Coal-burning Power Plants Research Articles

Bipartite interference and air pollution transport: estimating health effects of power plant interventions.

Evaluating air quality interventions is confronted with the challenge of interference since interventions at a particular pollution source likely impact air quality and health at distant locations, and air quality and health at any given location are likely impacted by interventions at many sources. The structure of interference in this context is dictated by complex atmospheric processes governing how pollution emitted from a particular source is transformed and transported across space and can be cast with a bipartite structure reflecting the two distinct types of units: (i) interventional units on which treatments are applied or withheld to change pollution emissions; and (ii) outcome units on which outcomes of primary interest are measured. We propose new estimands for bipartite causal inference with interference that construe two components of treatment: a "key-associated" (or "individual") treatment and an "upwind" (or "neighborhood") treatment. Estimation is carried out using a covariate adjustment approach based on a joint propensity score. A reduced-complexity atmospheric model characterizes the structure of the interference network by modeling the movement of air parcels through time and space. The new methods are deployed to evaluate the effectiveness of installing flue-gas desulfurization scrubbers on 472 coal-burning power plants (the interventional units) in reducing Medicare hospitalizations among 21,577,552 Medicare beneficiaries residing across 25,553 ZIP codes in the United States (the outcome units).

δ26Mg, δ44Ca and 87Sr/86Sr isotope ratios constrain Mg and Ca input–output mass balances in a heavily acidified headwater catchment

A Central European catchment underlain by base-poor orthogneiss was studied using mass budgets and Mg–Ca–Sr isotope systematics. For 50 years, the catchment received large amounts of partly soluble dust from a nearby cluster of coal-burning power plants, while suffering from acid rain and severe spruce die-back. Our objective was to investigate to what extent anthropogenic dust contributes to Mg and Ca in runoff and to identify fractionations affecting Mg and Ca isotope composition of 13 ecosystem pools and fluxes. We hypothesized that if Mg and Ca runoff fluxes were significantly larger than their atmospheric inputs, Mg and Ca isotope ratios in runoff would converge to those of bedrock Mg and Ca. This relationship could be obscured by isotope fractionations. Strontium characterized by negligible isotope fractionations served as a Ca proxy. There was a strong positive correlation between Mg and Ca fluxes via spruce throughfall and catchment runoff. Monitoring of rainfall, canopy throughfall and runoff fluxes revealed a 20-, 15- and 15-fold excess of Mg, Ca and Sr in runoff, respectively, compared to atmospheric deposition fluxes. This sizeable excess per se would indicate predominance of geogenic base cations in runoff. The behavior of Mg and Ca isotopes was de-coupled. Petrographic study indicated that 92% of bedrock Mg was bound to easily dissolving biotite, 97% Ca was present in plagioclase, and nearly all Sr was in orthoclase. While Mg isotope ratios in bedrock and runoff were indistinguishable, corroborating predominantly geogenic Mg in runoff, Ca and Sr isotope ratios in bedrock and runoff were significantly different, consistent with a non-negligible contribution of atmospheric Ca and Sr to runoff. Previous study of sites underlain by felsic rocks indicated that the δ44Ca value of apatite was often higher than the δ44Ca value of plagioclase. Should weathering of apatite and/or plagioclase preferentially release Ca that is isotopically heavier than bulk rock, the geogenic Ca source at JEZ would converge to the mean δ44Ca value of runoff. Calcium isotope data would then become more consistent with a major role of geogenic Ca in JEZ runoff indicated by mass balance data.

Sustainable Use of Recycled Plastic and Coal Bottom Ash in the Development of Construction Material

Mineral coal bottom ash (CBA) is a by-product of coal combustion in power plants. Its potential use in building materials has attracted interest due to its beneficial properties and environmental implications. The aim of this study is to assess the feasibility of using mineral coal slag from the Anou Araren coal company in Niger (Sonichar), in combination with plastic waste, in various construction applications. In this case, the focus is on compressive strength and slip potential for floor coverings. Following a technical characterization of the various elements involved in the production of the proposed material, 02 firing methods are described, with the advantages and disadvantages of each. Mixtures with varying proportions of plastic waste and bottom ash (30%/70%, 40%/70% and 50%/50%) were studied. For the mix selected, the results show that the CBA/plastic waste material has good compressive strength and low slip potential, making it suitable for use in a variety of construction applications.

