CNO Burning Research Articles

White Dwarf Photospheric Abundances in Cataclysmic Variables. IV. Deriving the [N/C] Ratio* *Based on observations made with the NASA/ESA Hubble Space Telescope, obtained from the data archive at the Space Telescope Science Institute. STScI is operated by the Association of University for Research in Astronomy, Inc. under NASA contract NAS 5-26555.

We present results from our ongoing far-ultraviolet archival analysis of cataclysmic variable white dwarf (WD) abundances for six more systems: four SU UMa dwarf novae (BW Scl, SW UMa, BC UMa, and VW Hyi) together with the dwarf nova RX And, and the novalike DW UMa. To derive a reliable nitrogen abundance, for the four SU UMa systems (with a WD temperature T wd ∼ 14,000 to ∼22,000 K), we use the dominant N i (1492 Å) absorption line; for DW UMa (with T wd possibly as high as 60,000 K), we use the N v (∼1240 Å) doublet; and for RX And (with T wd = 33,800 K), we use the N iii (1183.0 and 1184.6 Å) absorption lines. We find a [N/C] ratio of the order of 1–100 (in solar units). Oxygen, silicon, phosphorus are mostly underabundant while aluminum is mostly overabundant. We also derive magnesium, sulfur, calcium, and iron for a few systems. VW Hyi has a solar composition secondary implying the suprasolar [N/C] ratio very likely originates in the WD itself, e.g., accretion-driven dredge-up, mixing, and convection bringing material from deeper regions to the WD surface. If the donor star in the other five systems is nonevolved, the WD is the origin for the [N/C] ratio in these systems, either directly as in VW Hyi or due to contamination of the donor and accretion disk by the repetitive explosive CNO burning during the common envelope stage of the nova explosions.

A stripped-companion origin for Be stars: clues from the putative black holes HR 6819 and LB-1

ABSTRACT HR 6819 is a bright (V = 5.36), blue star recently proposed to be a triple containing a detached black hole (BH). We show that the system is a binary and does not contain a BH. Using spectral decomposition, we disentangle the observed composite spectra into two components: a rapidly rotating Be star and a slowly rotating B star with low surface gravity (log g ≈ 2.75). Both stars show periodic radial velocity (RV) variability, but the RV semi-amplitude of the B star’s orbit is $K_{\rm B}= (62.7 \pm 1)\, \rm km\, s^{-1}$, while that of the Be star is only $K_{\rm Be} = (4.5\pm 2)\, \rm km\, s^{-1}$. This implies that the B star is less massive by at least a factor of 10. The surface abundances of the B star bear imprints of CNO burning. We argue that the B star is a bloated, recently stripped helium star with mass ${\approx}0.5\, \mathrm{ M}_{\odot }$ that is currently contracting to become a hot subdwarf. The orbital motion of the Be star obviates the need for a BH to explain the B star’s motion. A stripped-star model reproduces the observed luminosity of the system, while a normal star with the B star’s temperature and gravity would be more than 10 times too luminous. HR 6819 and the binary LB-1 probably formed through similar channels. We use MESA (Modules for Experiments in Stellar Astrophysics) models to investigate their evolutionary history, finding that they likely formed from intermediate-mass ($3\!-\!7\, \mathrm{ M}_{\odot }$) primaries stripped by slightly lower-mass secondaries and are progenitors to Be + sdOB binaries such as ϕ Persei. The lifetime of their current evolutionary phase is on average 2 × 105 yr, of the order of half a per cent of the total lifetime of the Be phase. This implies that many Be stars have hot subdwarf and white dwarf companions, and that a substantial fraction ($20\!-\!100{{\ \rm per\ cent}}$) of field Be stars form through accretion of material from a binary companion.

CNO Cycle Burning in Ultra-low Metallicity Solar Mass Stars

Abstract We use the 1D stellar evolution code MESA to run select models at one solar mass at near zero metallicity to examine the effect of a lack of catalysts for CNO burning on the evolution of these models. We find that for metallicities below 10−10 Z ⊙ a loop occurs on the HR diagram as the star evolves off the main sequence, corresponding to the onset of significant CNO burning in the core of the star. This feature is visible in the Kippenhahn diagram as a period where the core becomes convective while the burning takes place. During this loop, the degeneracy of the core is lifted as CNO burning produces around 3.7% of the total nuclear energy.

