Chromophoric Dissolved Organic Matter Research Articles

DOM Associates with Greenhouse Gas Emissions in Chinese Rivers under Diverse Land Uses.

Growing evidence indicates that rivers are hotspots of greenhouse gas (GHG) emissions and play multiple roles in the global carbon budget. However, the roles of terrestrial carbon from land use in river GHG emissions remain largely unknown. We studied the microbial composition, dissolved organic matter (DOM) properties, and GHG emission responses to different landcovers in rivers (n = 100). The bacterial community was mainly constrained by land-use intensity, whereas the fungal community was mainly controlled by DOM chemical composition (e.g., terrestrial DOM with high photoreactivity). Anthropogenic stressors (e.g., land-use intensity, gross regional domestic product, and total population) were the main factors affecting chromophoric DOM (CDOM). DOM biodegradability exhibited a positive correlation with CDOM and contributed to microbial activity for DOM transformation. Variations in CO2 and CH4 emissions were governed by the biodegradation or photomineralization of dissolved organic carbon derived from autotrophic DOM and were indirectly affected by land use via changes in DOM properties and water chemistry. Because the GHG emissions of rivers offset some of the climatic benefits of terrestrial carbon (or ocean) sinks, intensified urban land use inevitably alters carbon cycling and changes the regional microclimate.

Addition of Tumeric Flour in Ration on The Growth of Super-Native Chickens Aged 11-18 Weeks

The main components in turmeric are essential oils and curcuminoids, which are yellow color substances in turmeric, essential oils, and Curcuminoids can increase the digestibility of dry matter and protein, increase digestive enzymes so that feed digestibility increases and results in the digestive tract emptying faster, and ultimately provide consumption increases. The design used is a completely randomized design (CRD) with 5 (five) treatments and 3 (three) replicates. The experimental treatments are designated as follows: P0 represents the control group without the addition of turmeric flour, P1 represents the group with 1% turmeric flour, P2 represents the group with 2% turmeric flour, P3 represents the group with 3% turmeric flour, and P4 represents the group with 4% turmeric flour. This study's variables recorded and analyzed included initial body weight, final body weight, weight gain, ration consumption, and feed conversion ratio The findings of this investigation demonstrated that The incorporation of turmeric flour showed a statistically significant effect (P <0.05) on Final Body Weight, Weight Gain, and Feed Consumption Ratio. However, it was shown that the variables under investigation did not significantly impact ration consumption (P>0.05). Giving turmeric flour up to 2% can provide the best results

Coupling between chromophoric dissolved organic matter and dissolved inorganic carbon in Indian estuaries

This study investigates the coupling between Chromophoric Dissolved Organic Matter (CDOM) and Dissolved Inorganic Carbon (DIC) in eighteen Indian estuaries across salinity gradient of the east and west coasts during the monsoon season, characterized by significant river discharge. The hypothesis that humic acids (HA) and fulvic acids (FA), prominent in estuarine CDOM, closely correspond to the ‘organic alkalinity’ (Aorg) component of total alkalinity is examined. In most estuaries, specifically those along the northeast coast (NE) and southwest coast (SW), a significant linear relationship exists between DIC, CDOM abundance, and pH level. Notably, minor estuaries along the southeast coast (SE) and northwest coast (NW) exhibit elevated DIC levels beyond what this relationship predicts. These estuaries also reveal heightened ammonium levels, increased δ15N values, and decreased δ13C values, indicative of anthropogenic influence. CDOM properties, such as spectral slope (S300–500) and spectral slope ratio (SR, S275–295:S350–400), align with these findings, with SE and NW estuaries displaying higher values. On average, CDOM contributes 110.5 μM (6.8 %) to DIC in NE, 390.7 μM (11 %) in SE, 24.4 μM (4.8 %) in SW, and 122.2 μM (4 %) in NW estuaries. The relationship between total alkalinity minus DIC (TA-DIC) and pH25 suggests that CDOM, mediated by HA/FA, buffers the inorganic carbon system in estuaries. This buffering capacity weakens at elevated DIC levels, and this condition is marked by anomalous SR values compared to the baseline salinity-SR linear regression. This Study suggests that estuarine CDOM could largely represent “organic alkalinity” and could help monitor acidification in estuaries.

