ABSTRACT This study investigates the air oxidation and rusting traits of fully austenitic alloy 254 stainless steel samples at 700°C after pulse current gas tungsten arc welding (PCGTA) and CO2 laser beam welding (CO2 LBW), with or without molten salt, relevant to coal-fired plants and waste incinerator settings. Among the weldments studied, CO2 laser weldments demonstrate greater resilience to corrosive gas and salt amalgamation, as well as air oxidation, compared to gas tungsten arc weldments, possibly due to thermal disparities and microstructural differences inherent in the welding processes. Protective oxides enhance corrosion resistance in air-oxidised samples, while corrosive compounds like CrS, Cr2K2O7, etc., reduce corrosion resistance and promote spallation in salt-degraded material. A thermogravimetric approach was used to assess rusting effects, alongside microstructural analysis employing optical, Scanning electron microscopy/ Energy dispersive x-ray spectroscopy (SEM/EDS), and X-Ray diffraction analysis (XRD) techniques.
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