Carbon Isotope Ratios in Planetary Nebulae: The Unexpected Enhancement of 13C

Abstract The 12C/13C ratio has been measured toward a sample of planetary nebulae (PNe) using millimeter observations of CO, HCN, HNC, CN, and other species, conducted with the 12 m antenna and the Submillimeter Telescope of the Arizona Radio Observatory. The observed nebulae spanned the entire lifetime of PNe, from ∼900 to 12,000 yr, and include well-known objects such as NGC 7293 (Helix), NGC 6720 (Ring), and NGC 2440, as well as relatively unexplored nebulae (M3–28, M2–48, and M3–55). In most cases, multiple molecules and transitions were used in the ratio determination, resulting in the most accurate values available to date, with 10%–40% uncertainties. The ratios found were unexpectedly low, lying in the range 12C/13C ∼1.0 ± 0.7–13.2 ± 4.9, with an average value of 3.7—drastically less than found in the envelopes of C-rich AGB stars, and, in some cases, lower than the minimum value achieved in equilibrium CNO burning. Such low values are expected for the two O-rich nebulae studied (M2–9 and M2–48), because of insufficient third dredge-up events. However, most of the PNe observed were clearly carbon-rich, as deduced from the large number of C-bearing molecules present in them. Because nucleosynthesis ceases in the PN stage, both the C/O and the 12C/13C ratios must reflect abundances at the end of the AGB. These consistently low 12C/13C ratios, combined with the bipolar/multipolar morphologies of all planetary nebulae observed, suggest an explosive process involving proton-capture occurred at the AGB–PN transition.

A quantitative NLTE analysis of visual and ultraviolet spectra of four helium-rich subdwarf O stars

Aims. Hot subdwarf stars represent a poorly understood late phase of stellar evolution. While binary evolution plays an important role for the formation of B-type subdwarfs (sdB), the origin of the helium dominated subclass of O-type subdwarfs (He-sdO) is still unknown. We search for chemical signatures of their genesis by means of quantitative spectral analyses of high-quality visual and ultraviolet spectra. Methods. Four prototypical He-sdO stars, one belonging to the nitrogen-rich and three to the C-rich subclass, were selected for which archival far-ultraviolet spectra from the FUSE satellite as well as high-resolution visual and UVA spectra taken with the ESO-UVES/FEROS spectrographs are available. Using T LUSTY200/S YNSPEC49 to compute line blanketed-non-local thermodynamic equilibrium (NLTE) model atmospheres and synthetic spectra, atmospheric parameters and the abundances patterns have been derived. The final models included H, He, C, N, O, Ne, Mg, Al, Si, P, S, Fe, and Ni represented by the most detailed model atoms available. Because of the enrichment of either nitrogen or carbon, it turned out, that models including these elements at the appropriate high abundance provide sufficiently accurate approximations to the temperature stratification of full models. Results. No indications for binarity were found, neither radial velocity variations nor photometric evidence for the presence of a companion could be detected. All stars have helium-dominated atmospheres almost free of hydrogen and temperatures between 42 000 K and 47 000 K while their surface gravities lie between log g = 5.4 and 5.7. The abundance pattern of CD–31°4800 displays the signatures of CNO burning, while heavier elements are subsolar by about 0.4 dex, except for Ne and Si which are close to solar. The abundance patterns of the C-rich He-sdOs are more complex. A slightly subsolar metallicity is accompanied by N-enrichment and O-deficiency, less pronounced than in CD–31°4800. Neon is mildly to strongly enriched, up to a factor of ten with respect to the sun in LS IV +10° 9. The nickel-to-iron ratio is significantly super-solar. Using spectral energy distributions and Gaia parallaxes the masses of the stars were determined. They are found to scatter around the canonical mass for the core helium flash, although the uncertainties are large. Conclusions. The abundance pattern observed for CD–31°4800 is consistent with predictions of models for slow (cold) mergers of pairs of equal mass helium WDs except for the low oxygen abundance observed. Models for composite mergers were considered for the C-rich stars, but predict abundance pattern dissimilar to those determined. [CW83] 0904−02, though, may be a candidate for a composite He-WD merger, as it rotates and appears to be more massive than the other program stars. New evolutionary models for the hot flasher scenario predict abundance patterns similar to those determined for the C-rich stars. Hence, C-rich He-sdO may well result from late He flashes with deep-mixing episodes.

