Breccia Clasts Research Articles

Lunar feldspathic meteorite Dhofar 081: Petrochemical constraints on petrogenesis

Two alternative petrogenetic models, plagioclase flotation and serial magmatism have been proposed to explain the origin of the lunar anorthositic crust, covering ~80% of the lunar highland. In this study, we re-examine the possible relict igneous texture present in an inferred lunar highland breccia clast (area ~1 mm2) in the Dhofar 081 meteorite. Our new petrographic and in-situ mineral microprobe chemical data on this clast show this coarse grained (average grain size ~0.5 mm) clast preserves relict igneous texture where subhedral, prismatic low-Ca pyroxene has intergrown with anhedral anorthitic plagioclase, suggesting its eutectic crystallization from its parent silicate magma. Absence of maskelynite and similarity of Na, K contents of plagioclase with the FAN assemblages negate the possibility of crystallization of the studied relict clast from an impact melt. The mineral-chemical data of Dhofar 081 suggest it is FAN (Ferroan anorthosite) in composition (after Warren in Annu. Rev. Earth Planet. Sci. 13:201–240, 1985). Hence, intergrown crystallization of minerals in the present relict igneous clasts and other reported FAN samples argues against a cumulate origin of the lunar anorthosite. The orthopyroxenes present in the unbrecciated portion of this meteoritic clast include bimodal low- and high-iron geochemical sub-groups. The application of orthopyroxene and plagioclase thermobarometry (after Gasparik in Contrib. Mineral. Petrol. 96:357–370, 1987) on our new microprobe data, and also two-pyroxene thermometry (after Lindsley in Am. Mineral. 68:477–493, 1983; Putirka in Rev. Mineral. Geochem. 69(1):61–120, 2008) on our new microprobe data and synthesis of literature data constrain the pressure and temperature of crystallization of lunar anorthosite parent magma close to 8 kbar and 1050°C, respectively. Application of Fo–An–Q experimental phase diagram at high pressure (up to 20 kbar) negates the possibility of generation of lunar anorthosite from a lherzolite source, the parent magma of these anorthosites probably lie on or close to Fo–An join of this phase diagram close to the spinel field.

Providing context to the Homo naledi fossils: Constraints from flowstones on the age of sediment deposits in Rising Star Cave, South Africa

Rising Star Cave in the Cradle of Humankind, South Africa, contains one of the richest hominin-bearing deposits in the world, and is the type locality for the Homo naledi fossils. This paper provides a stratigraphic and geochronological framework, within which published and future fossil finds from Rising Star Cave can be placed. Detailed mapping of flowstone horizons combined with new age constraints based on both U-Th disequilibrium and 234U/238U dates and one new OSL date help define seven periods of flowstone formation that punctuate episodes of clastic sedimentation and erosion. Clastic sediments entered the cave through an opening in the roof of the Postbox Chamber from about 600 ka onward, until the opening was choked by coarse breccia blocks, probably sometime after 180 ka. Depositional and erosional events changed the internal morphology of the cave chambers over time, and thereby changed the access route into the Dinaledi Chamber where the bulk of the H. naledi fossils were found.Periods of pervasive flowstone formation at all levels of the cave occurred at >600 ka, ~500–400 ka, ~225–190 ka and ~110-90 ka. Additional periods of localised flowstone growth restricted to individual chambers (or parts thereof) occurred at ~300 ka, ~160 ka, ~70 ka, ~50 ka, ~30 ka, and ~10 ka. Flowstone horizons bracket sedimentary units that include a variety of sediment types that changed with time. The oldest flowstones overlie lithified mud clast breccias (LMCB), which were partly eroded before they were covered by externally derived laminated orange sands (LOS) and 500–400 ka flowstones. These flowstones and sands were removed between 290 ka and 225 ka, with sediment transported to deeper parts of the cave via erosion channels characterised by massive orange sands (MOS). In this period of time, the access route into the Dinaledi Chamber may have further changed due to the collapse of the Dragon's Back block. Deposition of laminated orange-red mud (LORM) from suspension occurred between 225 and 190 ka and temporally overlaps with widespread flowstone formation around ~225 ka and ~200 ka. The LORM deposits were largely removed from the upper chambers by ~110 ka, before the youngest group of flowstones formed in the cave; some of which are still growing today.The U-Th ages from Rising Star Cave, combined with other dating constraints reveal age clusters of flowstone formation, which coincided with warmer interglacial or interstadial periods. The patterns recognised in Rising Star Cave overlap with periods of flowstone formation recognised in nearby caves in the Cradle of Humankind, thereby confirming a regional climatic control on flowstone growth in caves during the past 500 ky.The new ages further constrain the minimum age of H. naledi to ~241 ka. Thus, H. naledi entered the cave between 241 ka and 335 ka, during a glacial period, at which time clastic sediments inside the cave were undergoing erosion. H. naledi would probably have entered the cave through an access point in the roof of the Postbox Chamber and made its way along a SW trending fracture towards the Dragon's Back and Dinaledi Chambers.

