Clausius-Clapeyron Research Articles

Evaluation of the Hydrological Response of Nature-Based Solutions (NBS) in Socio-Economically Vulnerable Tropical Urban Settlements: A Case Study in La Guapil, Costa Rica, Under Climate Change Scenarios

Urbanization increases the number of impervious surfaces in watersheds, reducing infiltration and evapotranspiration, which increases runoff volumes and the risks of flooding and the pollution of water resources. Nature-based solutions (NBS) mitigate these effects by managing water volume and quality, restoring the hydrological cycle, and creating sustainable livelihoods that can promote socioeconomic equity by providing green space. In light of the aforementioned information, this study analyzes the hydrological response of NBS in La Guapil, a densely populated and socioeconomically vulnerable area of Costa Rica with approximately 80% impervious surfaces, focusing on their effectiveness in stormwater management and improving hydrological conditions. Field data from the study area’s storm drainage system, as well as hydrological analyses, were collected and processed to evaluate RCP8.5 climate change scenarios using the Clausius–Clapeyron (CC) relationship. Three scenarios were proposed: (1) the “status quo”, reflecting current conditions, (2) green roofs and green improvements, and (3) detention ponds and green improvements, evaluated using the SWMM, with the latter scenario also using the Iber model. Simulations showed that Scenario 2 achieved the greatest reduction in peak flow (53.74%) and runoff volume (57.60%) compared to Scenario 3 (peak: 28.37%; volume: 56.42%). Both scenarios demonstrate resilience to climate change projections. The results of this study provide a foundation for further research into NBS in Costa Rica and other comparable regions.

Methane Hydrate-in-Oil Systems in the Presence of Natural Amino Acid-Equilibrium Phase Condition Measurements.

This experimental study reports the thermodynamic influence of three different amino acids on methane hydrate in oil-dominated systems, namely, glycine, proline, and alanine. To thoroughly examine the effect of selected amino acids on methane (CH4) hydrate formation compared to the commercial inhibitor monoethylene glycol (MEG) in the presence of oil, the hydrate liquid-vapor equilibrium (H-Lw-Lo-V) curve is used to measure amino acid aqueous solutions. All experiments are performed at a concentration of 10 wt % by using the isochoric T-cycle technique in a high-pressure reactor cell at the selected range of pressures with temperatures of 4.0-9.0 MPa and 276.5-286.0 K, respectively. Results show that all studied amino acids inhibit hydrate formation of methane; the inhibition trend shows as glycine > alanine > proline in both systems; in the brine water system, the inhibition performance was higher than in the pure water system due to the presence of NaCl. Glycine showed the highest inhibition strength in both systems with an average reduced temperature in pure and brine water of 0.92 and 1.75 K, respectively, at 10 wt %, making the inhibition performance of glycine comparable to the commercial inhibitor MEG. The inhibition effect is attributed to the amino acid's hydrogen bonding energies and side group alkyl chain. Calculating the dissociation enthalpies of methane hydrates in the presence of amino acids using the Clausius-Clapeyron equation implies that the amino acids do not occupy the cage structures during methane hydrate formation.

Future changes in rainfall variability for the mainland Indochina southwest monsoon

Researching future changes in rainfall variability is critical for mitigating the possible effects of global warming, especially in areas where vulnerability is high, such as Indochina. While changes in mean and extreme rainfall have received a great deal of attention, rainfall variability has been poorly researched, despite its importance. We endeavored to determine the anticipated changes in rainfall variability during the mainland Indochina southwest monsoon (MSWM) by utilizing data derived from 5 ensemble models participating in the Coupled Model Intercomparison Project Phase 6 (CMIP6). Employing band pass filtering techniques on daily rainfall data, we discerned variability across an expansive spectrum of temporal scales. Our research indicates that, in the event of global warming, the variability in MSWM rainfall is expected to increase by approximately 10-25% throughout the whole region. Notably, this increased unpredictability appears uniformly throughout a wide range of time intervals. Changes in average rainfall significantly aid in explaining the majority of the intermodal variance in the predicted MSWM rainfall variability. To gain further insight into this phenomenon, we examined the effects of elevated atmospheric moisture content through the estimation of modifications resulting from idealized local thermodynamic enhancement. We showed that increased atmospheric moisture, as suggested by the Clausius-Clapeyron relation, accounts for most of the predicted changes in rainfall variability at all time scales.

