Unidiameter Vertical Interpenetrating Cylindrical Surfaces (UVICS, also called T-pipe surfaces) are a type of typical complex surface that exists in facilities or equipment such as oil storage tanks and industrial pipelines. The shape and surface characteristics of a component undergoing spraying will have a significant impact on the spray flow field and the resulting coating film. In order to optimize the coating effects of complex surfaces, the Euler-Euler approach was utilized to model a spray film formation process that encompasses both a spray flow field model and a wall adhesion model. Subsequently, the influence of the geometric features, geometric dimensions, lateral air pressure of the spray gun, and spraying distance on the coating film characteristics of this kind of surface were systematically investigated. It is determined that the film thickness uniformity could be enhanced by decreasing the dimensions of the workpiece or increasing the lateral air pressure and spraying distance in an appropriate manner when spraying at the location with the most complex geometric features of UVICS. Furthermore, the optimal parameters under varying spraying conditions were identified. The experiments validated the accuracy of the numerical simulation results and demonstrated the feasibility of this simulation model. The study is of significant value in addressing the challenges associated with film formation during spraying on complex surfaces, developing a comprehensive theoretical framework for air spraying, and expanding the scope of applications for automatic spraying technology.