3D outcrop modelling of large discordant breccia bodies in basinal carbonates of the Apulian margin, Italy

Large discordant breccia bodies (LDBBs) are important record keepers of the tectonic and gravitational evolution in platform-to-basinal settings, and have important implications for fluid-flow migration and compartmentalization of tight carbonate reservoirs. In the Gargano Promontory of southern Italy, LDBBs occur within a Cretaceous slope and basinal carbonate succession. We use field mapping and Unmanned Aerial Vehicle (UAV) -based Structure from Motion (SfM) Photogrammetry to document otherwise inaccessible cliff-side exposures of seismic-to subseismic-scale vertical discordant breccias. LDBBs are up to 50 m in width, more than 80 m in height and display internal chaotic or aligned clast fabrics. The formation which generally contains the LDBBs is characterized by beds of cherty pelagic limestone intercalated with calcarenites, calciturbidites and horizons of mass transport deposits. The mass-transport deposits can be correlated across the chaotic breccia bodies, indicating only slight or no vertical displacement across the adjacent walls. The bases of the breccia bodies are always hidden below current sea level, while the rarely exposed tops are capped by bedded intervals of the host rock formation. Timing and origin of the studied breccias were determined using several lines of evidence, such as stratigraphic provenance of clasts in breccias, mutual relationships of structural and sedimentologic features, and previous studies which establish that the age of dolomitizing cements in the LDBBs formed at different times and by different processes (fault shearing and solution collapse). This work investigates the size, shape and geometry of these breccia bodies whilst also providing cm-scale detail of the textural features in otherwise inaccessible outcrops. We suggest that breccias formed as a result of solution exploiting a pre-existing fracture network characterized by large-scale vertical strike-slip or oblique-slip faults. Initial displacement along these faults created a wide fault damage zone, where fluid migration was later focused to create a zone highly susceptible to solution and subsequent periodic sidewall collapse.

Carbonates at the supergiant Olympic Dam Cu-U-Au-Ag deposit, South Australia. Part 1: Distribution, textures, associations and stable isotope (C, O) signatures

The supergiant Olympic Dam Cu-U-Au-Ag deposit in South Australia is a type example of the iron-oxide copper–gold (IOCG) deposit family. Hosted entirely within heterogeneous breccia in 1.59 Ga granite, the deposit contains a volumetrically substantial and mineralogically diverse component of carbonate minerals. Carbonate minerals are always associated with ore minerals (sulfides, uraninite), implying a genetic relationship and providing an opportunity to use gangue carbonates to better understand ore formation. This study provides the first detailed and comprehensive petrographic and chemical/isotopic study of Olympic Dam carbonates, with a particular emphasis on petrography and texture, and an attempt is made to relate carbonate formation to local and regional events that have affected Olympic Dam.Based on a set of 196 carbonate-bearing samples, carbonate minerals are observed in all lithologies present at Olympic Dam. Carbonates occur as cement in breccia and conglomerates, as breccia clasts, in veins crosscutting ore-rich breccia and other rock types, in pores and ooids, and in the form of laminated carbonate. Siderite and siderite-rhodochrosite-magnesite solid solution are by far the most common carbonate types, whereas calcite, dolomite-ankerite solid solution and REE-fluorocarbonates are locally abundant. Single carbonate grains typically show compositional zones (simple or oscillatory) and replacement textures (including mutual replacement of carbonates with other carbonates and with hematite) are common. In the absence of consistent, deposit-wide paragenetic relationships, the carbonates were placed in seven associations based on host rock, mineralogy and texture: (1) coarse-grained calcite veins in weakly brecciated granite and rhyolite, (2) carbonates in strongly brecciated granite, (3) carbonate veins in bedded clastic facies, (4) carbonates in mafic and ultramafic igneous rocks, (5) massive barite-fluorite-dominated veins with minor carbonate, (6) laminated siderite, and (7) carbonate matrix in conglomerate-breccia-sandstone above the unconformity. Some of these associations can be related to regional tectonic events based on local context and relationships with dated assemblages. δ13C (−6.5‰ to −2‰) values for the carbonates show a relatively limited range whereas δ18O is more variable (+9.4‰ to + 20.9‰). C-O isotopic compositions for the various carbonate associations tend to overlap, suggestive of mixed fluid sources, recycling of older carbonate and perhaps other fractionation processes. The C-O isotope data overlap the compositional fields of several major carbon–oxygen reservoirs (magmatic, sedimentary) and carbon sources in local granite, felsic volcanics, older BIF and sedimentary rocks are all possible at different stages of carbonate deposition.

