CO2 Ice Research Articles

Infrared free-electron laser irradiation of carbon dioxide ice

Interstellar ice grains are believed to play a key role in the formation of many of the simple and complex organic species detected in space. However, many fundamental questions on the physicochemical processes linked to the formation and survival of species in ice grains remain unanswered. Field work at large-scale facilities such as free-electron lasers (FELs) can aid the investigation of the composition and morphology of ice grains by providing novel tools to the laboratory astrophysics community. We combined the high tunability, wide infrared spectral range and intensity of the FEL beam line FELIX-2 at the HFML-FELIX Laboratory in The Netherlands with the characteristics of the ultrahigh vacuum LISA end station to perform wavelength-dependent mid-IR irradiation experiments of space-relevant pure carbon dioxide (CO2) ice at 20 K. We used the intense monochromatic radiation of FELIX to inject vibrational energy at selected frequencies into the CO2 ice to study ice restructuring effects in situ by Fourier Transform Reflection–Absorption Infrared (FT-RAIR) spectroscopy. This work improves our understanding of how vibrational energy introduced by external triggers such as photons, electrons, cosmic rays, and thermal heating coming from a nascent protostar or field stars is dissipated in an interstellar icy dust grain in space. Moreover, it adds to the current literature debate concerning the amorphous and polycrystalline structure of CO2 ice observed upon deposition at low temperatures, showing that, under our experimental conditions, CO2 ice presents amorphous characteristics when deposited at 20 K and is unambiguously crystalline if deposited at 75 K.

Mid-IR and VUV spectroscopic characterisation of thermally processed and electron irradiated CO2 astrophysical ice analogues

The astrochemistry of CO2 ice analogues has been a topic of intensive investigation due to the prevalence of CO2 throughout the interstellar medium and the Solar System, as well as the possibility of it acting as a carbon feedstock for the synthesis of larger, more complex organic molecules. In order to accurately discern the physico-chemical processes in which CO2 plays a role, it is necessary to have laboratory-generated spectra to compare against observational data acquired by ground- and space-based telescopes. A key factor which is known to influence the appearance of such spectra is temperature, especially when the spectra are acquired in the infrared and ultraviolet. In this present study, we describe the results of a systematic investigation looking into: (i) the influence of thermal annealing on the mid-IR and VUV absorption spectra of pure, unirradiated CO2 astrophysical ice analogues prepared at various temperatures, and (ii) the influence of temperature on the chemical products of electron irradiation of similar ices. Our results indicate that both mid-IR and VUV spectra of pure CO2 ices are sensitive to the structural and chemical changes induced by thermal annealing. Furthermore, using mid-IR spectroscopy, we have successfully identified the production of radiolytic daughter molecules as a result of 1 keV electron irradiation and the influence of temperature over this chemistry. Such results are directly applicable to studies on the chemistry of interstellar ices, comets, and icy lunar objects and may also be useful as reference data for forthcoming observational missions.

A Geoscientific Review on CO and CO2 Ices in the Outer Solar System

Ground-based telescopes and space exploration have provided outstanding observations of the complexity of icy planetary surfaces. This work presents our review of the varying nature of carbon dioxide (CO2) and carbon monoxide (CO) ices from the cold traps on the Moon to Pluto in the Kuiper Belt. This review is organized into five parts. First, we review the mineral physics (e.g., rheology) relevant to these environments. Next, we review the radiation-induced chemical processes and the current interpretation of spectral signatures. The third section discusses the nature and distribution of CO2 in the giant planetary systems of Jupiter and Saturn, which are much better understood than the satellites of Uranus and Neptune, discussed in the subsequent section. The final sections focus on Pluto in comparison to Triton, having mainly CO, and a brief overview of cometary materials. We find that CO2 ices exist on many of these icy bodies by way of magnetospheric influence, while intermixing into solid ices with CH4 (methane) and N2 (nitrogen) out to Triton and Pluto. Such radiative mechanisms or intermixing can provide a wide diversity of icy surfaces, though we conclude where further experimental research of these ices is still needed.

