Tb3+/Eu3+co-doped sodium nepheline transparent glass ceramics with the weight percentage composition of 27Na2O-19Al2O3-23SiO2-13H3BO3-6TiO2-6ZrO2-3Tb4O7-3Eu2O3were prepared by melting crystallization method. The heat treatment system, crystal phase, micromorphology, transmittance and luminescent properties of the samples were tested and characterized by DSC, XRD, SEM, UV-Vis-NIR and fluorescence spectrometer, respectively. The results show that the optimum heat treatment condition of glass at 480°C nucleated 1h and 580°C grew 1h., the crystal phase was NaAlSiO4(35-0424), and the incorporation of rare earth ions did not affect the crystal phase. The transmittance of glass ceramics in the visible area can reach 78%. The effect of different Tb3+/Eu3+doping concentration on the luminescent properties of glass ceramic samples was discussed. It was found that there was a phenomenon of Tb3+to Eu3+energy transfer, and the luminescence effect was best when the percentage of mass of Tb3+/Eu3+was 1:1.