Coal Gasification Research Articles

Towards Integrating Pressure-Sound Piezo Energy Generator in Sports Facility Energy Mix

The paper examines the evolving landscape of energy sources within sports facilities. Traditionally reliant on electrical power and other forms of power from non-renewable resources such as coal, petroleum, and natural gas, these facilities face the inevitability of resource depletion and environmental repercussions. In response, this paper advocates for the adoption of new avenues, including energy conservation, emission reduction, energy recovery, and embracing renewable energy sources. A pioneering focus is on the implementation of a piezoelectric power generation system, tapping into typically wasted sources such as sound and human locomotion. An experimental approach explored the feasibility of such a system in order to ascertain its reliability, efficiency, and sustainability. With applications ranging from powering low-power electronic devices to environmental monitoring sensors, the successful integration of this technology promises a substantial advancement in the use of other renewable energy sources, diminishing reliance on non-renewable sources albeit on a small scale. The paper endeavours to shed light on the potential application of piezoelectric power generation in the electricity production field, aligning with the overarching objective of harvesting energy from unconventional sources and converting it into usable electrical energy. Moreover, it aims to shed light on the potential integration of piezoelectric and audio-electric generators in the energy or renewable energy mix of sports facilities, and address emerging technologies, societal impacts, and strategies to overcome barriers to adoption.

CO enhancement in coal gasification with CO2: Effect of minerals

To investigate the effect of minerals in brown coal on CO yield in a CO2 atmosphere, we impregnated pickled coal with nitrate and quartz to simulate the mineral content and assessed their impact on CO yield during gasification. It demonstrated that the reaction of Ca2+ and Fe3+ forming CaFe2O4 enhanced the CO yield. In the 100 % CO2 atmosphere, pickled coal containing CaFe2O4 produced five fold the amount of CO as after-pickling coal. The effect of minerals on CO generation under the CO2 atmosphere was explored by adding specific amounts of 1.96 wt% Ca, 1.80 wt% Fe, 6.83 wt% Al, 0.53 wt% Mg, and 11.64 wt% Si to acid-washed brown coal. The results show that the addition of Ca2+ contributes to the enhancement of CO, whereas the combined addition of Ca2+ and Fe3+ increases CO yield. CaFe2O4 enhances CO yield for two reasons: firstly, it is oxidized by CO2 to produce CO; secondly, CaFe2O4 can further react with CO2 to form Ca2Fe2O5, Ca2Fe2O5 then reacts with carbon in the brown coal to generate CO. This study has significant implications for the utilization of brown coal resources.

Stability evaluation method of gasification coal pillar under thermal coupling condition for prevention of environment secondary pollution

The instability of gasification coal pillars can easily induce the further development of water-conducting fractures, which leads to the connection of gasification combustion space and aquifer, and then causes groundwater pollution. Therefore, it is crucial to assess the stability of gasification coal pillar to forestall the potential risk of environmental contamination resulting from underground coal gasification. In this paper, based on the shape of the combustion space area of underground coal gasification, considering the influence of the mechanical properties of the coal pillar and the temperature field under the condition of thermal coupling, the calculation method of the yield zone width of gasification coal pillar is proposed. Considering the destabilizing factors affecting the coal pillar and the relationship between actual and ultimate bearing capacities after stripping and yielding, a stability evaluation method for the ‘hyperbolic’ coal pillar is proposed. Additionally, the effects of various factors on the stripping, yielding, and safety factor of the coal pillar are analyzed. The new method was applied to the Ulanqab underground coal gasification test site, which proved its effectiveness. The research results are of great practical significance for designing underground coal gasification production and preventing environmental pollution.

Efficient separation of coal gasification fine slag from Texaco gasifier and microstructures and elemental characteristics of separated components

ABSTRACT Coal gasification fine slag (CGFS) is one of the by-products of coal gasification process, which is mainly composed of inorganic minerals and residual carbon. The key to realize the high-value utilization of CGFS is separating the residual carbon and mineral in CGS effectively. Owing to irregular distribution of carbon in different size of CGFS, which could not be enriched by simple grinding and screening for component enrichment. In this paper, the enrichment of CGFS was carried out by the float-sink method, which is low-cost and does not result in the loss of raw materials. The carbon-rich particles (CRP, ash: 27.89%) and mineral-rich particles (MRP, ash: 78.01%) were obtained, where CRP contains a large amount of amorphous carbon with rich porous structure, while MRP is a heterogeneous material containing not only inorganic minerals but also organic carbon with low porosity. The mineral particles exist as aluminosilicates with a high degree of polymerization. The results of this paper will provide theoretical and technical support for the high-value utilization of CGFS.

