Circular Route Research Articles

New insights into the catalyzed ozonation mechanism of a hydroxyl riched goethite: Contributions of H2O2 and surface Fe2+

Fe-based catalysts have been widely used to catalyze ozonation during water treatment. Among these catalysts, goethite (α-FeOOH) is of concern for the properties of low cost, easy availability, and excellent performance. In general, the surface hydroxyl groups of goethite are believed to be crucial catalytic sites. However, the contributions of Fe2+ on the goethite surface and H2O2 produced from pollutant degradation have rarely been mentioned. In this study, a goethite with rich surface hydroxyl was fabricated to remove aromatics by O3 catalysis. Probe and quenching experiments together proved that although the •OH was produced less than the O2•⁻ and 1O2 in the catalytic system, it contributed about 95 % of the target removal. EDTA complexation and heating experiments suggested that when the surface Fe2+ of the catalyst was destroyed, although the Fe-site hydroxyl or the vacancy hydroxyl of the catalyst was retained, its catalytic activity was reduced greatly. The outcomes of degradation kinetics of acetic acid further confirmed that, in the catalytic process, most of •OH originated from the reaction of Fe2+ reducing HO2• and Fe2+ ozonation, while the surface hydroxyl contributed less than 44.7 %. Moreover, as the main source of HO2•, the role of H2O2 produced from aromatics degradation cannot be ignored. The detection of H2O2 precursors in the degradation byproducts further confirmed this opinion. Finally, an efficient circular route for •OH production was proposed. This may be beneficial for the development of efficient Fe-based catalysts.

Train Trajectory-Following Control Method Using Virtual Sensors.

Trajectory-following control is the basis for the practical application of an articulated virtual rail train transportation system. In this paper, a planar nonlinear dynamics model of an articulated vehicle is derived using the Euler-Lagrange method. A trajectory-following control strategy based on the first following point is proposed, and a feedback linearization control algorithm is designed based on the vehicle dynamics model to achieve the trajectory following of the rear vehicle. Based on the target trajectory formed by the first following point and measured by virtual sensors, a vector analysis method grounded in geometric relationships is proposed to solve in real time for the desired position, velocity, and acceleration of the vehicle. Finally, a MATLAB/SIMPACK dynamics virtual prototype is established to test the vehicle's trajectory-following effectiveness and dynamics performance under lane change and circular curve routes. The results indicate that the control algorithm can achieve trajectory following while maintaining good vehicle dynamics performance. It is robust to variations in vehicle mass, vehicle speed, tire cornering stiffness, and road friction coefficient.

A customized self-assembled synergistic biocatalyst for plastic depolymerization

The enzymatic degradation of plastic offers a green, sustainable strategy and scalable circular carbon route for solving polyester waste. Among the earlies discovered plastic-degrading enzymes are PET hydrolase (PETase) and MHET hydrolase (MHETase), which act synergistically. To promote the adsorption of enzymes on PET surfaces, increase their robustness, and enable directly depolymerization, we designed hydrophobin HFBI fused-PETase and MHETase. A customized self-assembled synergistic biocatalyst (MC@CaZn-MOF) was further developed to promote the two-step depolymerization process. The tailored catalysts showed better adhesion to the PET surface and desirable durability, retaining over 70% relative activity after incubation at pH 8.0 and 60 °C for 120 h. Importantly, MC@CaZn-MOF could directly decompose untreated AGf-PET to generate 9.5 mM TPA with weight loss over 90%. The successful implementation of a bifunctional customized catalyst makes the large-scale biocatalytic degradation of PET feasible, contributing to polymer upcycling and environmental sustainability.

The LimoFish Circular Economy Process for the Marine Bioeconomy.

The outcomes of applying the zero-waste extraction "LimoFish" process based on defatting fish processing waste with limonene to leftovers of European sardine (Sardina pilchardus) and European anchovy (Engraulis encrasicolus), compared to conventional extraction with oil-derived solvents such as n-hexane and with petroleum ether, show that the process has general applicability. Meeting the principles of green extraction and those of the marine biorefinery requiring high process efficiency, the process establishes an "innovation through integration" circular economy production route enabling the marine bioeconomy.

The catabolism of ethylene glycol by Rhodococcus jostii RHA1 and its dependence on mycofactocin.

