Chondritic Porous Interplanetary Dust Particles Research Articles

The grain size distribution of matrix in primitive chondrites

AbstractThe matrix of primitive chondrites is composed of submicron crystals embedded in amorphous silicates. These grains are thought to be the remains of relatively unprocessed dust from the inner regions of the protoplanetary disk. The matrix of primitive meteorites is often compared to chondritic porous interplanetary dust particles (CP‐IDPs) which are believed to be of cometary origin, having accreted in the outermost regions of the solar nebula. Crystalline grains in CP‐IDPs show evidence of a size–density relationship between the silicates and sulfides suggesting that these components experienced sorting prior to accretion. Here, we investigate whether such evidence of sorting is also present in the matrix constituents of primitive chondrites. We report findings from our study of grain size distributions of discrete silicate and opaque (sulfide and metal) grains within the matrix of the primitive meteorites Acfer 094 (C2‐ung.), ALHA77307 (CO3), MIL 07687 (C3‐ung.), and QUE 99177 (CR2). Mean radii of matrix silicate grains range from 103 nm in QUE 99177 to 2018 nm in MIL 07687. The opaque grains show a wider variation, with average radii ranging from 15 nm in QUE 99177 to 219 nm in MIL07687. Our results indicate that, in contrast to CP‐IDPs, the size distribution of matrix components of these primitive meteorites cannot be explained by aerodynamic sorting that took place prior to accretion. We conclude that any evidence of sorting is likely to have been lost due to a greater variety and degree of processing experienced on these primitive chondrites than on cometary parent bodies.

Diverse oxygen isotopic compositions among cometary vapor-phase condensates

Filamentary enstatite crystals, formed by gas–solid condensation in the solar nebula, are found in chondritic porous interplanetary dust particles of probable cometary origin. We measured the oxygen isotopic composition of four filamentary enstatite grains, two whiskers (1.8 μm and 2.3 μm in length) and two ribbons (3.4 μm and 6.1 μm in length), from the giant cluster interplanetary dust particle U2-20 GCP using NanoSIMS ion imaging. These grains represent both the 16O-rich solar (δ17,18O ≈-70‰) and 16O-poor planetary (δ17,18O ≈0‰) isotope reservoirs. Our measurements provide evidence for very early vaporization of dust-poor and dust-rich regions of the solar nebula, followed by condensation and outward transport of crystalline dust to the comet-forming region very far from the Sun. Similar processes are likely responsible for the crystalline silicates observed in the outer regions of protoplanetary disks elsewhere in the Galaxy.

Condensation of cometary silicate dust using an induction thermal plasma system

Glass with embedded metal and sulfides (GEMS), the major components of chondritic-porous interplanetary dust particles (CP-IDPs), is one of the most primitive materials in the Solar System and may be analogous to the amorphous silicate dust observed in various astronomical environments. Mineralogical characteristics of GEMS should reflect their formation process and condition. In this study, synthetic experiments in the sulfur-bearing system of Fe–Mg–Si–O–S were performed with a systematic change in redox conditions using thermal plasma systems to reproduce the mineralogy and textures of GEMS. The resulting condensates were composed of amorphous silicates with Fe-bearing nano-inclusions. The Fe content and texture in the amorphous silicates as well as the mineral phases of the nanoparticles correlate with redox conditions. Fe dissolved in the amorphous silicate as FeO in oxidizing conditions formed Fe-metal nanoparticles in intermediate redox conditions, and gupeiite (Fe3 Si) nanoparticles in reducing conditions. In intermediate to reducing redox conditions, Fe-poor amorphous silicate formed a biphasic texture with Mg- and Si-rich regions, indicating liquid immiscibility during the melt phase. Most Fe-metal particles were surrounded by FeS and formed on the surface of amorphous silicate grains. Condensates produced in intermediate to slightly reducing redox conditions resemble GEMS in that they have similar mineral assemblages and chemical compositions to amorphous silicate, except that the Fe-metal grains are absent from the interior of the amorphous silicate grains. This textural difference can be explained by the sulfidation at high temperatures in this study, in contrast to sulfidation occurring at low temperatures in the presence of H2 in natural GEMS formation. Based on the two-liquid structures observed in the experimental products and in GEMS, also recognized in infrared spectra, we propose that GEMS condensed as silicate melt under limited redox conditions followed by incorporation of multiple metal grains into the silicate melt or by aggregation of coreshell structured grains before sulfidation of the metallic iron. Condensates produced in oxidizing conditions are similar to GEMS-like material in the matrices of primitive carbonaceous chondrite meteorites, indicating the possibility that they form by direct condensation from nebula gas in relatively oxidizing conditions compared to GEMS.