Dewatering promoting of carbon-rich coal gasification coarse slag by size reduction with surface modification

ABSTRACT Coal gasification coarse slag (CGCS) has become a bulk coal-based solid waste that threatens the ecological environment. The high moisture content of carbon-rich coal coarse gasification slag (CR-CGCS) seriously limits its utilization. In this study, a pore water releasing method was proposed to promote the dewatering of CR-CGCS through size reduction with surface modification. Hexadecyl trimethyl ammonium bromide (CTAB), sodium dodecyl sulfate (SDS), and kerosene were added during the grinding process, respectively. The results showed that kerosene can significantly improve the dewatering efficiency of CR-CGCS more than CTAB and SDS. The final moisture content of the CR-CGCS could be reduced from 47.50% to 33.01%. The SEM and FTIR results illustrated that kerosene could effectively reduce the content of oxygen-containing functional groups on the surface of CR-CGCS more than CTAB and SDS. Meanwhile, the PVM results showed that CR-CGCS modified by kerosene tended to form hydrophobic agglomerates. The LF-NMR results indicated that only the water in the macropores of CR-CGCS could be released in grinding process, but the water in micropores could be reduced when kerosene, CTAB, or SDS was added in grinding. This study provides new insight into enhancing the dewatering of CR-CGCS and theoretical support for the efficient utilization of CR-CGCS.

Mechanism of one-step hydrothermal nitric acid treatment for producing high adsorption capacity porous materials from coal gasification fine slag

The increasing amount of coal gasification fine slag (CGFS) necessitates its resource utilization. CGFS, mainly composed of porous carbonaceous particles and partially fused spherical or agglomerated ash particles, is an inexpensive and high-quality raw material for preparing adsorbent materials. However, the challenge remains in developing a simple, low-cost, and environmentally friendly method to produce high-performance porous materials from CGFS. In this study, a one-step treatment method using 2 mol/L nitric acid under hydrothermal conditions was proposed for CGFS. The adsorbent material (CGFS-2 M) prepared under a solid–liquid ratio of 2:5 and an initial concentration of 200 mg/L methylene blue (MB) exhibited an equilibrium adsorption capacity as high as 210.20 mg/g. The excellent adsorption performance of CGFS-2 M can be attributed to several factors: acid leaching for mineral removal and pore formation, resulting in a specific surface area and total pore volume 2.2 and 1.6 times that of untreated CGFS, respectively, and an optimized mesoporous pore size distribution favorable for MB adsorption; optimal mineral removal and a well-defined carbon microcrystal structure providing more space for MB adsorption; nitric acid treatment increasing the surface oxygen content and hydrophilicity, enhancing its ability to remove MB. The synergistic effect of pore structure improvement and surface modification indicates a feasible research direction for enhancing the performance of CGFS-based adsorbent materials. These results provide theoretical support for the development of efficient CGFS-based adsorbents.