Ethylene glycol (EG) is a widely used industrial chemical with manifold applications and also generated in the degradation of plastics such as polyethylene terephthalate. Rhodococcus jostii RHA1 (RHA1), a potential biocatalytic chassis, grows on EG. Transcriptomic analyses revealed four clusters of genes potentially involved in EG catabolism: the mad locus, predicted to encode mycofactocin-dependent alcohol degradation, including the catabolism of EG to glycolate; two GCL clusters, predicted to encode glycolate and glyoxylate catabolism; and the mft genes, predicted to specify mycofactocin biosynthesis. Bioinformatic analyses further revealed that the mad and mft genes are widely distributed in mycolic acid-producing bacteria such as RHA1. Neither ΔmadA nor ΔmftC RHA1 mutant strains grew on EG but grew on acetate. In resting cell assays, the ΔmadA mutant depleted glycolaldehyde but not EG from culture media. These results indicate that madA encodes a mycofactocin-dependent alcohol dehydrogenase that initiates EG catabolism. In contrast to some mycobacterial strains, the mad genes did not appear to enable RHA1 to grow on methanol as sole substrate. Finally, a strain of RHA1 adapted to grow ~3× faster on EG contained an overexpressed gene, aldA2, predicted to encode an aldehyde dehydrogenase. When incubated with EG, this strain accumulated lower concentrations of glycolaldehyde than RHA1. Moreover, ecotopically expressed aldA2 increased RHA1's tolerance for EG further suggesting that glycolaldehyde accumulation limits growth of RHA1 on EG. Overall, this study provides insights into the bacterial catabolism of small alcohols and aldehydes and facilitates the engineering of Rhodococcus for the upgrading of plastic waste streams.IMPORTANCEEthylene glycol (EG), a two-carbon (C2) alcohol, is produced in high volumes for use in a wide variety of applications. There is burgeoning interest in understanding and engineering the bacterial catabolism of EG, in part to establish circular economic routes for its use. This study identifies an EG catabolic pathway in Rhodococcus, a genus of bacteria well suited for biocatalysis. This pathway is responsible for the catabolism of methanol, a C1 feedstock, in related bacteria. Finally, we describe strategies to increase the rate of degradation of EG by increasing the transformation of glycolaldehyde, a toxic metabolic intermediate. This work advances the development of biocatalytic strategies to transform C2 feedstocks.

Structure Formation by 3D-Printing of Cellulose from Cellulose-NMMO-Water Solutions: Analysis of Extrusion, Regeneration, and Drying Stages.

Processing cellulose from 4-methyl morpholine n-oxide (NMMO)-water solutions is a completely circular route that produces biodegradable cellulose fibers or films while recovering reusable NMMO [Guo, Y.; Cai, J.; Sun, T.; Xing, L.; Cheng, C.; Chi, K.; Xu, J.; Li, T. The purification process and side reactions in the N-methylmorpholine-N-oxide (NMMO) recovery system. Cellulose 2021, 28(12), 7609-7617]. Despite proven success in two-dimensional applications, challenges in transitioning to three-dimensional objects arise from the critical changes that cellulose undergoes during deposition, regeneration, and postregeneration stages. While emphasizing the critical diffusion-driven precipitation during regeneration, this investigation explores the influence of extrusion temperature, printing alignment, regeneration, and drying processes on interfilament fusion, bonding, shape integrity, and mechanical properties. Three distinct drying processes: ambient, vacuum, and freeze-drying were investigated. Tensile and flexural bending tests provided insight into the delamination of dried specimens. Ambient and vacuum drying enhanced the properties of specimens, while freeze-drying resulted in a more stable shape. The findings contribute to advancing the understanding of 3D-printing cellulose from NMMO solutions, addressing crucial aspects of the extrusion, regeneration, and drying stages for enhanced applications in sustainable manufacturing.