Elucidation of the Photochemical Fate of Methionine in the Presence of Surrogate and Standard Dissolved Organic Matter under Sunlight Irradiation.

The abiotic fate of dissolved free amino acids considerably contributes to the cycling of dissolved sulfur and nitrogen in natural aquatic environments. However, the roles of the functional groups of chromophoric dissolved organic matter (CDOM) and the fate of free amino acids under sunlight irradiation in fresh waters are not fully understood. This study aims to elucidate the fate of photolabile methionine in the presence of three CDOM surrogate compounds, i.e., 1,4-naphthoquinone, 2-naphthaldehyde, and umbelliferone, and two standard CDOM by coupling experimental measurement, quantum chemical computations, and kinetic modeling. Results indicate that excited triplet-state CDOM and hydroxyl radicals are able to cleave the C-S bond in methionine, resulting in the formation of smaller amino acids and volatile sulfur-containing compounds. Singlet oxygen forms methionine sulfoxide and methionine sulfone. The distribution of phototransformation products offers an improved understanding of the fate of nitrogen- and sulfur-containing compounds and their uptake by microorganisms in natural aquatic environments.

Spatiotemporal patterns of multiple pesticide residues in central Argentina streams

Pollution of surface waters is a global threat, with particular concern about pesticides due to their severe negative effects on ecosystem functioning and human health. The aims of this study were to identify the spatiotemporal patterns of water and sediment quality, and the key variables related to the variation in pesticide pollution (122 compounds), in headwater streams (surrounding land uses: crop or mixed crop-livestock systems) and floodplain streams (surrounding land uses: urban development or natural wetland) of the Paraná River basin in the central area of Argentina. We found significant differences in water and sediment quality related to local land uses among headwater streams, but not among floodplain streams. These differences were more noticeable during spring than during autumn. Pesticides were widespread in all the streams, independently of the surrounding land use, reflecting the combination of local inputs and the role of floodplain hydrological connectivity in transporting pollutants from upstream sources. The most frequently detected compound was atrazine (75 %), whereas the highest concentration of an individual compound was observed for the glyphosate metabolite aminomethylphosphonic acid (AMPA, up to 4 μg L−1). The significant explanatory variables for pesticide pollution were turbidity, chromophoric dissolved organic matter (CDOM), sub-basin area, side slope of streams (positive relations), wetland cover, and precipitations (negative relations). Our results can be useful for the design of monitoring programs that capture the spatial and temporal variability of pesticide pollution.

Spatial-Temporal Regularities of Hydrooptical Characteristics of the Ob River

Field studies conducted in spring (March 26 — April 9, 2022) and summer (June 5-16, 2022) in the Ob River mouth region at the three hydromorphological stations „Kazym-Mys“, „Azovy“, and „Salemal“ (YaNAO) to obtain new data on the hydrooptical characteristics of water in the Lower Ob river. Also, the trophic status and ecological state of the Lower Ob river region were assessed. The greatly varying light attenuation coefficient ε(λ) was calculated at the four characteristic wavelengths of 430, 450, 550, and 670 nm, respectively. It ranges from 9.3 m-1 to 22.1 m-1 during the winter low water (freeze-up) period and from 7.3 m-1 to 33.0 m-1 during the open water (high water) period. The calculated relative spectral contributions of major optically active components of water (pure water, suspension, yellow substance, chlorophyll) to ε(λ) suggest that suspension and yellow substance make up the maximal contribution at different horizons. Additionally, the calculated coefficient of light absorption by yellow substance кys(λ) varies within the ranges from 5.5 m-1 to 9.9 m-1 (spring) and from 3.1 m-1 to 17.0 m-1 (summer), respectively. The relative transparency was measured using the Secchi disc. The concentrations of yellow substance and major photosynthetic pigments — chlorophylls a, b, c, and carotenoids — were estimated alongside. The obtained results could be useful for environmental monitoring and predicting the dynamics of aquatic ecosystems in the region under climate change and increased anthropogenic pressure caused by the use of natural resources.

