Clay Rock Research Articles

IMPROVING THE RELIABILITY OF THE THREE-DIMENSIONAL GEOLOGICAL BASIS OF COMPLEX DEVELOPMENT TARGETS

This article proposes a new method for identifying different groups of reservoirs when constructing a three-dimensional geological and hydrodynamic model of the target. Productive formations of the Bajocian and Bathonian stages of the Jurassic system of the Kalamkas field were selected as the object of study. This field is tectonically associated with the northern part of the North Buzachinsky arch, located at the northwestern end of the Turan plate. It was noted that these productive deposits have a complex geological structure, due in lithological terms to uneven alternation of sand-siltstone and clay rocks. In addition, four different reservoir classes are identified within each tier, which are characterized by their own permeability-porosity correlation relationships. As a result, for reliable construction of the filtration field, it is necessary to determine the distribution zones of each of the identified reservoir classes within the reservoir. This is due to the fact that due to the different filtration field, the development of reserves from each group of reservoirs will occur unevenly both in area and in section. In this regard, the integrated Flow Zone Indicator (FZI) was evaluated using the results of laboratory core studies. In order to obtain a continuous FZI parameter for wells without core sampling and laboratory analysis, the results of laboratory studies were compared with the results of well geophysical studies (well logging). As a result, analytical dependence of FZI and log data was obtained. Based on this analytical dependence, new three-dimensional models were constructed and zones of distribution of different groups of reservoirs were identified. To verify the obtained results, the synthetic FZI curve calculated from the obtained analytical relationship was compared with the FZI estimate based on the results of laboratory core studies. It is concluded that the synthetic FZI curve is consistent with the FZI estimate based on the results of laboratory core studies and, therefore, the proposed approach can be used when performing work related to 3D modeling.

Sensitivity Analysis of Different Hydrothermal Characteristics in the Variable Thermodynamic Processes of Soft Clay Rock

Sensitivity Analysis of Different Hydrothermal Characteristics in the Variable Thermodynamic Processes of Soft Clay Rock

Yurmatinian/Karatavian Boundary in the Riphean Stratotype: Comparison of the Geochemical Features of Clay Rocks of the Avzyan Formation and Biryan Subformation (Zilmerdak Formation)

Yurmatinian/Karatavian Boundary in the Riphean Stratotype: Comparison of the Geochemical Features of Clay Rocks of the Avzyan Formation and Biryan Subformation (Zilmerdak Formation)

The Identification of Faults using Magnetic Method in Kulonprogo, Yogyakarta, Indonesia

The aims of this study to identify faults and identify subsurface lithology using magnetic anomaly data in the Kulonprogo. In the acquisition was carried out using a Proton Procession Magnetometer (PPM) Geotron G5 with 62 measurement points and a distance of ±1 km between point. Measurements were made on Kebobutak (Tmok), Aluvium (Qa), Andesit (a), and Sentolo (Tmps) formations. The total magnetic field data processing is done with several correction, namely diurnal correction, IGRF, reduce to equator, upward continuation at an altitude of 2000 m, and reduce to pole, and 2D modelling using the forward modelling method. The result of the analysis obtained magnetic field anomaly values in the range of values -400 to 950 nT. The 2D modelling shows that the research area is composed of 4 dominating rock types, namely andesite rock with a susceptibility value of 94 x 10-3, andesite breccia rock with a susceptibility value of 29 x 10-3, clay rock with a susceptibility value of 0,013 x 10-3, and sandstone with a susceptibility value of 5 x 10-3. The identification result show the existence of faults line on Mount Watuaglik, Mount Kamal, and Mount Bodag.

Research on an Equivalent Algorithm for Predicting Gas Content in Deep Coal Seams