Lexical Expressions of Motion in Physical Environments a Cognitive Linguistics Perspective

This study aims to delve into the interaction between motion verbs, manners, and paths in the Vietnamese language to look at the lexicalization of motion occurrences. Utilizing Talmy's lexicalization patterns for cognitive linguistics, the study seeks to understand how Vietnamese encodes and conceptualizes motion events in a variety of physical contexts, such as the air, water, and land. A mixed-methods approach is used in this work, integrating qualitative analysis of annotated textual data with quantitative frequency analysis. Vietnamese has a rich system of motion verbs that may be paired with manner and path expressions to produce complex and subtle descriptions of movement, according to the research. The language displays intricate differences when describing the direction, velocity, and kind of vehicle of motion, in addition to various linear, curved, vertical, circular, and multidirectional routes. The complex interplay between language, cognition, and the embodied experience of motion is highlighted by this linguistic variety, which is a reflection of Vietnamese speakers' astute observation and interpretation of the physical world. The work adds to our knowledge of how language organizes and expresses the basic idea of motion and provides insights into the cognitive and cultural bases of language expression.

An Autoregressive Model of Electromagnetic Disturbances in An Autonomous Electric Vehicle’s Route

Electromagnetic Interference (EMI) can cause a malfunction of on-board electronic circuits in an autonomous electric vehicle and supporting electronic devices located in the environment of autonomous electric vehicles as well. In order to navigate an autonomous electric vehicle safely, it is important to have electromagnetic field characteristic in the environment. Since the information of electromagnetic field characteristic is hard to find, it needs to be modeled. This paper presents a model of electromagnetic field characteristic that is generated by using autoregression in order to estimate potential EMI. The EMI estimation is based on electromagnetic characteristic in an environment. Unlike other applications that use time history of data to build a model, we present a spatial electromagnetic field strength data in a previous route to estimate the future data in a new route. To obtain historical data for auto-regression process, we measured electric field strengths along a circular route in a campus near Jakarta. This surrounding environment represents a typical area of suburbs. The input variables for auto-regression process are the first 27 correlated data of 155 measured data. The result shows that the use of 13 predictor coefficient produces a variance of prediction error near to zero, with an improvement from maximum prediction error of 15.1257 to prediction error of 0.1862.

Совершенствование транспортной системы и перспектива развития туризма в Республике Алтай

Introduction. The Altai Republic is a mountainous region of the Russian Federation with a unique nature and a large number of attractions. Here, in recent years, the tourism sector has been actively developing; the annually increasing tourist flow (2021 - about 2.2 million people, 2022 - 2.5 million people) requires studying the relationship of the transport system with the tourism infrastructure and scientific substantiation of the prospects development of tourism activities in general. Materials and methods. The research is based on a combination of frame and route approaches to identify the territorial features of tourism development. The framework approach forms the basis of spatial planning methodology. The supporting framework of the region, as a linear-nodal structure of the territorial and functional relationship between its elements, gives the most complete picture of the organization of tourism in the region. Results. Transport accessibility largely determines the localization of the main tourist complexes and the prospects for implementing projects to create tourist infrastructure. In the region, a large volume of road construction was implemented within the framework of the regional program “Increasing the volume of construction and reconstruction of highways of the Altai Republic in the period 2015 - 2022.” However, most of the roads are adjacent to the federal highway R-256 (Chuysky tract); therefore the republic is characterized by a predominance of linear-radial routes. The use of the frame approach as a methodological basis for the study made it possible to identify the main linear objects and centers of tourism development on the territory of the Altai Republic. In combination with the route approach, an analysis of the distribution of the spatial configuration of the main route network was carried out across the region. This made it possible to identify opportunities for the development of ring structures, which will become a prospect for the development of the tourist network. Conclusion. Based on differences in natural resources, intensity of traffic flows, and features of tourist infrastructure, three sections of the Chuisky tract were identified. At each of these sites, key attractors have been identified that are places of disparagement for tourists and investors. Resume. We have identified prospects for circular routes that will contribute to the development of tourism infrastructure.

Diasporic Roots/Circular Routes: Kamin Mohammadi’s Search for Home in The Cypress Tree; A Love Letter to Iran (2011)

This paper explores Kamin Mohammadi’s position regarding the discourses of national belonging through the scrutiny of her circular route from England to Iran. Reflecting the interrelation between identity, home and the modern nation-state, The Cypress Tree: A Love Letter to Iran (2011) recounts the story of Mohammadi’s journey back to Iran in search of a singular self. It recounts her story of growing up in Iran and England and the reason behind her displacement from both of these countries in 1979 and 1997. Indebted to Stuart Hall’s take on the diaspora, Gaston Bachelard’s reading of home and Homi Bhabha’s notion of hybridity, this paper rejects the synonymy between home and home country as well as exclusive belonging intrinsic to nationalism. The aim of this paper is to read Mohammadi’s ultimate choice to settle down in England as a challenge to the homogenizing forces of nationalism that inhibited her sense of belonging to Britain and drew her toward Iran. As she embraces a hybrid identity by telling her circular story, beginning and ending in London, her literary contribution is a way to dismantle the link between belonging and the nation-state, as well as a challenge to the alleged homogeneity of the nation-states to which she belongs.