Regional Models for Sentinel-2/MSI Imagery of Chlorophyll a and TSS, Obtained for Oligotrophic Issyk-Kul Lake Using High-Resolution LIF LiDAR Data

The development of regional satellite bio-optical models for natural waters with high temporal and spatial variability, such as inland seas, reservoirs, and coastal ocean waters, requires the implementation of an intermediate measuring link in the chain, “water sampling—bio-optical models”, and this link must have certain intermediate characteristics. The most crucial of them are the high-precision measurements of the main water quality parameters, such as the concentration of chlorophyll a (Chl a), colored dissolved organic matter (CDOM), and total suspended sediments (TSS) in the upper water layer, together with a high operational rate and the ability to cover a large water area in a short time, which corresponds to a satellite overpass. A possible solution is to utilize laser-induced fluorescence (LIF) of water constituents measured by a marine LiDAR in situ with a high sampling rate from a high-speed vessel. This allows obtaining a large ground-truth dataset of the main water quality parameters simultaneously with the satellite overpass within the time interval determined by NASA protocols. This method was successfully applied to the oligotrophic Issyk-Kul Lake in Kyrgyzstan, where we obtained more than 4000 and 1000 matchups for the Chl a and TSS, respectively. New preliminary regional bio-optical models were developed on the basis of a one-day survey and tested for archive Sentinel-2A data for 2022. This approach can be applied for regular monitoring and further correction in accordance with seasonal variability. The obtained results, together with previously published similar studies for eutrophic coastal and productive inland waters, emphasize the applicability of the presented method for the development or adjustment of regional bio-optical models for water bodies of a wide trophic range.

Spectral Characteristics and Source Analysis of Chromophoric Dissolved Organic Matter in Surface Water of Taihu Lake Before Cyanobacterial Blooming

Chromophoric dissolved organic matter (CDOM) is an important part of the nutrient biogeochemical cycle in aquatic ecosystems. To explore the characteristics and sources of CDOM components in the surface water of Taihu Lake, UV-visible spectroscopy and excitation emission matrix fluorescence spectroscopy-parallel factor analysis were used to analyze CDOM components in surface water. Combined with CDOM optical parameters (a355, SUVA254, a250/a365, FI, BIX, and HIX), the spatial differences and pollution sources were identified, and a preliminary comparison was made between this study and the historical data of CDOM components in Taihu Lake. According to the results, a355, SUVA254, and a250/a365 showed the characteristics of high concentration, high aromatic ability, and low relative molecular weight of CDOM in the surface water of the eastern part of Taihu Lake; however, the northern part showed the opposite characteristics. Four components were isolated from CDOM using parallel factor analysis:one tyrosine-like (C1), two types of tryptophan (C2 and C4), and one fulionic acid (C3). The main component C1 had a strong linear relationship with the C2 and C3 components, suggesting that different components originated from similar pollution sources. The fluorescence index showed that CDOM in different areas of Taihu Lake were differently affected by endogenous and terrestrial inputs; however, the overall humification degree was low. This indicated that the CDOM components in Taihu Lake were primarily protein-like (C1, C2, and C4) (>85%) and autogenous, with good biochemical availability.

Phototransformation of Lignin-related Compounds in Chromophoric Dissolved Organic Matter Solutions

Lignin is a major terrestrial source of chromophoric dissolved organic matter (CDOM), and studying the phototransformation of lignin monomers and their related compounds can enhance our understanding of CDOM intramolecular interactions. Coniferyl aldehyde (Coni) and sinapaldehyde (Sina) form ground-state complexes with CDOM, with equilibrium constants of 7,800 (± 1,800) and 20,000 (± 2,000) M−1, respectively. In comparison, vanillin (Van) exhibits minimal affinity for CDOM complexation. The bimolecular reaction rate constants between singlet oxygen (1O2) and these phenolic carbonyl compounds ranged from 0.46 (± 0.02) to 1.8 (± 0.1) × 107 M−1s−1, which is approximately one order of magnitude lower than their reaction rate constants (0.51 (± 0.02)–1.25 (± 0.02) × 108 M−1s−1) with the triplet excited state of CDOM (3CDOM*). In acidic CDOM solutions (pH 5.0), 1O2, H2O2, and organic peroxyl radicals had negligible impact on the transformation. Comparing the initial transformation rate in the presence and in the absence of NaN3 or furfuryl alcohol led to an overestimation of the contribution of 1O2 to the transformation of Van, Coni, or Sina. 3CDOM* scavengers could not fully inhibit the transformation of Coni or Sina. The remaining transformation is considered to arise from either the unquenched intra-CDOM phase 3CDOM* or a fraction of Coni⊂CDOM or Sina⊂CDOM complex, which underwent intramolecular photoinduced chemical reactions.