The Norfolk Ridge seamounts: Eocene–Miocene volcanoes near Zealandia’s rifted continental margin

New age and geochemical data are used to investigate the origin of a ∼670 km-long line of eight seamount volcanoes along the western side of the Norfolk Ridge between New Caledonia and New Zealand. Altered lavas and limestones were dredged from three volcanoes during the 2015 Volcanic Evolution of South Pacific Arcs cruise of N/O l’Atalante, so a total of four, including the northernmost and southernmost, have now been directly sampled and analysed. Dating of lava and volcanic breccia clasts by Ar–Ar methods gives north-to-south ages from these sites of 31.3 ± 0.6, 33 ± 5, 21.5 ± 1.0 and 26.3 ± 0.1 Ma. These ages, along with supporting stratigraphic data on a fifth seamount from IODP borehole U1507, provisionally refute the hypotheses that the seamounts represent a southward-younging, age-progressive, intraplate volcanic chain on the Australian Plate or a subduction-related chain of restricted age range. Geochemically, the upper Eocene to lower Miocene lavas have alkaline and subalkaline basaltic compositions, and some could be shoshonitic. The location of the volcanoes along the western side of the Norfolk Ridge suggests an origin related to late Eocene and early Miocene melting near an intracontinental lithosphere–asthenosphere step. Involvement of a deep slab in petrogenesis is also possible. KEY POINTS Eight seamounts form a line along the Norfolk Ridge. Dating and geochemistry indicate the seamount line is not a hotspot track. A rift-related origin, possibly with influence by subduction, is proposed.

Characteristics of a wing-like sandstone intrusion, Volund Field

Abstract Reservoirs in the Volund Field are all sandstone intrusions with wings on three sides forming the main reservoir volumes. The southern wing was the target of exploration and appraisal wells, which led to the field development. Identification of three smaller intrusions proves the southern wing to be a composite intrusion, similar to outcrop analogues. Identification from core and borehole logs shows that it comprises sandstone-, mudstone- and mudstone-rich intervals, including mudstone clast breccia. Mudstone clast breccia constitutes a significant missed pay candidate. Breccia is porous and has a sand-supported matrix, which gives it excellent reservoir quality. This may be missed pay using analysis of borehole logs. Well data, largely borehole logs, show consistently uniform sandstone porosity distribution within the intrusions, independent of depth. Significantly, at about 100 m from the depth at which the wing emanates from sills, porosity has a broader spread of values. The spread of values is attributable to mudstone clast breccia and thin-bedded sandstone and mudstone. Porosity derived from borehole logs does not differentiate breccia from siltstone, but inference is possible using calibration of logs with core.

Petrographic and geochemical evidence of the diagenetic environment and fluid source of dolomitization of dolomite: a case study from the Ma55 to Ma51 submembers of the Ordovician Majiagou Formation, central Yishan Slope, Ordos Basin, China

Dolomite is the most important component of the prolific reservoirs in the Ma55 to Ma51 submembers of the Ordovician Majiagou Formation in the central Yishan Slope, Ordos Basin. However, the origins of the different types of dolomite are unclear because of the different diagenetic environments and complex diagenetic fluids. This paper mainly focuses on the diagenetic environment and diagenetic fluid associated with the dolomite. The petrographic features of the dolomite were studied on the basis of core observation and thin section identification. Geochemical characteristics were analyzed according to the O, C and Sr stable isotopes and major and trace elements. The results demonstrate that, petrographically, the dolomite can be divided into four types, namely, type 1, type 2, type 3 and type 4. Type 1 is mainly characterized by dolomite with gypsum and salt dissolution as well as breccia structures with no clay minerals filling between breccia clasts. Type 2 is characterized by powder-fine crystalline dolomite with apparent residual textures and residual intergranular and intercrystal pores. Type 3 is characterized by leopard limestone or dolomite with leopard textures and massive bioborings. Finally, type 4 is characterized by karst breccia dolomite with many fractures and caves filled by abundant terrigenous clay minerals. In combination with the petrographic data, analysis of the geochemical data reveals that the type 1 dolomite formed in an early near-surface diagenetic environment and the diagenetic fluid might have been early freshwater. Type 2 and type 3 dolomite formed in a shallow-burial diagenetic environment. The diagenetic fluid of type 2 dolomite might have been hypersaline brine that was influenced by freshwater, but that of type 3 dolomite might have been a mixed fluid consisting of seawater and freshwater, which was less saline than the type 2 dolomite fluid. Type 4 dolomite formed in an epidiagenetic near-surface environment and the diagenetic fluid might have been superficial freshwater carrying abundant terrigenous clay minerals. The study shows that the analysis of the diagenetic environment and fluid of dolomite has great significance for research on dolomite origins. The porosity and permeability values of the four types of dolostone reservoirs indicate that type 1 dolomite reservoirs are the best reservoir, type 2 dolomite reservoirs have good physical properties, type 4 dolomite reservoirs are relatively good reservoirs, and the worst reservoir is the type 3 dolomite reservoirs.

