The paper presents the results of development and research of an innovative thin-layer thermal insulation material that protects the building from heat loss due to thermal radiation. The material is a dry mortar of cement binder and filler of hollow aluminosilicate microspheres. A thin-layer coating made from this optimally combines the functions of effective heat protection and external finishing warm plastering that is advantageous when reconstructing and restoring historical objects with a lavish decoration. The conducted studies have shown that aluminosilicate microspheres in the composite thermal insulation coating are also involved in the reflection of infrared radiation. The use of Class 2 admixtures made it possible to synthesize additional crystalline hydrates with the aluminate phase of clinker brick, which contributed to the strengthening of the cement composite at the micro- and submicrolevels. This was confirmed by electron microscopy. For the developed composition of the mineral thin-layer thermal insulation coating, the cost of the mixture is almost 3 times lower than for the known composition of the thermal insulation coating on the polymer binder. In addition, unlike polymer analogs, there are no restrictions in terms of temperature and service life. The thermal insulation coating may be applied both exteriorly and interiorly with no condensation being formed between the wall and the coating. Applying the developed thin-layer thermal insulation coating on a brick wall measuring 10 m by 10 m in the climatic conditions of Kharkiv allows reducing heat consumption by 0.188% per 1 m2 per year.