Light Absorption by Optically Active Components in the Arctic Region (August 2020) and the Possibility of Application to Satellite Products for Water Quality Assessment

In August 2020, during the 80th cruise of the R/V “Akademik Mstislav Keldysh”, the chlorophyll a concentration (Chl-a) and spectral coefficients of light absorption by phytoplankton pigments, non-algal particles (NAP) and colored dissolved organic matter (CDOM) were measured in the Norwegian Sea, the Barents Sea and the adjacent area of the Arctic Ocean. It was shown that the spatial distribution of the three light-absorbing components in the explored Arctic region was non-homogenous. It was revealed that CDOM contributed largely to the total non-water light absorption (atot(λ) = aph(λ) + aNAP(λ) + aCDOM(λ)) in the blue spectral range in the Arctic Ocean and the Barents Sea. The fraction of NAP in the total non-water absorption was low (less than 20%). The depth of the euphotic zone depended on atot(λ) in the surface water layer, which was described by a power equation. The Arctic Ocean, the Norwegian Sea and the Barents Sea did not differ in the Chl-a-specific light absorption coefficients of phytoplankton. In the blue maximum of phytoplankton absorption spectra, Chl-a-specific light absorption coefficients of phytoplankton in the upper mixed layer (UML) were higher than those below the UML. Relationships between phytoplankton absorption coefficients and Chl-a were derived by least squares fitting to power functions for the whole visible domain with a 1 nm interval. The OCI, OC3 and GIOP algorithms were validated using a database of co-located results (day-to-day) of in situ measurements (n = 63) and the ocean color scanner data: the Moderate Resolution Imaging Spectroradiometer (MODIS) onboard the Terra (EOS AM) and Aqua (EOS PM) satellites, the Visible and Infrared Imager/Radiometer Suite (VIIRS) onboard the Suomi National Polar-orbiting Partnership (S-NPP) and JPSS-1 satellites (also known as NOAA-20), and the Ocean and the Land Color Imager (OLCI) onboard the Sentinel-3A and Sentinel-3B satellites. The comparison showed that despite the technological progress in optical scanners and the algorithms refinement, the considered standard products (chlor_a, chl_ocx, aph_443, adg_443) carried little information about inherent optical properties in Arctic waters. Based on the statistic metrics (Bias, MdAD, MAE and RMSE), it was concluded that refinement of the algorithm for retrieval of water bio-optical properties based on remote sensing data was required for the Arctic region.

Rethinking terrestrial dissolved organic matter in dam reservoirs before mixing: Linking photodegradation and biodegradation and the phenanthrene binding behavior

With the increased construction of dam reservoirs and the demand for water security, terrestrial dissolved organic matter (DOM) has received attention because of its role in regulating water quality, ecological functions, and the fate and transport of pollutants in dam reservoirs. This study investigated the transformations of soil DOM and vegetation DOM of dam reservoirs following photodegradation and biodegradation before conservative mixing, as well as the resultant effects on phenanthrene binding. Based on the results, terrestrial DOM could undergo transformation via photodegradation and biodegradation before conservative mixing in dam reservoirs. Although both processes resulted in substantial decreases in DOM concentrations, the changes in chromophoric DOM and fluorescent DOM depended on the original DOM sources. Furthermore, the photodegradation of terrestrial DOM resulted in more pronounced photobleaching than photomineralization. In addition, photodegradation of terrestrial DOM resulted in the generation of DOM-derived by-products with low molecular weight and low aromaticity, whereas the biodegradation of terrestrial DOM resulted in DOM-derived by-products with low molecular weight and high aromaticity. Subsequently, the photodegradation and biodegradation of terrestrial DOM substantially enhanced the binding affinity of phenanthrene. Soil DOM is prior to vegetation DOM when predicting the ecological risk of HOCs. These results indicate that the terrestrial DOM in dam reservoirs should be reconsidered before conservative mixing. Further studies on the coupling effects of both biogeochemical processes, as well as on the relative contributions of soil DOM and vegetation DOM after transformation to the aquatic DOM in dam reservoirs, are required. This study provides information on the environmental effects of dam construction from the perspective of biogeochemical processes.