A Study of Shock-Metamorphic Features of Feldspars from the Xiuyan Impact Crater

Feldspar is the most abundant mineral in the Earth’s crust and is widely distributed in rocks. It is also one of the most common minerals in meteorites. Shock-metamorphic features in feldspar are widely used to calibrate the temperature and pressure of shock events and can also provide clues for searching for impact craters on Earth. In this study, shocked alkali feldspars in the lithic breccia and suevite from Xiuyan Impact Crater were investigated using polarizing optical microscopes, Raman spectroscopy and electron microprobes to better constrain the shock history of this crater. For this study, feldspar grains occurring in gneiss clasts in the impact breccia and four shock stages were identified, e.g., weakly shocked feldspar, moderately shocked feldspar, strongly shocked feldspar, and whole rock melting. According to the shock classification system for alkali feldspar and felsic rocks, we estimated the shock pressure (SP) and post-shock temperature (PST) histories of these gneiss clasts. Weakly shocked feldspars display irregular fractures and undulatory extinction, and their shock stage is F-S2, which indicates that SP and PST are from ~5 to ~14 GPa and ~100 °C, respectively. Moderately shocked feldspars show planar deformation features and are partially transformed into diaplectic glass, which indicates that the F-S5 shock stage of SP and PST is from ~32 to ~45 GPa and 300–900 °C. Strongly shocked feldspars that occur as vesicular glass indicate a shock stage of F-S6, and the SP and PST are 45–60 GPa and 900–1500 °C, respectively. The whole felsic rock melting occurs as mixed melt glass clast and belongs to the F-S7 stage, and SP and PST are >60 GPa and >1500 °C, respectively.

Evidences of seismic events during the sedimentation of Sete Lagoas Formation (Bambuí Group – Ediacaran, Brazil)

The Sete Lagoas Formation (Ediacaran), located in the central part of the São Francisco Craton (Brazil), consists of limestones and dolostones deposited in very shallow waters in the inner part of the carbonate platform. Four breccia types occur throughout the stratigraphic succession: evaporitic breccia with tepees, flat-pebble breccia, hydrothermal breccia and brecciated stromatolites. Here we combine a detailed sedimentological and stratigraphic analyses of the flat-pebble breccia in order to determine its origin and the processes and environmental conditions that originated these brecciated facies. The studied interval consists of a 20 m thick succession of tabular beds composed of flat-pebble breccia interbedded with laminated microbialites. In these breccia beds, the clasts are usually platy or oblate with angular edges and are mainly disposed horizontally within the sedimentary bed, suggesting that they were not transported or reworked. The presence of microbialite clasts with sharp edges and vertices in the Sete Lagoas flat-pebble breccia suggests that the lithification process started very early in diagenesis and, even the sediments exposed at the bottom were, at least, partially lithified. Some breccia levels show bidirectional imbrication and clast size analyses reveal a NE-SW long-axis clast orientation whereas square clasts tend to fill the space among oriented clasts. Breccia clasts are vertically oriented and show deformation features increasing upwards, typically of deforming beds formed by ascendant expulsion of liquefied sediment. Disrupted layers or presenting folds and synsedimentary faults commonly occur confined between undeformed beds. Other evidences of liquefaction and soft-sediment deformation are the injection structures, as flame and load cast-like features, in the base of the brecciated beds. These structures commonly penetrate the upper bed and disrupt the sedimentary layer immediately above promoting local brecciation. These features are found both in modern and ancient deposits of seismic influence, which suggests a similar origin for the Sete Lagoas flat-pebble breccia. Thus, the processes that led to the formation of the studied flat-pebble breccia are interpreted as seismically triggered, since: a) the breccia beds are laterally continuous and extend for several kilometers; b) the breccia beds are restricted to a 20 m thick stratigraphic interval; c) the clasts of the breccia are the same lithology of non-deformed beds below and above the interval of breccia; d) the interbedding of breccia beds and laminated microbialite beds is recurrent; e) the breccia beds are subhorizontal and present irregular upper and lower contacts; f) the presence of liquefaction structures and dyke injection. Thus, this seismic-triggered breccia deposits represent the product of the synsedimentary tectonism occurred within the São Francisco Craton during the terminal Ediacaran and correspond to a very well-defined local stratigraphic marker in the Bambuí Basin. The seismic activities could be related to the NW regional faults in the regional Paleoproterozoic basement of the study area, which were reactivated during the deposition of the Sete Lagoas Formation in the Ediacaran Period.