SHARAD Observations of Temporal Variations of CO2 Ice Deposits at the South Pole of Mars

Mars’s polar regions are covered by kilometers-thick layered deposits which carry a record of the planet’s climate history. The deposition and volatilization of the shallow CO2 deposits in the south pole have a large impact on the planet’s atmosphere and environment. This research focuses on the timing variation of the thickness of the shallow deposits based on the SHARAD data collected from the past 11 terrestrial years, and analysis of the contributing factors based on the volatilization and deposition mechanisms of surface and subsurface materials. In this work, we selected more than four thousand data points, covering several seasons and Martian years, to extract radar echoes and calculate the thickness changes in the subsurface layer over time. We found that the thickness of the CO2 layer becomes thinner in the summer, with seasonal variation in the range of ~16–45 m. The thickness variations have a Gaussian-like distribution and do not increase with the distance between the compared node pair, implying that the phenomenon is not caused by regional differences. The overall thickness within the 11 terrestrial years does not show a clear trend of thickening or thinning, indicating a moderate vertical change of the southern deposits.

A CO2 Cycle on Ariel? Radiolytic Production and Migration to Low-latitude Cold Traps

Abstract CO2 ice is present on the trailing hemisphere of Ariel but is mostly absent from its leading hemisphere. The leading/trailing hemispherical asymmetry in the distribution of CO2 ice is consistent with radiolytic production of CO2, formed by charged particle bombardment of H2O ice and carbonaceous material in Ariel’s regolith. This longitudinal distribution of CO2 on Ariel was previously characterized using 13 near-infrared reflectance spectra collected at “low” sub-observer latitudes between 30°S and 30°N. Here we investigated the distribution of CO2 ice on Ariel using 18 new spectra: 2 collected over low sub-observer latitudes, 5 collected at “mid” sub-observer latitudes (31°N–44°N), and 11 collected over “high” sub-observer latitudes (45°N–51°N). Analysis of these data indicates that CO2 ice is primarily concentrated on Ariel’s trailing hemisphere. However, CO2 ice band strengths are diminished in the spectra collected over mid and high sub-observer latitudes. This sub-observer latitudinal trend may result from radiolytic production of CO2 molecules at high latitudes and subsequent migration of this constituent to low-latitude cold traps. We detected a subtle feature near 2.13 μm in two spectra collected over high sub-observer latitudes, which might result from a “forbidden” transition mode of CO2 ice that is substantially stronger in well-mixed substrates composed of CO2 and H2O ice, consistent with regolith-mixed CO2 ice grains formed by radiolysis. Additionally, we detected a 2.35 μm feature in some low sub-observer latitude spectra, which might result from CO formed as part of a CO2 radiolytic production cycle.

Quantification of O2 formation during UV photolysis of water ice: H2O and H2O:CO2 ices