This document introduces a novel equivalent algorithm for forecasting gas content within deep coal seams, which is subject to constraints stemming from the advancements and precision achieved in well and roadway engineering endeavors. This algorithm meticulously acknowledges that coal seam gas content comprises three fundamental components: the inherent gas emission rate of the equivalent stratum, the residual gas content retained within the coal seam itself, and the influence imparted by the gas content within the coal seam. Furthermore, the approach thoroughly considers variations in the level of porosity development within the coal seam and its surrounding rock formations, as well as the occurrence of gas within these structures. The equivalent layer is classified into two distinct groups: the sandstone zone and the clay zone. The sandstone zone utilizes pertinent parameters pertaining to fine sandstone, whereas the clay zone distinguishes between clay rock and thick mudstone. The influencing factor considerations solely encompass natural elements, such as the coal seam’s occurrence and geological structure. The residual gas content employs either existing measured parameters or acknowledged experimental parameters specific to the coal seam. Based on this predictive approach, an intelligent auxiliary software (V1.0) for mine gas forecasting was devised. The software calculates the gas content of deep coal seams within the mine at intervals of 100 m × 100 m, subsequently fitting the contour lines of gas content across the entire area. The gas content predictions derived from this equivalent algorithm demonstrate robust adaptability to variations in gas content caused by construction activities, and the prediction results exhibit an acceptable level of error on-site. Notably, the prediction process is not constrained by the progress of tunnel engineering, ensuring that the prediction outcomes can accurately represent the distribution characteristics of deep coal seam gas content. After a year of application, the prediction results have consistently met on-site requirements, providing a scientific foundation for the implementation of effective gas prevention and control measures in the mining area. Furthermore, this approach can effectively guide the formulation of medium- and long-term gas prevention and control plans for mines.

Активизация пластовой микрофлоры для повышения нефтеотдачи

Constant optimization of technological processes of oil production is one of the integral parts of rational subsurface use. The study and implementation of new developments and technologies in the oil production process is primarily due to the economic effect. Methods of increasing oil recovery are of particular interest in the practical implementation of innovative technologies in the oil and gas industry. To date, a huge number of technologies have been developed and tested in field conditions aimed at preserving and increasing the volume of produced products, the classification of which is very diverse. The primary criteria for choosing a method or combination of methods of influencing a productive reservoir in order to increase oil recovery are the geological conditions of the productive horizon, as well as the composition and physico-chemical properties of reservoir fluids. Currently, of all the many methods of increasing oil recovery, the microbiological method is the least studied, as a result of which it is extremely rarely used in enterprises. The relevance of research on the effects of microorganisms on the reservoir rock is beyond doubt. The possibility of widespread application of oil recovery enhancement technology based on bacterial life processes is interesting both from the point of view of environmental safety and economic efficiency. One of the microbiological methods of increasing oil recovery is the activation of the existing reservoir microflora by feeding a nutrient medium into the reservoir. In the course of their vital activity, some types of bacteria are capable of destroying clay rocks, which entails changes in the filtration and capacitance properties of the reservoir rock and, as a result, the volume of products produced increases significantly. The advantage of this method is the absence of the need for forced “contamination” of the reservoir formation, since the necessary bacteria are already in it.

On the Initial Fabric of Naturally Occurring and Reconstituted Weakly Cemented Geomaterials

The understanding of naturally occurring materials such as clay, sand, hard and soft rocks under a common theoretical framework has been a topic of persistent research interest. Over the past few decades, various sample reconstitution techniques have been developed in the literature to mimic in situ conditions, and to parse carefully the influence of various components in a cohesive-frictional geomaterial such that their behavior can be folded into the broad ambit of a continuum mechanics framework. The initial fabric of natural rock specimens is compared with reconstituted cemented sand samples using X-ray computed tomography (XRCT) scans. The efficacy of laboratory reconstitution techniques in replicating the initial microstructural features of natural rocks is evaluated here. Additionally, discrete element method (DEM) protocols which are often employed in generating cohesive granular ensembles are employed here and compared against the naturally occurring and artificially reconstituted fabric. A significant difference is observed in the grain boundaries of reconstituted and naturally occurring rocks. Additionally, the arrangement of particles, the orientation of grain contacts, and their coordination number are examined to assess the efficacy of laboratory-reconstituted specimens at micro-length scale.

Substantiating of oil and gas prospects of Mesozoic sediments based on the geochemical model of mud volcanoes in the Shamakhi-Gobustan structural element of the South Caspian megadepression

