CO Column Density Research Articles

Carbon fractionation in photo-dissociation regions

We upgraded the chemical network from the UMIST Database for Astrochemistry 2006 to include isotopes such as ^{13}C and ^{18}O. This includes all corresponding isotopologues, their chemical reactions and the properly scaled reaction rate coefficients. We study the fractionation behavior of astrochemically relevant species over a wide range of model parameters, relevant for modelling of photo-dissociation regions (PDRs). We separately analyze the fractionation of the local abundances, fractionation of the total column densities, and fractionation visible in the emission line ratios. We find that strong C^+ fractionation is possible in cool C^+ gas. Optical thickness as well as excitation effects produce intensity ratios between 40 and 400. The fractionation of CO in PDRs is significantly different from the diffuse interstellar medium. PDR model results never show a fractionation ratio of the CO column density larger than the elemental ratio. Isotope-selective photo-dissociation is always dominated by the isotope-selective chemistry in dense PDR gas. The fractionation of C, CH, CH^+, and HCO^+ is studied in detail, showing that the fractionation of C, CH and CH^+ is dominated by the fractionation of their parental species. The light hydrides chemically derive from C^+, and, consequently, their fractionation state is coupled to that of C^+. The fractionation of C is a mixed case depending on whether formation from CO or HCO^+ dominates. Ratios of the emission lines of [C II], [C I], ^{13}CO, and H^{13}CO^+ provide individual diagnostics to the fractionation status of C^+, C, and CO.

GAS AND DUST ABSORPTION IN THE DoAr 24E SYSTEM

We present findings for DoAr 24E, a binary system that includes a classical infrared companion. We observed the DoAr 24E system with the Spitzer Infrared Spectrograph (IRS), with high-resolution, near-infrared spectroscopy of CO vibrational transitions, and with mid-infrared imaging. The source of high extinction toward infrared companions has been an item of continuing interest. Here we investigate the disk structure of DoAr 24E using the column densities, temperature, and velocity profiles of two CO absorption features seen toward DoAr 24Eb. We model the SEDs found using T-ReCS imaging, and investigate the likely sources of extinction toward DoAr 24Eb. We find the lack of silicate absorption and small CO column density toward DoAr 24Eb suggest the mid-infrared continuum is not as extinguished as the near-infrared, possibly due to the mid-infrared originating from an extended region. This, along with the velocity profile of the CO absorption, suggests the source of high extinction is likely due to a disk or disk wind associated with DoAr 24Eb.

Usability of optical spectrum analyzer in measuring atmospheric CO<sub>2</sub> and CH<sub>4</sub> column densities: inspection with FTS and aircraft profiles in situ

Abstract. The practical usefulness of a desktop optical spectrum analyzer (OSA) for measuring atmospheric CO2 and CH4 column densities at surface sites was examined in two separate measurement campaigns. The first comparison involved operating the OSA in parallel with a high resolution Fourier transform spectroscopy (FTS) situated at the University of Wollongong in Australia. Scale factors for the OSA were assigned for the column average volume mixing ratios of xCO2 and xCH4 by comparing with the well-studied FTS. The second method is a calibration against aircraft CO2 profiles in situ over Tsukuba in Japan obtained during a GOSAT validation campaign carried out from 28 January to 7 February 2011. The xCO2 values in the campaign, deduced by use of a derived OSA scale factor, were in excellent agreement with the integrated aircraft profiles.

Revealing the Physical Properties of GMC Complexes in the Spiral Arms of NGC 6946

