Core Chronology Research Articles

Tree-ring anomalies as time markers for ice-core chronologies, with special reference to 5281 BCE as the possible date of the Kikai volcanic event

The synchronization of Greenland and Antarctica ice core data with tree-ring data, other proxies, and direct observations of natural processes and events is important to understand past climatic variation and environmental change. One of the methods that is used to correct the dating of ice layers is to match volcanic eruption footprints in ice cores with tree rings, manifested as sulphate spikes and anomalous rings, respectively. In this study, we inventoried the occurrence of tree-ring anatomical anomalies and extremes in ring width during three 200-year periods. These periods included three of the eight largest Holocene volcanic eruptions, each with a Volcanic Explosivity Index (VEI) of 7. The initial period spanned from 6560 to 6360 BCE and included the eruption of Ilyinsky Volcano in Kamchatka. The second period was from 5780 to 5580 BCE, during which Mount Mazama Volcano in North America erupted. The third period was from 5380 to 5180 BCE when the Kikai Volcano in the Japanese Islands erupted. Throughout the first two periods, no substantial tree-ring anomalies were observed suggesting the absence of any significant climate consequences of a major volcanic eruption. However, in the 5380–5180 BCE period, a clear sharp decline in tree growth and an exceptionally high frequency of tree-ring anomalies were identified in 5281 BCE and the subsequent 5 years. We propose that the exceptionally narrow light rings in these 6 years are indicative of the climatic impact resulting from the Kikai volcanic eruption. We suggest utilising the year 5281 BCE as the reference year for synchronising the Greenland and Antarctica ice core chronologies. In the case that our assumption is correct, this would imply the necessity to adjust the time of the event to an earlier date compared to the dates indicated by the existing ice core chronologies of the GICC05 (Greenland Ice Core Chronology 2005), adjusted according to Kobashi (2017), and WD2014 used for creating HolVol 1.0 (Holocene ice-core volcanic eruption catalogue from 9500 BCE - 1900 CE) by 67 and 54 years, respectively, for the period around 5300 BCE. A verification of our assumption could be conducted by examining the nearby Miyake event, a spike in cosmogenic radiocarbon, of 5258 BCE. Ice core layers displaying potential signs of this event should be approximately 25 years later than the markers of the Kikai volcanic eruption.

What to monitor? Microplastics in a freshwater lake – From seasonal surface water to bottom sediments

Marine microplastics have received considerable attention, and efforts are underway to develop standardised methods for sampling, sample treatment, and analysis, while the observation of freshwater ecosystems remains relatively overlooked. To address this understudied environment, we present a comprehensive case study on microplastics in an urban lake from Baltic region of Northern Europe covering the seasonal dynamics of microplastics in surface water, deposition rate throughout one year in sediment traps and distribution of microplastics in dated sediment archive to determine the most representative environmental compartment for microplastic pollution monitoring. The following well-established microplastic research methods have been used: Manta trawling for surface water, trapping for assessing microplastics sedimentation rate and coring for sediments. Attenuated total reflection and micro-Fourier transform infrared spectroscopy methods were used to investigate the synthetic nature of identified particles. The sediment core chronology was based on 210Pb and Bayesian Plum model revealing sediment layers to represent even the time before the beginning of plastic mass production (approximately 1950). The surface water microplastic concentrations were higher in summer (5.71 particles/m3) and gradually decreased towards winter (0.75 particles/m3); they were almost 25 times higher in more recent (2018) sediments than in the deeper layers referring to years prior to 1890. Surprisingly, microplastic particles were found in sediments before the year 1950. The microplastic deposition rate was 9.47 particles/cm2/year or 4.31 µg/cm2/year. The most abundant polymers were polyethylene, polystyrene and polypropylene, and the prominent particle shapes were fibres in surface water and fragments in sediments. Our results provide a baseline for evaluating future contamination level changes in highly urbanized area. We recommend the combination of surface water filtering with net and sediment trapping methods for monitoring microplastics in lakes since this method requires little time and financial resources for sampling and processing and produces information on temporal microplastic occurrence and deposition.