Comprehensive Review of Fly Ash: Environmental Impact and Applications

ABSTRACTFly ash (FyA), a byproduct from coal combustion in power plants, has become increasingly valuable due to its pozzolanic properties. Primarily, FyA finds applications in the construction industry, including road and brick construction, forest road building, and the cement industry. When added to concrete, it enhances splitting tensile strength, compressive strength, and workability, while also reducing the environmental impact of cement production. Beyond construction, FyA is utilized for air pollutant removal and serves as an adsorbent for various contaminants. It also plays a role in creating geopolymers and nanocomposites, promoting the development of eco‐friendly construction materials. This review article presents current data on thermal power plants (ThPPs) in India, the challenges in FyA management, and its environmental impact. It also discusses relevant Indian policies and highlights ongoing research aimed at improving the efficiency and expanding the applications of FyA in various industrial sectors, such as battery manufacturing, zeolite synthesis, and cenosphere extraction. These efforts underscore FyA's potential in supporting sustainable practices. The findings of this review address critical issues related to FyA. By reducing the environmental footprint of cement manufacturing, removing air pollutants, and acting as an adsorbent for various contaminants, FyA demonstrates significant potential in pollution mitigation. It also contributes to the development of eco‐friendly construction materials and promotes sustainability in the construction sector. Effective management practices are essential to minimize FyA's negative impact on human health and the environment. The article emphasizes the need for greater awareness and implementation of policies to address these issues comprehensively. By providing a detailed understanding of the benefits and challenges associated with FyA, it aims to pave the way for more effective and sustainable utilization of this industrial byproduct.

Toxicity assessment of heavy metals translocation in maize grown in the Ganges delta floodplain soils around the Payra power plant in Bangladesh

As a cereal crop, maize ranked third place after wheat and rice in terms of land area coverage for its cultivation, and in Bangladesh, it ranked second place after rice in its production. As the substitution of wheat products, maize has been used widely in baking for human consumption and animal fodder. However, maize grown in this soil around the coal-burning power plant may cause heavy metals uptake that poses a risk to humans. The study was conducted at the maize fields in the Ganges delta floodplain soils of Bangladesh to know the concentration of eight heavy metals (Ni, Cr, Cd, Mn, As, Cu, Zn, and Pb) in soil and maize samples using an inductively coupled plasma mass spectrometer (ICP-MS) and to estimate the risk of heavy metals in maize grains. Mean concentrations of heavy metals (mg/kg) in soil were in decreasing order of Zn (10.12) > Cu (10.02) > Mn (5.48) > Ni (4.95) > Cr (3.72) > As (0.51) > Pb (0.27) > Cd (0.23). The plant tissues showed the descending order of heavy metal concentration as roots > grains > stems > leaves. BCF values for As, Cd, Pb, and Mn in roots were higher than 1.0, indicating considerable accumulation of these elements in maize via roots. Total hazard quotient (ƩTHQ) of heavy metals through maize grain consumption was 3.7E+00 and 3.9E+00 for adults and children, respectively, indicating non-cancer risk to the consumers. Anthropogenic influences contributed to the heavy metals enrichment in the Ganges delta floodplain soils around the thermal plant, and potential risks (non-carcinogenic and carcinogenic) were observed due to the consumption of maize grain cultivated in the study area.

Facile and sustainable upcycling of fly ash into multifunctional durable superhydrophobic coatings

Fly ash (FA), a hazardous byproduct of coal combustion in power plants, poses significant environmental and health risks due to improper disposal and utilization. This study introduces a facile, sustainable, and cost-effective method for converting FA into a robust superhydrophobic material for various substrates. -FA particles are modified with polydopamine (PD) in water and covalently grafted with octadecylamine (ODA) via the Michael Addition-Schiff Base reactions, resulting in robust superhydrophobic FA (SH-FA) with a water contact angle (WCA) of 163° (±3.1). When applied as a coating to jute, cotton, polyester fibers, PU sponge, and wood, they became superhydrophobic, with WCAs ranging from 154.7 to 161.2° except for the wood substrate, which achieved a WCA of 132° (±3°). The coated polyester fabric exhibited remarkable durability, retaining consistent WCA values after 70 abrasion cycles, 75 adhesive tape peelings, and 20 detergent washing cycles. It also showcased excellent self-cleaning properties, effectively repelling dust and various liquids. Additionally, the coated PU sponge demonstrated exceptional performance in separating oil from different oil/water mixtures, achieving rapid separation of organic solvents within seconds and maintaining a separation efficiency of over 98% even after 12 reuse cycles. These results indicate the potential for transforming FA through effective management.