ANALYSIS OF TYPES OF VEHICLE POWER PLANTS: ADVANTAGES AND DISADVANTAGES

This paper analyzes the advantages and disadvantages of vehicle power plants, examines the development and modern types of hybrid power plants used in transport. An analysis of carbon dioxide (CO2) emissions into the atmosphere from vehicles equipped with different types of powertrains, including internal combustion engines (ICE), hybrid drives, and electric motors, was performed. Studies have been conducted of emissions that occur during the operation of vehicles, as well as emissions associated with the production of high-voltage batteries for electric vehicles and the production of electricity required for their charging. It was concluded that electric vehicles, despite their popularity as environmentally friendly vehicles, can have a significant impact on the environment. This is due to high CO2 emissions during the production of batteries, which are a key component of electric vehicles. The production of these batteries requires significant energy costs and the use of various materials, the extraction and processing of which also lead to greenhouse gas emissions. In addition, the environmental impact of electric vehicles largely depends on the sources of electricity used to charge them. When electricity is generated from fossil fuels such as coal or natural gas, overall CO2 emissions can be significantly higher, reducing the environmental advantage of electric vehicles over internal combustion engines. On the other hand, the use of renewable energy sources, such as solar or wind energy, to charge electric vehicles significantly reduces CO2 emissions into the atmosphere. The work also considers hybrid vehicles that combine an internal combustion engine and an electric motor. Such cars usually have lower CO2 emissions during operation compared to traditional diesel vehicles, but their environmental impact also depends on the production and disposal of batteries. To make informed decisions about the choice of powertrain and the development of transport infrastructure, all aspects must be taken into account, including the production of vehicles, their operation and disposal. It is also important to develop technologies to reduce emissions and increase energy efficiency at all stages of a vehicle's life cycle. The work concluded that to reduce the overall impact of vehicles on the environment, it is necessary not only to develop electric vehicles, but also to combine the advantages of internal combustion engines and electric motors (develop a hybrid drive), improve battery production technologies, expand the use of renewable energy sources, and implement other measures to reduce CO2 emissions.

The Efficiency of Chemical and Electrochemical Coagulation Methods for Pretreatment of Wastewater from Underground Coal Gasification

This article compares chemical coagulation with electrocoagulation, two popular methods for the primary treatment of wastewater generated in the process of underground coal gasification (UCG). The primary aim was to determine which method is more effective in the removal of cyanide and sulphide ions, metals and metalloids, as well as organic compounds. In both cases, experiments were conducted in batch 1 dm3 reactors and using iron ions. Four types of coagulants were tested during the chemical coagulation study: FeCl2, FeSO4, Fe2(SO4)3, and FeCl3. In the electrocoagulation experiments, pure iron Armco steel was used to manufacture the sacrificial iron anode. Both processes were tested under a wide range of operating conditions (pH, time, Fe dose) to determine their maximum efficiency for treating UCG wastewater. It was found that, through electrocoagulation, a dose as low as 60 mg Fe/dm3 leads to >60% cyanide reduction and >98% sulphide removal efficiency, while for chemical coagulation, even a dose of 307 mg Fe/dm3 did not achieve more than 24% cyanide ion removal. Moreover, industrial chemical coagulants, especially when used in very high doses, can be a substantial source of cross-contamination with trace elements.

Synthesis of composites from coal gasification slag by acid leaching and NaOH activation for efficient adsorption of methylene blue

This study successfully developed a carbon-silicon composite material (C-Si@GS) by acid leaching (HCl) and alkali activation (NaOH) treatments from solid waste CGS and applied to the adsorption of methylene blue (MB). The effects of material dosage, pH, contact time, initial concentration and co-existing ions on the removal of MB were investigated. The results revealed C-Si@GS had good adsorption performance at different pH and cations, suggesting that the material had stable properties. The adsorption of MB by C-Si@GS reached the equilibrium within 12 h, and the removal rate was up to 99 %. The maximum adsorption capacity of C-Si@GS was 456.8 mg/g calculated by Langmuir model (C0 (MB) = 120 mg/L, pH=7 ± 0.2, dosage = 0.6 g/L, and T=298 K). The adsorption process is consistent with Pseudo-secondary and Freundlich models, suggesting that both physical and chemical adsorption processes coexist. Adsorption mechanisms are mainly van der Waals forces, hydrogen bonding, electrostatic attraction and π-π bond interaction, as analyzed by XPS and FT-IR. The composites were regenerated using HCl as desorption agent and the removal rate was about 50 % after 3 cycles. The results illustrated that C-Si@GS can serve as an effective adsorbent for removing MB.