Fine-Tuning of Sub-Annual Resolution Spectral Index Time Series from Eifel Maar Sediments, Western Germany, to the NGRIP δ18O Chronology, 26–60 ka

Recent technological advancements in spectral imaging core-scanning techniques have proved to be a promising tool to study lake sediments at extremely high resolution. We used this novel analytical approach to scan core AU3 of the Pleistocene Auel maar, Western Germany. The resulting ultra-high-resolution RABD670 spectral index, a proxy for the lake’s primary production, shows an almost complete succession of Greenland Interstadials of the NGRIP ice core chronology back to around 60,000 years. Using the ELSA-20 chronology and its anchor points to the NGRIP record as a stratigraphic basis, we were able to compare and fine-tune prominent climate signals occurring in both regions. This in-depth correlation yields strong evidence that the climates of Greenland and Central Europe were not only strongly coupled on timescales of stadials and interstadials but even on multidecadal scales, showing prominent climate cycles between 20 and 125 years. As climate changes in these regions were ultimately driven by variations in the North Atlantic meridional heat transport, their strong coupling becomes most apparent during cold and arid intervals. In contrast, longer-lasting warmer and more humid phases caused the activation of various regional feedback mechanisms (e.g., soil formation, forest growth), resulting in more complex patterns in the proxy records.

Dating the Neanderthal environment: Detailed luminescence chronology of a palaeochannel sediment core at the Palaeolithic site of Lichtenberg in the Lower Saxony, northern Germany

Northern Germany is famous for its numerous Neanderthal (Middle Palaeolithic) archaeological sites and well-preserved palaeoclimate records. Nevertheless, our understanding of how hominins responded to climate fluctuations and adapted to changing environments in this region remains limited because there are only a few reliable, highly-resolved chronological frameworks of long stratigraphic successions. Most of the Middle Palaeolithic sites in this region lack a reliable chronostratigraphy beyond the radiocarbon dating range. In this study, we present a high-resolution optically stimulated luminescence (OSL) chronology derived from a ∼21 m long sediment core (Li-BPa) that was drilled in close proximity to the known Neanderthal site of Lichtenberg. Quartz OSL dating was applied to the upper 6.5 m of the core. Subsequently, the obtained quartz OSL ages were compared with feldspar post-infrared (IR) IRSL (pIRIR) measured at 290 °C (pIRIR290), pulsed IR50 (pre-pIRIR225), and pulsed pIRIR225 ages to select a suitable feldspar signal to date older samples. A comparison of the quartz and feldspar ages indicates that only fading-corrected pulsed IR50 (pre-pIRIR225) and pIRIR225 ages agree well with quartz OSL ages. Finally, the age framework of the sediment sequence was established based on the 11 quartz OSL ages and 23 fading-corrected pulsed IR50 (pre-pIRIR225) and pulsed pIRIR225 ages. The resulting Bacon age-depth model agrees with litho- and biostratigraphic designations, indicating that the whole sequence was deposited between ca. 275 ka and ca. 24 ka, corresponding to the Saalian to Weichselian periods.

Palaeoenvironmental changes since the last deglaciation recorded at Moon Lake on the Bashang Plateau, northern China: implications for the future sustainability of regional forests

Warming-induced ecological degradation and the continuous shrinking of lakes have been observed in the Bashang Plateau, northern China, leading to the recent demise of cultivated forests. The objective of this paper is to investigate the long-term palaeoenvironmental context of these recent changes through a multi-proxy sediment core analysis at Moon Lake to better understand forest sustainability in the future. The core chronology was determined based on seven accelerator mass spectrometry (AMS) 14C dates and covers the period from 14,000 yr BP to the present. The Moon Lake record reveals four climate stages: (1) a warm and humid period followed by a cold and arid phase corresponding to the Allerod warm period and the Younger Dryas stadial (14,000 to 11,700 yr BP), (2) a relatively warm and humid period (11,700 to 7400 yr BP), (3) a period of fluctuating dry-wet-dry changes (7400 to 4000 yr BP), and (4) a relatively arid period (4000 yr BP to present). Since 1800 yr BP, drought conditions have intensified, and significant warming and drying trends have been observed over the past 500 yr BP. This consistent warming and drying trend over the past few centuries indicate that large-scale afforestation is no longer sustainable in the Bashang region. Coupled with instrumental records of soil drying and water scarcity, our Holocene records of climate change are useful for ecological resource management and sustainable forestry planning in the region.