The Appearance of a “Fresh” Surface on 596 Scheila as a Consequence of the 2010 Impact Event

Abstract Dust emission was detected on main-belt asteroid 596 Scheila in 2010 December and was attributed to the collision of a few-tens-of-meters projectile on the surface of the asteroid. In such an impact, the ejected material from the collided body is expected to mainly come from its fresh, unweathered subsurface. Therefore, it is expected that the surface of 596 was partially or entirely refreshed during the 2010 impact. By combining spectra of 596 from the literature and our own observations, we show that the 2010 impact event resulted in a significant slope change in the near-infrared (0.8–2.5 μm) spectrum of the asteroid, from moderately red (T type) before the impact to red (D type) after the impact. This provides evidence that red carbonaceous asteroids become less red with time due to space weathering, in agreement with predictions derived from laboratory experiments on the primitive Tagish Lake meteorite, which is spectrally similar to 596. This discovery provides the very first telescopic confirmation of the expected weathering trend of asteroids spectrally analog to Tagish Lake and/or anhydrous chondritic porous interplanetary dust particles. Our results also suggest that the population of implanted objects from the outer solar system is much larger than previously estimated in the main belt, but many of these objects are hidden below their space-weathered surfaces.

Condensation of cometary silicate dust using an induction thermal plasma system

Glass with embedded metal and sulfides (GEMS) is a major component of chondritic porous interplanetary dust particles. Although GEMS is one of the most primitive components in the Solar System, its formation process and conditions have not been constrained. We performed condensation experiments of gases in the system of Mg–Si–O (MgSiO3 composition) and of the S-free CI chondritic composition (Si–Mg–Fe–Na–Al–Ca–Ni–O system) in induction thermal plasma equipment. Amorphous Mg-silicate particles condensed in the experiments of the Mg–Si–O system, and their grain size distribution depended on the experimental conditions (mainly partial pressure of SiO). In the CI chondritic composition experiments, irregularly shaped amorphous silicate particles of less than a few hundred nanometers embedded with multiple Fe–Ni nanoparticles of ≤20 nm were successfully synthesized. These characteristics are very similar to those of GEMS, except for the presence of FeSi instead of sulfide grains. We propose that the condensation of amorphous silicate grains smaller than a few tens of nanometers and with metallic cores, followed by coagulation, could be the precursor material that forms GEMS prior to sulfidation.

The Formation of Carbonaceous Material in the Early Solar Nebula: The Role of Metal Dusting

Abstract For many years it has been suggested that the carbonaceous material found in association with Fe/Ni metal and metal carbides in primitive bodies is linked to the Fischer–Tropsch reaction. This is especially true with chondritic-porous interplanetary dust particles, which are considered to have a cometary origin and are among some of the most primitive and least processed materials available for study. Another phenomenon which occurs under the same carburizing conditions as the Fischer–Tropsch reaction is called metal dusting and could be a possible pathway to forming some of the carbonaceous material found in primitive bodies. Metal dusting is a catastrophic corrosion of metal under these carburizing conditions that results in a porous mixture of carbonaceous material, metal, and metal carbides. In the case of pure iron, type I metal dusting results in the formation of a metastable iron carbide, typically cementite, Fe3C. While metal dusting has been studied industrially for over 50 years, it does not appear to have been applied to the formation of carbonaceous material in astrophysical settings. In this work, the general mechanism of metal dusting on iron is described and a thermodynamic analysis of the dusting phenomena applied to solar nebula conditions. Rate measurements are made with pure iron samples over the temperature range from 400°C to 950°C. In addition, the products from experimental runs at 500°C and 600°C are studied by transmission electron microscopy. Results show that iron carbide particles are formed with carbonaceous material consisting of poorly graphitized carbon.