Carbon production on accreting neutron stars in a new regime of stable nuclear burning

Abstract Accreting neutron stars exhibit Type I X-ray bursts from both frequent hydrogen/helium flashes as well as rare carbon flashes. The latter (superbursts) ignite in the ashes of the former. Hydrogen/helium bursts, however, are thought to produce insufficient carbon to power superbursts. Stable burning could create the required carbon, but this was predicted to only occur at much larger accretion rates than where superbursts are observed. We present models of a new steady-state regime of stable hydrogen and helium burning that produces pure carbon ashes. Hot CNO burning of hydrogen heats the neutron star envelope and causes helium to burn before the conditions of a helium flash are reached. This takes place when the mass accretion rate is around 10 per cent of the Eddington limit: close to the rate where most superbursts occur. We find that increased heating at the base of the envelope sustains steady-state burning by steepening the temperature profile, which increases the amount of helium that burns before a runaway can ensue.

ON THE EFFECT OF EXPLOSIVE THERMONUCLEAR BURNING ON THE ACCRETED ENVELOPES OF WHITE DWARFS IN CATACLYSMIC VARIABLES

The detection of heavy elements at suprasolar abundances in the atmospheres of some accreting white dwarfs in cataclysmic variables, coupled with the high temperatures needed to produce these elements requires explosive thermonuclear burning. The central temperatures of any formerly more massive secondary stars in CVs undergoing hydrostatic CNO burning are far too low to produce these elements. Evidence is presented that at least some cataclysmic variables contain donor secondaries that have been contaminated by repeated novae ejecta and are transferring this material back to the white dwarf. This scenario does not exclude the channel in which formerly more massive donor stars underwent CNO processing in ystems that underwent thermal timescale mass transfer. Implications for the progenitors of CVs are discussed.

The timescale of low-mass proto-helium white dwarf evolution

A large number of low-mass (< 0.20 M_sun) helium white dwarfs (He WDs) have recently been discovered. The majority of these are orbiting another WD or a millisecond pulsar (MSP) in a close binary system; a few examples are found to show pulsations or to have a main-sequence star companion. There appear to be discrepancies between the current theoretical modelling of such low-mass He WDs and a number of key observed cases, indicating that their formation scenario remains to be fully understood. Here we investigate the formation of detached proto-He WDs in close-orbit low-mass X-ray binaries (LMXBs). Our prime focus is to examine the thermal evolution and the contraction phase towards the WD cooling track and investigate how this evolution depends on the WD mass. Our calculations are then compared to the most recent observational data. Numerical calculations with a detailed stellar evolution code were used to trace the mass-transfer phase in a large number of close-orbit LMXBs. Subsequently, we followed the evolution of the detached low-mass proto-He WDs, including stages with residual shell hydrogen burning and vigorous flashes caused by unstable CNO burning. We find that the time between Roche-lobe detachment until the low-mass proto-He WD reaches the WD cooling track is typically Delta_t_proto = 0.5 - 2 Gyr, depending systematically on the WD mass and therefore on its luminosity. The lowest WD mass for developing shell flashes is ~0.21 M_sun for progenitor stars of mass M2 <= 1.5 M_sun (and ~0.18 M_sun for M2 = 1.6 M_sun). The long timescale of low-mass proto-He WD evolution can explain a number of recent observations, including some MSP systems hosting He WD companions with very low surface gravities and high effective temperatures. We find no evidence for Delta_t_proto to depend on the occurrence of flashes and thus question the suggested dichotomy in thermal evolution of proto-WDs.