Context. The Rosetta and Giotto missions investigated the composition of the cometary comae of 67P/Churyumov-Gerasimenko and 1P/Halley, respectively. In both cases, a surprisingly large amount of molecular oxygen (O2) was detected and was well correlated with the observed abundances of H2O. Laboratory experiments simulating chemical processing for various astronomical environments already showed that formation of solid state O2 is linked to water. However, a quantitative study of O2 formation upon UV photolysis of pure H2O and H2O dominated interstellar ice analogues is still missing. Aims. The goal of this work is to investigate whether the UV irradiation of H2O-rich ice produced at the earliest stages of star formation is efficient enough to explain the observed abundance of cometary O2. Methods. The photochemistry of pure H216O (H218O) as well as mixed H2O:CO2 (ratio of 100:11, 100:22, 100:44) and H2O:CO2:O2 (100:22:2) ices was quantified during UV photolysis. Laser desorption post-ionisation time of flight mass spectrometry (LDPI TOF MS) was used to probe molecular abundances in the ice as a function of UV fluence. Results. Upon UV photolysis of pure amorphous H2O ice, deposited at 20 K, formation of O2 and H2O2 is observed at abundances of, respectively, (0.9 ± 0.2)% (O2/H2O) and (1.3 ± 0.3)% (H2O2/H2O). To the best of our knowledge, this is the first quantitative characterisation of the kinetics of this process. During the UV photolysis of mixed H2O:CO2 ices, the formation of the relative amount of O2 compared to H2O increases to a level of (1.6 ± 0.4)% (for H2O:CO2 ratio of 100:22), while the (H2O2/H2O) yield remains similar to experiments with pure water. In an ice enriched with O2 (2%), the O2 level increases up to 7% with regard to H2O, at low UV fluence, which is higher than expected on the basis of the enrichment alone. The resulting O2/H2O values derived for the H2O and H2O:CO2 ices may account for a (substantial) part of the high oxygen amounts found in the comae of 67P and 1P.

Strong Spatial Aggregation of Martian Surface Temperature Shaped by Spatial and Seasonal Variations in Meteorological and Environmental Factors

Spatio-temporal variation in the Martian surface temperature (MST) is an indicator of ground level thermal processes and hence a building block for climate models. However, the distribution of MST exhibits different levels of spatial aggregation or heterogeneity, and varies in space and time. Furthermore, the effect of regional differences in meteorological or environmental factors on the MST is not well understood. Thus, we investigated the degree of spatial autocorrelation of MST across the surface of Mars globally by Moran’s I, and identified the hot spots by GetisOrd . We also estimated the regional differences in the influence of seasonally dominant factors including thermal inertia (TI), albedo, surface pressure, latitude, dust and slope on MST by a geographically weighted regression model. The results indicate (1) that MST is spatially aggregated and hot and cold spots varied over time and space. (2) Hemispheric differences in topography, surface TI and albedo were primarily responsible for the hemispheric asymmetry of hot spots. (3) The dominant factors varied by geographical locations and seasons. For example, the seasonal Hadley circulation dominates at the low-latitudes and CO2 circulation at the high-latitudes. (4) Regions with extreme variations in topography and low TI were sensitive to meteorological and environmental factors such as dust and CO2 ice. We conclude that the spatial autocorrelation of MST and the spatial and seasonal heterogeneity of influencing factors must be considered when simulating Martian climate models. This work provides a reference for further exploration of Martian climatic processes.

Photolytic insertion of carbon monoxide into nitrosyl chloride: formation of nitrosoformyl chloride.

Nitrosocarbonyls are exotic intermediates that remain scarcely characterized. By UV photolysis (365 nm) of nitrosyl chloride (ClNO) embedded in solid CO ice at 20 K, the elusive nitrosoformyl chloride (ClC(O)NO) has been synthesized via CO-insertion into the Cl-N bond in ClNO. The characterization of ClC(O)NO with matrix-isolation IR spectroscopy is supported by 13C and 15N isotope labeling and quantum chemical calculations at the B3LYP/6-311+G(3df) level of theory. Upon subsequent laser irradiation at 266 nm, CO-elimination in ClC(O)NO occurs by reformation of ClNO. In line with the calculated potential energy surface for ClC(O)NO at the CCSD(T)-F12a/aug-cc-pVTZ//B3LYP/6-311+G(3df) level, the observed IR frequencies and the corresponding isotopic shifts coincide with the calculated values for the lowest-energy planar conformer, in which the CO and NO moities adopt trans configuration with respect to the C-N bond. Furthermore, the CO-insertion in ClNO involves a stepwise pathway by first homolytic cleavage of the Cl-N bond in ClNO (→ Cl˙ + ˙NO), followed by successive CO-trapping (CO + Cl˙ → ClCO˙) and radical combination (ClCO˙ + ˙NO → ClC(O)NO) inside the solid CO-matrix cages.

