Reaction Of Cl Research Articles

Reaction dynamics for the Cl(2P) + XCl → XCl + Cl(2P) (X = H, D, Mu) reaction on a high-fidelity ground state potential energy surface.

In this work, the dynamics of a prototypical heavy-light-heavy abstract reaction, Cl(2P) + HCl → HCl + Cl(2P), is investigated both by constructing a new potential energy surface (PES) and by rate coefficient calculations. Both the permutation invariant polynomial neural network method and the embedded atom neural network (EANN) method, based on abinitio MRCI-F12+Q/AVTZ level points, are used for obtaining globally accurate full-dimensional ground state PES, with the corresponding total root mean square error being only 0.043 and 0.056 kcal/mol, respectively. In addition, this is also the first application of the EANN in a gas-phase bimolecular reaction. The saddle point of this reaction system is confirmed to be nonlinear. In comparison with both the energetics and rate coefficients obtained on both PESs, we find that the EANN is reliable in dynamic calculations. A full-dimensional approximate quantum mechanical method, ring-polymer molecular dynamics with a Cayley propagator, is employed to obtain the thermal rate coefficients and kinetic isotopic effects of the title reaction Cl(2P) + XCl→ XCl + Cl(2P) (H, D, Mu) on both new PESs, and the kinetic isotope effect (KIE) is also obtained. The rate coefficients reproduce the experimental results at high temperatures perfectly but with moderate accuracy at lower temperatures, but the KIE is with high accuracy. The similar kinetic behavior is supported by quantum dynamics using wave packet calculations as well.

From Glow to Growth: Chemiluminescence Induced Cationic Polymerization Using Ferrocenium Salt

AbstractChemiluminescence (CL) has recently emerged as a novel light source for triggering various photoreactions with appealing features such as the elimination of continuous power supply and complex instrumentation. Here, CL‐induced cationic photopolymerization using ferrocenium salts as unimolecular photoinitiators is reported. The ferrocenium salts, facilely synthesized via ligand exchange reactions, absorb the visible light emitted from CL reactions and generate Lewis acids capable of initiating the cationic polymerization of oxirane and vinyl monomers. The presented method can be applied to create linear polymer chains and cross‐linked luminescent polymer networks, which have significant potential in the fabrication of new polymeric materials and various bioapplications.

Quantum Chemical and Kinetic Study of the Gas-Phase Reactions of Methane Sulfonamide with Cl Atom and the Fate of •CH2S(═O)2NH2 with 3O2 in the Atmosphere

The gas phase mechanism of the chlorine atom (•Cl)-initiated oxidation of methane sulfonamide (CH3S(═O)2NH2; MSAM) has been elucidated using ab initio/DFT electronic structure methods and chemical kinetic modeling. A reaction that commences via abstraction of an H-atom from the methyl group of MSAM to form a transition state with a barrier height of ∼4.8 kcal mol–1 above that of the MSAM + •Cl reactants, yielding •CH2S(═O)2NH2 + HCl was found to be a major path in comparison with the other possibilities. Rate coefficients for all possible H-atom abstraction reactions were calculated using the canonical variational transition state theory (CVT) with the small curvature tunneling (SCT) method in the temperature range of 200–400 K. The rate coefficient for the major reaction was found to be 1.6 × 10–14 cm3 molecule–1 s–1 at 300 K, while the overall rate coefficient for the MSAM + •Cl reaction is found to be 1.7 × 10–14 cm3 molecule–1 s–1 at 300 K. In addition, SCT contributions, branching ratios for each reaction path, and the atmospheric implications are provided and discussed. Based on the results, the MSAM + •Cl reaction proceeds to form •CH2S(═O)2NH2, which then further reacts with 3O2 under oxygen-rich conditions to form the corresponding RO2 adduct (•OOCH2S(═O)2NH2). Subsequent reactions of this radical result in the formation of greenhouse gases such as sulfur dioxide (SO2), carbon dioxide (CO2), carbon monoxide (CO), nitric acid (HNO3), nitrous oxide (N2O), and formic acid (HC(O)OH), which may contribute to climate change and formation of secondary organic aerosols and acid rain.