Moisture desorption isotherms and thermodynamic properties of ecalyptus globulus wood

This paper aimed to analyze the moisture desorption isotherms and specific thermodynamic properties of Algerian Eucalyptus globulus wood using the static gravimetric method. The study was conducted at height temperatures and relative humidity levels ranging from 5% to 90%. The desorption isotherms exhibited a sigmoidal shape, categorized as "type II." A suitable "thermodynamic" equation was chosen to describe the desorption isotherms under controlled conditions. The Clausius-Clapeyron relationship was employed to determine the isosteric heat of desorption. The results demonstrated that, for equilibrium moisture content below 4%, the differential enthalpy and entropy decreased exponentially with increasing moisture content. Specifically, the differential enthalpy decreased from 36 kJ/mol to 5 kJ/mol, while the entropy decreased from 76 J/ (mol K) to 13 J/ (mol K). The enthalpy-entropy compensation theory in the desorption reaction was validated by the observed difference between the isokinetic temperature and the harmonic temperature. Moreover, the wood-water desorption process was spontaneous, as confirmed by the negative value of Gibbs free energy (-1690 J/mol). With increasing temperature, the spreading pressure dropped; at 40°C, it was 2.47978 J/m², and at 80°C, it was 0.82328 J/m². Conversely, the rate of increase was 0.11% J/m² per relative humidity as the water activity increased.

Fast-get-faster explains wavier upper-level jet stream under climate change

Earth’s upper-level jet streams primarily flow in the eastward direction. They often exhibit a north-south component or waviness connected to extreme weather at the surface. Recently the upper-level eastward jet stream was found to exhibit a fast-get-faster response under climate change explained by the impact of the nonlinear Clausius-Clapeyron relation on the latitudinal density contrast. Here we show the fast-get-faster mechanism also applies to the upper-level north-south jet stream wind and the longitudinal density contrast, implying increased waviness under climate change. Arctic Sea ice loss, which has been proposed as a driver of increased waviness, cannot explain the response. It leads to a fast-get-slower waviness response at all vertical levels. We demonstrate the fast-get-faster waviness signal has emerged in reanalysis data in the Southern Hemisphere but not yet in the Northern Hemisphere. The results show the fast-get-faster mechanism explains upper-level waviness changes and highlights a tug of war between upper- and mid-level waviness under climate change.

Experimental measurements and thermodynamic modeling of dissociation pressure of CO2 hydrate in sulfate solutions

Carbon capture and storage (CCS) has been a popular strategy to mitigate climate change and has attracted significant attention from both industry and academia. CO2 can be stored in the form of CO2 hydrate in deeper locations in an ocean, which makes it a potential option for CO2 sequestration. Dissolved salts in the ocean brine can significantly affect the dissociation pressure of CO2 hydrate. Sulfate salts are one of the most common salt species in the oceanic brine. Although various experimental studies have been conducted to investigate the phase behavior of CO2 hydrate in brine, few studies focus on the effect of sulfate salts on the dissociation pressure of CO2 hydrate. In this study, we build an in-house experimental setup to investigate the effect of monovalent and divalent sulfate salts on the dissociation pressure of CO2 hydrate. The dissociation pressure of CO2 hydrate in Na2SO4, K2SO4, MgSO4, and CuSO4 aqueous solutions is measured using the isochoric pressure search method at different concentrations over the temperature range of 274.36 – 282.15 K and the pressure range of 1.50 – 4.03 MPa. A hybrid methodology incorporating the Soave-Redlich-Kwong Equation of State (SRK EOS), the van der Waals-Platteeuw (vdW-P) model, and the Pitzer model is applied to predict the dissociation pressure of CO2 in sulfate solutions. In addition, the dissociation enthalpies of CO2 hydrate in these sulfate solutions are calculated using the Clausius-Clapeyron equation based on the measured dissociation points. The experimental results show that the dissociation pressure of CO2 hydrate in Na2SO4, K2SO4, and MgSO4 solutions is higher than that in pure water, and the dissociation pressure of CO2 hydrate in sulfate solutions increases with an increasing salt concentration. Conversely, CuSO4 barely affects the dissociation pressure of CO2 hydrate, which is mainly attributed to the lower molar concentration of the ions compared with the other salt solutions and the ion specificity of Cu2+. The prediction results are in alignment with the experimental data measured in this study, which proves the feasibility of the thermodynamic model in predicting the dissociation pressure of CO2 hydrate in sulfate solutions. Additionally, the calculated dissociation enthalpies of CO2 hydrate show a dependence on both temperature and salt concentration. It is also revealed that Cu2+ exhibits ion specificity in affecting the dissociation enthalpy of CO2 hydrate, likely due to its more distinct ability to impact the cage occupancy of CO2 hydrate than the other ions. These findings enhance our understanding of the impact of sulfate salts on the dissociation behavior of CO2 hydrate and offer valuable insights for CO2 sequestration.