AbstractIn this study, we probe for the first time the molecular gas physical properties of several star forming regions located in the arms and inter-arms of the spiral galaxy NGC 6946. Combining our observations with additional data found in the literature, we provide in this study the most complete CO ladder ever obtained in these inter-arm and arm regions, i.e. the CO(1-0, 2-1, 3-2, 4-3, 6-5) and 13CO(1-0, 2-1) transitions. For each region studied, we use more precisely the large velocity gradient (LVG) assumption in order to derive the beam-averaged molecular gas physical properties. Namely, we obtained the gas kinetic temperature (i.e. 'best' TK), volume number gas density (i.e. 'best' n(H2)) and CO column density (i.e. 'best' N(CO)) which best reproduce the data for 8 regions investigated. Optical depths were also estimated for a large variety of CO lines in these regions. To identify the best values found, we used two complementary theoretical approaches when comparing the model predictions with the observations, i.e. the χ2 minimisation and the likelihood. Very different physical conditions for the molecular gas from a region to another have been obtained: TK ranges from 10 to 250 K, n(H2) ranges from 102.3 to 107.0 cm−3 and N(CO) ranges from 1015.0 to 1019.3 cm−2 among the arm and inter-arm regions. For each region probed, we also published for the first time the CO spectral line energy distribution (SLED) from CO(1-0) to CO(10-9) for this galaxy, mixing observations and model predictions which provide an essential insight for future follow-up observational programmes. Finally, in this work, we discuss the physical properties we obtained for each region in relation with the presence of young stellar population characteristics such as supernovae remnants (SNRs), Hi holes, Hii regions.

Molecular gas properties in early-type galaxies

We present detailed study of the physical properties of the molecular gas in a sample of 18 gas-rich early-type galaxies -ETGs- from the ATLAS3D sample. Our goal is to better understand the star formation processes occurring in those galaxies, starting in this work by determining the properties of their molecular star-forming gas. Such study has never been performed before for ETGs and open a new window for exploring the star formation processes in the Universe. We use here the 12CO(1-0, 2-1), 13CO(1-0, 2-1), HCN(1-0) and HCO+(1-0) transitions already obtained (Krips et al. 2010 and Crocker et al. 2012 and new detections of the 12CO(3-2) line that we present too (see Bayet et al. 2012, re-submitted). From this dataset, we derive the average H2 kinetic temperature, H2 volume density and column density of the emitting gas using a non-Local Thermodynamical Equilibrium theoretical approach. For most of the gas-rich ETGs included in our sample, the CO transitions can be reproduced by gas kinetic temperatures between 10-20 K, densities of 103−4 cm−3 and CO column densities of 1018–20 cm−2. Since the CO lines trace different physical conditions than those required to emit the HCN and HCO+ lines, they are treated separately. The physical parameters corresponding to the HCN and HCO+ gas component suffer from large uncertainties and have to be considered as indicative only. In this study, for the first time, we also compare the predicted CO spectral line energy distributions of our gas-rich ETGs and their gas properties with those of a sample of nearby well-studied disc galaxies. The gas excitation conditions in 12/18 early-type galaxies appear analogous to those in the center fo Milky Way, hence the star formation activity driving these conditions may be of a similar strength and nature. The conclusions drawn have to be nevertheless considered carefully since they are based only on a limited number of observations. We show from our models that the 12CO(6-5) line emission is particularly useful for improving these results.

UV-driven chemistry in simulations of the interstellar medium

Our main purpose is to estimate the effect of assuming uniform density on the line-of-sight in PDR chemistry models, compared to a more realistic distribution for which total gas densities may well vary by several orders of magnitude. A secondary goal of this paper is to estimate the amount of molecular hydrogen which is not properly traced by the CO (J = 1 -> 0) line, the so-called "dark molecular gas". We use results from a magnetohydrodynamical (MHD) simulation as a model for the density structures found in a turbulent diffuse ISM with no star-formation activity. The Meudon PDR code is then applied to a number of lines of sight through this model, to derive their chemical structures. It is found that, compared to the uniform density assumption, maximal chemical abundances for H2, CO, CH and CN are increased by a factor 2 to 4 when taking into account density fluctuations on the line of sight. The correlations between column densities of CO, CH and CN with respect to those of H2 are also found to be in better overall agreement with observations. For instance, at N(H2) > 2.10^{20} cm-2, while observations suggest that d[log N(CO)]=d[log N(H2)] = 3.07 +/- 0.73, we find d[log N(CO)]=d[log N(H2)] =14 when assuming uniform density, and d[log N(CO)]=d[log N(H2)] = 5.2 when including density fluctuations.