Palaeoclimatic shifts in the Central Ganga Basin during the Middle- to Late Holocene: Exploring the 4.2 ka arid event and its implications in northern India

The Central Ganga Basin is one of the most densely populated regions of India. It is agriculturally diverse and contributes much to the Indian economy. The region has housed numerous ancient and mediaeval empires. This study presents a continuous record of the paleomonsoon from the Chandrika Devi lake, Lucknow district of Uttar Pradesh, India which is linked with paleo vegetational shifts over the last ~6000 years (5871–75 cal yr BP). The chronology of the lake core is based on three accelerated mass spectrometry (AMS) radiocarbon and two Optically Stimulated Luminescence (OSL) dates. The multiproxy data (grain size, major and trace element ratio, total organic carbon (TOC wt%), carbon isotopes (δ13Corg‰) and pollen), suggest that the lake was initially a part of the Gomti river that began to transform into a lake at ~5000 cal yr BP with weakening of the Indian summer monsoon (ISM) in the Central Ganga Basin. The lake formation was completed at ~4100 cal yr BP under the influence of the 4.2 ka arid event. This phase marks the beginning of human presence as well as agricultural activities in the lake region with the appearance of Cerealia pollen and other agricultural taxa. The agricultural activity surrounding the lake catchment peaked at ~3000 cal yr BP. The lake gradually shrank and became a marshy lowland at ~75 cal yr BP. Our study is significant because it is the first comprehensive multiproxy study from the Lucknow region in the Central Ganga Basin on paleomonsoonal variability and its relationship to human activity, agricultural practices during the Late-Holocene with a focus on the 4.2 Ka arid event. Also, pollen record suggests that the changes in agriculture and human activity began just after 4.2 ka arid event in the study area.

Human-Altered Water and Carbon Cycles in the Lake Yangzong Basin since the Yuan Dynasty

Due to the dual influence of climate change and human activities, the water cycle patterns in the lakesheds of the Yunnan karst plateau are undergoing significant changes, leading to increasingly prominent ecological issues. In the history of Lake Yangzong, an artificial water-diversion channel was excavated, altering the lake basin structure. Human activities have intensified, posing severe challenges to water resource supply and water security in recent decades. To investigate the significant increase in human activities, the temporal and phase changes, and the resulting transformation of the water and carbon cycles in the Lake Yangzong basin, we applied X-ray fluorescence spectroscopy (XRF) to scan elements continuously in a 10.2 m sediment core from this lake. By combining correlation analysis, principal component analysis (PCA), core chronology, and total organic carbon (TOC) content, we reconstructed the historical sequence of geochemical element contents in the Lake Yangzong catchment over the past 13,000 years. The results show that PC1 and PC2 contribute 78.4% and 10.3%, respectively, suggesting that erosion intensity is the main factor influencing the lake sedimentation process. From 13,400 to 680 cal a BP (calibrated years before the present), the sedimentation process in Lake Yangzong was mainly controlled by climatic conditions, with vegetation degradation during cold periods and relatively high erosion intensity in the watershed. During the Yuan dynasty, a province was established by the central government in Yunnan, promoting settlement and attracting a large number of immigrants from other provinces to Yunnan. Human activities in the Lake Yangzong basin began to intensify, surpassing natural changes and becoming the dominant force influencing the sedimentation process. In the Ming and Qing dynasties, the population and cultivated land area in Yunnan further increased, resulting in the significant exacerbation of erosion and soil loss in the watershed due to vegetation destruction. In the year 1388, the Tangchi Canal was excavated, transforming Lake Yangzong to an outflow lake, causing Ca2+ to be lost through the Tangchi Canal and preventing the formation of precipitation due to oversaturation. The research results indicate that human activities in the Lake Yangzong area have intensified since the Yuan dynasty, leading to increased erosion intensity. The excavation of the outflow canal transformed Lake Yangzong from an inland lake basin into an outflow state, simultaneously generating a significant transformation in the water and carbon cycling patterns in the watershed.