Multiple factors influence telomere length and DNA damage in individuals environmentally exposed to a coal-burning power plant

Coal is a mixture of several chemicals, many of which have mutagenic and carcinogenic effects and are a key contributor to the global burden of mortality and disease. Previous studies suggest that coal is related to telomeric shortening in individuals occupationally exposed, however little is known about the effects of mining and burning coal on the telomeres of individuals living nearby. Therefore, the primary objective of this investigation was to assess the impact of proximity to coal power plants and coal mines on the genomic instability of individuals environmentally exposed, while also exploring potential associations with individual characteristics, oxidative stress, inflammatory responses, and the presence of inorganic elements. This study involved 80 men participants from three cities around a thermoelectric power plant and one city unexposed to coal and byproducts. DNA was extracted from peripheral blood samples obtained from each participant, and the telomeres length (TL) was assessed using quantitative real-time polymerase chain reaction (qPCR) methodology. No significant difference was observed between exposed individuals (6227 ± 2884 bp) when compared to the unexposed group (5638 ± 2452 bp). Nevertheless, TL decrease was associated with age and risk for cardiovascular disease; and longer TL was found to be linked with increased concentrations of silicon and phosphorus in blood samples. No correlations were observed between TL with comet assay (visual score), micronucleus test, oxidative stress, and inflammatory results. Additional research is required to ascertain the potential correlation between these changes and the onset of diseases and premature mortality.

Influence of Blending High-Calcium Additive on Environmental Safety of B, F, and Se: A Case Study from Thermodynamic Calculation

Coal remains an important fuel for use in thermal power plants. However, coal-burning power plants produce large amounts of CFA, which contains TEs such as B, F, and Se, which are leached upon contact with water and act as potential polluters of aquifer systems and soil. To study the transformation of TEs, a thermodynamic calculation (FactSage 7.2) was used. Paper sludge ash was used as a calcium compound additive. The influence of blending a high-calcium additive on the environmental safety of TEs was investigated based on the effect of the mass addition ratio of PS ash. This study’s results confirmed that the leaching processes of TEs, namely (CaO)2(Al2O3), CaF2, Ca10(PO4)F2, and CaSeO4(H2O)2, were caused by the formation of B, F, and Se compounds during the leaching process. Thus, it is clear that calcium has the greatest influence on the transformation of TEs due to their reaction, which, in turn, minimizes the effects of the TEs’ release into the environment. The concentrations of TEs from the sample and addition of PS ash decreased slightly, indicating that the inhibition of TEs was enabled through the addition of PS ash. Although the PS ash YB had the highest calcium content, the PS ash YC gave the best results during the B and Se inhibition processes. The experimental observation was also evaluated for comparison. For the analysis of TEs’ leaching ratios using the thermodynamic calculation and experiment, the experimental results were lower than those initially predicted. These results will help us to choose the best available control technology to minimize the effects of TEs released into the environment.

Investigating mercury in road sediment in Michigan City, Indiana: A new type of environmental pollution record

Mercury (Hg) is well recognized as a toxic heavy metal known to detrimentally impact the health of humans and wildlife. A common source of Hg pollution is coal combustion emissions associated with energy generation. This study takes the novel approach of using road sediment to assess the presence, distribution, and concentrations of Hg in the environment. Here, the spatial distribution of Hg in road sediment is also evaluated relative to the Northern Indiana Public Service Company (NIPSCO) Generating Station in Michigan City, Indiana, U.S.—a coal-burning power plant. Given that NIPSCO plans to decommission the plant by 2028, this data provides a baseline for evaluating Hg concentrations in the local environment and for future assessment of environmental recovery from legacy pollution and/or impacts of pollution redistribution associated with site redevelopment. Our data reveal an average concentration of 6.8 (µg/kg) of Hg and a range from 1.5 µg/kg to 28.5 µg/kg in road sediment samples (n = 42). Across the ∼53 km2 study area, the overall distribution of Hg is patchy and irregular spatially, however, higher concentrations are more proximal to the coal plant and are generally consistent with prevailing wind directions. Other significant Hg inputs are present in the region although, specifically two major areas of steel manufacturing located to the west of Michigan City and broadening the scope of sampling may be an essential next step. However, this investigation demonstrates that road sediment may be an effective medium for investigating Hg pollution in the environment globally.