Stripped red giant cores in eclipsing binary star systems

Red giant stars can be stripped of their outer layers by stellar collisions or mass transfer in binary star systems such as low mass X-ray binaries. If the star is stripped on or before its first ascent of the red giant branch it will eventually become a very low mass white dwarf composed almost entirely of helium. Very low mass white dwarfs are well known in binary milli-second pulsars and many have recently been found in surveys such as the Sloan Digital Sky Survey, but the precursor phase during which the remnant evolves to higher effective temperature at nearly constant luminosity has rarely been observed. The cooling timescale for very low mass white dwarfs is very uncertain because they are thought to be born with thick hydrogen envelopes which can sustain weak but stable p-p shell burning, but unstable phases of CNO burning (shell flashes) can remove this hydrogen envelope. The predicted number of shell flashes (if any) is dependent on the mass and composition of the star and other details of the models used. In this talk I present new observations of a bright eclipsing binary star recently discovered in the WASP archive in which a stripped red giant is eclipsed by an A-type dwarf star. These observations were used to derive precise masses and radii for both stars and have be used to test the formation scenario outlined above. In addition, I present the main characteristics of 17 new eclipsing binary stars that are also likely to contain the precursors of very low mass white dwarfs.

Hot bottom burning in the envelope of super asymptotic giant branch stars

We investigate the physical and chemical evolution of Population II stars with initial masses in the range 6.5-8 M ⊙ , which undergo an off-centre carbon ignition under partially degenerate conditions, followed by a series of thermal pulses, and supported energetically by a CNO burning shell, above an O-Ne degenerate core. In agreement with the results by other research groups, we find that the O-Ne core is formed via the formation of a convective flame that proceeds to the centre of the star. The evolution, which follows, is strongly determined by the description of the mass-loss mechanism. Use of the traditional formalism with the superwind phase favours a long evolution with many thermal pulses, and the achievement of an advanced nucleosynthesis, due to the large temperatures reached by the bottom of the external mantle. Use of a mass-loss recipe with a strong dependence on the luminosity favours an early consumption of the stellar envelope, so that the extent of the nucleosynthesis, and thus the chemical composition of the ejecta, is less extreme. The implications for the multiple populations in globular clusters are discussed. If the 'extreme' populations present in the most massive clusters are a result of direct formation from the super asymptotic giant branch (SAGB) ejecta, their abundances may constitute a powerful way of calibrating the mass-loss rate of this phase. This calibration will also provide information on the fraction of SAGBs exploding as single e-capture supernovae, leaving a neutron star remnant in the cluster.

CHEMICAL ABUNDANCE PATTERNS IN THE INNER GALAXY: THE SCUTUM RED SUPERGIANT CLUSTERS

The location of the Scutum Red-Supergiant (RSG) clusters at the end of the Galactic Bar makes them an excellent probe of the Galaxy's secular evolution; while the clusters themselves are ideal testbeds in which to study the predictions of stellar evolutionary theory. To this end, we present a study of the RSGs' surface abundances using a combination of high-resolution H-band spectroscopy and spectral synthesis analysis. We provide abundance measurements for elements C, O, Si, Mg, Ti, and Fe. We find that the surface abundances of the stars studied are consistent with CNO burning and deep, rotationally enhanced mixing. The average a/Fe ratios of the clusters are solar, consistent with a thin-disk population. However, we find significantly sub-solar Fe/H ratios for each cluster, a result which strongly contradicts a simple extrapolation of the Galactic metallicity gradient to lower Galacto-centric distances. We suggest that a simple one-dimensional parameterization of the Galaxy's abundance patterns is insufficient at low Galactocentric distances, as large azimuthal variations may be present. Indeed, we show that the abundances of O, Si and Mg are consistent with independent measurements of objects in similar locations in the Galaxy. In combining our results with other data in the literature, we present evidence for large-scale (~kpc) azimuthal variations in abundances at Galacto-centric distances of 3-5kpc. While we cannot rule-out that this observed behaviour is due to systematic offsets between different measurement techniques, we do find evidence for similar behaviour in a study of the barred-spiral galaxy NGC4736 which uses homogeneous methodology. We suggest that these azimuthal abundance variations could result from the intense but patchy star formation driven by the potential of the central bar.