There are up to 120 mud volcanoes in the Shamakhi-Gobustan region. During the process of mud volcano eruptions, a large amount of solid, liquid, and gaseous products are thrown to the Earth’s surface, which are widely used for the identification of oil and gas deposits and are considered the main indicator of the productivity of the basin. According to laboratory results from the analysis of solid, liquid, and gas products of mud volcanoes, it is possible to obtain detailed information about the oil-gas content of deep-lying sediments. Therefore, the study of the geochemical composition of the mud volcanoes in the Shamakhi-Gobustan trough plays a major role in the discovery of new oil-gas and gas-condensate deposits. To clarify the changes in the chemical and isotopic composition of gases from mud volcanoes in the Shamakhi-Gobustan trough and to evaluate the oil-bearing and gas-bearing potential of Mesozoic sediments, the characteristics of changes in the isotopic composition of methane gas, heavy hydrocarbons, carbon dioxide, ni- trogen, as well as CH4 and CO2, were studied. The amount of methane in the gas emissions released from mud volcanoes in the Azerbaijan region is more than 90%. The amount of CH4 in the mud volcanoes of the Shamakhi-Gobustan trough ranges from 78.5% to 97.56%. The minimum amount of methane is found in North Gobustan (Gizmeydan 86.8%, Malikchobanli 78.5%), while relatively high amounts are mainly noted in Central (Kushchu 97.55%) and South Gobustan (including Dashgil 97.57%, Goturdag 96.55%, Bahar 96.78%). Mud vol- canoes are less developed in the North Gobustan region and are small in size. In the Central zone, both the size and the number of volcanic cones increase significantly compared to North Gobustan. The largest and most active volcanoes have developed in the southern zone of the trough. Huge mud volcanoes such as Dashmerdan, Solakhay, Ayrantoken, Goturdag, Kirdag, and other volcanoes have developed along the Alat range. The mud volcanoes of North and Central Gobustan are mainly confined to Cretaceous and Paleogene sediments, and due to the low occurrence of plastic clay rocks in these sediment sections, mud volcanoes are rare and weakly active. On the contrary, to the south of these zones, that is, in South Gobustan, they are located in Pliocene sediments, and due to the presence of very thick plastic rocks in their section, mud volcanoes are widespread, and they are active volcanoes that are morphologically sharply reflected. It should be noted that in areas where plastic clay rocks with significant thickness and rheologically active properties are developed, large cones of mud volcanoes that erupt frequently are observed. The calculated gas production of mud volcanoes increases from the northern zone towards South Gobustan. Thus, while the calculated gas production of the Nabur volcano located in the Northern zone is 1500 m3/day, the calculated gas production of the Dashgil mud volcano located in South-Eastern Gobustan is 40,000 m3/day. In the central and south- ern zones of the Shamakhi-Gobustan trough, the presence of ancient rock fragments from the Oligocene-Miocene (Maykop) age rocks forming their roots in the solid waste of mud volcanoes (Cretaceous, Paleocene, Eocene), a large percentage of methane gas (97.57%), transverse elevations, and the presence of an intersection zone of longitudinal faults suggests that there is a tectonic rupture zone rich in natural gas below the base of the volcano. This is proven once again by the occurrence of gas flows in Anart (110,000 m3/day), Utalgi (50,000 m3/day), and the Touragay field (20,000 m3/day). The presence of oil films in the eruption products of mud volcanoes indicates the accumulation of oil alongside gas.

Multitemporal analysis of cliffs evolution along an Atlantic African coast (Safi Region, Morocco)

Unstable coastal cliffs represent a major threat to coastal infrastructure, housing, and economic activities, which depend on coastal stability. Understanding recession rates and the factors influencing them is therefore essential for enhancing risk prediction and management. Here, we investigated the evolution of coastal cliffs in a crucial sector of the Atlantic African coast in Morocco, stretching from Cap Beddouza in the north to Jorf Lihoudi in the south, covering an area of around 48 km and including the large city of Safi. The instability of these cliffs constitutes the main coastal geological hazard of the area, which has its geomorphological expression in different types of landslides punctuating the coastal cliff. We employed multidecadal aerial imagery along with GIS technique to calculate the rate of change of the cliff over 66 years. Our results indicate that most of the Safi Region coastal zone has undergone recession with rates of change generally variable from 0.04 to 0.08 m/yr ± 0.01 m. The central part of the study area, conversely, experienced the highest retreat rate, exceeding 0.10 m/yr. The spatial variability of recession rates is explained through geological and morphological factors such as the nature of low-strength clay rock formations, favoring large-scale gravity movements. These data are crucial to better define the current level of coastal hazard in this densely populated portion of the Moroccan coast, given that cliff recession have considerable effects on the economic, social and environmental risk of the area. Moreover, this study represents one of the first applications of the Digital Shoreline Analysis System (DSAS) method to an African coastline segment, specifically from Cape Beddouza to the Lihoudi cliffs. More generally, it is among the few studies focused on cliff recession rates in Africa. While a similar application has been conducted for the cliff base in the northern part of the same study area (Raja et al., 2023), that study primarily addresses coastal cliff failure hazards along the Safi coastline in Morocco. In contrast, the present study is focused on determining long-term cliff recession rates and understanding the distribution of these rates and modes of retreat in relation to the physical processes affecting the study area.