An annually resolved chronology for the Mount Brown South ice cores, East Antarctica

Abstract. Climate reconstructions of the last millennium rely on networks of high-resolution and well-dated proxy records. This study presents age-at-depth data and preliminary results from the new Mount Brown South (MBS) ice cores, collected at an elevation of 2084 m on the boundary of Princess Elizabeth Land and Kaiser Wilhelm II Land in East Antarctica. We show an initial analysis of the site meteorology, mean annual chemical species concentrations and seasonal cycles, including the identification of a seasonal cycle in fluoride concentrations. The annually resolved chronologies were developed from the chemistry data using a site-specific layer-counting methodology that employed seasonally varying trace chemical species and stable water isotopic ratios, combined with alignment to known volcanic horizons. The uncertainty in the determination of annual horizons via layer counting was also quantified. The chronologies developed include the “Main” 295 m record spanning 1137 years (873–2009 CE) and three surface cores spanning the most recent 39–52 years up to the surface age at the time of drilling (austral summer 2017/2018). Mean annual trace chemical concentrations are compared to the Law Dome ice core (located 1130 km east of the Mount Brown South site) and discussed in terms of atmospheric transport. The MBS chronologies presented here – named MBS2023 – will underpin the development of new palaeoclimate records spanning the past millennium from this under-represented region of East Antarctica.

Chronology of drill cores and the inferred coastal environmental evolution on Haitan Island, South China

ABSTRACTSoutheastern China's coastal region is considered one of the key areas for studying prehistoric human–land relationships in the Western Pacific region. This region, which is rich in records of marine civilization, provides an ideal location for recording coastal environmental evolution. In this study, the chronological framework of three borehole cores recovered from Haitan Island, South China, near the Keqiutou group of sites, was established using both optically stimulated luminescence (OSL) and accelerator mass spectrometry radiocarbon (AMS 14C) dating techniques. Various analyses, including lithologic characteristics, chroma, clay–water electric conductivity (EC), grain size and elemental geochemistry, were conducted to elaborate the sedimentary sequence and its paleoenvironmental implications. The findings suggest that (i) since the late Quaternary, the Haitan Island sedimentary sequence can be divided into three deposition stages: Old Red Sand formed during Marine Isotope Stage 3 (MIS3), intermittent sedimentation during the Last Glacial Maximum and coastal aeolian deposition during the Holocene. Furthermore, the study reveals that terrestrial debris was significant as a material source for Haitan Island. (ii) Due to the absence of tectonic uplift, Haitan Island has no thick marine sedimentary record during the Holocene period of high sea level. The Luyangpu coastal sand sheet can be dated to 2.78 ka, which is consistent with previous reports giving dates of 2.4 ka. Prior to the formation of the sand sheet, the sedimentary environment in the area was characterized by lagoon or marsh facies. (iii) Paleoanthropological activities were influenced by sedimentary environmental evolution and geomorphic processes, among others. The Keqiutou Culture experienced high sea levels, which created an intertidal environment near the site and facilitated fishing. However, regression at 5.7 ka led to terrestrial environments, which prompted the inhabitants to migrate. Approximately 3 ka ago, sea levels rose again, coinciding with the initiation of rice cultivation. These factors may have influenced the transition from the Neolithic to Bronze Age culture. This study reconstructs evolution of the sedimentary sequence since the late Quaternary, enhancing our understanding of past human–terrestrial relationship in the region.

Natural and anthropogenic controls on environmental change during the Holocene based on a multi-proxy record obtained from subalpine peatland in southern China

The interactions between past climate, human activity and environmental change in subtropical mountainous areas are poorly understood due to the lack of reliable records in South China. In this study, the evolution of the East Asian summer monsoon (EASM) during the Holocene, and the interactions between regional human activity and environmental change, were studied using multi-proxy records from a subalpine peat core recovered from South China. The chronology of this peat core has been well-constrained by 10 AMS 14C dates of peat stems. A series of proxy indicators, including carbon isotopes (δ13C), loss on ignition (LOI), magnetic susceptibility (MS), the chemical index of alteration (CIA), and geochemical elements from the Shiwangutian (SWGT) peatland were used to reconstruct the palaeohydrological changes during the Holocene. Regional moisture levels showed a generally arid–wet–arid pattern, and three phases of climatic change were detected as follows. 1) Between 11,600 and 9000 cal yr BP, the EASM was weak and a relatively dry climate developed. 2) Between 9000 and 4000 cal yr BP, the prevalence of humid climatic conditions was associated with a strong summer monsoon. 3) After 4000 cal yr BP, the climate shifted to relatively dry conditions. Further comparisons and analysis suggested that solar insolation, migration of the Intertropical Convergence Zone (ITCZ), and El Niño-Southern Oscillation (ENSO) activity played an important role in determining the variations in Holocene EASM intensity. In addition, the increase in both MS and heavy metal concentrations over the last 1000 years is consistent with an increase in the population of Hunan Province. Therefore, it can be inferred that population growth and the associated expansion of cropland and mining led to an increase in soil erosion and metal tool use. These findings suggest that the impact of human activity generally outweighed the natural climatic controls on the environment and landscape in the mountainous region of southern China over the last 1000 years.