Formation of mud clast breccias and the process of sedimentary autobrecciation in the hominin‐bearing (Homo naledi) Rising Star Cave system, South Africa

AbstractUnconsolidated mud clast breccia facies in the hominin‐bearing (Homo naledi) Rising Star Cave, Cradle of Humankind, South Africa, are interpreted to have formed through a process termed sedimentary autobrecciation in this study. This process, by which most of the angular mud clast breccia deposits are thought to have formed autochthonously to para‐autochthonously via a combination of erosion, desiccation, diagenesis and microbial alteration of laminated mud deposits, is thought to have taken place under relatively dry (i.e. non‐flooded) conditions inside the cave. Subsequently, gravitational slumping and collapse was the dominant mechanism that produced the mud clast breccia deposits, which commonly accumulate into debris aprons. The mud clast breccia is typically associated with (micro) mammal fossils and is a common facies throughout the cave system, occurring in lithified and unlithified form. This facies has not been described from other cave localities in the Cradle of Humankind. Additionally, sedimentary autobrecciation took place during the deposition of some of the fossils within the Rising Star Cave, including the abundant Homo naledi skeletal remains found in the Dinaledi Subsystem. Reworking of the mud clast breccia deposits occurs in some chambers as they slump towards floor drains, resulting in the repositioning of fossils embedded in the breccias as evidenced by cross‐cutting manganese staining lines on some Homo naledi fossil remains. The formation of the unlithified mud clast breccia deposits is a slow process, with first order formation rates estimated to be ca 8 × 10−4 mm year−1. The slow formation of the unlithified mud clast breccia facies sediments and lack of laminated mud facies within these deposits, indicates that conditions in the Dinaledi Chamber were probably stable and dry for at least the last ca 300 ka, meaning that this study excludes Homo naledi being actively transported by fluvial mechanisms during the time their remains entered the cave.

Evaluation of Various Methods for Determining Bulk Compositions of Chondrules and Other Objects in Petrographic Thin Sections

Studies of many objects in petrographic thin section, such as melt inclusions in igneous rocks, chondrules and Ca-Al rich inclusions in chondritic meteorites, or clasts in lunar and other breccias, require or can benefit from knowledge of their bulk compositions. Given the scarcity of these materials, the reluctance of curators to provide more abundant material, and the extreme difficulty of cleanly separating such objects from their rock matrices, geochemical and cosmochemical studies need the ability to determine their bulk compositions from in situ methods, such as defocused beam analysis, or quantitative chemical mapping by electron beam methods.

Evidence of chemical heterogeneity within lunar anorthosite parental magmas

Lunar anorthosites are known for displaying a limited range of plagioclase An content (∼An 94 to 98). Here we demonstrate that plagioclase trace-element variations from Apollo ferroan anorthosites (FAN) samples (collected by the Apollo 15 and 16 missions) display more significant chemical heterogeneity (e.g., chondrite-normalized [La/Sm] 0.33–5.42) than previously reported. We report mineral (plagioclase, pyroxene, and olivine) major- and trace-element abundances for a suite of Apollo FAN samples, in addition to, anorthositic clasts within Apollo 16 regolith breccias. This suite of data extends the compositional range currently reported for Apollo anorthosites and for anorthositic clasts previously found within lunar meteorites. Petrological classifications of the regolith breccia clasts (e.g., anorthosite versus noritic anorthosites) cannot always be accurately assessed due to the limited size (<1 cm) these rock fragments, however, the overlap in chemistry with the FAN suite highlights a genetic link with the FAN bedrock source. This observation emphasizes the usefulness of clasts and mineral fragments within regolith breccias, offering important insights into potentially unsampled bedrock lithologies from the Apollo 16 landing site. Melts in equilibrium with plagioclase can be used to assess parental melt compositions of the lunar magma ocean (LMO), from which anorthosites are generally agreed to have crystallized. In general, melts in equilibrium with the anorthosites reported here display slight light rare earth (LREE) depletions to LREE enrichments ([La/Sm]CI 0.87–2.5). The observed range of LREE enrichments from this suite, together with variations in ratios of other incompatible trace-elements (e.g., Th/Sm = 0.002–0.19) cannot be accounted for by fractional crystallization alone. We propose that the observed trace-element enriched anorthosites are related to overturn processes in the lunar mantle. During mantle overturn, the act of exhuming deep mafic-rich cumulates to the base of the lunar crust will trigger decompression melting. These are likely to be small degree (<10%) partial melts, which are typically enriched in incompatible elements. Variable mixing between such melts, KREEP, and overlying plagioclase-saturated residual melts or plagioclase-rich lithologies will result in lunar anorthosites that display variable incompatible element enriched signatures. This is similar to the proposal of Floss et al. (1998) that suggested infiltration of local LMO magmas occurred by more evolved liquids through a process of metasomatism. By understanding the petrogenesis of these lunar anorthosites, we are able to constrain some of the complexities associated with the solidification of a magma ocean. This in turn, has important implications for understanding the timing and formation mechanisms of the Moon’s crust.