Influence of solar flare X-rays on the habitability on the Mars

We probe the lethality of X-rays from solar flares to organisms on Mars based on the observations of 10 solar flares. We, firstly, estimate the doses produced by the strong flares observed by the RHESSI and GOES missions during the descending phase of sunspot cycle 23. Next, in order to realize the dependence of dose on flux and steepness of spectra, we model the incident spectra over a wide range of spectral index to estimate dose values and compare them with the observed doses. We calculate the distribution of surficial spectra visible to organisms on the martian surface by employing attenuation of X-rays due to CO2 column densities distribution over the South Pole. The surficial flux distribution after folding with the opacity of water enables us to estimate the dose distribution over the South Pole. The dose measured from the surficial spectrum produced by the observed 10 flares corresponding to the latitudes 50–60°, 60–70°, 70–80° and 80–90°S varies in the range of 6.39×10−9–1.80×10−6; 4.89×10−10–5.21×10−8; 5.10×10−11–5.20×10−9 and 4.42×10−10–4.89×10−12 gray (1 gray=104erg/g) respectively. Comparing the measured as well as the modeled doses with those proposed to be lethal for various organisms by Smith and Scalo (Smith, D.S., Scalo, J. [2007]. Planet. Space Sci. 55, 517–527); we report that the habitability of life on the South Pole remains unaffected even by the strongest solar flare occurred during descending phase of solar cycle 23. Further, the monthly integrated energy released by the solar flares in the most productive month viz. October 2003 and January 2005 from the GOES soft X-ray observations is estimated to be 8.43 and 3.32×1032ergs respectively, which is almost equal in order to the typical energy released by a single strong X-class flare. Therefore, we propose the life near the South Pole region on the Mars remain uninfluenced by X-ray emission even during monster phenomena of energy release on the Sun and/or Star.

Probing the mass and structure of the Ring Nebula in Lyra with SOFIA/GREAT observations of the [CII] 158 micron line

We have obtained new velocity-resolved spectra of the [CII] 158 micron line towards the Ring Nebula in Lyra (NGC 6720), one of the best-studied planetary nebulae, in order to probe its controversial 3-dimensional structure and to estimate the mass of circumstellar material in this object. We used the Terahertz receiver GREAT aboard the SOFIA airborne telescope to obtain the [CII] spectra at eight locations within and outside the bright optical ring of NGC 6720. Emission was detected at all positions except for the most distant position along the nebula's minor axis, and generally covers a broad velocity range, ~50 km/s (FWZI), except at a position along the major axis located just outside the optical ring, where it is significantly narrower (~25 km/s). The one narrow spectrum appears to be probing circumstellar material lying outside the main nebular shell that has not been accelerated by past fast wind episodes from the central star, and therefore most likely comes from equatorial and/or low-latitude regions of this bipolar nebula. Along lines-of-sight passing within about 10 arcsec of the nebular center, the CII column density is a factor 46 higher than the CO column density. The total mass of gas associated with the [CII] emission inside a circular region of diameter 87.5 arcsec is at least 0.11 solar masses. A significant amount of [CII] flux arises from a photodissociation region immediately outside the bright optical ring, where we find a CII to CO ratio of 6.5, lower than that seen towards the central region. Comparing our data with lower-quality CI spectra, which indicate similarly large CI/CO ratios in NGC 6720, we conclude that the bulk of elemental carbon in NGC 6720 is divided roughly equally between CII and CI, and that the emissions from these species are far more robust tracers of circumstellar material than CO in this object and other evolved planetary nebulae.

Modeling midwave infrared muzzle flash spectra from unsuppressed and flash-suppressed large caliber munitions

Time-resolved infrared spectra of firings from a 152mm howitzer were acquired over an 1800–6000cm−1 spectral range using a Fourier-transform spectrometer. The instrument collected primarily at 32cm−1 spectral and 100Hz temporal resolutions. Munitions included unsuppressed and chemically flash suppressed propellants. Secondary combustion occurred with unsuppressed propellants resulting in flash emissions lasting ∼100ms and dominated by H2O and CO2 spectral structure. Non-combusting plume emissions were one-tenth as intense and approached background levels within 20–40ms. A low-dimensional phenomenological model was used to reduce the data to temperatures, soot absorbances, and column densities of H2O, CO2, CH4, and CO. The combusting plumes exhibit peak temperatures of ∼1400K, areas of greater than 32m2, low soot emissivity of ∼0.04, with nearly all the CO converted to CO2. The non-combusting plumes exhibit lower temperatures of ∼1000K, areas of ∼5m2, soot emissivity of greater than 0.38 and CO as the primary product. Maximum fit residual relative to peak intensity are 14% and 8.9% for combusting and non-combusting plumes, respectively. The model was generalized to account for turbulence-induced variations in the muzzle plumes. Distributions of temperature and concentration in 1–2 spatial regions demonstrate a reduction in maximum residuals by 40%. A two-region model of combusting plumes provides a plausible interpretation as a ∼1550K, optically thick plume core and ∼2550K, thin, surface-layer flame-front. Temperature rate of change was used to characterize timescales and energy release for plume emissions. Heat of combustion was estimated to be ∼5MJ/kg.