Molecular simulation of CO2/N2 injection on CH4 adsorption and diffusion

As an efficient and clean energy, coalbed methane development and utilization have deep significance in promoting energy conservation and emission reduction, reducing greenhouse gas emissions. Therefore, molecular simulation was utilized to study the influence of N2/CO2 on the adsorption and diffusion of methane in coal under different gas injection methods and to elucidate the influence of varying gas injection methods on the efficiency of coalbed methane extraction, which provides a basis for the efficient development of coalbed methane. The results show that the adsorption effect of gases in coal decreases with the increase of temperature and increases with the rise of pressure, and the adsorption performance of the three gases in coal shows the law of CO2 > CH4 > N2. In addition, the injection of CO2/N2 had an obvious inhibition effect on CH4 adsorption, and the inhibition effect of CO2 was more significant, and the inhibition effect on CH4 adsorption reached the maximum when the two gases were mixture injected. In terms of diffusion, compared with separate injection, mixed injection of N2 + CO2 promotes CH4 diffusion more effectively, which can be reflected in the relative concentration distribution and velocity distribution. The injection of N2 helps to increase the porosity of coal, and the injection of CO2 and N2 + CO2 will lead to the decrease of porosity, but the mixed gas injection has less effect than the injection of CO2 alone.

Analysis on typical characteristics and causes of coal mine gas explosion accidents in China.

Large-scale coal mine gas explosion (CMGE) accidents have occurred occasionally and exerted a devastating effect on society. Therefore, it is essential to systematically identify the characteristics and association rules of causes of CMGE accidents through analysis on large-scale CMGE accident reports. In this study, 298 large-scale CMGE accidents in China from 2000 to 2021 were taken as the data sample, and mathematical statistical methods were adopted to analyze their general characteristics, coupling cross characteristics, and characteristics of gas accumulation and ignition sources. Moreover, the text mining technology and the Apriori algorithm were used for exploring the formation mechanism of CMGE accidents, during which 46 main causal factors were identified and 59 strong association rules were obtained. Furthermore, an accident causation network was constructed based on the co-occurrence matrix. The key causal items and sets of CMGE accidents were clarified through network centrality analysis. According to the research results, electrical equipment failure, cable short circuit, mine lamp misfire, hot-line work, and blasting spark are the key ignition sources of CMGE. Fan failure, airflow short circuit, and local ventilation fan damage are the main causes of gas accumulation. Besides, the confidence levels of two association rules of "static spark-fan failure" and "blasting spark-airflow short circuit" are higher than 70%, indicating that they are the two dominant risk-coupling paths of gas explosions. In addition, six causes appear frequently in the shortest risk paths of gas explosion and are closely related to other causes, i.e., fan failure, local ventilation fan damage, static sparks, electrical equipment failure, self-heating ignition, and friction impact sparks. This study provides a new perspective on identifying causes of accidents and their complex association mechanisms from accident report data for practical guidance in risk assessment and accident prevention.

Distribution, sources, and risk assessment of polycyclic aromatic hydrocarbons in surface soils and plants from industrial and agricultural areas, Junggar Basin, Xinjiang

The contamination characteristics of Polycyclic Aromatic Hydrocarbons (PAHs) in different environmental functional areas are different. In this study, the contamination of PAHs in soils and common plants in typical mining and farmland areas in Xinjiang, China, was analyzed. The results showed that the contamination levels of PAHs in mining soils were significantly higher than those in farmland soils, and the mining soils were dominated by 4-5-ring PAHs and farmland soils by 3-4-ring PAHs. Analysis of their sources using a positive definite factor matrix model showed that PAHs in mining soils mainly originated from coal and natural gas combustion, and transportation processes; while farmland soils mainly came from biomass and coal combustion, and fossil fuel volatile spills. The cancer risk of PAHs in soils was evaluated using a combination of the Monte Carlo and the lifetime carcinogenic risk models, and the results showed that the overall level of cancer risk for mining soils was higher than that for farmland soils, and can put some people in high risk of cancer. For plant samples, except for individual crop samples, the contamination levels of mining plants and crops were similar, with 4-5-ring PAHs dominating in desert plants in mining areas and the highest proportion of 3-ring PAHs in crops in agricultural fields, and PAHs in both plants were mainly from biomass and coal combustion. The results of correlation analysis showed that 2-ring PAHs in crop roots were significantly positively correlated with it in corresponding soils, and some high-ring PAHs in crop leaves were significantly negatively correlated with it in corresponding soils. Therefore, there were significant differences in the pollution characteristics of PAHs in soils and common plants in mining and agricultural areas. Human health risks and ecological risks are mainly concentrated in mining areas, and appropriate intervention measures should be taken for pollution remediation.