Discovery of Carbon/Oxygen-depleted Blue Straggler Stars in 47 Tucanae: The Chemical Signature of a Mass Transfer Formation Process

We use high-resolution spectra obtained with the ESO Very Large Telescope to measure surface abundance patterns of 43 blue straggler stars (BSSs) in 47 Tuc. We discovered that a subpopulation of BSSs shows a significant depletion of carbon and oxygen with respect to the dominant population. This evidence would suggest the presence of CNO burning products on the BSS surface coming from a deeply peeled parent star, as expected in the case of a mass transfer process. This is the first detection of a chemical signature clearly pointing to a specific BSS formation process in a globular cluster.

Helium‐rich Thermonuclear Bursts and the Distance to the Accretion‐powered Millisecond Pulsar SAX J1808.4−3658

We analyzed Rossi X-ray Timing Explorer observations of the accretion-powered 401 Hz pulsar SAX J1808.4-3658, in order to precisely determine the source distance. While the fluences for the five transient outbursts observed from 1996 were constant to within the uncertainties, the outburst interval varied significantly, so that the time-averaged flux (and accretion rate) decreased by around 40%. By equating the time-averaged X-ray flux with the expected mass transfer rate from gravitational radiation, we derived a lower limit on the distance of 3.4 kpc. Combined with an upper limit from assuming that the four radius-expansion thermonuclear bursts observed during the 2002 October outburst reached at most the Eddington limit for a pure He atmosphere, we found that the probable distance range for the source is 3.4-3.6 kpc. The implied inclination, based on the optical/IR properties of the counterpart, is i ≲ 30°. We compared the properties of the bursts with an ignition model. The time between bursts was long enough for hot CNO burning to significantly deplete the accreted hydrogen, so that ignition occurred in a pure helium layer underlying a stable hydrogen-burning shell. This is the first time that this burning regime has been securely observationally identified. The observed energetics of the bursts give a mean hydrogen fraction at ignition of ⟨X⟩ ≈ 0.1, and require that the accreted hydrogen fraction X0 and the CNO metallicity ZCNO are related by ZCNO ≈ 0.03(X0/0.7)2. We show that in this burning regime, a measurement of the burst recurrence time and energetics allows the local accretion rate onto the star to be determined independently of the accreted composition, giving a new method for estimating the source distance that is in good agreement with our other estimates.

Eddington‐limited X‐Ray Bursts as Distance Indicators. II. Possible Compositional Effects in Bursts from 4U 1636−536

We analyzed 123 thermonuclear (type I) X-ray bursts observed by the Rossi X-Ray Timing Explorer (RXTE) from the low-mass X-ray binary 4U 1636-536. All but two of the 40 radius expansion bursts in this sample reached peak fluxes normally distributed about a mean of 6.4 × 10-8 ergs cm-2 s-1, with a standard deviation of 7.6%. The remaining two radius-expansion bursts reached peak fluxes a factor of 1.69 ± 0.13 lower than this mean value; as a consequence, the overall variation in the peak flux of the radius-expansion bursts was a factor of ≈2. This variation is comparable to the range of the Eddington limit between material with solar H fraction (X = 0.7) and pure He. Such a variation may arise if, for the bright radius-expansion bursts, most of the accreted H is either eliminated by steady hot CNO burning or expelled in a radiatively driven wind. However, steady burning cannot exhaust the accreted H for solar composition material within the typical ≈2 hr burst recurrence time, nor can it result in sufficient elemental stratification to allow selective ejection of the H only. An additional stratification mechanism appears to be required to separate the accreted elements and thus allow preferential ejection of the hydrogen. We found no evidence for a gap in the peak flux distribution between the radius-expansion and non-radius-expansion bursts, previously observed in smaller samples. Assuming that the faint radius-expansion bursts reached the Eddington limit for H-rich material (X ≈ 0.7), and the brighter bursts the limit for pure He (X = 0), we estimate the distance to 4U 1636-536 (for a canonical neutron star with MNS = 1.4 M☉, RNS = 10 km) to be 6.0 ± 0.5 kpc, or for MNS = 2 M☉ at most 7.1 kpc.