The Antarctic Ice Core Chronology 2023 (AICC2023) chronological framework and associated timescale for the European Project for Ice Coring in Antarctica (EPICA) Dome C ice core

Abstract. The EPICA (European Project for Ice Coring in Antarctica) Dome C (EDC) ice core drilling in East Antarctica reaches a depth of 3260 m. The reference EDC chronology, the AICC2012 (Antarctic Ice Core Chronology 2012), provides an age vs. depth relationship covering the last 800 kyr (thousands of years), with an absolute uncertainty rising up to 8000 years at the bottom of the ice core. The origins of this relatively large uncertainty are twofold: (1) the δ18Oatm, δO2/N2 and total air content (TAC) records are poorly resolved and show large gaps over the last 800 kyr, and (2) large uncertainties are associated with their orbital targets. Here, we present new highly resolved δ18Oatm, δO2/N2 and δ15N measurements for the EDC ice core covering the last five glacial–interglacial transitions; a new low-resolution TAC record over the period 440–800 ka BP (ka: 1000 years before 1950); and novel absolute 81Kr ages. We have compiled chronological and glaciological information including novel orbital age markers from new data on the EDC ice core as well as accurate firn modeling estimates in a Bayesian dating tool to construct the new AICC2023 chronology. For the first time, three orbital tools are used simultaneously. Hence, it is possible to observe that they are consistent with each other and with the other age markers over most of the last 800 kyr (70 %). This, in turn, gives us confidence in the new AICC2023 chronology. The average uncertainty in the ice chronology is reduced from 1700 to 900 years in AICC2023 over the last 800 kyr (1σ). The new timescale diverges from AICC2012 and suggests age shifts reaching 3800 years towards older ages over marine isotope stages (MISs) 5, 11 and 19. But the coherency between the new AICC2023 timescale and independent chronologies of other archives (Italian Lacustrine succession from Sulmona Basin, Dome Fuji ice core and northern Alpine speleothems) is improved by 1000 to 2000 years over these time intervals.

The biogenic elements retention in reservoirs of the Yangtze River basin and effect on the nutrient flux into the sea

The Yangtze River catchment is among the most human-impacted basins globally, with a population of approximately 590 million and over 60,000 dams constructed by 2020. While the effect of reservoir dams on runoff and sediment has been extensively studied, assessing the impact of biogenic element retention in reservoirs on nutrient flux into the sea remains a challenge. This study analyzed the total organic carbon (TOC), total organic nitrogen (TN), biogenic silica (BSi), grain size, and 210Pb chronology of sediment cores collected from the Pengshui, Wuqiangxi, Three Gorges, and Danjiangkou reservoirs. The analysis was combined with the database of annual reservoir area and nutrient flux into the sea of the Yangtze River. The results showed that the average annual sedimentary retention of TOC, TN, and BSi in the four reservoirs increased by 16%, 18%, and 26% after dam construction and rapid eutrophication. The total water area of large reservoirs increased from 30 to 132,000 km2 between 1960 and 2016, resulting in total accumulated retention increments of TOC, dissolved inorganic nitrogen (DIN), dissolved inorganic phosphate (DIP), and dissolved silicon (DSi) in reservoirs reaching 27, 3.5, 0.1, and 27.2 million tons, respectively. The retention increments accounted for 20.6%, 7.0%, 8.8%, and 12.1% of the total flux of TOC, DIN, DIP, and DSi into the sea during the same period, respectively. The retention of TOC and DSi in reservoirs led to a decrease in their annual flux into the sea by 67.2% and 61.4% in 2016 compared to 1960. However, the retention of DIN and DIP increased their annual flux by 6.4-fold and 4.2-fold in 2016 compared to 1960, which was attributed to the substantial emission of fertilizer and sewage in the downstream catchment area of dams. These findings provide valuable insights into biogenic element retention in reservoir catchments and their impact on nutrient flux into the sea.