Coal chemistry, utilization potential, and coalbed methane (CBM) assessment of some coal deposits in Central Benue Trough, north-central Nigeria

Coalbed methane (CBM), a current global legislative priority for climate change mitigation, is an unconventional and eco-friendly clean source of energy that is considered a veritable alternative to conventional fossil fuels. Despite its overwhelming advantages, CBM evaluation studies of Nigerian coals have received little or no attention. To bridge the gap in knowledge, we have for the first time in Jangwa-Shankodi and Lafia-Obi, described the potential of harnessing CBM for its gainful utilization in Nigeria using some coal deposits in its north-central region as a case study. The gas contents of the coals were determined empirically by taking account of their ultimate and proximate properties. Other coal parameters such as fuel ratio and vitrinite reflectance (Ro (%)) have also been computed and discussed. Proximate analyses of the studied coal samples show moisture contents that vary between 2.28 and 2.56%, whereas, volatile matter yield is placed in the range of 29.98–30.34%. Ash yield ranges from 7.83 to 8.64%. Fixed carbon content varies from 55.97 to 56.30%. Variation in fuel ratio shows a restricted range from 1.72 to 1.87. All the coal samples were found to be low in sulphur (< 1%) with H/C ratios that vary from 0.072 (LAF 2, 3 and 4) to 0.086 (JSK 3). Moreover, the coals were found to be of medium-volatile bituminous rank, with gas contents that range from 12.65 to 13.20 cc/g. In the current study, kerogen lies in the Type IV zone, which suggests the generation of methane gas by the studied coal samples. Also the estimated range of vitrinite reflectance (Ro) which varies between 1.073% and 1.086% indicates thermogenic gas expulsion in the coals. There is a noticeable increase in gas content with coal maturity and depth. These values are indicative of good quality coals that show antecedents for CBM production. However, considering that this work is a pilot study, we recommend that core drilling be employed in obtaining insitu measurements of the coal gas contents and thus, verify these empirical estimates. Also, detailed laboratory study on pore structure (and its distribution) and adsorption isotherm curve are recommended to better understand the coal reservoir properties and hence, consolidate the present study.

Analysis of the influencing factors of emission trading price in China

China established pilot carbon markets in 2013. In 2020, it set targets for carbon peaking in 2030 and carbon neutrality by 2050. China’s national carbon market officially commenced operations in 2021. Based on the national market and seven pilot markets, this study established the factors influencing carbon trading prices by examining market participants, macroeconomics, energy prices, carbon prices in other markets, etc. Asymmetrical development among the seven pilot cities, for which the study employed a mixed-effects model, was the primary factor impacting carbon prices. The carbon prices in the pilot cities cannot be extrapolated to the entire country. In the national carbon market, where the study employed a multiple regression lag model, the SSE index was positively correlated with carbon prices, whereas the Dow Jones index had no significant effect on carbon prices in terms of macroeconomics. Coal and natural gas prices were negatively correlated with carbon prices, whereas oil prices were positively correlated with energy prices. The EU market prices have a positive correlation with prices in other markets. The significance of this study is that it covers the largest national Emissions Trading System (ETS) in the world and allows for comparing the characteristics of the Chinese market with those of other ETS markets. Additional studies, including more sectors, should be conducted as China’s ETS coverage increases.

Determination of the Advanced Mining Influence Range in Coal Mines Based on the Statistical Analysis of Mining-Induced Seismicity

Determining the advanced mining influence range of an underground working face is crucial for preventing dynamic disasters, such as coal bursts and gas outbursts. In this study, the occurrence of advanced seismicity before the working face as well as its correlation with the acoustic emission (AE) activity of coal and rocks under axial loading was analyzed. Based on the results, a novel statistical method to determine the advanced mining influence range based on advanced seismicity data was proposed and then validated with a case study. The results show that advanced seismicity is caused by the combined effects of static and dynamic stresses at the working face. This seismicity can be used to assess the mining influence degree of the working face on the advanced coal and rock mass, and determine the advanced mining influence range. Using the novel statistical method, the normalized curves for the total number and total energy of the advanced mining-induced seismicity can be plotted. Then, the advanced mining influence range can be determined using thresholds. The thresholds can be established based on the AE activities observed in coal and rock samples under axial static loading. In the case study in this research, the thresholds for the total seismic number and total seismic energy are 0.076 and 0.052, respectively. The corresponding advanced mining influence ranges are 275 m and 245 m, respectively. Field monitoring confirms an advanced mining influence range of 255 m, which validates the results obtained using the novel statistical method.