The rise time of the change of cometary brightness during its outburst

The paper presents a new method for determining the change in the brightness of a comet during an outburst in which particles are ejected into the coma at a uniform rate, i.e. via a long-lived jet. In the proposed approach, the mass flow rate by a jet and the time it takes to increase the brightness of the comet play key roles. Absolute values adopted for H2O ice and CO2 ice were taken from measurements by Rosetta of the jets observed on 67P/Churyumov–Gerasimenko. These two parameters significantly affect the amplitude of the change in the brightness of a comet during its outburst. The performed numerical calculations concern a hypothetical comet from the Jupiter family for which it was assumed that its sublimation activity was controlled by the sublimation of water ice and carbon dioxide. Based on numerical simulations, it was shown that the difference between the change in brightness for H2O ice and CO2 ice is about −3.4 magnitude for the same fraction of the area that is active and the same mass flow rate. This value corresponds to the rise time of the amplitude of the brightness change t = 3 h. In addition, it should be emphasized that this difference is a consequence of thermodynamic parameters, such as the speed of sublimating gas molecules, the sublimation rate of given ice, which determine the numerical values of the individual scattering cross-sections C(t1) and C(t2).

On the synthesis of N–O bearing species in astrophysical ices – an infrared spectroscopic study using heavy-ion irradiation of solid N2:CO samples

ABSTRACT The interstellar chemistry of nitrogen is considerably less understood than the chemistry of other common elements, such as carbon and oxygen. Even though a relatively large number of species containing nitrogen atoms have already been detected in the interstellar medium, only six of them bear a nitrogen–oxygen (N–O) bond. Some astrophysical and primeval Earth models suggest that N–O species, such as hydroxylamine (NH2OH), are potential precursors of prebiotic amino acids, and even peptides. In this work, we have analyzed an apolar ice mixture of N2:CO of astrophysical interest to investigate possible formation mechanisms of N–O bearing molecules due to processing of the sample by 64Ni24+ 538 MeV ions (8.4 MeV/u) at 14 K. The results show the formation of simple nitrogen oxides ($\rm {N_{1 - 2}}{O_y})$, but no CN–O species of any kind. We have also determined the formation cross-sections of some of the products, as well as the destruction cross-sections of precursors and products. The results presented here are discussed in light of our previous work on the processing of a NH3:CO ice mixture, which have found no N–O bearing molecules at all.

Simulation of Martian Dust Effects on Polar CO2 Ice Caps and Atmospheric Circulation Using the MarsWRF Model

AbstractMartian dust plays an important role in modulating climate. However, the effects of dust on polar CO2 ice caps, atmospheric circulation processes and the relationship between them are not yet clear. In this study, a Mars general circulation model (MarsWRF) was applied to investigate the impacts of the magnitude and timing of Martian dust storms on the spatiotemporal characteristics of polar CO2 ice caps and atmospheric circulation. The results show that dust can inhibit the sublimation of southern CO2 ice through the radiation effect. Under the “High Dust” scenario, the ice edge can extend up to 5° more equatorward than that under the “Standard” scenario around Ls = 220°. The extent of northern CO2 ice cap is hardly affected by dust because the impacts induced by dust mainly appear north of 80°N. By shifting the timing of maximum dust loading during the dust season, the "Early Dust" scenario inhibits the sublimation of the southern ice cap, while the "Late Dust" scenario accelerates the sublimation process. In addition, the variations in dust loading strength can lead to changes in three near‐surface wind belts, which are related to intensified Hardly circulation. The appearance of the warming vortex under the "Early Dust" scenario is delayed, and its intensity is 60 K lower than that observed in the "High Dust" and "Late Dust" scenarios. When dust loading increases, the northern CO2 condensation process in the Western Hemisphere accelerates, which is due to the increased pole‐to‐equator temperature gradient and the increased meridional wind speed.