Volcanic glass from the 1.8 ka Taupō eruption (New Zealand) detected in Antarctic ice at ~ 230 CE

Chemical anomalies in polar ice core records are frequently linked to volcanism; however, without the presence of (crypto)tephra particles, links to specific eruptions remain speculative. Correlating tephras yields estimates of eruption timing and potential source volcano, offers refinement of ice core chronologies, and provides insights into volcanic impacts. Here, we report on sparse rhyolitic glass shards detected in the Roosevelt Island Climate Evolution (RICE) ice core (West Antarctica), attributed to the 1.8 ka Taupō eruption (New Zealand)—one of the largest and most energetic Holocene eruptions globally. Six shards of a distinctive geochemical composition, identical within analytical uncertainties to proximal Taupō glass, are accompanied by a single shard indistinguishable from glass of the ~25.5 ka Ōruanui supereruption, also from Taupō volcano. This double fingerprint uniquely identifies the source volcano and helps link the shards to the climactic phase of the Taupō eruption. The englacial Taupō-derived glass shards coincide with a particle spike and conductivity anomaly at 278.84 m core depth, along with trachytic glass from a local Antarctic eruption of Mt. Melbourne. The assessed age of the sampled ice is 230 ± 19 CE (95% confidence), confirming that the published radiocarbon wiggle-match date of 232 ± 10 CE (2 SD) for the Taupō eruption is robust.

First occurrence of planktonic foraminiferal species Boliella adamsii as a marker for the Pleistocene-Holocene Boundary in the sea around Sumba Island

The expensive cost of Accelerator Mass Spectrometry radiocarbon dating (AMS 14C), the main tool for geochronology in Late Pleistocene-Holocene paleoclimate and paleoceanography study using marine sediment cores, hinders Indonesian researchers to produce competing research outputs. The first occurrences of planktonic foraminiferal species which have been applied as Pleistocene-Holocene Boundary markers in previous Quarternary marine sediment studies in the Indonesian region need to be confirmed as these species might actually occur since the Late Pleistocene. Quantitative foraminifera determination and oxygen isotope (δ18O) analysis of planktonic foraminiferal species Globigerinoides (Gs.) ruber have been carried out in marine sediment cores ST10 (off south Sumba) and ST14 (Sumba strait). δ18O of Gs. ruber was correlated to North Greenland Ice Core Project (NGRIP) Greenland Ice Core Chronology 2005 (GICC05) δ18O to determine the depth of the Pleistocene-Holocene Boundary (11653 BP) in core ST10 and ST14. Pleistocene-Holocene Boundary depth in core ST10 (31 cm) and ST14 (28 cm) are nearly coeval with the First occurrence (FO) of planktonic foraminifera Boliella adamsii, which at 34-35 cm depth interval in core ST10 and at 26-27 cm depth interval in core ST14. This indicated the practicality of Boliella adamsii FO as a Pleistocene-Holocene Boundary marker in the sea around Sumba Island, in case radiocarbon ages and proper planktonic foraminiferal δ18O data are not available. Future studies using a similar method in other Indonesian regions are needed to confirm the practicality of Boliella adamsii FO as a Pleistocene-Holocene Boundary marker in the Indonesian region.

Millennial-scale changes in the Asian monsoon during the MIS12 period as recorded by a Chinese stalagmite

Marine Oxygen Isotope Stage 12 (MIS 12), the last glacial period before the Mid-Brunhes event (MBE), is considered the coldest glacial period during the past several glacial/interglacial cycles and is important because it can help better understand the cyclicity and mechanism of the millennial-scale variability of a glacial period. However, owing to the lack of precisely dated and high-temporal-resolution records, the millennial-scale variability during this period remains unclear. A 230Th/U dated stalagmite from Luoshui Cave, Hubei Province, Central China, was analyzed for stable oxygen isotopes (δ18O). An ∼120-yr-resolution δ18O profile is presented to clarify the Asian summer monsoon (ASM) history between 464 and 420.6 kyr BP (Before present, where present = 1950 CE), which corresponds to the interval from the MIS 12 to the early part of the MIS 11. The MIS 12 monsoon generally followed the insolation differences on June 21 between 30°N and 30°S and was interrupted by ten Chinese interstadial events (CISs). At least nine prominent weak monsoon intervals (WMIs) were identified during MIS 12 and displayed a strong coupling with the northern high-latitude climate and Antarctic temperature through the bipolar seesaw model, suggesting a substantial relationship with the bipolar region. This indicates that millennial-scale variability in the ASM region is an inherent feature of the MBE and has a global teleconnection. Additionally, in contrast to the EPICA DOME C3 (EDC 3) timescale, the new absolutely dated speleothem record confirms the Antarctic Ice Core Chronology 2012 (AICC 2012) at MIS 12, a period with a large difference between the two ice record geochronologies over the past 800 kyr.