METHOD FOR ASSESSING THE IMPACT OF GEOLOGICAL HETEROGENEITY ON OIL SATURATION DISTRIBUTION

This article examines a method for assessing the impact of reservoir heterogeneity on the distribution of oil saturation in pay zones using the example of the Bajossian and Bathonian stages of the Jurassic system of the Kalamkas field. Within this field, the Jurassic oil and gas stratum under consideration lies on the eroded surface of various horizons of the Middle and Lower Triassic and is represented by uneven alternation of sand-siltstone and clay rocks, as a result of which these deposits have a complex geological structure, due in the lithological plan to uneven alternation of sand-siltstone and clay rocks. As a result, a rather complex distribution of oil (water) saturation may occur in the formation, which differs from the standard ideas about the geological structure of the object under study, i.e. the presence of such «unconventional» reservoir boundaries (oil-bearing contour) as capillary barriers of the first kind is possible. As a result of this approach, the following is obtained. For the conditions of occurrence of productive formations of the Bajossian stage of the field in question, in order to ensure that the dimensions of the capillary barrier in the reservoir do not exceed the height of 1 m at an average value of the porosity coefficient Kп = 27,6 % it is necessary to fulfill the inequality of Kпр ≥ 6,1∙10−3 μm2. For the conditions of occurrence of productive formations of the Bathonian stage, in order for the dimensions of the capillary barrier in the reservoir not to exceed the height of 1 m with an average value of the porosity coefficient Kп = 28,0 % it is necessary to Kпр ≥ 7,5∙10−3 μm2. Also, on the basis of this method, various ratios of Kпр permeability coefficients and porosity were obtained Kп at which the dimensions of the capillary barrier in the deposit will exceed the heights of 1.0, 1.5 and 2.0 m above the level of the accepted oil-water contact (OWC) for the conditions of occurrence of the Kalamkas field in question. It was noted that this approach makes it possible to assess uncertainties in the position of fluid contacts when justifying the boundaries of the oil potential contour and the distribution of oil reserves in formations with a wide range of reservoir properties.

Sediment-Hosted Rare-Earth Elements Mineralization from the Dian-Qian District, Southwest China: Mineralogy and Mode of Occurrence

The Xuanwei Formation’s claystones in the Dian-Qian District of Southwest China are rich in rare-earth elements (REEs), suggesting their potential as a source of medium and heavy rare earths. However, the REE content in these rocks is lower than other types of rare-earth deposits, and the interrelationship among clay minerals is intricate. There is no direct evidence indicating the mineralization of REEs, limiting their beneficiation and extraction. The objective of this study is the characterization of REE distribution in the Dian-Qian District. The sedimentary rocks in this district are mainly composed of kaolinite, boehmite, quartz, rutile, and pyrite. The results of continuous chemical extraction of REE-rich claystone and transmission electron microscope (TEM) observations have confirmed that REEs occurred as florencite in the rocks, and that the ion-absorption state makes only a negligible contribution to the REE content. A close relationship between florencite and kaolinite makes traditional mineral processing operations very difficult. Combined with the properties of kaolinite, roasting-acid leaching was the efficacious approach for rare-earth resources extracted from the rare earth-rich clay rocks of the Xuanwei Formation.

Prospects for the allocation of Paleorousels in the subsalt complex of the south-east of the Caspian sedimentary basin

development and features of the formation of the sedimentary complex of the south of the Caspian sedimentary basin are presented. The complex geological structure of the region is mainly due to the influence of tectonic, volcanic and denudation processes on sedimentation. The introduction of terrigenous material deep into the sedimentary basin (Matken-Ushmolinsk, Biikzhal and South Embin zones) by paleorubic flows contributed to the emergence of accumulative shafts and interbranch uplifts composed mainly of clay rocks with alternating siltstone-sandstones. In the paleorusls themselves, coarser sediments were deposited – gravelites and sandstones. The reconstruction of the conditions of formation of sand bodies made it possible to predict their facies composition, morphology and identify patterns of spatial placement, and are also of great interest in the search for oil and gas deposits in deep-lying lithological traps. The prospects of these structures and their resource potential are evidenced by the world experience in identifying large deposits of hydrocarbon raw materials. This is a new highly promising direction of large accumulations of hydrocarbons for the Caspian Basin. The results of drilling deep wells conducted in recent years have made it possible to refine the internal structure, substantiate new facilities in the Late Paleozoic sedimentary complex, and reassess the prospects of oil and gas potential and forecast oil and gas resources of the south of the Caspian Basin.

