Australian summer heat events have become more frequent and severe in recent times. Temperature-duration-frequency (TDF) curves connect the severity of heat episodes of various durations to their frequencies and thus can be an effective tool for analysing the heat extremes. This study examines Australian heat events using data from 82 meteorological stations. TDF curves have been developed under stationary and non-stationary conditions. Generalised Extreme Value (GEV) distribution is considered to estimate extreme temperatures for return periods of 2, 5, 10, 25, 50 and 100 years. Three major climate drivers for Australia have been considered as potential covariates along with Time to develop the non-stationary TDF curves. According to the Akaike information criterion, the non-stationary framework for TDF modelling provides a better fit to the data than its stationary equivalent. The findings can be beneficial in offering new information to aid climate adaptation and mitigation at the regional level in Australia.