Bicyclic Guanidine Promoted Mechanistically Divergent Depolymerization and Recycling of a Biobased Polycarbonate.

We here report the organocatalytic and temperature-controlled depolymerization of biobased poly(limonene carbonate) providing access to its trans-configured cyclic carbonate as the major product. The base TBD (1,5,7-triazabicyclo[4.4.0]dec-5-ene) offers a unique opportunity to break down polycarbonates via end-group activation or main chain scission pathways as supported by various controls and computational analysis. These energetically competitive processes represent an unprecedented divergent approach to polycarbonate recycling. The trans limonene carbonate can be converted back to its polycarbonate via ring-opening polymerization using the same organocatalyst in the presence of an alcohol initiator, offering thus a potential circular and practical route for polycarbonate recycling.

Bicyclic Guanidine Promoted Mechanistically Divergent Depolymerization and Recycling of a Biobased Polycarbonate

AbstractWe here report the organocatalytic and temperature‐controlled depolymerization of biobased poly(limonene carbonate) providing access to its trans‐configured cyclic carbonate as the major product. The base TBD (1,5,7‐triazabicyclo[4.4.0]dec‐5‐ene) offers a unique opportunity to break down polycarbonates via end‐group activation or main chain scission pathways as supported by various controls and computational analysis. These energetically competitive processes represent an unprecedented divergent approach to polycarbonate recycling. The trans limonene carbonate can be converted back to its polycarbonate via ring‐opening polymerization using the same organocatalyst in the presence of an alcohol initiator, offering thus a potential circular and practical route for polycarbonate recycling.

Intelligent Cellular Offloading With VLC-Enabled Unmanned Aerial Vehicles

This paper discusses a cellular network assisted by an energy-and spectral-efficient unmanned aerial vehicle (UAV), in which the UAV is deployed to serve mobile users in the cellular network and enable mobile data offloading from a ground base station (GBS) by taking a circular flight route. We explore a visible light communication (VLC)-enabled UAV, in which a light-emitting diode (LED) is mounted on a rotary-wing UAV to offer communications to the users. Our aim is to simultaneously optimize both energy efficiency (EE) and spectral efficiency (SE) of the VLC-enabled UAV by jointly optimizing the common throughput of all users as well as the UAV’s trajectory and flying speed. We employ a unified metric, called resource efficiency (RE), and explore the RE optimization to obtain an adaptive EE-SE tradeoff. The problem posed is seen in a complex and non-convex shape, making it hard to solve. Motivated by the enormous achievement of deep reinforcement learning (DRL) in solving complex control problems, we propose a DRL-based approach to handle this non-convex and complicated optimization. The findings of the simulation reveal that the developed framework achieves a substantial performance in terms of the solution convergence as well as the promising quality of the solutions.

Применение метода Кларка – Райта в задачах тушения лесных пожаров силами авиационной охраны

Introduction. The purpose of this study is to determine the minimum cost of a path to a standstill forest fire and its localization. To achieve this goal, it is necessary to perform the tasks of analyzing the selected method for calculating the minimum costs for the process of unloading a fire landing and the process of localization of a low forest fire accordingly; identifying and characterizing the necessary equipment used in localizing a low forest fire; on definition of the optimal way and the number of employees of the Ministry of Emergency Situations as part of a fire landing force using an algorithm in the form of a pseudocode. The analytical part. The models, methods and algorithms of search of shortest way, optimization, circulation routing of transport are reviewed. Some problem of extinguishing of forest fire is set. The application of the modi­fied Clarke and Wright algorithm, which considers a possibility of variation of depth of route splice and definition of optimal value of probability of realization of the worsening step, makes it possible to find the minimum time spent by aviation forest protection for localization of a low forest fire. A solution to the problem of fire troop deli­very thanks to pseudocode implementing the basic Clarke and Wright algorithm is given. Conclusions. The solution based on the modified Clarke and Wright algorithm provides circular air routes that will be assigned to a helicopter, so that the delivery of firefighting troops will become economically feasible. The results of the research will be useful to analysts and software developers for the implementation of aerial firefighting activities.