Прооксидантно-антиоксидантні процеси в крові та печінці мишоподібних гризунів (Myodes Glareolus та Apodemus Flavicollis) за разового опромінення

The effect of total single X-ray irradiation (1.5 Gy) on the course of free radical processes (FRP) in the blood and liver of red fistula (Myodes glareolus) and yellow-throated mouse (Apodemus flavicollis) was studied. It is shown that physicochemical regulation of FRP in the blood of murine rodents under total X-ray irradiation (1.5 Gy) in the early stages is carried out mainly due to catalase and reduced glutathione (GSH). This is evidenced by the stoichiometry of the CL reaction and symbat changes in the prooxidant-antioxidant ratio (PAR) and basic kinetic parameters of the CL reaction (Imax, Ifin) and antibat changes to PAR - catalase and GSH.

State-to-State Dynamics in Mode-Specific Reactions of Cl + CH3D(v1-I, v1-II, and v4 = 1; |10⟩): Loss of Memory or Not

Several decades of the study of reaction dynamics culminate in the concept of mode specificity and bond selectivity in polyatomic systems. Until very recently, the main concern of those studies has been total reactivity and little attention has been paid to the mode-specific effects on the more detailed product-state and angular distributions. Conventional wisdom would anticipate that the fine detail should reveal a more pronounced mode dependency. However, a few recent studies showed that the product distributions could appear to be surprisingly insensitive to the modes of internal excitation of reagents. This counterintuitive finding led to a concept of loss of memory. Here, we present detailed experimental results in the reactions of the Cl atom with three distinct stretching-excited CH3D(vCH3 = 1) reagents. In conjunction with the previous reports on various aspects of this reaction, such a comprehensive set of data enables us to perform an in-depth examination of the validity of this new concept.

Lipid modulation of membrane protein conformational equilibria does not require lipid immobilization in long-lasting protein-lipid complexes.

Lipid regulation of membrane proteins is widely rationalized as a process whereby lipid molecules become immobilized in a complex with the protein, supposedly due to strong, specific interactions. While this conventional paradigm might apply to some regulatory processes, we posit that it is not a universal mechanism. As a counterexample, we examine the mechanism by which lipids modulate the dimerization reaction of the bacterial CL−/H+ antiporter CLC-ec1. Using molecular simulations, we have shown that monomeric CLC-ec1 induces a pronounced defect in the morphology of the surrounding membrane, including thinning of the hydrophobic core due to drastic lipid tilting and entanglement of the two bilayer leaflets. Upon dimerization, this interface becomes buried, and the morphological defect in the membrane is completely eliminated. Using advanced simulation methods, we have shown that the free-energy gain resulting from the elimination of this defect accounts for much of the free-energy of CLC-ec1 association measured experimentally. These experiments, based on single-molecule microscopy, also demonstrate that introduction of short-chain lipids drastically destabilize dimerization, but the concentration dependence of this inhibitory effect is incoherent with a conventional competitive ligand-binding process. To examine the microscopic mechanism underlying these intriguing observations, we calculate a continuous 40-microsecond molecular dynamics trajectory of all-atom monomeric CLC-ec1 embedded in a 70:30 mixture of POPC and DLPC lipids. This simulation shows that DLPC molecules become enriched within the thinned-membrane defect, alleviating its energetic cost and hence inhibits dimerization. However, we find that this enrichment does not stem from the immobilization of these lipids in a long-lasting protein-lipid complex, but from subtle yet statistically significant differences in the residence times and exchange frequency of PO and DL lipids within the first solvation shells.

Comparison of the Yield and Chemical Composition of Secondary Organic Aerosol Generated from the OH and Cl Oxidation of Decamethylcyclopentasiloxane

Cyclic volatile methyl siloxanes (cVMS) that are emitted from industrial processes and consumer products often dominate the burden of volatile organic compounds (VOCs) in occupied spaces. cVMS may contribute to oxygenated VOC and secondary organic aerosol (SOA) formation following oxidation by gas-phase radicals in both indoor and outdoor source regions. Several recent studies examined the SOA formation potential of decamethylcyclopentasiloxane (D5) following exposure to hydroxyl radicals (OH) and found that this reaction generates SOA in high yield following multiple days of oxidative aging. Chlorine atoms (Cl) may compete with OH for the oxidative loss of D5 in indoor and outdoor source regions with active chlorine chemistry, but the SOA formation potential of D5 + Cl reactions has not been studied. Here, we characterized the yield and chemical composition of SOA generated from Cl oxidation of D5 in an oxidation flow reactor (OFR) under dry [relative humidity (RH) < 5%] and humid (RH = 40%) conditions and compared results to the yield and composition of SOA generated from OH oxidation of D5. D5 was oxidized using integrated OH and Cl exposures (OHexp and Clexp) ranging from 1.1 × 1012 to 8.2 × 1012 cm–3 s and from 1.6 × 1010 to 1.6 × 1012 cm–3 s, respectively. Like OH, Cl facilitated multistep SOA oxidative aging over the range of OFR conditions that were studied, with maximum SOA mass yields of 1.5 and 1.3 obtained following OH and Cl oxidation of D5 under humid conditions. These results suggest that indoor and outdoor source regions that are significantly influenced by chlorine chemistry may enhance the atmospheric SOA formation potential of D5.