CO depletion in the Gould Belt clouds

We present a statistical comparison of CO depletion in a set of local molecular clouds within the Gould Belt using Sub-millimetre Common User Bolometer Array (SCUBA) and Heterodyne Array Receiver Programme (HARP) data. This is the most wide-ranging study of depletion thus far within the Gould Belt. We estimate CO column densities assuming local thermodynamic equilibrium and, for a selection of sources, using the radiative transfer code RADEX in order to compare the two column density estimation methods. High levels of depletion are seen in the centres of several dust cores in all the clouds. We find that in the gas surrounding protostars, levels of depletion are somewhat lower than for starless cores with the exception of a few highly depleted protostellar cores in Serpens and NGC 2024. There is a tentative correlation between core mass and core depletion, particularly in Taurus and Serpens. Taurus has, on average, the highest levels of depletion. Ophiuchus has low average levels of depletion which could perhaps be related to the anomalous dust grain size distribution observed in this cloud. High levels of depletion are often seen around the edges of regions of optical emission (Orion) or in more evolved or less dynamic regions such as the bowl of L1495 in Taurus and the north-western region of Serpens.

Carbon monoxide from shortwave infrared reflectance measurements: A new retrieval approach for clear sky and partially cloudy atmospheres

The GMES atmospheric services include global and European air quality monitoring and forecasting which require near real time delivery of atmospheric CO abundances. To achieve this, a numerically efficient retrieval approach for operational data processing is needed to derive CO column densities from shortwave infrared measurements in the 2.3μm band of the Sentinel 5 missions and its Precursor mission. The expected performance of both spectrometers will allow for clear-sky CO column retrievals over land with a precision of ≤10% and an overall accuracy of ≤15% even for background CO abundance and low surface reflection in the shortwave infrared spectral range. In this context, we present a new algorithm approach of the retrieval of CO from shortwave infrared measurements in clear sky and partially cloudy atmospheres over land and ocean surfaces. The algorithm employs simplified radiative transfer, where the model atmosphere is separated in a clear sky part, and a part which is bounded below by an elevated Lambertian reflector to account for atmospheric scattering by clouds and aerosols. Within the inversion scheme, Tikhonov regularization is used to determine, for each individual measurement, not only the vertically integrated CO column density and its retrieval error, but also the column averaging kernel. For the retrieval, a prior estimate of methane abundance is used to characterize the light path by retrieving effective cloud parameters from the shortwave infrared band itself. A performance analysis shows that, for a single cloud layer in the middle and lower troposphere, the bias on the CO retrieval due to the Lambertian cloud model is less than 2–3%. The effect of boundary layer aerosols can also be treated with similar accuracy. In contrast, the presence of elevated dust plumes above bright surfaces or a single layer cirrus cloud causes significant errors and, in these cases, a reasonably low retrieval bias can only be achieved for an optical depth in the shortwave infrared spectral range lower than 0.4. Another relevant error source for the CO retrieval algorithm is given by the prior uncertainty of methane. It is found that a 5% uncertainty in the methane column density causes biases of 3–9% on the retrieved CO column, depending on cloud fraction.