Accessibility in a multiple transport mode urban park based on the “D-D” model: A case study in Park City, Chengdu

Park City is a new concept for sustainable urban development. Urban Parks are the core of Park City, where park accessibility is the central index of park services. Previous studies have been conducted primarily from residents' perspective, based on the “O-D” (origin to destination) model to access the park accessibility. However, urban parks should be considered a place supporting the coexistence of tourists and residents. Moreover, tourists' movement patterns differ from those of residents, which are expressed as “no turning back” and traverse circular or nodal routes. Consequently, this paper proposes that the traditional “O-D” model be expanded to be consistent with the movement patterns of tourists.This paper employs Park City Chengdu as an exemplar and proposes a “D-D” (destination to destination) model to facilitate further park accessibility. The calculation process was based on a multiple transportation mode measure with multiple time thresholds, entrances, and exits, supported by Web API. The results reveal the key time nodes and park accessibility rankings for four transportation modes. In particular, the park accessibility presents a “dual-core, several sub-centers and cluster-types” circle structure. Furthermore, the park accessibility in Chengdu was generally balanced, except within 25 min, as well as walking and public transport. This paper provides new hypothetical perspectives and practical experiences for studying urban park accessibility, and novel ideas for parks' sites and distribution while serving as a model for cities worldwide for sustainable urban development.

Guidance Law for Autonomous Takeoff and Landing of Unmanned Helicopter on Mobile Platform Based on Asymmetric Tracking Differentiator

For some flight missions, such as autonomous landing on mobile platforms, the demands on indicators such as target-tracking accuracy and so on are relatively high. To achieve this, a guidance system with excellent precision is necessary. An asymmetric tracking differentiator based on a tracking differentiator is proposed to establish the guidance system. On the basis of the proposed asymmetric tracking differentiator, an altitudinal and horizontal helicopter guidance system structure is designed. In this paper, a guidance law is designed in order to meet the accuracy and precision requirements in the autonomous landing and transition process. Apart from that, a plane-motion-guidance law is also designed to realize static and dynamic point tracking, linear route tracking and circular route tracking to improve the trajectory smoothness and accuracy. Finally, simulations of the autonomous landing process on moving platforms, including three stages, namely approaching, tracking and landing, are completed. The application effects and precision of the autonomous landing guidance algorithm under different wave heights and period conditions are analyzed through the obtained simulation curves.

Korištenje kapacitivnog problema usmjeravanja vozila s ograničenjem kapaciteta čvorova u vodnom prometu

The paper discusses the option of using the capacitated vehicle routing problem with the capacity limitation of nodes in water transportation. The problem is used to design circular routes for vehicles of different carriers, each of which services the selected nodes of the transportation network. The goal is to design circular routes where the capacity of vehicles is not exceeded and the value of the objective function is minimal. The limited capacity of nodes is given by the limited number of vehicles that can be operated at a particular node at any given time. The problem allows to design circulation so that the waiting time of vehicles to release the capacity of the node is minimized. This makes it possible to achieve an additional reduction in the total traffic time. The possibility of using the role of the CVRPCLN in water transportation is demonstrated in a case study for the design of circular routes for vessels serving ports. The design of routes is performed using the described problem and using the capacitated vehicle routing problem, which does not take into account the limited capacity of the nodes. To solve both problems, the author uses an evolutionary algorithm, which is part of the optimization module Solver. A comparison of the results indicates that the use of the investigated task can lead to a significant reduction in waiting times in ports for selected tasks in the field of water transportation. This also leads to a significant reduction in the total traffic time.

Shape-Guided Mixed Metro Map Layout.