Replacing fly ash with a natural pozzolan in normal strength concrete and ultra-high performance concrete

Fly ash is a widely-used supplementary cementitious material (SCM) in concrete. Common reasons for using fly ash in normal strength concrete (NSC) are to reduce cement consumption and mitigate alkali-silica reaction. Additionally, fly ash is being used in ultra-high performance concrete (UHPC) to reduce use of silica fume which is more expensive than fly ash. Fly ash and silica fume are important SCMs in UHPC that provide a dense microstructure, improving UHPC strength and durability. However, fly ash is becoming less available because the energy industry has been investing in renewable energy production and removing coal burning power plants from operation. Therefore, there is a need to identify sustainable SCMs to replace fly ash in NSC and UHPC mixtures. Natural pozzolans are a diverse class of siliceous or siliceous and aluminous materials that can form compounds possessing cementitious properties in the presence of water. Since natural pozzolans are easily mined, they are usually considered to be more sustainable than Portland cement and nearly as sustainable as other SCMs such as fly ash and silica fume. This experimental study evaluated the effects of a natural pozzolan (pumicite) as a potential replacement for fly ash that can produce comparable rheological and mechanical properties in NSC and UHPC mixtures. Results indicated that workability of both NSC and UHPC mixtures containing pumicite was consistent enough to achieve the targeted workability in just a few trials. Additionally, NSC mixtures with 30% pumicite had comparable compressive strength compared to NSC mixtures with 30% fly ash. Modulus of rupture (MOR) for NSC mixtures containing 30% pumicite (greater than 4.10 MPa) exceeded the MOR for specimens containing 30% fly ash. For UHPC mixtures, results showed that up to 75% of the fly ash in the control mixture could be replaced with pumicite while still producing acceptable compressive and flexural strengths. Based on these results, it appears that pumicite can be a reliable alternative for fly ash in NSC and UHPC mixtures in terms of rheological and mechanical properties.

Diagnosis of Respiratory Sounds using Deep Neural Networks

Abstract: Respiratory diseases are on the rise around the world and the impact of COVID-19 has highlighted the need for early and better diagnosis of respiratory diseases. The growing air pollution from vehicles, wildfires, coal-burning power plants and other natural and non-natural causes, particularly in the developing world is leading to more deaths due to respiratory problems leaving many in need of diagnosis and treatment. The use of machine learning for preliminary analysis and diagnosis of diseases is evolving rapidly, particularly in the area of analysis of medical images to help sort through and analyze hundreds of X-ray, CT-Scan or MRI images to highlight the area affected by a potential medical condition and suggest a possible diagnosis. This has allowed timely detection of potentially life-threatening diseases, reduced diagnosis time, improved efficiency and better coverage. These medical aids are also being integrated into the medical scanning equipment and related software to further improve the diagnostic process. This paper attempts to expand the use of deep learning as a method of assisting in the early diagnosis of respiratory diseases using audio recordings. The paper describes an approach for analyzing lung sounds captured using an electronic stethoscope from different parts of a patient’s chest wall. The paper describes the processes used to extract features from the sound signals, dataset preparation, neural network architectures evaluated and the prediction results.

INFLUENCE OF THE USE OF WASTE GENERATED BY THERMOELECTRIC POWER PLANT ON SUSTAINABLE ASPHALT MIXES

The main objective of this research is to evaluate the influence of using waste generated by a coal-burning thermoelectric power plant in asphalt mixes. The matrices called fly ash, bottom ash and a composition with 50 % of each type were analyzed, and compared to conventional crushed gneissic rock particles, all used as filling material (filler) at 6.0 % passing through the mesh opening 0.075 mm, in the granulometric curves of asphalt mixes. The matrices studied are technically viable for use in asphalt mixes, creating the potential for large-scale market use of bottom ash, especially in the southern region of the State of Santa Catarina. Thus, to benefit more directly from the proximity to the source producing these inputs, the South region can explore the use of power plant waste, given the easy access and shorter transport distances.