Phase equilibria and guest gas occupancy characteristics of H2-DIOX sII hydrates based on calorimetric and Raman analysis

Hydrogen (H2) as the most abundant element offers a clean energy solution for a sustainable future. Thermodynamic hydrate promoters can enhance hydrate-based H2 storage under mild pressure conditions. 1,3-dioxolane (DIOX) as a low-toxicity promoter has attracted attention for its potential to improve H2 hydrate kinetics. However, the phase equilibria of H2-DIOX in the presence of DIOX and its thermodynamic promotion mechanism are not fully elaborated and warrant thorough investigation. In this study, the phase equilibria of H2-DIOX hydrates were measured for DIOX concentrations (CDIOX) ranging from 2.0 mol% to 5.56 mol%. The equilibrium temperature of H2-DIOX hydrates shifted rightward by 2.3 K at 15.0 MPa for 5.56 mol% DIOX compared to 2.0 mol% DIOX. The measured thermodynamic data were validated by fitting the H2-DIOX hydrate phase equilibira using the Clausius–Clapeyron equation. The cage occupancy of H2 and DIOX in H2-DIOX sII hydrates was revealed through Raman spectroscopy and DSC thermal analysis. Two types of hydrates (DIOX and H2-DIOX) were observed for all CDIOX. Single H2 molecules were enclathrated in the 512 cages of H2-DIOX hydrates and increasing CDIOX effectively enhanced DIOX molecules enclathration in the 51264 cages but had limited effect on the H2 molecules in the 512 cages. The findings of this study provide fundametnal thermodynamic data and cage occupancy charateristics for H2-DIOX sII hydrates below 15.0 MPa. The results provide guidance on the optimal thermodynamic promoter concentrations for future large-scale hydrate-based H2 storage application.

A combined experimental-mathematical study on the kinetics of dry ice sublimation under different airflow velocities and blowing modes

The sublimation rate of dry ice, crucial for its cooling performance, is typically influenced by environmental temperature, pressure, and specific surface area. However, the effect of wind speed under forced air convection is not well understood, and current sublimation kinetic models inadequately capture this influence, leading to discrepancies between simulations and experiments. This study examines the sublimation kinetics of static dry ice particles under varying wind speeds and blowing modes. A mathematical model was developed to determine the sublimation kinetic parameters by integrating the Clausius-Clapeyron equation, mass transfer theory, and hybrid particle swarm optimization (HPSO) algorithm. These parameters were then used to create a cooling model for a small insulated box, and the results were validated against experimental data. The findings show that increasing wind speed enhances the sublimation rate of dry ice, with upward-blowing conditions resulting in higher rates than side-blowing conditions. The model’s predictions closely match experimental data, with a maximum mass change deviation of less than 3 % and a maximum temperature deviation of less than 4 °C, demonstrating high reliability.

A Methodological Approach to Improving Extreme Precipitation Reanalysis Data Using the Clausius-Clapeyron Relationship: A Case Study in a Mediterranean City

Climate change is a crucial issue of the 21st century, leading to more frequent and severe extreme precipitation events globally. These events result in significant social and economic disruptions, including flooding, loss of life, and damage to infrastructure. Projections suggest that extreme rainfall will intensify in the latter half of the century, underscoring the need for accurate and timely forecasting. Despite advancements in meteorological and climate models that offer high accuracy for various weather parameters, these models still struggle to detect extreme values, particularly for precipitation. This research examines the sensitivity of extreme precipitation events to temperature, based on the Clausius-Clapeyron relationship, focusing on Thessaloniki, Greece. It also evaluates the effectiveness of reanalysis data in identifying extreme precipitation and explores how rainfall-temperature relationships can enhance prediction accuracy. The findings are vital for improving the estimation of extreme rainfall events and informing the design of flood-resilient infrastructure.