THE X-FACTOR IN GALAXIES. I. DEPENDENCE ON ENVIRONMENT AND SCALE

Characterizing the conversion factor between CO emission and column density of molecular hydrogen, X_CO, is crucial in studying the gaseous content of galaxies, its evolution, and relation to star formation. In most cases the conversion factor is assumed to be close to that of giant molecular clouds (GMCs) in the Milky Way, except possibly for mergers and star-bursting galaxies. However, there are physical grounds to expect that it should also depend on the gas metallicity, surface density, and strength of the interstellar radiation field. The XCO factor may also depend on the scale on which CO emission is averaged due to effects of limited resolution. We study the dependence of X_CO on gas properties and averaging scale using a model that is based on a combination of results of sub-pc scale magneto-hydrodynamic simulations and on the gas distribution from self-consistent cosmological simulations of galaxy formation. Our model predicts a value of X_CO that is consistent with the Galactic value for interstellar medium conditions typical for the Milky Way. For such conditions the predicted X_CO varies by only a factor of two for gas surfaced densities in the range \sim 50 - 500 M_sun / pc^2. However, the model also predicts that more generally on the scale of GMCs, X_CO is a strong function of metallicity, and depends on the column density and the interstellar UV flux. We show explicitly that neglecting these dependencies in observational estimates can strongly bias the inferred distribution of H2 column densities of molecular clouds to have a narrower and offset range compared to the true distribution. We find that when averaged on \sim kpc scales the X-factor depends only weakly on radiation field and column density, but is still a strong function of metallicity. The predicted metallicity dependence can be approximated as X_CO \sim Z^{-{\gamma}} with {\gamma} ~ 0.5 - 0.8.

CHARACTERIZING CO FOURTH POSITIVE EMISSION IN YOUNG CIRCUMSTELLAR DISKS

ABSTRACT Carbon monoxide is a commonly used IR/submillimeter tracer of gas in protoplanetary disks. We present an analysis of ultraviolet CO emission in Hubble Space Telescope Cosmic Origins Spectrograph spectra for 12 Classical T Tauri stars (CTTSs). Several ro-vibrational bands of the CO A 1Π–X 1Σ+ (Fourth Positive) electronic transition system are spectrally resolved from emission of other atoms and H2. The CO A 1Π v′ = 14 state is populated by absorption of Lyα photons, created at the accretion column on the stellar surface. For targets with strong CO emission, we model the Lyα radiation field as an input for a simple fluorescence model to estimate CO rotational excitation temperatures and column densities. Typical column densities range from N CO = 1018 to 1019 cm−2. Our measured excitation temperatures are mostly below T CO = 600 K, cooler than typical M-band CO emission. These temperatures and the emission line widths imply that the UV emission originates in a different population of CO than that which is IR-emitting. We also find a significant correlation between CO emission and the disk accretion rate and age. Our analysis shows that ultraviolet CO emission can be a useful diagnostic of CTTS disk gas.

Spatially resolving the outer atmosphere of the M giant BK Virginis in the CO first overtone lines with VLTI/AMBER

The mass-loss mechanism in normal K--M giant stars with small variability amplitudes is not yet understood, although they are the majority among red giant stars. We present high-spatial and high-spectral resolution observations of the 2.3 micron CO lines in the M7 giant BK Vir with a spatial resolution of 9.8 mas and a spectral resolution of 12000, using AMBER at the Very Large Telescope Interferometer (VLTI). The angular diameters observed in the CO lines are 12--31% larger than those measured in the continuum. We also detected asymmetry in the CO line-forming region. The data taken 1.5 months apart show possible time variation on a spatial scale of 30 mas (corresponding to 3 x stellar diameter) at the CO band head. Comparison of the observed data with the MARCS photospheric model shows that whereas the observed CO line spectrum can be well reproduced by the model, the angular sizes observed in the CO lines are much larger than predicted by the model. Our model with two additional CO layers above the MARCS photosphere reproduces the observed spectrum and interferometric data in the CO lines simultaneously. This model suggests that the inner CO layer at ~1.2 stellar radii is very dense and warm with a CO column density of ~10^{22} cm^{-2} and temperatures of 1900--2100K, while the outer CO layer at 2.5--3.0 stellar radii is characterized by column densities of 10^{19}--10^{20} cm^{-2} and temperatures of 1500--2100K. Our AMBER observations of BK Vir have spatially resolved the extended molecular outer atmosphere of a normal M giant in the individual CO lines for the first time. The temperatures derived for the CO layers are higher than or equal to the uppermost layer of the MARCS photospheric model, implying the operation of some heating mechanism in the outer atmosphere.