Ice Core Methane Analytical Techniques, Chronology and Concentration History Changes: A Review

Ice cores are invaluable in paleoclimate research, offering unique insights into the evolution of the natural environment, human activities, and Earth’s climate system. Methane (CH4) is a crucial greenhouse gas, second only to CO2 in its contribution to global warming, and is one of the primary anthropogenic greenhouse gases. Understanding historical CH4 concentration changes is essential for predicting future trends and informing climate change mitigation strategies. By analyzing gas components trapped in ice core bubbles, we can directly examine the composition of ancient atmospheres. However, there are relatively few comprehensive reviews on ice core CH4 testing techniques, chronology, and concentration history records. In response to this gap, our paper systematically reviews ice core CH4 analytical techniques, chronology, and concentration history changes. Our review indicates that current research on CH4 in non-polar ice cores is insufficient compared to polar ice cores, facing challenges such as high data dispersion, outlier frequency, and the presence of non-atmospheric signals. These limitations hinder our in-depth understanding of CH4 signals in non-polar ice cores, and the reliability of atmospheric CH4 concentration changes they reflect. To address these challenges, we propose exploring and applying advanced testing techniques, such as Continuous Flow Analysis technology, in non-polar ice cores. Additionally, we emphasize the research gap in utilizing CH4 records for age determination in ice core chronology. Future research should focus on this area to advance our understanding of ice core chronology and the history of atmospheric CH4 changes in non-polar regions, ultimately contributing to more effective climate change mitigation efforts.

The 239Pu nuclear fallout as recorded in an Antarctic ice core drilled at Dome C (East Antarctica)

Starting from 1952 C.E. more than 540 atmospheric nuclear weapons tests (NWT) were conducted in different locations of the Earth. This lead to the injection of about 2.8 t of 239Pu in the environment, roughly corresponding to a total 239Pu radioactivity of 6.5 PBq. A semiquantitative ICP-MS method was used to measure this isotope in an ice core drilled in Dome C (East Antarctica). The age scale for the ice core studied in this work was built by searching for well-known volcanic signatures and synchronising these sulfate spikes with established ice core chronologies. The reconstructed plutonium deposition history was compared with previously published NWT records, pointing out an overall agreement. The geographical location of the tests was found to be an important parameter strongly affecting the concentration of 239Pu on the Antarctic ice sheet. Despite the low yield of the tests conducted in the 1970s, we highlight their important role in the deposition of radioactivity in Antarctica due to the relative closeness of the testing sites.

Multidecadal heavy metals and microplastic deposition records in an urban lake: the ecological risk assessments and influencing factors.

With the development of urbanization and economic growth, the urban lake ecosystem faces many challenges derived from external factors. As pollutants in the aquatic environment, heavy metals and microplastics negatively influence the urban lake ecosystem due to their intrinsic properties. To understand the distribution patterns and multidecadal deposition characteristics of heavy metals and microplastics, six sediment cores were collected in March 2021 from a Chinese urban lake, Xinghu Lake, and the isotopic composition of cesium-137 and lead-210 was analyzed for the chronology of the sediment core. Here, the classifications of comprehensive ecological risk evaluation methods for heavy metals and microplastics were adjusted further. Meanwhile, the correlations among heavy metals, microplastics, sediment grains, and natural and social factors were further analyzed. The results showed that the sediments of Xinghu Lake were mainly fine silt (39%), and the average surface area of sediment was 1.82 ± 0.60 m2/g. The average concentrations of cadmium, chromium, copper, nickel, lead, vanadium, and zinc were 0.268 ± 0.077, 59.91 ± 16.98, 23.29 ± 6.48, 52.16 ± 13.11, 36.83 ± 11.78, 119.57 ± 26.91, and 88.44 ± 29.68mg/kg, respectively. The average comprehensive potential ecological risk indexes of heavy metals and microplastics in sediment cores were 46.59 ± 9.98 and 105.78 ± 23.32 in Xinghu Lake, and their risks were projected to reach high and very high levels by 2030 and 2050. The annual average temperature was the key natural factor for the abundances of heavy metals and microplastics, and the small sediment grain had a significant correlation with these. Agricultural activities were major pollution sources of heavy metals and microplastics, while the chemical fibers and plastic products were closely related to the abundance of microplastics.