Identification of interfacial influence zone (IIZ) in clay rock-cement mortar binary based on the macro-pore distribution in space: An NMR and CT investigation

The interfacial influence zone (IIZ) is a weak link between cast-in-situ cement materials and bulk geological materials. Identifying IIZ is essential for studying binary structure’s mechanical properties. This paper aims to locate the IIZ of a clay rock-cement mortar (C-C) binary by macro-pore distribution in space using CT and NMR tests. First, the porous properties of clay rock and cement mortar were analyzed by the T2 spectrum of the NMR test. Mortar’s macro-pore volume is larger than clay rock’s. Second, the 3D pore-matrix models of these two materials were reconstructed., with larger porosity in mortar than clay rock, consistent with NMR tests. Therefore, the method of pore location using 3D reconstructed models based on CT images may be reliable. Finally, a pore-matrix model of the C-C binary was reconstructed, and the IIZ was identified by pore distribution. The IIZ shape is an approximately ellipsoidal area with thin ends and thick middle, with a max thickness of 8 mm.

Improved method for quantitative fault sealing evaluation in sand-clay sequences: A case study from the west subsag of Bozhong Sag in the Bohai Bay basin, China

This research aims to enhance the assessment of fault sealing capacity and predicting sealing hydrocarbon column height prior to drilling, which is instrumental in enhancing drilling success rates. Traditional methods for fault seal evaluation, which primarily consider the fault rock's clay content, often overlook the influence of effective fault normal stress (σNeff). This research analyzed numerous drilled fault-bounded reservoirs in the west subsag of Bozhong Sag to determine the fault sealing's buoyancy pressure (Pb). The shale gouge ratio (SGR) and σNeff for these faults were computed, and a calibration of the relationship between SGR and Pb across varying σNeff ranges was conducted to define the sealing failure envelope. This calibration reveals distinct fault sealing failure envelopes at different σNeff intervals, underscoring the significant impact of σNeff on fault sealing capacity. Consequently, an improved SGR parameter (ISGR) was proposed to incorporate both the fault rock's clay content and the influence of σNeff on fault sealing. By plotting ISGR against Pb, fault sealing failure envelopes were established, and a relationship between fault sealing capacity and ISGR was formulated. This relationship provides a novel means to evaluate the Pb sealable at specific ISGR values. Comparisons of the ISGR algorithm with other algorithms demonstrate a superior correlation with seal capacity in our samples. The fault sealing capacity of drilled fault-bounded traps was evaluated using this relationship, and the predicted hydrocarbon column heights are in close alignment with actual measurements, validating the reliability and accuracy of the ISGR algorithm in fault sealing evaluation. The consideration of both clay content and σNeff in the ISGR parameter and the associated calibration method makes it particularly suitable for assessing the fault's sealing capacity in diverse sand-clay sequences with varying strike and burial depths.

Petrography of terrigenous and clay rocks in the Dostlug field area

Petrography of terrigenous and clay rocks in the Dostlug field area

Gas migration at the granite–bentonite interface under semirigid boundary conditions in the context of high‐level radioactive waste disposal

AbstractThe corrosion of waste canisters in the deep geological disposal facilities (GDFs) for high‐level radioactive waste (HLRW) can generate gas, which escapes from the engineered barrier system through the interfaces between the bentonite buffer blocks and the host rock and those between the bentonite blocks. In this study, a series of water infiltration and gas breakthrough experiments were conducted on granite and on granite–bentonite specimens with smooth and grooved interfaces. On this basis, this study presents new insights and a quantitative assessment of the impact of the interface between clay and host rock on gas transport. As the results show, the water permeability values from water infiltration tests on granite and granite–bentonite samples (10−19–10−20 m2) are found to be slightly higher than that of bentonite. The gas permeability of the mock‐up samples with smooth interfaces is one order of magnitude larger than that of the mock‐up with grooved interfaces. The gas results of breakthrough pressures for the granite and the granite–bentonite mock‐up samples are significantly lower than that of bentonite. The results highlight the potential existence of preferential gas migration channels between the rock and bentonite buffer that require further considerations in safety assessment.