Improving the rheological characteristics of fly ash water slurry using aqueous extract of Diascorea hispida

ABSTRACT Transportation of high-concentration slurry is a specialized field that requires a deep understanding of the rheological behavior of slurry. Fly ash, a fine, powdery residue of pulverized coal combustion in power plants, is transported in pipelines as a slurry with water as a carrier medium and flow-improver additives. The current research aims to compute the rheological properties of the fly ash-water slurry by adding 0.1 to 1 g/mL of Diascorea hispida extract as a natural drag reducer or flow improver. In addition to the effect of D. hispida, other parameters such as temperature, addition of fly ash, and fly ash-bottom ash mixture on the rheological performance of fly ash-water slurry have been investigated. The economic effect of the developed dispersant, D. hispida, has been examined by applying Darby – Melson combined equation by varying the slurry flow rate from 1 m/s to 3 m/s at a fixed 250 mm pipe diameter. The slurry head loss, solids conveying rate, hydraulic power need, and specific power consumption at different .D hispida concentrations were calculated.

Research on manufacturing of precast concrete hollow wall panels using thermoelectric ASH and slag as replacements for natural aggregates

Precast concrete hollow wall panels have emerged as a compelling choice in the construction industry because of their lightweight characteristics, which effectively mitigate structural burdens, coupled with their commendable acoustic and thermal insulation properties. Additionally, their expedited construction process provides a significant advantage over labor-intensive brick wall alternatives. It is noteworthy that the production of these precast concrete panels heavily relies on the utilization of natural aggregates, a practice that has raised concerns, particularly in light of the progressively dwindling reserves of sand resources within our country. Concurrently, there is an escalating volume of ash slag emissions from coal-burning thermal power plants in Vietnam. Therefore, research endeavors aimed at exploring alternative materials, specifically the incorporation of thermal power ash and slag wastes into concrete production for the manufacturing of precast hollow wall panels, assume a dual significance—both from a scientific and practical perspective. These initiatives not only alleviate the strain on our natural aggregate resources but also offer a sustainable solution for managing thermal power wastes, thereby carrying substantial environmental and societal implications. This article presents empirical findings derived from a comprehensive investigation into the integration of thermoelectric ash and slag as substitutes for natural aggregates, encompassing replacement ratios ranging from 70% to 100%, within the production processes of precast concrete hollow wall panels, employing extrusion technology. The results unequivocally demonstrate that with a replacement rate of up to 100% of aggregates with thermoelectric ash and slag, the quality of wall panels using thermoelectric ash slag completely meets the technical requirements according to TCVN 11524:2016 "Wall panels hollow precast concrete using extrusion technology" for use in construction projects.

Evaluation of Using Fly Ash as a Weighing Material for Oil-Based Drilling Fluid.

Innovation and sustainability are essential in the fast-changing oil and gas business. Fly ash, a byproduct of coal combustion in power plants and factories, has become a valuable resource in many industries, changing the concept of waste materials. Fly ash is essential to sustainable development and environmental care due to its unique qualities and multiple applications. In the drilling industry, a well-designed drilling fluid is essential and this requires the use of various additives that serve specific functions to achieve a successful borehole. This study investigates the use of fly ash as a weighing material in oil-based mud, with the intent to develop an economically acceptable drilling fluid system using industrial waste. The study compared fly ash to three commonly used weighing materials in the drilling industry: calcium carbonate (CaCO3), barite (BaSO4), and ilmenite (FeTiO3). Drilling fluids were prepared using these weighing materials at various weights, and their properties (density, electrical stability, rheological features, and filtration properties) were measured using API-recommended methods. The rheology and filtration tests were conducted at elevated temperatures (350 °F). The results indicate that fly ash has the potential to be a useful weighing material in drilling operations. It can increase the fluid density up to 10 ppg without affecting the rheological properties at 350 °F. Additionally, the electrical stability of the drilling fluid was enhanced compared to the other used weighing materials. The addition of fly ash also improved rheological characteristics such as plastic viscosity, yield point, and gel strength without affecting HPHT filtration properties. The carrying capacity was improved by 53 and 86% over calcium carbonate and barite, respectively. Overall, the findings suggest that fly ash can be a viable alternative to other weighing materials in the recommended density range.