Human Activity Coupled With Climate Change Strengthens the Role of Lakes as an Active Pipe of Dissolved Organic Matter

AbstractDissolved organic matter (DOM) composition in lakes is controlled by multiple environmental drivers, but the relative importance of various drivers remains poorly understood at the continental scale. Here, we established a model resolving possible influencing pathways of climate, land cover, societal development, and water retention time of lakes on the quantity and quality of chromophoric DOM (CDOM) from 182 lakes spanning across strong climatic and economic gradients in China. Our results indicate that land cover and societal development both exhibit positive direct effects on lake CDOM quantity, highlighting the significant role of well‐vegetated soils and anthropogenic activities as sources of lake DOM on a continental scale. Climate has two strong but opposite effects—a warming and wet climate facilitates soil OM production and export, while it also enhances CDOM in‐lake transformation. Three proxies are proposed as indicators of the magnitude of biogeochemical drivers influencing lake DOM across different ecoclimatic zones, including fluorescent DOM/DOC indicating economic activity, percentages of a degraded fluorescent DOM component indicating solar irradiation, and percent tyrosine‐like DOM reflecting DOM processing time within the watershed and lake. Collectively, our findings indicate that the effects of climate change and rapid societal development will result in increased loadings of terrestrial and anthropogenic DOM into lakes and drive higher rates of within‐lake processing of DOM. Consequently, lakes will play a more important role as an “active pipe” in mediating the flux and transformation of organic carbon, intensifying the coupling between terrestrial and aquatic carbon cycles on a continental scale.

하계 남극 킹조지섬 마리안소만에서의 유색용존유기물(CDOM) 분포

하계 남극 킹조지섬 마리안소만에서의 유색용존유기물(CDOM) 분포

Regulated vs. unregulated rivers: Impacts on CDOM dynamics in the eastern James Bay

The eastern James Bay (EJB) coast harbors numerous rivers, but there is a dearth of knowledge concerning dissolved organic matter (DOM) in the downstream coastal water. Here we report a four-year (2018–2021) and multi-seasons field study on the mixing behavior and characteristics of the chromophoric DOM (CDOM) in the nearshore EJB. Freshwater discharged from the extensively regulated La Grande River (LGR) was constantly depleted in DOM compared with the unregulated rivers (URRs), being on average 3.35 times lower in CDOM absorption coefficient at 440 nm (aCDOM(440)) and 2.50 times lower in dissolved organic carbon (DOC). In contrast, the absorption spectral slope between 275 and 295 nm (S275–295, a proxy of molecular weight) and the specific absorption coefficient at 254 nm (a*CDOM(254), an indicator of aromaticity) of the LGR CDOM were only 10.6% lower and 11.7% higher than those of the URRs CDOM, respectively. Riverine input was found to be the dominant source of CDOM in the study area, with little influence from sea ice formation or melting. CDOM distribution fell into two distinct regimes: the LGR-influenced low-CDOM area in the north and the URRs-influenced high-CDOM area in the south. The two areas showed strong conservative but separate aCDOM(440)–salinity relationships converging at a common marine endmember (salinity ∼25) with little seasonality. The composite data combing both areas and all seasons and years exhibited non-linear relationships between S275–295, a*CDOM(254) and aCDOM(440) and a robust simple linear correlation of DOC to aCDOM(440). This study suggests a strong impact of river regulation on CDOM input into the EJB, reveals low seasonal variability of CDOM mixing dynamics and characteristics, and demonstrates the feasibility of using remote sensing from space for real-time and synoptical assessment of DOM dynamics and the associated biogeochemical cycles in the EJB.