Diffusive convective overshoot in core He-burning intermediate mass stars

We present detailed evolutionary calculations focused on the evolution of intermediate mass stars with 3M⊙≤ M≤ 9M⊙ of metallicity typical of the Large Magellanic Cloud (LMC), i.e. Z = 0.008. We compare carefully the models calculated by adopting a diffusive scheme for chemical mixing, in which nuclear burning and mixing are self-consistently coupled, while the eddy velocities beyond the formal convective core boundary are treated to decay exponentially, and those calculate d with the traditional instantaneous mixing approximation. We find th at: i) the physical and chemical behaviour of the models during the H-burning phase is independent of the scheme used for the treatment of mixing inside the CNO burning core; ii) the duration of the He-burning phase relative to the MS phase is systematically longer in the diffusive models, due to a slower redistribution of helium to the core from the outer layers; iii) the fraction of time spent in the blue part of the clump, compared to the stay in the red, is larger in the diffusive models. The differences described in points ii) and iii) tend to vanish for M > 6M⊙. In terms of the theoretical interpretation of an open cluster stellar popu lation, the differences introduced by the use of a self-consistent scheme for mixing in the core with adjacent exponential decay are relevant for ages in the range 80 Myr < t < 200 Myr. These results are robust, since they are insensitive to the choice of the fr ee-parameters regulating the extension of the extra-mixing region.

Abundances of C, N, O in slightly evolved stars in the globular clusters NGC 6397, NGC 6752 and 47 Tuc

Abundances of C and N are derived from features due to the CH G-band and to the UV CN band measured on high resolution (R ~ 40,000) UVES spectra of more than 40 dwarfs and subgiants in NGC 6397, NGC 6752 and 47 Tuc. Oxygen abundances (or upper limits) are available for all stars in the sample. Isotopic ratios 12C/13C were derived from the CH molecular band. This is the first determination of this ratio in unevolved dwarf stars in globular clusters. By enlarging the sample of subgiants in NGC 6397 studied in Gratton et al. (2001), we uncovered, for the first time, large variations in both Na and O also in this cluster. The origin of the chemical inhomogeneities must be searched for outside the stars under scrutiny. Our data indicate that in unevolved or slightly evolved stars in these clusters C abundances are low but not zero, also in stars with large N-enhancements and O-depletions, and that the isotopic ratios 12C/13C are low, but never reach the equilibrium value of the CN-cycle. When coupled with the run of O and Na abundances, these findings possibly require that, in addition to CNO burning and p-captures, some triple-alpha process is also involved: previously evolved intermediate-mass AGB stars are then the most likely polluters.

The Early Evolution of Globular Clusters: The Case of NGC 2808

Enhancement and spread of helium among globular cluster stars have been recently suggested as a way to explain the horizontal-branch blue tails in those clusters that show a primordial spread in the abundances of C, N, O, and other elements involved in advanced CNO burning. Helium enhancement is unavoidable if the matter responsible for the abundance spreads is identified with the matter lost by massive asymptotic giant branch stars, which evolve during the early phases of globular cluster life, as we noted in 2002. In this paper we examine the implications of the hypothesis that, in many globular clusters, stars were born in two separate events: an initial burst (first generation), which gives origin to probably all high- and intermediate-mass stars and to a fraction of the cluster stars observed today, and a second, prolonged star formation phase (second generation), in which stars form directly from the ejecta of the intermediate-mass stars of the first generation. In particular, we consider in detail the morphology of the horizontal branch in NGC 2808 and argue that it unveils the early cluster evolution, from the birth of the first star generation to the end of the second phase of star formation. This framework provides a feasible interpretation for the still-unexplained dichotomy of the NGC 2808 horizontal branch, attributing the lack of stars in the RR Lyrae region to the gap in the helium content between the red clump, whose stars are considered to belong to the first stellar generation and have primordial helium, and the blue side of the horizontal branch, whose minimum helium content reflects the helium abundance in the smallest progenitor mass (~4 M☉) contributing to the second stellar generation. This scenario provides constraints on the required initial mass function, in such a way that a great many remnant neutron stars and stellar mass black holes might have been produced.

The bottleneck of CNO burning and the age of Globular Clusters

The transition between the Main Sequence and the Red Giant Branch in low mass stars is powered by the onset of CNO burning, whose bottleneck is 14 N(p, γ) 15 O. The LUNA collaboration has recently improved the low energy measurements of the cross section of this key reaction. We analyse the impact of the revised reaction rate on the estimate of the Globular Cluster ages, as derived from the turnoff luminosity. We found that the age of the oldest Globular Clusters should be increased by about 0.7-1 Gyr with respect to the current estimates.

