The coal-fired power industry in the United States faces growing needs to improve wastewater treatment and disposal practices, especially for wet flue gas desulfurization (FGD) systems. Zero liquid discharge (ZLD) treatment systems may be implemented, and one ZLD option is the coupling of brine concentration with solidification/stabilization (S/S). This S/S process could be achieved by co-disposing the concentrated FGD brines with coal fly ash (CFA) and Portland cement. S/S using bituminous CFA (BCFA) achieved good retainment (average 68–90%) of AsV, CdII, HgII, and SeIV in the toxicity characteristic leaching procedure (TCLP); however, poor retainment was observed for CrVI and SeVI. Separate experiments showed good sorption of AsV, CdII, HgII, and SeIV (average 56–100%) but poor sorption of CrVI and SeVI to S/S solids. Meanwhile, CrVI and SeVI retainment could be enhanced by addition of FeSO4 to the S/S mixture, likely due to reduction of these metals to lower oxidation states. Compared to BCFA, S/S using sub-bituminous CFA (SCFA) resulted in higher pH S/S solids and final TCLP leachate, which increased retainment of AsV, CdII, and SeVI. Apart from the pH impact on the process, AsV retainment was likely improved by the high Ca content of SCFA and SeVI retainment was improved by the incorporation of SeO42– in Friedel’s salt (AFm-Cl) by exchange with Cl–. Friedel’s salt was positively identified by X-ray diffraction in the SCFA S/S solids but not for the BCFA S/S solids. Even so, reduction of SeVI plus S/S is likely a better immobilization strategy than SeO42– substitution in the AFm phase because of higher stability under long-term landfill conditions.
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