A Locally Available Natural Pozzolan as a Supplementary Cementitious Material in Portland Cement Concrete

For several decades, class F fly ash has been an attractive supplementary cementitious material, at least in part, due to its ability to reduce Portland cement consumption and mitigate alkali-silica reactions in concrete. However, fly ash availability is becoming uncertain as the energy industry decommissions coal burning power plants as it transitions to renewable energy production. This situation creates a need to identify viable and sustainable alternative supplementary cementitious materials. There are several types of supplementary cementitious materials, such as natural pozzolans, metakaolin, or ground granulated blast-furnace slag, which appear to be potential alternatives to fly ash in concrete. In this research, a locally available natural pozzolan (pumicite) was selected to replace fly ash in concrete. After conducting alkali-silica reaction tests on mortar mixtures, rheological and strength properties, shrinkage, resistance to freezing and thawing, and chloride ion permeability of concrete mixtures containing different amounts of fly ash and natural pozzolan were evaluated. The results showed that pumicite was more effective than fly ash at mitigating the alkali-silica reaction, and a pumicite content of 20% was necessary to mitigate the alkali-silica reaction. Ternary mixtures containing both pumicite and fly ash were the most effective cementitious materials combinations for mitigating the alkali-silica reaction expansion. Additionally, pumicite provided acceptable compressive strength and modulus of rupture values (greater than 4.0 MPa) that exceeded the flexural strengths provided by established mixtures containing only fly ash. Shrinkage and durability factor values for all mixtures were less than 710 μstrain and greater than 75, which are generally considered acceptable. Additionally, all mixtures with acceptable alkali-silica reaction expansions had very low chloride permeability. These results indicate that pumicite can be a reliable alternative for fly ash.

Winter-time pollution in Central European cities shifts the 208Pb/207Pb isotope ratio of atmospheric PM2.5 to higher values: Implications for lead source apportionment

Atmospheric lead pollution has adverse health effects on humans. Identification of anthropogenic Pb sources is thus crucial for understanding of pollution-related risks and for formulation of efficient abatement strategies. We analyzed concentrations and isotope ratios of Pb in fine air-borne particulate matter (PM2.5) in three Central European cities. Aerosol sampling in 12-h intervals was performed during summer and winter in Hradec Králové, Olomouc and Brno, regional centers of highly industrialized Czech Republic, each with a population of more than 90 thousand. Lead analysis was complemented with concentration measurements of Zn, Cu, Cd, As, Sb, and S. Trace element and PM2.5 concentrations were higher in winter than in summer in all studied cities, on average by 47%. The overall mean concentration of PM2.5 in urban air was 21 μg m−3, similar to that in Bern (Switzerland) and Vienna (Austria). Across the sites, 206Pb/207Pb ratios ranged from 1.142 to 1.178 in summer and from 1.143 to 1.173 in winter. The mean 206Pb/207Pb ratios were statistically indistinguishable in all three studied cities (1.165 in Hradec Králové, 1.163 in Olomouc, and 1.160 in Brno). In the 206Pb/207Pb vs.208Pb/207Pb graph, Pb isotope composition of summer samples formed a straight line, whereas Pb isotope composition of winter samples was shifted toward higher 208Pb/207Pb ratios. A Pb isotope inventory of regional pollution sources indicated that winter-time Pb pollution was not caused solely by household heating and increased electricity production in coal-burning power plants. Recycling of industrial Pb originating from Variscan ores and waste incineration could have shifted the 208Pb/207Pb ratio of PM2.5 to higher values, however, such sources do not emit more Pb in winter than in summer. Remobilization of legacy alkyl-Pb from gasoline additives and Pb emissions from current unleaded gasoline and diesel could have shifted both Pb isotope ratios to lower values.

Determination of concentrations of Sr and Ba in coal and coal combustion by-products: A comparison between results by ICP-MS and XRF techniques