Origin of lunar Very High Potassium (VHK) basalts: A combination of endogenous and exogenous processes

Very high potassium or VHK basalts have been described from the Apollo 14 landing site at Fra Mauro on the lunar near side. Many of the known samples are clasts in polymict breccias with a few as <1 cm rocklets in the regolith samples. VHK basalts are distinct from the high-Al basalts that are more common at the Apollo 14 site in that they are enriched in the alkali/alkaline earth elements (e.g., K, Rb, Ba, etc.). The source of this enrichment was initially proposed to be through assimilation of granite by a crystallizing high-Al basaltic magma. However, with the discovery of more VHK basalt clasts from three Apollo 14 polymict breccias, the number of different AFC episodes and granite assimilants had to increase in order to explain the whole rock compositional diversity within the VHK basalt suite.New work completed on fourteen VHK basalts include Crystal Size Distributions (CSDs) and in-situ chemical analyses and element maps collected by electron probe microanalysis (EPMA). CSDs completed on three VHK basalt samples indicate that these basalts are not impact melts and represent endogenous melts of the lunar interior. Potassium Kα element maps reveal the spatial relationship between the K-rich material and the basalt clasts with attached breccia matrix if present. In-situ EPMA analyses have identified two distinct types of K-rich material: K-feldspar and K-rich glass. With these new data, an additional mechanism for an exogenic petrogenesis of VHK basalts is proposed that involves the impact process. VHK basalts can be divided into two groups based on density and viscosity. VHK-1 basalts formed when a hot impact ejecta covered the granite/felsite-rich matrix material containing high-Al basalt clasts. Heat from the impact ejecta partially melted and possibly evaporated nearby K-bearing materials, which then infiltrated and contaminated the high-Al clasts. VHK-2 basalts are consistent with the hypothesis of granite assimilation by a high-Al magma, as seen in the higher abundances of network-forming elements.

Shallow-rooted mud volcanism in Lake Baikal

Abstract Lake Baikal is the only freshwater basin containing sediments with gas hydrate accumulations, some of which are associated with mud volcano activity. Twenty-two mud volcanoes have already been identified in different areas of Lake Baikal, but the formation process and source depth remained unknown due to a lack of conclusive evidences. Here we discuss a set of geological and geophysical data to report the discovery of the hydrate-bearing Akadem mud volcanic complex (AMVC) on the Academician Ridge in central Lake Baikal. The obtained results allowed for the first time to concretely estimate the source depth of the mobilized fluids and sediments. Analysis of diatom skeletons present in the mud breccia revealed that the oldest diatom specimen is Cyclotella Iris et var. This species is characteristic for a short age interval ranging between 4.8 and 5.6 Ma. The same diatom was also detected between 230 and 310 m below the lake floor (mblf) in the borehole BDP-98 drilled near the AMVC. Combining biostratigraphic correlation and seismostratigraphy, it is estimated that the same interval is located at 200–300 mblf below the mud volcanic field. The elevated heat flow measured at AMVC indicates that the original base of gas hydrate stability (regionally located at ∼212 mblf) is currently shifted upwards of ∼100 m. The acquired data are consistent with a scenario envisaging the rise of warm fluids throughout the mud volcano complex zone. We suggest that migration of deep fluids could have initiated the gas hydrate dissociation and, in turn, rapidly generated overpressured shallow mud chambers. The ultimate piercing and triggering of the mud volcanoes activity resulted in the eruption of mud breccia and formation of densely packed crater sites in the study area. The depicted scenario can be applied to many mud volcanoes in Lake Baikal where similar anomalous heat flow conditions have been measured. These findings also emphasize that the genetic association between gas hydrate dissociation and the initiation of eruptive activity explains numerous peculiarities of the “Baikal” sedimentary volcanism (e.g. lack of lithified rocks among mud breccia clasts, gas hydrates, moderately elevated heat flow). This type of mud volcanism differentiates from the typically deeply rooted piercements observed worldwide in mature (marine) sedimentary basins. Ultimately our findings open a new prospective for mud volcano research worldwide, emphasizing that gas hydrates are not just one of the common features for sedimentary volcanism, but may have an active role as a triggering mechanism for the process itself.

Intermediate-depth brecciation along the subduction plate interface (Monviso eclogite, W. Alps)