Effect of (H2O)n (n = 1 and 2) on HOCl + Cl reaction.

In the present work, we investigate the effect of water molecules (H2O and (H2O)2) on HOCl + Cl˙ → ClO˙ + HCl (R1), and HOCl + Cl˙ → OH˙ + Cl2 (R2) reactions using quantum chemical and kinetics calculations. The present investigation suggests that a water molecule decreases the energy barrier of both reactions significantly, compared to uncatalyzed reaction. However, the effective rate constants for the water catalyzed path for both channels (R1 and R2) were found to be lower than the bimolecular rate constant of the uncatalyzed path. Further, it was found that the R2 reaction will dominate over the R1 reaction, with or without catalyst. Interestingly, the uncatalyzed title reaction was found to be two times faster than the HOCl + OH˙ reaction, but in the presence of water, HOCl + OH˙ becomes the dominant reaction compared to the HOCl + Cl˙ reaction in the atmosphere. In addition, the concentration of bimolecular complexes formed in the presence of a catalyst are found to be higher than the precursor molecule of the uncatalyzed reaction, which suggests that in the presence of catalyst, the HOCl + Cl˙ reaction would favor the catalyzed path rather than the uncatalyzed path.

Competitive dynamics of E2 and SN2 reaction driven by collision energy and leaving group.

The competition between E2 and SN2 reactions is essential in organic chemistry. In this paper, the reaction mechanism of F- + CH3CH2Cl is investigated utilizing direct dynamics simulations, and unravel how the collision energy (Ecoll) and the leaving group affect the competition between SN2 and E2 in the F- + CH3CH2Y (Y = Cl and Br) reactions. Simulation results for F- + CH3CH2Cl reaction show that the anti-E2 channel is dominant, but with the increase of Ecoll from 0.04 to 1.9 eV the branching ratio of the anti-E2 pathway significantly decreases by 21%, and the SN2 pathway becomes more important. A transition from indirect to direct reaction has been revealed when Ecoll is increased from 0.04 to 1.90 eV. At lower Ecoll, a large ratio of indirect events occurs via a long-lived hydrogen-bonded complex, and as the collision energy is increased, the lifetimes of the hydrogen-bonded complexes are shortened, due to an initial faster relative velocity. The simulation results of F- + CH3CH2Cl are further compared with the F- + CH3CH2Br reaction at Ecoll of 0.04 eV. Changing the leaving group from Cl to Br drastically suppresses the indirect events of anti-E2 with a branching ratio decreasing from 0.46 to 0.36 due to the mass effect, and promotes direct rebound mechanism resulting from a looser transition state geometry caused by varied electronegativity.

A Novel Chemiluminescent Method for Efficient Evaluation of Heterogeneous Fenton Catalysts Using Cigarette Tar

The evaluation of the catalytic capacity of catalysts is indispensable research, as catalytic capacity is a crucial factor to dictate the efficiency of heterogeneous Fenton catalysis. Herein, we obtained cigarette tar-methanol extracts (CTME) by applying methanol to cigarette tar and found that CTME could cause CL reactions with Fe2+/H2O2 systems in acidic, neutral, and alkaline media. The CL spectrum experiment indicated that the emission wavelengths of the CTME CL reaction with Fe2+/H2O2 systems were about 490 nm, 535 nm, and 590 nm. Quenching experiments confirmed that hydroxyl radicals (•OH) were responsible for the CL reaction for CTME. Then the CL property of CTME was applied in-situ to rapidly determine the amounts of •OH in tetrachloro-1,4-benzoquinone (TCBQ)/H2O2 system in acidic, neutral and alkaline media, and the CL intensities correlated the best (R2 = 0.99) with TCBQ concentrations. To demonstrate the utility of the CTME CL method, the catalytic capacity of different types and concentrations of catalysts in heterogeneous Fenton catalysis were examined. It was found that the order of CL intensities was consistent with the order of degradation efficiencies of Rhodamine B, indicating that this method could distinguish the catalytic capacity of catalysts. The CTME CL method could provide a convenient tool for the efficient evaluation of the catalytic capacity of catalysts in heterogeneous Fenton catalysis.

