In this work, the influence of polysilicon doping on thin oxides (thickness equal or below 10nm) quality and reliability (thickness equal or below 10nm) in MOS capacitors with polysilicon gate is evaluated. By observing the polysilicon deposed in vertical and horizontal furnaces, a higher degradation in the oxide–silicon interface at high doping concentration has been found. In the case of vertical furnaces, a more evident charge trapping in the constant current stress (CCS) V(t) curves and Qbd (ERCS) degradation have also been noticed. Resistivity measurements at different concentrations show a saturation effect just in correspondence of the oxide degradation. From a morphological point of view, the poly deposited in vertical furnaces consists of grains which are larger than the ones found in horizontal furnace polysilicon and contains lower microdefectivity. Starting from these observations a model explaining the polysilicon morphology role in the oxide reliability can be proposed. According to it, the degradation of the interface is caused by the phosphorus coming from the “in situ” doped polysilicon. The hypothesis is that, at high concentrations and in presence of very large polysilicon grains, phosphorous cannot segregate at the interfaces among the polysilicon grains and, moving through the thin oxide, damages the silicon interface. This model has been confirmed by electrical, AFM and TEM analysis and all the collected data have been related to the finished devices performances (yield and reliability of CMOS flash memories, 0.25μm technology and below).
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