CO2-ice Collisions: A New Experimental Approach

Abstract The coagulation of micrometer-sized particles marks the beginning of planet formation. For silicates a comprehensive picture already exists, which describes under which conditions growth can take place and which barriers must be overcome. With increasing distance to the central star volatiles freeze out and the collision dynamics is governed by the properties of the frozen volatiles. We present a novel experiment facility to analyze collisions of CO2 agglomerates consisting of micrometer-sized particles with agglomerate sizes up to 100 μm. Experiments are conducted at temperatures around 100 K with collision velocities up to 3.4 m s−1. Below impact velocities of around 0.1 m s−1 sticking is observed and at collision velocities of 1 m s−1 fragmentation also starts to occur. The experiments show that agglomerates of CO2 ice behave like silicate agglomerates with a comparable grain size distribution. Models developed to describe the collision dynamics of silicate dust can be applied to CO2 ice. This holds for the coefficient of restitution as well as for the threshold conditions for the transitions between sticking, bouncing, or fragmentation.

Modelling the water and carbon dioxide production rates of Comet 67P/Churyumov–Gerasimenko

ABSTRACT The European Space Agency Rosetta/Philae mission to Comet 67P/Churyumov–Gerasimenko in 2014–2016 is the most complete and diverse investigation of a comet carried out thus far. Yet, many physical and chemical properties of the comet remain uncertain or unknown, and cometary activity is still not a well-understood phenomenon. We here attempt to place constraints on the nucleus abundances and sublimation front depths of H2O and CO2 ice, and to reconstruct how the nucleus evolved throughout the perihelion passage. We employ the thermophysical modelling code ‘Numerical Icy Minor Body evolUtion Simulator’, or nimbus, to search for conditions under which the observed H2O and CO2 production rates are simultaneously reproduced before and after perihelion. We find that the refractories to water–ice mass ratio of relatively pristine nucleus material is μ ≈ 1, that airfall material has μ ≈ 2, and that the molar abundance of CO2 relative H2O is near 30 per cent. The dust mantle thickness is typically $\lesssim 2\, \mathrm{cm}$. The average CO2 sublimation front depths near aphelion were $\sim 3.8\, \mathrm{m}$ and $\sim 1.9\, \mathrm{m}$ on the northern and southern hemispheres, respectively, but varied substantially with time. We propose that airfall material is subjected to substantial fragmentation and pulverization due to thermal fatigue during the aphelion passage. Sub-surface compaction of material due to CO2 activity near perihelion seems to have reduced the diffusivity in a measurable way.

Molecules with ALMA at Planet-forming Scales (MAPS). VII. Substellar O/H and C/H and Superstellar C/O in Planet-feeding Gas

Abstract The elemental composition of the gas and dust in a protoplanetary disk influences the compositions of the planets that form in it. We use the Molecules with ALMA at Planet-forming Scales (MAPS) data to constrain the elemental composition of the gas at the locations of potentially forming planets. The elemental abundances are inferred by comparing source-specific gas-grain thermochemical models with variable C/O ratios and small-grain abundances from the DALI code with CO and C2H column densities derived from the high-resolution observations of the disks of AS 209, HD 163296, and MWC 480. Elevated C/O ratios (∼2.0), even within the CO ice line, are necessary to match the inferred C2H column densities over most of the pebble disk. Combined with constraints on the CO abundances in these systems, this implies that both the O/H and C/H ratios in the gas are substellar by a factor of 4–10, with the O/H depleted by a factor of 20–50, resulting in the high C/O ratios. This necessitates that even within the CO ice line, most of the volatile carbon and oxygen is still trapped on grains in the midplane. Planets accreting gas in the gaps of the AS 209, HD 163296, and MWC 480 disks will thus acquire very little carbon and oxygen after reaching the pebble isolation mass. In the absence of atmosphere-enriching events, these planets would thus have a strongly substellar O/H and C/H and superstellar C/O atmospheric composition. This paper is part of the MAPS special issue of the Astrophysical Journal Supplement.

