) enrichment. Estimates of sulfur and chlorine concentrations using partitioning models for apatite in QMP return similar features, where the biotite-hosted apatites yield highly variable melt S (315–2025 ppm) and Cl (0.1–1.2 wt%) contents. The presence of biotite-hosted S-Cl enriched apatites with overgrowth texture, together with the resorbed medium-Al amphiboles in QMP, both suggest that they have crystallized from an extra sulfur supplement process caused by the injection of a series of S-Cl enriched magma, and even subsequent remelting of the preexisting dioritic batholith and its interior apatites. Such magma processes further account for the fluid exsolution and alteration from medium-Al amphiboles to low-Al ones. Whereas, those from the barren CQD systematically returns normal SO3 (0.18–0.70 wt%) and Cl (0.03–0.51 wt%) concentrations with estimates of melt S (335–1321 ppm) and Cl (0.1–0.5 wt%) contents exhibiting features of typical arc basalts (300–1000 ppm; 0.01–0.85 wt%, respectively). Although the acicular apatite of MMEs has normal SO3 contents (0.19–0.37 wt%), its abundance also confirm an extra sulfur supplement process. The altered apatites of both QMP and CQD showing pitted surface with visible voids and LREE-rich mineral inclusions return low SO3 (<0.06 wt%) and Cl (<0.22 wt%) concentrations, indicating that these elements were depleted during potassic and phyllic alteration.Given that Sr/Y ratios (2.21–3.62) of apatite at Pulang do not vary significantly with changing melt composition (Mg = 119.1–528.8 ppm), the Sr/Y and Eu/Eu* ratios of apatite from QMP have confirmed a water-rich, oxidized magma origin, whereas the CQD are originated from a water-poor, reduced source. Besides, the hydrothermal alteration possibly accounts for the abnormally increased Ce/Ce* ratios of altered apatites from CQD and decreased Sr/Y ratios of the low-Al amphibole-hosted apatite from QMP. Therefore, using trace elements as indicators for petrogenetic studies would be more robust for those apatites enclosed in igneous minerals. Our studies demonstrate that apatite inclusions can be linked to discrete periods in the crystallization history of its host phases, thus providing insight into the magma evolution process.

Characteristics of the Microstructure and Mineral Composition of Completely Decomposed Migmatitic Granite

Based on the characteristics of special mineral composition, complex internal structure and remarkable water effect of completely decomposed migmatitic granite(CDMG), the mineral composition distribution was obtained by X-ray powder diffraction (XRD), and the microstructure of CDMG with different water content was studied by using scanning electron microscope(SEM). The following new progress was made: The mineral composition of the rock samples is mainly quartz, feldspar, montmorillonite, illite and kaolinite. The microstructure of the sample is composed of coarse-grained quartz and feldspar as the framework, and laminated and fragmental clay minerals as the filling materials, forming a relatively dense framework filling structure. Through statistical analysis of the particle morphology and pore distribution data of CDMG samples, it is found that with the increase of moisture content, the filling structure changes from dense to loose. Because of the swelling potential induced by water absorption of hydrophilic clay minerals, and the uneven distribution of clay minerals such as montmorillonite, the filling materials are not uniformly expanded, which eventually leads to the destruction of the original filling structure and the decrease of the density.

Generation of the Giant Porphyry Cu-Au Deposit by Repeated Recharge of Mafic Magmas at Pulang in Eastern Tibet

Abstract The giant Pulang porphyry Cu-Au district (446.8 Mt at 0.52% Cu and 0.18 g/t Au) is located in the Yidun arc, eastern Tibet. The district is hosted in an intrusive complex comprising, in order of emplacement, premineralization fine-grained quartz diorite and coarse-grained quartz diorite, intermineralization quartz monzonite, and late-mineralization diorite porphyry, which were all emplaced at ca. 216 ± 2 Ma. Mafic magmatic enclaves are found in both the coarse-grained quartz diorite and quartz monzonite. The well-preserved primary mineral crystals in such a systematic magma series (including contemporaneous relatively mafic intrusions) with well-defined timing provide an excellent opportunity to investigate upper crustal magma reservoir processes, particularly to test the role of mafic magma recharge in porphyry Cu formation. Two groups of amphibole crystals, with different aluminum contents, are observed in these four rocks. Low-Al amphibole crystals (Аl2О3 = 6.2–7.6 wt %) with crystallization temperatures of ~780°C mainly occur in the coarse-grained quartz diorite and quartz monzonite, whereas high-Al amphibole crystals (Al2O3 = 8.0–13.3 wt %) with crystallization temperatures of ~900°C mainly occur in the fine-grained quartz diorite and diorite porphyry. These characteristics, together with detailed petrographic observations and mineral chemistry studies, indicate that the coarse-grained quartz diorite and quartz monzonite probably formed by crystal fractionation in the same felsic magma reservoir, whereas the fine-grained quartz diorite and diorite porphyry formed from relatively mafic magmas sourced from different magma reservoirs. The occurrence of mafic magmatic enclaves, disequilibrium phenocryst textures, and cumulate clots indicates that the coarse-grained quartz diorite and quartz monzonite evolved in an open crustal magma storage system through a combination of crystal fractionation and repeated mafic magma recharge. Mixing with incoming batches of hotter mafic magma is indicated by the appearance of abundant microtextures, such as reverse zoning (Na andesine core with Ca-rich andesine or labradorite rim overgrowth), sharp zoning (Ca-rich andesine or labradorite core with abrupt rimward anorthite decrease) and patchy core (Ca-rich andesine or labradorite and Na andesine patches) textured plagioclase, zoned amphibole, high-Al amphibole clots, skeletal biotite, and quartz ocelli (mantled quartz xenocrysts). Using available partitioning models for apatite crystals from the coarse-grained quartz diorite, quartz monzonite, and diorite porphyry, we estimated absolute magmatic S contents to be 20–100, 25–130, and &amp;gt;650 ppm, respectively. Estimates of absolute magmatic Cl contents for these three rocks are 1,000 ± 600, 1,800 ± 1,100, and 1,300 ± 1,000 ppm, respectively. The slight increase in both magmatic S and Cl contents from the premineralization coarse-grained quartz diorite magma to intermineralization quartz monzonite magma was probably due to repeated recharge of the relatively mafic diorite porphyry magma with higher S but similar Cl contents. Mass balance constraints on Cu, S, and Cl were used to estimate the minimum volume of magma required to form the Pulang porphyry Cu-Au deposit. Magma volume calculated using Cu mass balance constraints implies that a minimum of 21–36 km3 (median of 27 km3) of magma was required to provide the total of 2.3 Mt of Cu at Pulang. This magma volume can explain the Cl endowment of the deposit but is unlikely to supply the sulfur required. Recharge of 5–11 km3 of diorite porphyry magma to the felsic magma reservoir is adequate to account for the additional 6.5–15 Mt of S required at Pulang. Repeated diorite porphyry magma recharge may have supplied significant amounts of S and some Cl and rejuvenated the porphyry system, thus aiding formation of the large, long-lived magma reservoir that produced the porphyry Cu-Au deposit at Pulang.