Sheet-assembled Zn-based sorbents towards highly efficient desulfurization of hot coal gas: H2S-absorption/COS-release behavior and sulfur-release inhibiting mechanism

It is still challenging to obtain high-temperature sorbents with strong abilities of absorbing H2S and suppressing COS-release during coal-gas desulphurization process. Furthermore, the related inhibiting mechanism is unclear. Herein, functional Zn-based sorbents, with HTLCs (hydrotalcite-like compounds) as the precursor, were designed and fabricated via microwave-assisted co-precipitation method. Doping of metals (Mo/Ni/Co) with function of catalyzing COS-hydrogenolysis was proposed for sorbent modification. The resultant sorbents exhibit hierarchical structure self-assembled from nanosheets. As expected, Mo-, Ni-, and Co-doping result in significant decrease (by 78 %–85 %, 83 %–90 %, and 59 %–74 %, respectively) in the amount of released COS for sorbents. Moreover, Ni-doping generally causes the smallest negative effect on H2S-uptake behavior. It is related to a decline (by about 40 %) in the length of laminas unit and more porous structure of sorbents because of Ni-doping. Especially, the sorbent with the lowest Ni-doping ratio shows high sulfur capacity (27.1 g S/100 g sorbent, desulfurization efficiency: > 99.5 %) and low COS-release amount (1.5 × 10−3 g COS/100 g sorbent). More importantly, it also maintains relatively stable performance over successive sulfidation-regeneration cycles. In addition, the analysis of COS-hydrogenation behavior over individual components in desulfurizers reveals that the doped metals greatly accelerate the COS-hydrogenolysis reaction, responsible for less COS emission of modified sorbents.

Modeling, parameter estimation and optimization of fluidized bed-based alternative ironmaking process for CO2 emission reduction

This study presents the development of a comprehensive process model for simulating and optimizing the FINEX process consists of the multi-stage fluidized beds, the melter-gasifier unit, and a gas recycling system. The model is developed using Pyomo, a Python-based open-source software package that provides extensive capabilities for formulating, solving, and analyzing optimization models. It incorporates heat and mass balance equations and captures a wide range of chemical reactions, including the reduction of iron ore by hydrogen and carbon monoxide, the calcination of carbonate materials, the water–gas shift reaction, and coal gasification and combustion. Unknown parameters in the model, such as heat loss in each reactor, the extent of the calcination reaction, and the outlet gas temperature from the melter-gasifier, were estimated to calibrate the model. These parameters were estimated by solving an optimization problem that minimizes the gap between the model and real plant data. The optimized model was employed to investigate various scenarios for minimizing CO2 emissions in the FINEX process. This included assessing the impact of HBI charging rates, iron ore quality, and the integration of a CCUS unit. For each scenario, an optimization problem was formulated to minimize production costs across a range of CO2 tax levels. The optimal solutions revealed the relationships between process economics and CO2 emissions for each variable.

Exploring the superior mild temperature performance of nickel-infused fibrous titania silica for enhanced dry reforming of methane