Determination of pioglitazone hydrochloride by flow injection chemiluminescence tris(2,2'-bipyridyl)ruthenium (II)-silver (III) complex system.

A novel flow injection-chemiluminescence (FI-CL) approach is proposed for the assay of pioglitazone hydrochloride (PG-HCl) based on its enhancing influence on the tris(2,2'-bipyridyl)ruthenium (II)-silver (III) complex (Ru (bipy)3 2+ -DPA) CL system in sulfuric acid medium. The possible CL reaction mechanism is discussed with CL and UV spectra. The optimum experimental conditions were found as: Ru (bipy)3 2+ , 5.0×10-5 M; H2 SO4 , 1.0×10-3 M; DPA, 1.0×10-4 M; KOH, 1.0×10-3 M; flow rate 4.0 mL min-1 for each flow stream and sample loop volume, 180 μL. The CL intensity of PG-HCl was linear in the range of 1.0×10-3 -5.0 mg L-1 (R2 = 0.9998, n = 10) with limit of detection (LOD, S/N = 3) of 2.2×10-4 mg L-1 , limit of quantification (LOQ, S/N = 10) of 6.7×10-4 mg L-1 , relative standard deviation (RSD) of 1.0-3.3% and sampling rate of 106 h-1 . The methodology was satisfactorily used to quantify PG-HCl in pharmaceutical tablets with recoveries ranging from 93.17 to 102.77 and RSD from 1.9 to 2.8%.

Theoretical Studies on OH−+NH2Cl Reaction: Nucleophilic Substitution at Neutral Nitrogen

The SN2 and proton transfer (PT) pathways for [Formula: see text]Cl reaction are represented by employing various electronic structure computations. Both back-side SN2 and PT channels are exothermic and stationary points of PESs are below the reactant asymptote. Overall, the PES is similar to the C-centered SN2 reactions. Conversely, ion-dipole complex was not found for [Formula: see text]Cl system. The N–HOH/NH–Cl hydrogen bond characterizes on either side of the reaction barrier of nitrogen complexes. Moreover, a halogen-bonded complex (HO−–ClNH2) and two types of H-bond complexes (HONH2–Cl− and Cl−–HONH2) were described, predicting an important role in dynamics. The PT pathway may be the major channel in the title system, which is contradictory to [Formula: see text]Cl and [Formula: see text]Cl reactions. Here, MP2, B3LYP and CAM-B3LYP methods show overall excellent consistency with CCSD(T)/CBS energies and are recommended to carry out dynamics simulations.

Dioxygen Splitting by a Tantalum(V) Complex Ligated by a Rigid, Redox Non-Innocent Pincer Ligand.

The reaction of TaMe3 Cl2 with the rigid acridane-derived trisamine H3 NNN yields the tantalum(V) complex [TaCl2 (NNNcat )]. Subsequent reaction with dioxygen results in the full four-electron reduction of O2 yielding the oxido-bridged bimetallic complex [{TaCl2 (NNNsq )}2 O]. This dinuclear complex features an open-shell ground state due to partial ligand oxidation and was comprehensively characterized by single crystal X-ray diffraction, LIFDI mass spectrometry, NMR, EPR, IR and UV/VIS/NIR spectroscopy. The mechanism of O2 activation was investigated by DFT calculations revealing initial binding of O2 to the tantalum(V) center followed by complete O2 scission to produce a terminal oxido-complex.

Dye mineralization under UV/H2O2 promoted by chloride ion at high concentration and the generation of chlorinated byproducts