A DIRECT MEASUREMENT OF THE TOTAL GAS COLUMN DENSITY IN ORION KL

The large number of high-J lines of C^(18)O available via the Herschel Space Observatory provide an unprecedented ability to model the total CO column density in hot cores. Using the emission from all the observed lines (up to J = 15-14), we sum the column densities in each individual level to obtain the total column after correcting for the population in the unobserved states. With additional knowledge of source size, V_(LSR), and line width, and both local thermodynamic equilibrium (LTE) and non-LTE modeling, we have determined the total C^(18)O column densities in the Extended Ridge, Outflow/Plateau, Compact Ridge, and Hot Core components of Orion KL to be 1.4 × 10^(16) cm^(–2), 3.5 × 10^(16) cm^(–2), 2.2 × 10^(16) cm^(–2), and 6.2 × 10^(16) cm^(–2), respectively. We also find that the C^(18)O/C^(17)O abundance ratio varies from 1.7 in the Outflow/Plateau, 2.3 in the Extended Ridge, 3.0 in the Hot Core, and to 4.1 in the Compact Ridge. This is in agreement with models in which regions with higher ultraviolet radiation fields selectively dissociate C^(17)O, although care must be taken when interpreting these numbers due to the size of the uncertainties in the C^(18)O/C^(17)O abundance ratio.

Comparison of Model-simulated Atmospheric Carbon Dioxide with GOSAT Retrievals

Global atmospheric CO₂ distributions were simulated with a chemical transport model (GEOS-Chem) and compared with space-borne observations of CO₂ column density by GOSAT from April 2009 to January 2010. The GEOS-Chem model simulated 3-D global atmospheric CO₂ at 2°×2.5°horizontal resolution using global CO₂ surface sources/sinks as well as 3-D emissions from aviation and the atmospheric oxidation of other carbon species. The seasonal cycle and spatial distribution of GEOS-Chem CO₂ columns were generally comparable with GOSAT columns over each continent with a systematic positive bias of ~1.0%. Data from the World Data Center for Greenhouse Gases (WDCGG) from twelve ground stations spanning 90°S-82°N were also compared with the modeled data for the period of 2004-2009 inclusive. The ground-based data show high correlations with the GEOS-Chem simulation (0.66≤R₂≤0.99) but the model data have a negative bias of ~1.0%, which is primarily due to the model initial conditions. Together these two comparisons can be used to infer that GOSAT CO₂ retrievals underestimate CO₂ column concentration by ~2.0%, as demonstrated in recent validation work using other methods. We further estimated individual source/sink contributions to the global atmospheric CO₂ budget and trends through 7 tagged CO₂ tracers (fossil fuels, ocean exchanges, biomass burning, biofuel burning, net terrestrial exchange, shipping, aviation, and CO oxidation) over 2004-2009. The global CO₂ trend over this period (2.1 ppmv/year) has been mainly driven by fossil fuel combustion and cement production (3.2 ppmv/year), reinforcing the fact that rigorous CO₂ reductions from human activities are necessary in order to stabilize atmospheric CO₂ levels.

RESOLVING THE CO SNOW LINE IN THE DISK AROUND HD 163296

We report Submillimeter Array (SMA) observations of CO (J=2--1, 3--2 and 6--5) and its isotopologues (13CO J=2--1, C18O J=2--1 and C17O J=3--2) in the disk around the Herbig Ae star HD 163296 at ~2" (250 AU) resolution, and interpret these data in the framework of a model that constrains the radial and vertical location of the line emission regions. First, we develop a physically self-consistent accretion disk model with an exponentially tapered edge that matches the spectral energy distribution and spatially resolved millimeter dust continuum emission. Then, we refine the vertical structure of the model using wide range of excitation conditions sampled by the CO lines, in particular the rarely observed J=6--5 transition. By fitting 13CO data in this structure, we further constrain the vertical distribution of CO to lie between a lower boundary below which CO freezes out onto dust grains (T ~ 19 K) and an upper boundary above which CO can be photodissociated (the hydrogen column density from the disk surface is ~ 10^{21} cm-2). The freeze-out at 19 K leads to a significant drop in the gas-phase CO column density beyond a radius of ~155 AU, a "CO snow line" that we directly resolve. By fitting the abundances of all CO isotopologues, we derive isotopic ratios of 12C/13C, 16O/18O and 18O/17O that are consistent with quiescent interstellar gas-phase values. This detailed model of the HD 163296 disk demonstrates the potential of a staged, parametric technique for constructing unified gas and dust structure models and constraining the distribution of molecular abundances using resolved multi-transition, multi-isotope observations.