The Monviso meta-ophiolite complex (Northern Italy, Western Alps) represents an almost intact fragment of Tethyan oceanic lithosphere metamorphosed at ~80 km depth (~2.6GPa–550 °C) during the Alpine subduction. We focus our study on a major shear zone cutting across this slab fragment at low angle (the Lower Shear Zone; LSZ). Here, in its talc and tremolite-rich serpentinite matrix, are embedded (together with metasedimentary lenses) variously brecciated Fe-Ti and Mg-Al metagabbro blocks. The latter were either interpreted as eclogitic breccias resulting from intermediate-depth rupture or as inherited, overprinted oceanic core complex features. Our new field, structural and petrographic data testify the genesis of this metagabbro breccia blocks at eclogite-facies conditions. Three types of eclogitic blocks can be distinguished, with non-random distribution (and decreasing size from top to base) throughout the ~200-m-thick and ~15 km-long LSZ: (1) Fe-Ti-metagabbros, brecciated and scattered in the upper to intermediate levels of the LSZ; (2) meter-size blocks and decameter-scale slivers of intact Mg-Al metagabbros, locally brecciated; (3) dm- to m-scale blocks of intact Fe-Ti metagabbros without breccia fabrics. Brecciation at eclogite facies conditions (at ~80 km depth) is documented by: i) the eclogitic foliation of intact Mg-Al-rich metagabbros (composed of omphacite + clinozoisite ± rutile and locally garnet) cut by breccia planes (cemented by omphacite + garnet ± lawsonite) and ii) the occurrence in breccia clasts of minerals that are fractured and offset along peak P-T omphacite-bearing planes. Rupture preferentially affected the Fe-Ti metagabbros, suggesting that rheological contrasts controlled the locus of brecciation. The occurrence of a first omphacite-rich matrix (M1, ~2.7GPa - 580 °C) crosscut by omphacite + garnet-bearing matrix M2 (~2.4GPa - 560 °C), witnesses multiple brittle rupture events, prior to a stage of eclogite facies fluid ingression marked by massive lawsonite recrystallization (matrix M3).

Investigating Variations in Water Abundances in Lunar Felsite Clasts Using Coordinated Field-Emission STEM and NanoSIMS Analyses

As representatives of petrochemically-evolved igneous rocks on the Moon, the granitic felsite clasts in lunar breccias have come under renewed focus as part of new efforts to use feldspars for assessing the inventory of lunar water and other volatiles. Previous petrologic studies of these clasts were tilted towards finding those assemblages and relationships most likely to be direct products of magmatic processes. In support of our on-going NanoSIMS (Nanoscale Secondary Ion Mass Spectrometry) measurements of trace water contents in the feldspars in these clasts, we are using coordinated analytical SEM (Scanning Electron Microscopy), electron probe microanalyzer (EPMA) and analytical field emission scanning transmission electron microscopy (FE-STEM) techniques to re-evaluate the full diversity of processes under which the feldspar-bearing assemblages in these clasts formed. Here we report a comparison of FE-STEM imaging and microanalysis results obtained on focused ion beam (FIB) sections extracted from felsite (alkali feldspar plus SiO2 plus or minus plagioclase) clasts in lunar breccias 15405 and 12013. The feldspars in these clasts have water contents which, although relatively low (7-18 ppm) by terrestrial standards, still show values significantly higher than measurements (approximately 0.5 ppm) of nominally anhydrous NanoSIMS standards.

The genesis of the Hehuashan Pb–Zn deposit and implications for the Pb–Zn prospectivity of the Tongling district, Middle–Lower Yangtze River Metallogenic Belt, Anhui Province, China

The Hehuashan lead–zinc deposit is located in the central Tongling Cu–Au–Mo mining district of eastern China and consists of stratabound ore bodies that are generally hosted by dolostone and limestone units of the Lower Triassic Lower Nanlinghu Formation. The deposit contains two types of sphalerite, namely tan to brown fine-grained (∼40 μm) type I sphalerite that is hosted by a dolomite, calcite, quartz and sericite gangue assemblage and colorless to brown coarse-grained (∼2 mm) type II sphalerite hosted within clasts in calcite-cemented breccias or within dolostone-hosted veins. Plotting these sphalerites in a Fe vs. Cd diagram indicates they have a similar composition as those within typical Mississippi Valley-type (MVT) deposits, suggesting that the Hehuashan deposit may have an MVT affinity. In addition, in-situ sulfur stable isotopic analysis of fine-grained (−7.8‰ to +3.0‰) and coarse-grained (+3.4‰ to +9.7‰) sphalerite indicates that the sulfur in the hydrothermal fluids that formed the deposit was derived from the country rocks within the Hehuashan area. Fluid inclusions within calcite and fluorite from the Hehuashan deposit have low homogenization temperatures (mean of 126 °C) and moderate salinities (mean of 7.1 wt% NaCl equivalent) that demonstrate the deposit formed from low temperature and moderate salinity hydrothermal fluids. This suggests that the Hehuashan deposit was almost certainly not formed from magmatic-hydrothermal fluids but instead was formed as a result of the mixing of basinal brines and meteoric water, again consistent with an MVT origin for this deposit. In summary, the Hehuashan lead–zinc deposit is an MVT deposit, suggesting that the Tongling district of Anhui Province, China is prospective for MVT mineralization and that the Triassic dolostones and limestones in this area represent high priority exploration targets for this style of mineralization.