Chloride ion (Cl−) may promote or inhibit the oxidation of specific organic compounds treated by hydroxyl radical based advanced oxidation processes (HR-AOPs) depending on the reactivity of chlorine radicals towards the organics. However, the effects of high contents of Cl− on the removal of total organic compounds (TOC) in high salinity organic wastewater treated by HR-AOPs were unclear. The removal and mineralization of azo dye Orange II (OrgII) by UV/H2O2 process with Cl− at high contents under various pH conditions were investigated. As the pH conditions increased higher than pH 5, TOC removal rates increased slightly possibly related to the increase of O2− production and the reduce of futile decomposition of H2O2 into O2. Cl− at relative high concentration (1000 and 2000 mM) significantly promoted the mineralization of dyes with TOC removal increasing by 10 %–40 % under both acid and alkaline conditions. The proposed mechanism is that the reaction of Cl− with OH would decline the decomposition of H2O2 into O2 by inhibiting the reaction between OH and H2O2, and the generated chlorine species (Cl and Cl2−) could further promote the oxidation of dye molecules into intermediates and be helpful for the subsequent mineralization process. In addition, H2O2 and Cl− can slowly react to give HClO and ClO−, which may partly contribute to the decolorization and mineralization of OrgII. Meanwhile, an appropriate relative proportion between Cl2− and OH depending on Cl− contents and pH conditions is important to enhance the TOC removal. However, the formation of various chlorinated byproducts especially under alkaline condition may increase the risk of environmental pollution accidents. The results demonstrate the promotion of TOC removal by UV/H2O2 under certain high contents of Cl− and provide new insight into the application of HR-AOPs to the pretreatment of high salinity organic wastewater.

Ab initio characterization of the potential energy profiles for the multi-channel reactions: H/Cl + CH3OH

In this work, we study two prototypical reactions Cl / H + CH3OH by theory. In addition to the hydrogen abstraction channels, for the first time, we report substitution channels: the groups linked to the carbon atom are substituted by the attacking atom (CH3Cl + OH and ClCH2OH + H for the Cl + CH3OH reaction, CH4 + OH and CH3OH + H for the H + CH3OH reaction), and others take place with groups on the oxygen atom substituted (CH3OCl + H and CH3 + HOCl, CH3OH + H and H2O + CH3). The substitute reactions occurred at oxygen atom have higher barriers than that at carbon atom for the Cl + CH3OH reaction, while it is contrast in H + CH3OH. Structures, energies, and harmonic frequencies of relevant stationary points are calculated by CCSD(T)-F12a/aug-cc-pVnZ (n = T, D). Quantitative and new insights are expected by the benchmark calculations.

Kinetic and Products Study of the Atmospheric Degradation of trans-2-Hexenal with Cl Atoms.

The gas-phase reaction between trans-2-hexenal (T2H) and chlorine atoms (Cl) was studied using three complementary experimental setups at atmospheric pressure and room temperature. In this work, we studied the rate constant for the titled oxidation reaction as well as the formation of the gas-phase products and secondary organic aerosols (SOAs). The rate constant of the T2H + Cl reaction was determined using the relative method in a simulation chamber using proton-transfer reaction time-of-flight mass spectrometry (PTR-ToF-MS) to monitor the loss of T2H and the reference compound. An average reaction rate constant of (3.17 ± 0.72) × 10–10 cm3 molecule–1 s–1 was obtained. From this, the atmospheric lifetime of T2H due to Cl reaction was estimated to be 9 h for coastal regions. HCl, CO, and butanal were identified as primary products using Fourier transform infrared spectroscopy (FTIR). The molar yield of butanal was (6.4 ± 0.3)%. Formic acid was identified as a secondary product by FTIR. In addition, butanal, 2-chlorohexenal, and 2-hexenoic acid were identified as products by gas chromatography coupled to mass spectrometry but not quantified. A reaction mechanism is proposed based on the observed products. SOA formation was observed by using a fast mobility particle sizer spectrometer. The measured SOA yields reached maximum values of about 38% at high particle mass concentrations. This work exhibits for the first time that T2H can be a source of SOA in coastal atmospheres, where Cl concentrations can be high at dawn, or in industrial areas, such as ceramic industries, where Cl precursors may be present.

Chloride-Enhanced Removal of Ammonia Nitrogen and Organic Matter from Landfill Leachate by a Microwave/Peroxymonosulfate System