Near‐Infrared Spectrophotometry and the CO Emission in V2274 Cygni (Nova Cygni 2001 No. 1)

Infrared spectroscopy of V2274 Cygni (=Nova Cygni 2001 No. 1) is presented for two widely separated epochs, 17 and 370 days after discovery. In addition to the Paschen and Brackett series of H I, the early-time spectrum shows strong emission lines of C I and N I, fluorescently excited lines of O I, and emission from the first overtone of carbon monoxide. Because the initial data were probably acquired no more than 18 days after outburst, CO molecule formation occurred remarkably quickly in the dense, cool, carbon and oxygen rich ejecta. Rapid formation was also seen in NQ Vul, V842 Cen, and V705 Cas, three other novae in which first-overtone CO emission has been detected. Formation of the CO molecule may occur chemically in a process that requires H2 as a precursor or directly through radiative association. The overtone emission of V2274 Cyg indicates a temperature of ~2500 K. The vibrational levels show no obvious departures from thermal equilibrium, which may indicate high optical depths in the fundamental. A large 13C/12C ratio (0.83 ± 0.3) is also indicated by the observations, consistent with the fast CNO burning expected in novae explosions. By the time of the second epoch observations, the emission lines of the neutral C, N, and O had disappeared. He I λ10830 was the dominant emission feature in the spectrum. In addition to the hydrogen lines, recombination features of He II were also strong. The common nebular lines of [S III] were seen but only two coronal line, [S VIII] λ9911 and [Si VI] λ19645, were detected. The CO emission had disappeared, but a strong thermal dust component was present. The interstellar reddening for the system was found to be E(B-V) = 1.3. This extinction, together with the absolute magnitude derived from the rate of decline of the light curve, suggest a distance of ~10.8 kpc. This places V2274 Cyg well out of the Galactic plane. The small number of novae with spectroscopic detections of carbon monoxide all have prominent C I lines, moderate speed classes and ejection velocities, exhibit marked dust formation events, and result from an explosion on a CO-type white dwarf. Based on these similarities, the spectrum of V2274 is proposed as a likely near-infrared spectral template for other novae that display carbon monoxide emission.

Yields from low metallicity, intermediate mass AGB stars:

We present the results of extensive computation of the Thermal Pulse phase AGB evolution of stars of metallicities in mass fraction 2 10 4 Z 0:01, for those masses in the range 2:5 M=M 6, which suer the Hot Bottom Burning (HBB) phase. The evolution is fully computed, by assuming a mass loss rate consistent with the observations of the Magellanic Clouds lithium-rich stars, and modelling convection with the Full Spectrum of Turbulence model by Canuto and Mazzitelli. The results are discussed in the framework of their importance for the evolution of proto-Globular Clusters, whose spectra show that the stars are very probably formed from matter contaminated by the ejecta of these stars, or have accreted it after formation. The main results we find are the following: 1) for metallicities Z 10 3 , masses above4 M suer complete CNO cycling in HBB, so that they show at the surface the result of this process, and the oxygen abundance is reduced; 2) most models suer the third dredge up. Although carbon is processed to nitrogen by HBB, the oxygen burning is so strong in the lowest metallicities (2 10 4 )t hatcarbon becomes more abundant than oxygen: in other words, low-metallicity intermediate mass stars may show up as carbon stars due to the drastic oxygen burning; 3) if Globular Cluster stars are contaminated by matter processed through these phases, we must expect a non negligible helium enhancement in their composition: from a Big Bang abundance Y= 0:24, e.g., we might expect an abundance Y= 0:28. This may have no practical consequences if pollution concerns only the external parts of the stars, but is very important if the stars formed as a whole from a helium rich environment. 4) The lithium yields, although not important for galactic chemical evolution, are very interestingly close to the initial Big Bang abundance: processing by HBB is the only way in which we can obtain substantial amounts of gas which have gone through full CNO burning, but preserve a reasonable abundance of lithium.