The application of potentiostatic techniques to large scale laboratory and pilot plant studies in such fields as fuel-cell investigation and metal production by fused salt electrolysis, has led to the development of high power potentiostats, which can supply currents as high as fifty amperes. Two instruments intended for these purposes are described.The first is a carrier-frequency potentiostat, with a twelve-tube (parallel connected) class B output stage, which can supply 10 V, 50 A. Overload protection is secured by a relay circuit.The other instrument illustrates the recent possibilities afforded by the combination of semi-conductors and electron tubes. To have a high input impedance and a low drift, the first stage is fitted with high gain pentodes, in a symmetrical configuration. Dc stability can be further improved by a Goldberg type drift-correcting chopper amplifier (Zerostat), which compares the potential difference between the reference and working electrode with a controlling voltage, and supplies to the main amplifier a corrective signal. The second stage, a cathode follower, drives the transistor output stage. As transistors are easily damaged by overloads, a current-limited dc supply is included. Polarity of output voltage (±20 V) and current (±10 A) can reverse without switching.
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