A humification-based method toward refining Holocene radiocarbon chronologies: Wetland records from southeastern China

Holocene paleoclimate reconstructions and comparisons largely rely on accurate age-depth modeling. However, uncertainties in chronology, such as those caused by sparse radiocarbon dates, will hamper inter-core comparisons and correlations, and might result in misleading “cause and consequence” conclusions. This study aimed to find a solution to increase the comparability and minimize the uncertainty of wetland chronology as much as possible. Sediment cores were recovered and radiocarbon dated from the Lianhuachi wetland located in Southeastern China. Humification degree and loss-on-ignition (LOI) were determined using colorimetric and combustion methods respectively. Our data were compared with previously published datasets obtained in the same wetland. The results show that independent humification profiles from the Lianhuachi wetland displayed high similarities. This high similarity between the humification profiles allowed us to transfer radiocarbon ages from one core to another using sequence slotting correlation. Applying the humification-based chronology refinement method to all sediment cores resulted in an improvement in the correlation coefficients between the same but independently measured proxy sequences from the wetland, which suggests both the inter- and intra-core comparability was improved. Because determining peat humification degree is easy, inexpensive, and time-saving, we suggest that humification can serve as a tool that can be used to correlate different cores and to transfer published radiocarbon ages within the same wetland (peatland) or in a comparable geological setting, to establish a more robust chronology of these comparable cores. The degree of peat humification can thus serve as a relative dating technique to refine the chronology of wetland (including peatland) records.

Reconstruction of Dead Sea lake level and mass balance back to 237 ka BP using halite fluid inclusions

The lake level of the Dead Sea, Southern Levant, has fluctuated with an amplitude of ∼250 m in response to the last glacial-interglacial cycle. This exceptional sensitivity to climate change, and the availability of long sedimentary archives, make the Dead Sea a benchmark for long quantitative paleohydrological reconstructions. However, discontinuities and chronological uncertainties in the marginal sedimentary record have hampered the reconstruction of Dead Sea lake levels beyond the Last Glacial (70–14 ka before present, BP). Here, we apply a two-pronged methodology. First, we measure the lake water density along ICDP deep core 5017-1-A using a new method, Brillouin spectroscopy on two-phase halite fluid inclusions; we combine it with the composition of pore water and the thickness of halite layers in the core to reconstruct lake level, volume, mass balance and subsidence rate. Second, we tune the chronology of lake levels from outcrops by matching it to the chronology of the deep core. The resulting lake level reconstruction, spanning 237–70 ka BP, is validated by the excellent agreement between outcrop- and mass balance-based methodologies. It shows a long-term recession of the lake, its level decreasing from one interglacial to the other, down to a Holocene record low. There are two reasons for this lake level fall. First, with an average rate of 2.65 ± 0.15 m/ka, subsidence has outpaced sedimentation at least over the last ∼130 ka. Second, by reducing the solute inventory of the lake, massive halite precipitation events such as that of 131–116 ka BP have durably increased surface water activity and evaporation, and thus lowered the lake level, up to today. Conversely, our analysis suggests that, during 191–11 ka BP, the dissolution of Mount Sedom salt diapir and freshwater inflows provided to the lake about three times the mass of solute NaCl contained in the modern Dead Sea (in 1985). This massive solute influx, occurring mainly during glacial highstands, strongly contributed to lowering surface water activity and evaporation and, therefore, to increasing the lake volume. Our results suggest that Dead Sea lake levels are more accurately interpreted in terms of climatic change if surface water activity is taken into account.