A new lithostratigraphic framework for portions of the Pongola Supergroup within the Nkandla sub-basin, southern Kaapvaal Craton, South Africa; insights into Mozaan Group stratigraphy

AbstractA revised lithostratigraphic framework for Mozaan Group-equivalent strata within the Nkandla sub-basin is presented based on new field data, remote sensing and genetic sequence stratigraphic interpretations. Although previous literature has suggested that no Mozaan Group lithologies were deposited within the sub-basin, reinterpretations presented here indicate that 90% of the lithostratigraphy developed within the main basin occurs within the Nkandla and Mhlatuze inliers. Mozaan Group units previously defined as the Vutshini and Ekombe formations are correlated with stratigraphy from the lowermost Sinqeni Formation to the Gabela Formation. Although thinner than units within the type area in the main basin, thicknesses of the Sinqeni Formation are comparable to those observed within the White Mfolozi Inlier. A ~1 000 m composite reference profile is measured within the Mdlelanga Syncline of the Nkandla Inlier. Further profiles were measured for sequences in the Gem-Vuleka Syncline of the Nkandla Inlier, as well as within the Mhlatuze Inlier. These latter profiles, however, host only lower Mozaan Group strata. In all sections the basal portion of the sequence comprises two quartz arenite units, separated by a ferruginous shale, which hosts minor iron formation interbeds. This predominantly coarse-grained lower sequence is overlain by a shale-dominated succession with multiple sandstone interbeds. A prominent coarse-grained quartz arenite unit forms a distinct marker in the middle portion of the sequence. This is overlain by a sequence of shales and sandstones with two prominent igneous units present. Genetic sequence stratigraphic interpretations indicate cyclical deposition of dominantly shallow marine sediments with condensed sections, marked by iron formations or ferruginous shales, denoting periods of marine highstand along the southeastern margin of the Kaapvaal Craton. The evidence of Mozaan Group stratigraphy within the Nkandla sub-basin supports a passive margin tectonic model whereby deposition occurred in an arcuate shallow continental margin which opened to the southeast. The extension of Mozaan Group strata into the Nkandla sub-basin suggests that the Mozaan Basin likely formed a single depository rather than separate sub-basins as previously proposed.

Deformation-induced Japan twinning in quartz during incipient mylonitization

Abstract Many crystalline rocks of the continental crust contain coarse-grained quartz as a main mineral (e.g., granitoids). Incipient deformation of coarse quartz, which likely controls the accumulation of bulk strain in heterogeneously deformed crustal rock volumes, commonly develops microshear zones (MSZs) of localized recrystallization. At mid-crustal conditions, where quartz deformation is mostly accomplished by subgrain rotation recrystallization, grains of MSZs can show an abrupt change in crystallographic orientation (large misorientation angle) with respect to the host quartz that is still not fully understood. We analyzed MSZs (20–200 µm thick) from deformed coarse-grained (millimeter grain size) quartz veins in the Austroalpine Schobergruppe (Eastern Alps). Electron backscatter diffraction analysis reveals that the MSZs are characterized by a nearly 90° misorientation angle between the c-axes of the host and new grains, which also share one {m} and one {1122} pole, compatible with Japan twinning. This abrupt switch of the c-axis orientation can promote geometrical softening and shear localization. So far, Japan twinning has been interpreted as a growth feature. We show that deformation-induced twinning in quartz, including Japan and Dauphiné twinning, can play an important role in initiation of crystal-plastic deformation within the crust.