Landfill leachate contains not only high concentrations of refractory organic matter and ammonia nitrogen, but also high concentrations of chloride ions (Cl−). The modification of reactive species of the peroxymonosulfate (PMS) oxidation system by Cl− and its priority sequence for the removal of NH4+-N and organic matter from landfill leachate remain unclear. This study investigated the removal characteristics of NH4+-N and organic matter in the microwave (MW)/PMS system with high Cl− content. The results show that increasing Cl− concentration significantly improves the production of hypochlorous acid (HOCl) in the MW/PMS system under acidic conditions, and that the thermal and non-thermal effects of MW irradiation have an important influence on the HOCl produced by PMS activation. The maximum cumulative concentration of HOCl was 748.24 μM after a reaction time of 2 min. The formation paths of HOCl are (i) SO4•− formed by the MW/PMS system interacting with Cl− and HO•, and (ii) the nucleophilic addition reaction of PMS and Cl−. Moreover, the high concentration of HOCl produced by the system can not only remove NH4+-N in situ, but also interact with PMS to continuously generate Cl• as an oxidant to participate in the reaction with pollutants (e.g., NH4+-N and organic matter). Common aqueous substances (e.g., CO32−, HCO3−, NO3−, and humic acid) in landfill leachate will compete with NH4+-N for reactive species in the system, and will thereby inhibit its removal to a certain extent. It was found that when NH4+-N and leachate DOM co-exist in landfill leachates, they would compete for reactive species, and that humic acid-like matter was preferentially removed, leading to the retention of fulvic acid-like matter. It is hoped that this study will provide theoretical support for the design and optimization of methods for removing NH4+-N and organic matter from landfill leachate with high chloride ion content.

Trajectory surface hopping molecular dynamics on Chemiluminescence of cyclic peroxides

AbstractChemiluminescence (CL) of peroxides is one of the most highly sensitive and most useful analytical techniques. Although the mechanisms of CL were studied experimentally and theoretically in the past decades, the chemiexcitation that a ground‐state specie being excited from its electronic ground state to yield excited‐state products by a chemical reaction is still not completely understood. Direct dynamics simulation on CL reaction which takes into account the full complexity of the relevant potential energy surface characterizes nonadiabatic processes involved in chemiexcitation and could provide access not only to the available reaction channels but also to statistical quantities such as reaction times and quantum yields. In the last decade, the trajectory surface hopping (TSH) molecular dynamics (MD) which is one of the mixed quantum‐classical approaches is hence adopted to simulate the nonadiabatic process in CL of cyclic peroxides. In this article, the basic principle of TSH‐MD and the successful applications on the CL reactions were shortly review.

MnOx Film-Coated NiFe-LDH Nanosheets on Ni Foam as Selective Oxygen Evolution Electrocatalysts for Alkaline Seawater Oxidation.

Compared to freshwater electrolysis, seawater electrolysis to produce hydrogen is preferable and more promising, but this technology is plagued by the electrode's corrosion and oxidative reactions of the competitive Cl- ion on the anode. To develop efficient oxygen evolution reaction (OER) catalysts for seawater electrolysis, the ultrathin MnOx film-covered NiFe-layered double-hydroxide nanosheet array is directly assembled on Ni foam (MnOx/NiFe-LDH/NF) by hydrothermal and electrodeposition in turn. This catalyst demonstrates excellent OER-selective activity in alkaline saline electrolytes. In 1 M KOH/0.5 M NaCl and 1 M KOH/seawater electrolytes, MnOx/NiFe-LDH/NF exhibits lower overpotentials at 100 mA cm-2 (η100 values of 265 and 276 mV, respectively) and Tafel slopes (73 and 77 mV decade-1, respectively) than does the NiFe-LDH/NF electrode (η100 values of 298 and 327 mV and Tafel slopes of 91 and 140 mV decade-1, respectively). In alkaline saline solutions, the stability and durability of the former are also better than those of the latter. The good OER selectivity and catalytic performance are attributed to the MnOx overlayer that selectively blocks Cl- anions from approaching catalytic centers, and the good conductivity, fast kinetics, more oxygen vacancies, and abundant active sites of MnOx/NiFe-LDH/NF. The robust stability is due to the enhanced resistance for Cl- corrosion stemming from the MnOx protective film. Hence, MnOx/NiFe-LDH/NF can act as a promising OER electrocatalyst for alkalized natural seawater electrolysis.

Three-Component Reaction of Pentafluorosulfanyl Chloride, Alkenes and Diazo Compounds and Synthesis of Pentafluorosulfanylfurans.

We report herein the three-component radical addition reaction of SF5 Cl, alkene and diazo compounds for the selective formation of α-alkyl-α-SF5 carbonyl compounds. The three-component addition reaction proceeded through the first reaction of SF5 radical with the diazo compound followed by the addition of the in situ generated carbon radical to alkene. The synthetic useful α-allyl-α-SF5 carbonyl compounds were successfully prepared when allyl trimethylsilanes were used as the alkene substrates. Furthermore, the three-component adducts formed from SF5 Cl, α-diazoacetophenones and vinyl acetates were converted into pentafluorosulfanylfurans. This transformation provided a practical and efficeint method for the synthesis of pentafluorosulfanylfurans.