Carbon Dioxide Cold Traps on the Moon

AbstractWater ice is expected to be trapped in permanently cold regions near the lunar poles. Other ices (“super‐volatiles”) are trapped at lower temperatures, close to the lowest temperatures measured within the lunar permanently shadowed regions (PSRs). Here, the thermal stability of solid carbon dioxide in the south polar region is determined by analysis of 11 years of temperature measurements by Diviner, a radiometer onboard the Lunar Reconnaissance Orbiter. Sublimation rates averaged over a draconic year are far lower than peak sublimation rates. Small spatially contiguous pockets of CO2 ice stability are found in the craters Amundsen, Haworth, de Gerlache, and others, over a cumulative area of roughly 200 km2. The LCROSS probe impacted one of those pockets and released CO2, serving as validation of the thermal stability calculations. Future surface missions can utilize this highly localized resource for the production of fuel, steel, and biological materials.

Radiolytic Destruction of Uracil in Interstellar and Solar System Ices.

Uracil is one of the four RNA nucleobases and a component of meteoritic organics. If delivered to the early Earth, uracil could have been involved in the origins of the first RNA-based life, and so this molecule could be a biomarker on other worlds. Therefore, it is important to understand uracil's survival to ionizing radiation in extraterrestrial environments. Here we present a study of the radiolytic destruction kinetics of uracil and mixtures of uracil diluted in H2O or CO2 ice. All samples were irradiated by protons with an energy of 0.9 MeV, and experiments were performed at 20 and 150 K to determine destruction rate constants at temperatures relevant to interstellar and Solar System environments. We show that uracil is destroyed much faster when H2O ice or CO2 ice is present than when these two ices are absent. Moreover, destruction is faster for CO2-dominated ices than for H2O-dominated ones and, to a lesser extent, at 150 K compared with 20 K. Extrapolation of our laboratory results to astronomical timescales shows that uracil will be preserved in ices with half-lives of up to ∼107 years on cold planetary bodies such as comets or Pluto. An important implication of our results is that for extraterrestrial environments, the application of laboratory data measured for the radiation-induced destruction of pure (neat) uracil samples can greatly underestimate the molecule's rate of destruction and significantly overestimate its lifetime, which can lead to errors of over 1000%.

Decomposition of the CO stretching vibration band of laboratory H2O-CO ices irradiated by heavy ions

Abstract H2O and CO molecules are the main constituents of the interstellar dust grain ice mantles. Infrared spectra of the ices in line of sights of young stellar objects and background stars have shown that the CO stretching vibration band can be decomposed into three main components: 2143, 2139 and 2136 cm−1, assigned to CO in different environment sites. The relative strengths between the components have been associated to an evolutionary track of the interstellar molecular clouds. H2O:CO (3:2) and (10:1) ices samples were irradiated by 0.79 MeV/u 58Ni13 + ions to simulate the effects produced by heavy ion cosmic rays in typical interstellar ices mixtures. The CO stretching vibration band is decomposed into six Gaussians functions (2150, 2144, 2141, 2138, 2136 and 2133 cm−1) and their integrated absorbances were measured as a function of fluence. The results have shown that, at the final fluence, the component 2138 cm−1 is the main component of the CO stretching vibration band. The component 2150 cm−1 disappears at the beginning of irradiation. Based on the present and previous results, a time scale for the components in the interstellar ices is proposed. For H2O:CO ice in the ISM it is predicted that, after 1 Myrs, the main components of the CO stretching vibration band are the 2138 cm−1 and 2141 cm−1, due to the CO monomers and dimers, respectively.