Investigation of impact melt in allochthonous crater‐fill deposits of the Steen River impact structure, Alberta, Canada

AbstractThe Steen River impact structure (SRIS) formed in mixed target rocks, with Devonian carbonates, shales, and evaporites overlying granitic basement rocks of the Canadian Shield. A detailed study of impact melt phases within a continuous sequence of polymict impact breccia, as intersected by drill core, evaluated the relationship of impact melt to the breccia, identified the target rocks that contributed to the melt, and calculated the amount of melt within the breccia. Impact melt in the SRIS breccia occurs in three main forms (1) as individual matrix‐supported clasts, (2) as rims enveloping granitic clasts, and (3) as layers of agglomerated melt. Major and minor element abundances of large impact melt clasts (&gt;1 mm) are similar to granitic basement, aside from elevated CaO and K2O wt% oxides in these melt clasts from incorporation of carbonates and calcareous shales. In contrast, submillimeter‐sized impact melt clasts have a composition derived almost exclusively from melting of shales. The small size of the shale‐derived melt clasts is attributed to increased fragmentation and a wider dispersion due to the volatile‐rich nature of the shale protolith. The wide compositional range of impact‐melted target lithologies documented at the SRIS contradicts breccia clast formation by impact melts that merged into larger bodies but were subsequently disrupted. Our observations are consistent with disruption of impact melt early in its formation history, and the volatile‐rich nature of the target materials likely contributed to this disruption. Bimodal thin section scans provide an estimate of the proportion of impact melt phases in the SRIS breccias (~19 vol%). When compared to similarly sized, mixed‐target impact structures, our results are consistent with the estimated volume of impact melt clasts from Ries, Germany (21 vol%), but are roughly twice that observed at Haughton, Canada (&lt;10 vol%).

The Shah-Ali-Beiglou Zn-Pb-Cu (-Ag) Deposit, Iran: An Example of Intermediate Sulfidation Epithermal Type Mineralization

The Shah-Ali-Beiglou epithermal base metal-silver deposit is located in the Tarom-Hashjin metallogenic province (THMP) in northwestern Iran. This deposit is hosted by quartz monzonite dikes of Oligocene age and surrounded by andesite to trachyandesite volcanic and volcaniclastic rocks of Eocene age. The subvolcanic rocks in the study area vary in composition from quartz-monzonite to monzonite and have metaluminous, calc-alkaline to shoshonitic affinity. These rocks have I-type geochemical characteristic and are related to post-collisional tectonic setting. The mineralization occurs as NE-SW and E-W-trending brecciated veins controlled by strike-slip and normal faults, which are associated to the Late Oligocene compressional regime. The mineral paragenesis of the vein mineralization is subdivided into pre-ore stage, ore stage, post-ore stage, and supergene stage. Pre-ore stage is dominated by quartz, sericite, and subhedral to anhedral pyrite as disseminated form. Ore-stage is represented by quartz, sphalerite (from 0.1 mol % to 4 mol % FeS), galena, chalcopyrite, tetrahedrite-tennantite, minor seligmannite and enargite, as vein-veinlet, cement and clast breccias. Post-ore stage is defined by deposition of quartz and carbonate along with minor barite, and supergene stage is characterized by bornite, chalcocite, covellite, hematite, goethite, and jarosite. The ore mineralization is associated with the silicic alteration. The styles of alteration are silicic, carbonate, sericitic, chloritic, and propylitic. Fluid inclusions in sphalerite have a wide range of salinities between 0.35 wt % and 21.4 wt % NaCl equivalent and homogenization temperatures range from 123 to 320 °C. The isotopic values of sulfides vary from 2.8‰ to 6.7‰ suggesting a magmatic source for the sulfur. In the present study, based on geological setting, alteration style of the host and wall rocks, main textures, mineral assemblages, composition of ore minerals, and structural features, it is suggested that the mineralization in the Shah-Ali-Beiglou is similar to intermediate-sulfidation style of epithermal deposits.

Mudstone Clast Breccia in the Cretaceous Athabasca Oil Sands, Western Canada: Fluvial Debris-Flow Transitions into Traction Carpets

AbstractThe origin and distribution of mudstone clast breccia bed deposits of the middle McMurray Formation responded to a range of current flow conditions associated with downchannel migrations by kilometers-long point bars, which accumulated as reservoirs of the Cretaceous Athabasca oil sands in northern Alberta. Fabrics consisting of dispersed clast entrainments within centimeters- to decimeters-thick stratified sand beds accumulated as grain flows and small-scale debris flows that filled shallow, flat-bottomed troughs during bed erosion on the point bar. Most low-density clast dispersals were sourced by eroded mudstone beds exposed along the bar bed surfaces. Clast-laden debris flows, 1–2 m thick, filled deeper troughs on the point bar, often as overlying flow-surge deposits, resulting in internal erosional surfaces within the breccia bed. Elsewhere, voluminous debris flows were sourced by undercut older channel walls that eroded mud-dominated counter point bar beds or exhumed lower McMurray floodplai...