Concentrations of trace elements in coal and coal combustion products are commonly analyzed by inductively coupled plasma-mass spectrometry (ICP-MS) due to large number of elements detected and the relatively the low detection limits of this technique. Like other geological samples, complete dissolution of coal and coal combustion products is also essential for accurate ICP-MS results. In this study, Sr and Ba in coal and coal combustion products (fly and bottom ashes) from two coal-combustion power plants from North China analyzed by XRF and ICP-MS were comparatively studied. The concentrations of Sr and Ba analyzed by ICP-MS, when a mixture of acids (2 ml HF + 5 ml HNO3 for each 50 mg coal sample and 5 ml HF + 2 ml HNO3 for each 50 mg ash sample) was used for microwave-assisted digestion, do not fit well with the their relative XRF results. This is most probably due to the formation of the fluorides during microwave digestion, and this assumption is supported by the presence of various fluoride compounds, NaMgAl(F, OH)6·H2O, NH4MgAlF6, AlF3, and K2SiF6, in the residues of all the coal and ash samples in our sequential extraction experiment. Cations of Sr and Ba were probably trapped into the divalent cation sites of the fluorides. Concentrations of Sr and Ba analyzed by ICP-MS using increased HF and HF/HNO3 ratio (7 ml HF and 2 ml HNO3 for each 50 mg coal/ash sample) are in better agreement with the XRF results. Our results indicate that excess amount of HF probably has led to the suppression of these elements due to fluoride precipitation. The results indicate that the modified digestion method is capable of achieving complete digestion of coal samples and results in a reliable analysis of Sr and Ba concentrations in coal samples and most fly ashes by ICP-MS. However, the formation of insoluble fluorides is probably not completely suppressed for some bottom ash samples, which can result in underestimation of Sr and Ba concentrations. Nevertheless, XRF analysis can serve as a reliable cross-check method to assist in the evaluation of the accuracy of ICP-MS results.

Evaluating Properties of Blended and High Volume Fly Ash Bottom Ash (FABA) Concrete in Peat Water

FABA is a by-product of coal combustion in power plants comprising fly ash (FA) and bottom ash (BA) in ratios of 80/20. Fly ash has great potential as a mineral ingredient in concrete, while bottom ash compromises its strength and durability. However, both materials are used to improve the strength and durability of structures in sulfate, chloride, and acidic environments. This research evaluated the properties of blended and high-volume FABA concrete, such as the strength, porosity, weight loss, and sorptivity in organic acidic peat water. OPC (Ordinary Portland Cement) was compared to the blended concrete containing 25% FABA and its high-volume containing 50% and 75% FABA with target strengths of 15, 21, and 29 MPa. The compressive strength of blended and high volume FABA increased during the immersion period, while the porosity and sorptivity rates decreased. Furthermore, the strength of the OPC concrete declined at 28 days, with a gradual marginal weight loss of 5% observed in all mixes. This research suggested that blended and high-volume FABA has potential as a construction material in an acidic peatland environment.

High contribution of vehicular exhaust and coal combustion to PM2.5-bound Pb pollution in an industrial city in North China: An insight from isotope

Although industrial emissions are the major pollution source of PM2.5-bound Pb, which affects air quality in cities, their influence has gradually decreased with the enhancement of industrial control in recent years. Thus, at present, the source of PM2.5-bound Pb is unclear, especially in an industrial city in North China. In this study, by incorporating the stable Pb isotopic compositions into a Bayesian isotope mixing model (MixSIAR), source apportionment of PM2.5-bound Pb was conducted during autumn and winter in 2017, and summer in 2018 in Changzhi. The daily average concentrations of PM2.5 and PM2.5-bound Pb during the study period were lower than the second-grade limit value of China (75 μg m−3) and the Chinese National Ambient Air Quality Standard (1 μg m−3), respectively. The pollution sources of PM2.5-bound Pb were fully distinguishable using Pb isotopes. In Changzhi, the 206Pb/207Pb ratio in soil (average: 1.0891) and exhaust dust from gasoline (average: 1.0832) and diesel (average: 1.0814) showed low levels of Pb isotope signature in Changzhi, whereas the rest of the source exhibited Pb isotope signature levels. The source apportionment results revealed that in an industrial city with many steel and coking plants, the primary source of PM2.5-bound Pb were motor vehicle emission (29.7%) and coal combustion (26.9%), rather than industrial emission (26.5%). Moreover, seasonal variations in PM2.5 of Pb sub-sources were observed: soil dust (21.7% and 18.4%) and diesel motor vehicles emission (16.4% and 15.6%) in summer and autumn; domestic coal combustion (17.1%) and coal-fired power plant emission (15.5%) in winter. The carcinogenic risk from motor vehicle emission in autumn was higher than that from industrial and coal sources in winter, and higher than that from motor vehicle sources in summer. This finding is a critical evidence of an anomalistic enrichment of PM2.5-bound Pb in an industrial city. These results obtained through Pb isotopic composition and MixSIAR model also improved the accuracy of source apportionment of atmospheric PM2.5-bound Pb, representing a high scientific significance and reference value for Pb pollution control in North China.