Multiwavelength observations of cirrus clouds in the North Celestial Loop: physical parameters of molecular sites

In this third paper of the series, we continue to investigate the transition between atomic and molecular gas in two potential sites of molecule formation at high Galactic latitude, which we call the Spider and Ursa Major. Using Five College Radio Astronomical Observatory 12 CO (J = 1–0) observations and four clump identification algorithms, the clump properties are first determined in both regions, showing similar properties compared to the clumps found in translucent clouds. New higher resolution 12 CO (J = 1–0) and 13 CO (J = 1–0) observations from the Institut de Radioastronomie Millim´ etrique and new 12 CO (J = 2–1) observations from the James Clerk Maxwell Telescope (resolution ≈20 arcsec) are also presented in five fields for the Spider (560 spectra) and in two fields for Ursa Major (288 spectra). Using a large velocity gradient model, physical parameters (density and column density) are determined in each field. The densities are smaller at the location of the infrared excess peaks (<200 cm −3 ) than at the locations of the 12 CO peaks (≈10 3 cm −3 ), confirming that a small density could explain the absence of coincidence between the infrared excess peak and the 12 CO peak. Self-shielding is probably efficient given the computed 12 CO column densities (≈10 15 cm −2 ).

High resolution spectroscopy of Pluto’s atmosphere: detection of the 2.3 μm CH4bands and evidence for carbon monoxide

The goal is to determine the composition of Pluto's atmosphere and to constrain the nature of surface-atmosphere interactions. We perform high--resolution spectroscopic observations in the 2.33--2.36 $\mu$m range, using CRIRES at the VLT. We obtain (i) the first detection of gaseous methane in this spectral range, through lines of the $\nu_3$ + $\nu_4$ and $\nu_1$ + $\nu_4$ bands (ii) strong evidence (6-$\sigma$ confidence) for gaseous CO in Pluto. For an isothermal atmosphere at 90 K, the CH$_4$ and CO column densities are 0.75 and 0.07 cm-am, within factors of 2 and 3, respectively. Using a physically--based thermal structure model of Pluto's atmosphere also satisfying constraints from stellar occultations, we infer CH$_4$ and CO mixing ratios q$_{CH_4}$= 0.6$^{+0.6}_{-0.3}$% (consistent with results from the 1.66 $\mu$m range) and q$_{CO}$ = 0.5$^{+1}_{-0.25}$$\times10^{-3}$. The CO atmospheric abundance is consistent with its surface abundance. As for Triton, it is probably controlled by a thin, CO-rich, detailed balancing layer resulting from seasonal transport and/or atmospheric escape.

Physical condition of the molecular gas at the centre of NGC 1097

We have used the Xco conversion factor, Local Thermal Equilibrium and Large Velocity Gradient approximation to parametrize the cold and warm phase of the interstellar medium from five different low transitions of CO in the central 21"(kpc) of NGC 1097. We have applied a one-component model and derived a typical kinetic temperature of ~33K, and its molecular Hydrogen density and a CO column density. A two-component model results in 85% cold-to-total gas fraction with a 90K warm counterpart. Furthermore, we "resolve" the spatially unresolved single dish observations by selecting velocity channels that in an interferometric velocity map correspond to specific regions. We have selected five such regions and found that the physical properties in these regions are comparable to those derived from the full line profile. This implies that the central kpc of NGC 1097 is rather homogeneous in nature, and, although the regions are not uniquely located within the ring, the star formation along the ring is homogeneously distributed (in agreement with recent Herschel observations). We have further revised the mass inflow rate onto the Supermassive Black Hole in this prototype LINER/Sy1 galaxy and found that, accounting for the total interstellar medium and applying a careful contribution of the disc thickness and corresponding stability criterion, increases the previous estimations by a factor 10. Finally we have calculated the Xco for the centre of NGC 1097 using an independent estimation of the surface density to the CO emission, and obtained Xco=(2.8+-0.5)x10^20 cm^-2(K km s^-1)^-1 at radius 10.5" and Xco=(5.0+-0.5)x10^20 cm^-2(K km s^-1)^-1 at 7.5". With the approach and analysis described, we have demonstrated that important physical properties can be derived to a resolution beyond the single dish resolution element, however, caution is necessary for interpreting the results.(Abriged)