The Recency, Frequency, and Monetary model, also known as the RFM model, is a popular and widely used business model for determining beneficial client segments and analyzing profit. It is also recommended and frequently used in superstores to identify customer segments and increase profit margins. Later, the Length, Recency, Frequency, and Monetary model, also known as the LRFM model, was introduced as an improved version of the RFM model to identify more relevant and exact consumer groups for profit maximization. Superstores have a varying number of different products. In RFM and LRFM models, the relationship between profit and purchased quantity has never been investigated. Therefore, this paper proposed an efficient customer segmentation model, namely LRFMV (Length, Recency, Frequency, Monetary and Volume) and studied the profit-quantity relationship. A new dimension V (volume) has been added to the existing LRFM model to show a direct profit-quantity relationship in customer segmentation. The V stands for volume, which is derived by calculating the average number of products purchased by a frequent superstore client in a single day. The data obtained from feature extraction of the LRMFV model is then clustered by using conventional K-means, K-Medoids, and Mini Batch K-means methods. The results obtained from the three algorithms are compared, and the K-means algorithm is chosen for the superstore dataset of the proposed LRFMV model. All clusters created using these three algorithms are evaluated in the LRFMV model, and a close relationship between profit and volume is observed. A clear profit-quantity relationship of items has yet not been seen in any prior study on the RFM and LRFM models. Grouping customers aiming at profit maximization existed previously, but there was no clear and direct depiction of profit and quantity of sold items. This study applied unsupervised machine learning to investigate the patterns, trends, and correlations between volume and profit. The traits of all the clusters are analyzed by the Customer-Classification Matrix. The LRFMV values, larger or less than the overall average for each cluster, are identified as their traits. The performance of the proposed LRFMV model is compared with the legacy RFM and LRFM customer segmentation models. The outcome shows that the LRFMV model creates precise customer segments with the same number of customers while maintaining a greater profit.