Anthropogenic influence on precipitation in Aotearoa New Zealand with differing circulation types

This study quantifies the influences of anthropogenic forcing to date on precipitation over Aotearoa New Zealand (ANZ). Large ensembles of simulations from the weather@home regional climate model experiments are analysed under two scenarios, a natural (NAT) or counter-factual scenario which excludes human-induced changes to the climate system and an anthropogenic (ANT) or factual scenario. The impacts of anthropogenic forcing on precipitation are analysed in the context of large-scale circulation types characterized using an existing Self Organizing Map classification. The combined effect of both thermodynamics and dynamics are compared with values expected from the Clausius–Clapeyron (C–C) relation. Changes in the precipitation intensity due to greenhouse gas-forced temperature rise are lower than the expected C–C value. However extreme precipitation changes approach the C–C value for some circulation types. Specifically westerly flows enhance precipitation change across ANZ relative to the C–C rate, particularly over the West Coast. Conversely, northwesterly flows reduce the change over the North Island relative to the C–C value. Moreover, the wet day frequency generally reduces in the ANT scenario relative to NAT, reductions are largest on the West Coast of the South Island for westerly flows. Additionally, the frequency of days with extreme precipitation rises over ANZ for most circulation patterns, except in Northland and for northwesterly flows. This underscores the combined influence of dynamics and thermodynamics in shaping both precipitation intensity and frequency patterns across ANZ.

Assessment of dissociation enthalpies of methane hydrates in the absence and presence of ionic liquids using the Clausius-Clapeyron approach

The Clausius-Clapeyron (CC) equation is generally preferred to obtain dissociation enthalpies (ΔH) of hydrate-forming systems due to its ease of use. The application of other direct and indirect methods becomes more problematic if complex additives such as ionic liquids (ILs) are also present in the system. In this work, around 400 equilibrium data points for methane hydrates in the presence of over 80 ILs were collected from the literature in the temperature and pressure ranges of (272.10 – 306.07) K and (2.48 – 100.34) MPa, respectively. The ΔH of methane hydrates in the absence and presence of ionic liquids (ILs) have been calculated using the CC equation. The compressibility factor (z), required to calculate ΔH at each phase equilibrium condition has been obtained from three different approaches viz., Peng-Robinson (PR) equation of state, Soave-Redlich-Kwong (SRK) equation of state and Pitzer (Pz) correlation. The results were compared to the experimentally reported dissociation enthalpy (54.5 ± 1.5 kJ.mol−1) of methane hydrates. The role of the compressibility factor along with the slope of the equilibrium data set and the temperature/pressure range in determining the outcome of the CC equation has been discussed. The effect of molar mass, molar volume, and hydrate suppression temperature of the ILs on the ΔH of methane hydrates has been explored. The tested ILs do not show a systematic and significant influence on enthalpies, rather they show a large scattering in the ΔH values, which might mask any existing subtle effect of the ILs on the dissociation enthalpies. Therefore, this approach should be dealt with care to obtain molecular-level insights.

Effect of the gas layer evolution on electrolytic plasma polishing of stainless steel

In recent years, electrolytic plasma polishing technology has attracted wide attention due to its advantages of shape adaptability, high efficiency, better precision, environmental friendliness, and non-contact polishing. However, the lack of research on the evolution mechanism of the gas layer at the anode interface restricts the improvement of the material removal mechanism and the regulation of the polishing effect. Firstly, the thermodynamic conditions of gas layer formation were analyzed based on the Clapeyron-Clausius equation, and the key parameters affecting the gas layer were identified. Secondly, the laws of voltage and electrolyte temperature on the dynamic evolution of the gas layer and its polishing effect were revealed. Additionally, the influence of the gas layer on the voltage-current characteristics was also investigated by analyzing the experimental phenomena. The results indicate that the optimal polishing effect is achieved at a voltage level of 300 V resulting in a decrease in Ra from 0.451 μm to 0.076 μm. Similarly, superior polishing results are obtained when the electrolyte temperature is 80 °C, with a decrease in Ra from 0.451 μm to 0.075 μm. This study provides theoretical guidance for the further development and application of electrolytic plasma polishing technology.

Enthalpies and entropies of sublimation and vaporization of aza crown ethers and cryptands measured by TGA

AbstractIn this work, the solid–gas and liquid–gas change of phase enthalpies of three aza crown ethers and two cryptands are derived from thermogravimetric data. For each of the compounds under study, the mass loss rate, dm/dt, was measured by isothermal thermogravimetry, then Pieterse and Focke equation combined with that of Clausius–Clapeyron was applied to correlate mass loss rate with temperature and to derive the respective vaporization or sublimation enthalpies at the experimental temperature and at 298.15 K. Such enthalpies are reported with the derived entropies and Gibbs energies of change of phase for the analyzed compounds. The results show a general trend of increasing value of the thermodynamic property as the number of the nitrogen atoms increases in the molecular structure of the macrocycle.