Metro or transit maps, are schematic representations of transit networks to facilitate effective route-finding. These maps are often advertised on a web page or pamphlet highlighting routes from source to destination stations. To visually support such route-finding, designers often distort the layout by embedding symbolic shapes (e.g., circular routes) in order to guide readers' attention (e.g., Moscow map and Japan railway map). However, manually producing such maps is labor-intensive and the effect of shapes remains unclear. In this paper, we propose an approach to generalize such mixed metro maps that take user-defined shapes as an input. In this mixed design, lines that are used to approximate the shapes are arranged symbolically, while the remaining lines follow classical layout convention. A three-step algorithm, including (1) detecting and selecting routes for shape approximation, (2) shape and layout deformation, and (3) aligning lines on a grid, is integrated to guarantee good visual quality. Our contribution lies in the definition of the mixed metro map problem and the formulation of design criteria so that the problem can be resolved systematically using the optimization paradigm. Finally, we evaluate the performance of our approach and perform a user study to test if the embedded shapes are recognizable or reduce the map quality.

Recycling and Reusing Aspect of Green Circular Economy to Overcome Engineering and Environmental Challenges

The environmental issues of mineral oil-based drilling muds and additives in spite of their excellent technical performance such as good lubricity and high wear protection characteristics and the technical issues of water-based drilling muds such as the poor lubricity and wear resistance characteristics in spite of their excellent environmental traits require the development of high performance water-based drilling muds to overcome the current as well as the future drilling engineering and other oil and gas field challenges. Hence, several value-added green products have been developed adopting the recycling and reusing aspect of green circular economy of waste cook oil (WCO) to develop eco-friendly fluid additives and demonstrate their applications to explore and exploit oil and gas resources without any damage to the terrestrial, coastal and the marine environments and the ecosystems. Analyses of technical performance of the WCO derived green products with respect to the equivalent commercial products indicate similar or superior technical performance with the added benefit of no environmental impact. Hence, the recycling and reusing of the WCO provide a sustainable circular economical route for ecofriendly product development to overcome the technical and the environmental challenges simultaneously. It also provides a potential avenue for the growth and development of local, regional, national and global industries and infrastructures, development and creation of new job opportunities for the local, regional and the global communities, especially in developing and under-developed countries to create a positive societal and economic impact. Although this paper highlights mainly the oil and gas industry applications, WCO has huge potential for other industrial applications to overcome the technical problems without any negative environmental consequences. It can be used as a sustainable raw material for the development of a large variety of value-added green chemicals and polymers such as plasticizers, binders, surfactants, eco-greases, biopolymers, etc for other industrial applications. The renewable, sustainable and locally available source of the raw material have high potential to bring long-term stability to the oil and gas field additive supply chain for continuous and uninterrupted drilling and production operation. The paper highlights the applications of several WCO-based value-added products to overcome the technical and environmental challenges faced by the oil and gas industry.

Scan-to-BIM technique in building maintenance projects: practicing quantity take-off

PurposeIn Hong Kong, over 20,000 private residential buildings will be 50 plus years old by 2039. However, building maintenance has not been owners’ popular interest because of the high cost as well as the complexities in justifying whether the quantities and prices of the maintenance works are reasonable. This paper therefore aims to validate the practicality of adopting Scan-to-BIM: Terrestrial Laser Scan (TLS) and Building Information Modelling (BIM) to perform quantity take-offs (QTO) for estimating building maintenance costs.Design/methodology/approachA 64-year-old tenement building was selected to conduct a case study. In this instance, the building had undergone a Scan-to-BIM survey approach to generate QTO for the bills of quantities for external painting works. The Scan-to-BIM approach includes site visit, positioning of scanning equipment, assignment of circular scan routes, point cloud registration and identification of residual error. After that, time, cost and quality data were logged into contrast with QTO on as-built plans for external wall plastering works.FindingsThe “time”, “cost” and “quality” of the Scan-to BIM practice were then examined and compared with the prevailing practices of manual measurements on as-built drawings. As noted from the results, the initial cost of Scan-to BIM is high, owing to the cost of equipment, software and capable available operators. However, the authors identified that the time and cost can be significantly minimised by developing and implementing efficient practices such as preparing a detailed scan plan, equipping modeller with quantity surveying knowledge, using automated object recognition and 5D BIM software packages such as Vico Office and CostX.Practical implicationsThe upshot is that Scan-to-BIM could be one of the measures to advance the clarity in the QTO and estimated price of the maintenance projects.Originality/valueThe practicability of Scan-to-BIM has received limited attention on existing building maintenance project. The Scan-to-BIM approach was examined using a case building of a 64-year-old tenement building. The approach demonstrated in this research study is promised to advance the clarity in the QTO and estimated price of maintenance project.