Determination Of Liquefaction Sediment Volume In Balaroa VillageUsing The Geoelectric Resistance Type Method

Introduction: Research has been carried out titled "Determining the Volume of Liquefaction Sediment Using the Geoelectric Resistivity Type Method in Balaroa Village". Methods: This research aims to identify subsurface lithology and determine the volume of liquefaction sediment in Balaroa Village. This research uses the resistivity method Wenner configuration. Result and Discussion: Measurements were carried out in 4 passes with the distance between electrodes on Tracks 1 - 3 being 7 m and on Track 4 a distance of 10 m. From the results of measurements and data interpretation, it was obtained that the type resistance value was 2.98 - 436.14 Ωm with lithology in the form of clay, sand, and gravel. The calculated volume of liquefaction sediment in Balaroa Village is 370,883 m³. Conclusion: Clay and sand rocks are liquefaction sediments with resistance values of less than 67.86 Ωm. Meanwhile, gravel and building debris are non-liquefaction rocks with resistance values of more than 67.86 Ωm. The calculated liquefaction sediment in Balaroa Village is around 370,883 m³. The volume of liquefaction sediment increases in thickness in the eastern part, which is caused by morphological conditions that tend to be more gentle in that part.

Применение бентонитовой глины в качестве гидроизоляционного материала

Purpose: analytical study of usability bentonite is a natural mineral with high waterproofing and adsorption properties in various fields. Methods: methods of comparative analysis, synthesis, generalization, analogy were used. Results: this article examines various applications of bentonite, allowing to position bentonite as a universal material, which is widely used in various industries due to its unique properties. The advantages of bentonite over other waterproofing materials are noted, including environmental friendliness, durability, efficiency and economy. The properties of bentonite clay have been studied, the ability of which to swell and create a waterproofing barrier in contact with water makes it an effective material for protection against moisture. It is indicated that the high frost resistance of bentonite is ensured due to the complex structure of the material consisting of metal oxide atoms and silicon atoms, which form a dense structure. The interlayer space in which the exchange cations are concentrated is the physical and physicochemical basis for the sorption activity of bentonite clay rocks. Bentonite has been found to be of value in its self-healing properties, as is the case when used at negative temperatures. This is due to its molecular structure. The microscopic particles that make up bentonite have a negative charge, they are able to adsorb water molecules. Practical significance: waterproofing works are carried out in many areas of construction. However, bentonite materials are not widely used. In this aspect, the article describes in detail such waterproofing materials as bentonite mats, clay lock, injectable bentonite waterproofing. The authors believe that the demand for the use of bentonite as a reliable and promising means of waterproofing in the construction industry will increase.

Riphean of the Kamsko-Belsk aulacogen: Hiatuses and lithogeochemistry of clastic rocks

Research subject. Sandstones and clay rocks of the Lower, Middle, and Upper Riphean (the Kyrpino, Serafimovo, and Abdulino groups, respectively) of the Kamsko-Belsk aulacogen. Changes in the characteristic values of the ratios of a number of oxides and some trace elements that are the indicators of rock composition in paleowatersheds are considered, taking the hiatuses of different nature and duration into account. Methods. An analysis of the average values of K2O/Al2O3 etc., Th/Sc, La/Co and (La/Yb)N, characteristic of sandstones and fine-grained clastic rocks (shales, fine-grained clayey siltstones and mudstones) of the main lithostratigraphic units of the Riphean section, as well as an analysis of their changes given the position below and above the break surface. Results. Throughout the entire Riphean, regardless of breaks in sedimentation associated with certain rearrangements in the recharge and sedimentation areas, the lithogeochemical characteristics of both sandstones and fine-grained clastic rocks (K2O/Al2O3, TiO2/Al2O3, Th/Sc, La/Co, etc.) were found to experience no signi ficant changes. Conclusions. The hiatuses presented in the Riphean section of the Kamsko-Belsk aulacogene were unlikely to have any significant effect on the average values of a number of ratios–indicators of rock composition in paleowatersheds (K2O/Al2O3, SiO2/Al2O3, TiO2/Al2O3, Th/Sc, La/Co, and (La/Yb)N) in sandstones and clay rocks occurring below and above the hiatus surfaces. This suggests that there were no cardinal changes in the composition of rocks in the paleowatersheds surrounding such a large negative structure as the Kamsko-Belsk aulacogene during the Riphean. Similarly, no fundamental changes occurred in the pathways of clastics entering the sedimentation area associated with the named structure.

Sorption of a Mixture of Heavy Metal Ions by Clay Rocks of the Bryansk Oblast

Sorption of a Mixture of Heavy Metal Ions by Clay Rocks of the Bryansk Oblast