Adsorption of Carbon Dioxide and Nitrogen in Co3(ndc)3(dabco) Metal-Organic Framework.

Metal-organic frameworks (MOFs) are promising materials for processes such as carbon dioxide (CO2) capture or its storage. In this work, the adsorption of CO2 and nitrogen (N2) in Co3(ndc)3(dabco) MOF (ndc: 2,6-naphthalenedicarboxylate; dabco: 1,4-diazabicyclo[2.2.2]octane) is reported for the first time over the temperature range of 273-323 K and up to 35 bar. The adsorption isotherms are successfully described using the Langmuir isotherm model. The heats of adsorption for CO2 and N2, determined through the Clausius-Clapeyron equation, are 20-27 kJ/mol and 10-11 kJ/mol, respectively. The impact of using pressure and/or temperature swings on the CO2 working capacity is evaluated. If a flue gas with 15% CO2 is fed at 6 bar and 303 K and regenerated at 1 bar and 373 K, 1.58 moles of CO2 can be captured per kg of MOF. The analysis of the multicomponent adsorption of typical flue gas streams (15% CO2 balanced with N2), using the ideal adsorbed solution theory (IAST), shows that at 1 bar and 303 K, the CO2/N2 selectivity is 11.5. In summary, this work reports essential data for the design of adsorption-based processes for CO2 capture using a Co3(ndc)3(dabco) MOF, such as pressure swing adsorption (PSA).

A Quasi-Steady Model for Estimating the Rate of Frost Heave When Subjected to Overburden Pressure

The soil beneath buildings constructed in cold regions is affected by frost heave, causing the walls to crack and even the buildings to incline and collapse. Therefore, predicting the frost heave when subjected to overburden pressure is crucial for engineering buildings in cold areas. Utilizing the conservation equation of mass, Darcy’s equation, and the assumption that the pore water pressure at the top of a frozen fringe, denoted as uw, during the quasi-steady state can be approximately estimated using the Clapeyron equation, a quasi-steady frost heave rate model considering the overburden pressure was proposed. This study considered the difference in pore water pressure within the frozen fringe, which causes water to move from the unfrozen zone to the ice lens, where it subsequently accumulates and freezes into ice. The pore water pressure at the bottom of the frozen fringe, denoted as uu, can be estimated using the soil water characteristic curve (SWCC). The thickness of the frozen fringe was determined using the freezing temperature, segregation temperature, and temperature gradient. The segregation temperature was determined using the two-point method. Additionally, the model suggested that, when uw = uu, the movement of water stopped, leading to the end of frost heave. To validate the proposed model, three existing frost-heaving experiments were analyzed. The findings demonstrated that the estimated rates of frost heave of the samples closely matched the experimental data. Additionally, external pressure delayed water migration. This study can offer theoretical support for building engineering in cold regions.

A description of the melting of ice with the modified Clapeyron-Clausius equation

A description of the melting of ice with the modified Clapeyron-Clausius equation

Enhanced precipitation responses over the Tibetan Plateau following future Tambora-size volcanic eruption

Hydroclimate over the Tibetan Plateau (TP) notably influences the eco-environment of the Northern Hemisphere. Given its high elevation and complex topography, the climate in the TP shows a high sensitivity to anthropogenic warming and volcanic-induced cooling. The mechanism by which a future volcanic or similar radiative perturbation affects precipitation in the TP under an anthropogenic warming climate must be addressed not only to enable regional adaptation but deepen our understanding of how a climate system evolves under such a dual force. Here, based on the Community Earth System Model version 1.2 and ensemble simulations under pre-industrial and RCP8.5 scenarios, we showed that a Tambora-sized volcanic perturbation led to severe rainfall reduction over the south TP in the following summer (June–August). Evaporation response accounted for a minor and relatively constant share of precipitation reduction following the Clausius–Clapeyron scaling, whereas dynamic processes triggered an El Niño-like response in the eastern equatorial Pacific, which suppressed the Walker and Hadley circulation and contributed to drying anomalies. Global warming renders the post-Tambora hydroclimate responses with 30% higher severity as a result of the increased climatological moisture content and intensified El Niño response, which enhanced hydroclimate sensitivity and attenuated monsoon circulation. The results illustrate the amplification effect of global warming on the plateau's hydroclimate responses to external forcings, which may add another layer of uncertainty on climate adaptation in this already complex region.