Impact of size-dependent grain temperature on gas-grain chemistry in protoplanetary disks: The case of low-mass star disks

Context. Grain surface chemistry is fundamental to the composition of protoplanetary disks around young stars. Aims. The temperature of grains depends on their size. We evaluate the impact of this temperature dependence on the disk chemistry. Methods. We modeled a moderately massive disk with 16 different grain sizes. We used the 3D Monte Carlo POLARIS code to calculate the dust grain temperatures and the local uv flux. We modeled the chemistry using the three-phase astrochemical code NAUTILUS. Photo processes were handled using frequency-dependent cross sections and a new method to account for self and mutual shielding. The multi-grain model outputs are compared to those of single-grain size models (0.1 μm); there are two different assumptions for their equivalent temperature. Results. We find that the Langmuir-Hinshelwood mechanism at equilibrium temperature is not efficient to form H2 at 3–4 scale heights (H), and we adopt a parametric fit to a stochastic method to model H2 formation instead. We find the molecular layer composition (1–3 H) to depend on the amount of remaining H atoms. Differences in molecular surface densities between single and multi-grain models are mostly due to what occurs above 1.5 H. At 100 au, models with colder grains produce H2O and CH4 ices in the midplane, and those with warmer grains produce more CO2 ices; both of these allow for an efficient depletion of C and O as soon as CO sticks on grain surfaces. Complex organic molecules production is enhanced by the presence of warmer grains in the multi-grain models. Using a single-grain model mimicking grain growth and dust settling fails to reproduce the complexity of gas-grain chemistry. Conclusions. Chemical models with a single-grain size are sensitive to the adopted grain temperature and cannot account for all expected effects. A spatial spread of the snowlines is expected to result from the ranges in grain temperature. The amplitude of the effects depends on the dust disk mass.

Simulating Observations of Ices in Protoplanetary Disks

Abstract Ices are an important constituent of protoplanetary disks. New observational facilities, notably the James Webb Space Telescope (JWST), will greatly enhance our view of disk ices by measuring their infrared spectral features. We present a suite of models to complement these upcoming observations. Our models use a kinetics-based gas–grain chemical evolution code to simulate the distribution of ices in a disk, followed by a radiative transfer code using a subset of key ice species to simulate the observations. We present models reflecting both molecular inheritance and chemical reset initial conditions. We find that near-to-mid-IR absorption features of H2O, CO2, and CH3OH are readily observable in disk-integrated spectra of highly inclined disks while CO, NH3, and CH4 ice do not show prominent features. CH3OH ice has low abundance and is not observable in the reset model, making this species an excellent diagnostic of initial chemical conditions. CO2 ice features exhibit the greatest change over disk lifetime, decreasing and increasing for the inheritance and reset models, respectively. Spatially resolved spectra of edge-on disks, possible with JWST's integral field unit observing modes, are ideal for constraining the vertical distribution of ices and may be able to isolate features from ices closer to the midplane (e.g., CO) given sufficient sensitivity. Spatially resolved spectra of face-on disks can trace scattered-light features from H2O, CO2, and CH3OH, plus CO and CH4 from the outermost regions. We additionally simulate far-IR H2O ice emission features and find they are strongest for disks viewed face-on.

Seasonal seismic activity on Mars

The rate of occurrence of High Frequency (HF) marsquakes, as recorded by InSight at Homestead Hollow, Elysium Planitia, increased after about LS=33∘, and ceased almost completely by LS=187∘, following an apparently seasonal variation with a peak rate near aphelion. We define seismic rate models based on the declination of the Sun, annual solar tides, and the annual CO2 cycle as measured by atmospheric pressure. Evaluation of Akaike weights and evidence ratios shows that the declination of the Sun is the most likely, and the CO2 cycle the least likely driver of this seismic activity, although the discrimination is weak, and the occurrence of a few events in August 2020 is in favor for a triggering by CO2 ice load. We also show that no periodicity related to Phobos' orbit is present in the HF event sequence. Event rate forecasts are presented to allow further discrimination of candidate mechanisms from future observations.