Carbon (IV) oxide (CO2) and methane (CH4) contribute significantly to greenhouse gas emissions and global warming. One potential approach for reducing their environmental impact is transforming these gases into synthesis gas (CO + H2). This study illustrates the advancement of catalysts supported by fibrous titania silica (FTS), which have nickel loadings of 1%, 3%, and 5%. The FTS support, a modified variant of silica-titania, has a distinct fibrous structure and exhibits mesoporous material properties such as a type IV isotherm and an H1 hysteresis loop. After 72 h of operation, the 1Ni/FTS catalyst converted over 80% of CH4 and CO2 with low coke deposition, outperforming other catalysts. The bare FTS support had reduced CH4 conversion at 600°C, CO2 conversion at 650°C, and H2/CO ratio at 700°C. However, the 5Ni/FTS and 3Ni/FTS catalysts showed consistent increases in CH4 conversion at 600°C. The 1Ni/FTS catalyst, with a pore size of 7.39 nm, had strong metal-support interaction and moderate basicity sites, which helped with reactant dissociation and coke gasification. Despite the slightly higher CH4 conversion of the 3Ni/FTS catalyst and the high basicity of the 5Ni/FTS catalyst, the 1Ni/FTS catalyst demonstrated superior thermal stability and coking resistance, as evidenced by negligible weight loss during TGA analysis. Raman shifts revealed the presence of carbon synthesis and the buildup of disordered amorphous carbon. The Id/Ig ratios of FTS, 1Ni/FTS, 3Ni/FTS, and 5Ni/FTS were 1.01, 0.98, 1.01, and 1.01, respectively. The lower Id/Ig ratio of 1Ni/FTS suggests less disorder. The FTS support promises mild-temperature, carbon-neutral CH4 reforming with long-term catalytic applications. This study demonstrates the efficacy of FTS-supported catalysts in constructing long-term and efficient systems for converting greenhouse gasses.

Heat-dependent properties of methane diffusion in coal: an experimental study and mechanistic analysis.

Coalbed methane thermodynamic extraction, as an emerging ECBM recovery method, can effectively improve gas recovery rates. And clarifying methane diffusion and migration law in coal under thermal stimulation is crucial for the selection of its process parameters. Based on laboratory methane adsorption-release experiments, the evolution law of methane diffusion characteristics with temperature and pressure was studied, and the control mechanism of heat-dependent methane diffusion behavior was explored. The results show that both thermal stimulation and high adsorption pressure accelerated the methane diffusion rate in coal. Adsorption pressure had little effect on methane diffusion percentage, but thermal stimulation promoted a significant increase in diffusion percentage and improved the net methane yield. The influence mechanisms of adsorption pressure and thermal stimulation on methane diffusion characteristics are elucidated in relation to the amount and proportion of methane-activated molecules in the diffusion process. The constant diffusion coefficient of methane is heat-dependent, based on which a diffusion model is derived to accurately predict the methane release process in coal. Additionally, temperature has a more important effect on transient diffusion coefficient than pressure. Thermal stimulation leads to a net increase rather than a decrease in diffusion coefficient in the early diffusion stages and can also accelerate the attenuation of diffusion coefficient, with this intensifying effect becoming more pronounced at higher temperatures. The research results can provide some reference for the determination of coal seam gas content and the selection of heat injection process parameters.

Comparison of Gravimetric Determination of Methane Sorption Capacities of Coals for Using Their Results in Assessing Outbursts in Mines

The gravimetric method for determining coal gas sorption has many advantages and limitations. The article presents the influence of various factors on the results of methane sorption on coal. In mining practice, in addition to sorption properties of coal, knowledge of methane sorption capacity and effective diffusion coefficient determined when assuming a unipore sorption/desorption model are crucial for predicting sudden releases of methane from coal seams to a mine ventilation environment. In Poland, determining sorption capacities of coals for methane is mandatory when starting mining operations in new parts of coal deposits threatened by outbursts. Traditionally, gravimetric microbalances, such as intelligent gravimetric analysis (IGA), are used to determine adsorption capacity and desorption rate. Recently, newer microbalances XEMIS have been introduced to the market. Two gas laboratories, AGH in Krakow and CLP-B in Jastrzebie-Zdroj, respectively, compared experimental adsorption isotherms using XEMIS microbalances with mutually exchanged coal samples. Both sorption capacity at the pressure of 1 bar (a1bar) and effective diffusion coefficient (De) were independently determined for the coal samples tested. The results obtained are comparable despite the use of different microbalance XEMIS models. The conducted studies and comparative evaluation of the results allowed for assessing procedures for determining sorption properties using XEMIS microbalances. The exchange of laboratory experiences also allowed for the identification of methodology factors crucial for the development of a uniform procedure for conducting similar studies with XEMIS microbalance. The proposed factors for testing the sorption behavior of methane in coal structures may be helpful in mining practice.