Comparison of surface adsorption efficacies of eco-sustainable agro/animal biomass-derived activated carbon for the removal of rhodamine B and hexavalent chromium.

Effective management and remediation strategies are crucial to minimize the impacts of both organic and inorganic contaminants on environmental quality and human health. This study investigates a novel approach utilizing cotton shell activated carbon (CSAC), rice husk activated carbon (RHAC), and wasp hive activated carbon (WHAC), produced through alkali treatment and carbonization under N2 atmosphere at 600°C. The adsorption capacities of biomass-derived mesoporous activated carbons (CSAC, RHAC, WHAC) alongside macroporous commercial activated carbons (CAC) were evaluated for removing rhodamine B (Rh B) and hexavalent chromium (Cr6+). The CSAC exhibits remarkable adsorption efficiency (255.4mg.g-1) for Cr(VI) removal, while RHAC demonstrates superior efficacy (174.2mg.g-1) for Rh B adsorption. Investigating various optimal parameters including initial pH (pH 3 for Cr and pH7 for Rh B), catalyst dosage (200mg.L-1), and initial concentration (20mg.L-1), the Redlich-Peterson isotherm model is applied to reveal a hybrid adsorption mechanism encompassing monolayer (chemisorption) and multilayer (van der Waals adsorption) processes. Kinetic analysis highlights the pseudo-second-order and Elovich models as the most suitable, suggesting physiochemisorption mechanisms. Thermodynamic analysis indicates the endothermic nature of the adsorption process, with increased randomness at the solid-solution interface. Isosteric heat investigations using Clausius-Clapeyron, Arrhenius, and Eyring equations reveal a heterogeneous surface nature across all activated carbons. Further confirmation of Rh B and Cr(VI) adsorption onto activated carbons is provided through FTIR, FESEM, and EDAX analysis. This study highlights the innovation and promise of utilizing biomass-derived activated carbons for effective pollutant removal.

A novel phase-field lattice Boltzmann framework for diffusion-driven multiphase evaporation

Heat transfer and phase change phenomena, particularly diffusion-driven droplet evaporation, play pivotal roles in various industrial applications and natural processes. Despite advancements in computational fluid dynamics, modeling multiphase flows with large density ratios remains challenging. In this study, we developed a robust and stable conservative Allen–Cahn-based phase-field lattice Boltzmann method to solve the flow field equations. This method is coupled with the finite difference discretization of vapor species transport equation and the energy equation. The coupling between the vapor concentration and temperature field at the interface is modeled by the well-known Clausius–Clapeyron correlation. Our approach is capable of simulations under real physical conditions and is compatible with graphics processing unit architecture, making it ideal for large-scale industrial simulations. Three validation test cases are conducted to demonstrate the consistency of the presented model, including simulations of Stefan flow, the evaporation of suspended droplets containing water, acetone, and ethanol in the air, and the evaporation of a water sessile droplet on a flat surface. The results show that the model is able to predict the behavior and characteristics of each case accurately. Notably, our numerical results exhibit a maximum relative error of approximately 1% in simulations of Stefan flow. In the case of suspended droplet evaporation, the observed maximum difference between the calculated wet bulb temperatures and those derived from psychrometric charts is approximately 0.9 K. Moreover, our analysis of the sessile droplet reveals a good agreement between the results obtained by our model for the evaporative mass flux and those obtained from the existing models in the literature for different contact angles.

Experimental characterisation of the isosteric desorption energy of VeRCoRs concrete: Comparison of the isotherms and hygrometric methods

The Clausius-Clapeyron equation is an effective tool for describing the effect of temperature on water vapour adsorption isotherms in cementitious materials. The key information is the isosteric energy. This can currently be characterised experimentally using two approaches: (1) the isotherms method, which involves experimentally acquiring the desorption isotherm for two (or more) different temperatures, and (2) the hygrometric method, which involves monitoring the increase in vapour pressure at equilibrium with a small sample subjected to increasing temperature steps. It turns out that although each method has a fairly high uncertainty, the results obtained are similar. Finally, the results seem to suggest that the isosteric energy of Portland-based cementitious materials could be considered unique.