Phytoplanktonic community and bio-optical properties in coastal waters of an Argentinian Patagonian gulf

The influence of the phytoplankton community in the light absorption budget was quantified in coastal waters of the North region of the San Jorge Gulf (Argentinian Patagonia). The phytoplanktonic composition and their absorption spectra were determined. Nanoflagellates and diatoms were the dominant groups. The toxigenic dinoflagellate Dinophysis acuminata was recorded in all the sampling sites. The optical characterization of the particulate material showed that 60 % of the absorption at 443 nm and 88 % of absorption at 675 nm was due to phytoplankton. The contributions of phytoplankton to total absorption at 443 nm wavelengths reached 50 %. The absorption by chromophoric dissolved organic matter (CDOM) and non-algal particles (NAP) was predominant in turbulent waters (>60 %). This study shows the influence of submesoscale physical-biological interactions in the light absorption budget. The field absorption spectra of active optical components are of interest in the assessment and development of regional ocean color satellite algorithms.

Distributions of humic substances in an estuarine region (Otsuchi Bay, Japan) determined using electrochemical and optical methods

Humic substances are major components of the dissolved organic carbon pool in aquatic environments that can bind to trace metals like copper and iron as organic ligands. The unique chromophoric and fluorescence properties of humic substances enabled measurements using conventional optical methods but recently a new electrochemical method using cathodic stripping voltammetry has emerged. In this study, we employed both methods to measure humic substances and elucidate their distribution patterns in Otsuchi Bay in Japan. The electroactive humic substances (eHS) detected using the electrochemical method were higher in the rivers (range 0.24 to 4.3 mg L−1) than in the coastal bay (range 0.08 to 0.69 mg L−1). Both methods revealed significantly higher humic concentrations in the surrounding rivers than in Otsuchi Bay, indicating that riverine sources are an important source of humic substances to Otsuchi Bay, consistent with previous observations in riverine systems globally. eHS correlated well with optical indices of dissolved organic matter (DOM) including humic and marine humic-like fluorescent DOM and chromophoric DOM. Furthermore, comparison with data from the literature suggests that about 20% of the weaker Cu-binding organic ligand pool in Otsuchi Bay may consist of eHS. As Cu-binding organic ligands, eHS may be important in buffering temporal or seasonal increases in Cu fluxes in estuarine regions, with possible implications for nutrient bioavailability and toxicity for primary producers.

UV-vis absorbance and chromophoric dissolved organic matter (CDOM) characterization of Sto. Tomas Cove surface water

UV-vis absorbance and chromophoric dissolved organic matter (CDOM) characterization of Sto. Tomas Cove surface water

Seasonal and spatial variability in bio-optical properties of the Persian Gulf: Implications for ocean color remote sensing

In this study, the absorption coefficients of phytoplankton community (aPh(λ)), Colored Dissolved Organic Matter (CDOM) [aCDOM(λ)], and Non-Algal Particles (NAP) [aNap(λ)] were analyzed in the northern Persian Gulf, a Mediterranean-type semi-enclosed marginal sea, through seven cruise expeditions conducted from May 2018 to February 2022. The highest and lowest aPh(443) values were observed in the shallow area (depth ≤20 m) during the wet season (November–April) (0.043 ± 0.004 m-1) and within the deep area (depth >20 m) through the dry season (July–September) (0.024 ± 0.003 m-1), respectively. The chlorophyll-specific absorption (a*Ph(λ)) values increased from the deep to shallow areas as well as the wet to dry seasons. A significant difference was further detected in a*Ph(λ) magnitude at the blue (443 nm) and red (675 nm) wavelengths, with the mean values of 0.0124/0.0223 m2 mg−1 and 0.0069/0.0135 m2 mg−1 in the wet/dry seasons, respectively. The mean values of aCDOM(443) in the shallow area during the wet season (0.10 ± 0.001 m-1) were significantly larger than those in the deep area during the dry season (0.06 ± 0.002 m-1). Similarly, aNAP(443) decreased from the shallow (0.056 ± 0.021 m-1) to deep areas (0.019 ± 0.011 m-1), and from the wet (0.035 ± 0.020 m-1) to dry (0.029 ± 0.015 m-1) seasons. The statistical analysis revealed that the differences in aCDOM(λ) and aNAP(λ) spectral distribution were not statistically significant for the duration of the wet and dry seasons, whereas significant differences were observed in the shallow and deep samples. During both wet and dry seasons, the magnitude of the blue-green absorption spectra was dominated by CDOM, but the red bands were associated with phytoplankton dominated samples. The ratio of aCDOM(λ)/a*Ph(λ) was utilized as an index for uncertainty assessment to estimate Chl-a concentrations by the National Aeronautics and Space Administration (NASA) standard Chl-a algorithms for the Moderate Resolution Imaging Spectrometer (MODIS; OC3M) and Sentinel-3 Ocean and Land Color Instrument (OLCI) (OLCI; OC4v6). The results additionally demonstrated that the satellite-derived Chl-a was overestimated due to higher aCDOM(λ) and underestimated owing to lower a*Ph(λ) at the low (<0.5 mg m−3) and high (>3 mg m−3) concentrations of Chl-a, respectively. The study findings established that the red bands should be considered for tuning or developing new Chl-a algorithms in the Persian Gulf.

Global modeling of lake-water indirect photochemistry based on the equivalent monochromatic wavelength approximation: The case of the triplet states of chromophoric dissolved organic matter.

Chromophoric dissolved organic matter (CDOM) plays key role as photosensitizer in sunlit surface-water environments, and it is deeply involved in the photodegradation of contaminants. It has recently been shown that sunlight absorption by CDOM can be conveniently approximated based on its monochromatic absorption at 560nm. Here we show that such an approximation allows for the assessment of CDOM photoreactions on a wide global scale and, particularly, in the latitude belt between 60°S and 60°N. Global lake databases are currently incomplete as far as water chemistry is concerned, but estimates of the content of organic matter are available. With such data it is possible to assess global steady-state concentrations of CDOM triplet states (3CDOM*), which are predicted to reach particularly high values at Nordic latitudes during summer, due to a combination of high sunlight irradiance and elevated content of organic matter. For the first time to our knowledge, we are able to model an indirect photochemistry process in inland waters around the globe. Implications are discussed for the phototransformation of a contaminant that is mainly degraded by reaction with 3CDOM* (clofibric acid, lipid regulator metabolite), and for the formation of known products on a wide geographic scale.

Quantification of Discharge‐Specific Effects on Dissolved Organic Matter Export From Major Arctic Rivers From 1982 Through 2019

AbstractLong‐term increases in Arctic river discharge have been well documented, and observations in the six largest Arctic rivers show strong positive correlations between dissolved organic carbon (DOC) concentration, river discharge, and chromophoric dissolved organic matter (CDOM) content. Here, observations of DOC and CDOM collected from 2009 to 2019 by the Arctic Great Rivers Observatory were used to estimate chromophoric DOC (CDOC) concentrations in the Kolyma, Lena, Mackenzie, Ob', Yenisey, and Yukon Rivers. All rivers except the Mackenzie showed significant positive correlations between annual watershed runoff and the proportion of the DOC that is chromophoric. Historical estimates of DOC and CDOC export were calculated for 1982–2019 by extrapolating the DOC and CDOC concentration—discharge relationships from 2009 to 2019 as a hindcast modeled estimate. For the six rivers combined, modeled DOC and CDOC exports increased, but CDOC increased faster than total DOC. The Lena and Ob' Rivers showed significant increases in DOC export individually, with annual trends of 39.1 and 20.4 Gg C yr−1 respectively. November–April (winter) DOC and CDOC exports increased in all rivers but the Yenisey, with the hindcast winter Kolyma export increasing by more than 20% per decade. There were no significant trends in discharge or associated DOC and CDOC fluxes during the observational period from 2009 to 2019; only when hindcasted values driven by changes in river discharge were analyzed did trends in DOC and CDOC emerge. This demonstrates how shifting seasonal distributions and increases in discharge can drive changes in DOC and CDOC concentrations and exports independent of other environmental factors.