Sampling interplanetary dust from Antarctic air

AbstractWe built a collector to filter interplanetary dust particles (IDPs) larger than 5 μm from the clean air at the Amundsen Scott South Pole station. Our sampling strategy used long duration, continuous dry filtering of near‐surface air in place of short duration, high‐speed impact collection on flags flown in the stratosphere. We filtered ~107 m3 of clean Antarctic air through 20 cm diameter, 3 µm filters coupled to a suction blower of modest power consumption (5–6 kW). Our collector ran continuously for 2 years and yielded 41 filters for analyses. Based on stratospheric concentrations, we predicted that each month’s collection would provide 300–900 IDPs for analysis. We identified 19 extraterrestrial (ET) particles on the 66 cm2 of filter examined, which represented ~0.5% of the exposed filter surfaces. The 11 ET particles larger than 5 µm yield about a fifth of the expected flux based on >5 µm stratospheric ET particle flux. Of the 19 ET particles identified, four were chondritic porous IDPs, seven were FeNiS beads, two were FeNi grains, and six were chondritic material with FeNiS components. Most were <10 µm in diameter and none were cluster particles. Additionally, a carbon‐rich candidate particle was found to have a small 15N isotopic enrichment, supporting an ET origin. Many other candidate grains, including chondritic glasses and C‐rich particles with Mg and Si and FeS grains, require further analysis to determine if they are ET. The vast majority of exposed filter surfaces remain to be examined.

Injection of meteoric phosphorus into planetary atmospheres

This study explores the delivery of phosphorus to the upper atmospheres of Earth, Mars, and Venus via the ablation of cosmic dust particles. Micron-size meteoritic particles were flash heated to temperatures as high as 2900 ​K in a Meteor Ablation Simulator (MASI), and the ablation of PO and Ca recorded simultaneously by laser induced fluorescence. Apatite grains were also ablated as a reference. The speciation of P in anhydrous chondritic porous Interplanetary Dust Particles was made by K-edge X-ray absorption near edge structure (XANES) spectroscopy, demonstrating that P mainly occurs in phosphate-like domains. A thermodynamic model of P in a silicate melt was then developed for inclusion in the Leeds Chemical Ablation Model (CABMOD). A Regular Solution model used to describe the distribution of P between molten stainless steel and a multicomponent slag is shown to provide the most accurate solution for a chondritic-composition, and reproduces satisfactorily the PO ablation profiles observed in the MASI. Meteoritic P is moderately volatile and ablates before refractory metals such as Ca; its ablation efficiency in the upper atmosphere is similar to Ni and Fe. The speciation of evaporated P depends significantly on the oxygen fugacity, and P should mainly be injected into planetary upper atmospheres as PO2, which will then likely undergo dissociation to PO (and possibly P) through hyperthermal collisions with air molecules. The global P ablation rates are estimated to be 0.017 ​t ​d−1 (tonnes per Earth day), 1.15 ​× ​10−3 ​t ​d−1 and 0.024 ​t ​d−1 for Earth, Mars and Venus, respectively.

Dust of comet 67P/Churyumov-Gerasimenko collected by Rosetta/MIDAS: classification and extension to the nanometer scale

Context. The properties of the smallest subunits of cometary dust contain information on their origin and clues to the formation of planetesimals and planets. Compared to interplanetary dust particles or particles collected during the Stardust mission, dust collected in the coma of comet 67P/Churyumov-Gerasimenko (67P) during the Rosetta mission provides a resource of minimally altered material with known origin whose structural properties can be used to further the investigation of the early solar system. Aims. The cometary dust particle morphologies found at comet 67P on the micrometer scale are classified, and their structural analysis is extended to the nanometer scale. Methods. We present a novel method for achieving the highest spatial resolution of imaging obtained with the MIDAS Atomic Force Microscope on board Rosetta. 3D topographic images with resolutions down to 8 nm were analyzed to determine the subunit sizes of particles on the nanometer scale. Results. Three morphological classes can be determined: (i) fragile agglomerate particles of sizes larger than about 10 μm comprised of micrometer-sized subunits that may themselves be aggregates and show a moderate packing density on the surface of the particles. (ii) A fragile agglomerate with a size of about a few tens of micrometers comprised of micrometer-sized subunits that are suggested to be aggregates themselves and are arranged in a structure with a fractal dimension lower than two. (iii) Small micrometer-sized particles comprised of subunits in the size range of hundreds of nanometers that show surface features that are again suggested to represent subunits. Their differential size distributions follow a log-normal distribution with means of about 100 nm and standard deviations between 20 and 35 nm. Conclusions. The properties of the dust particles found by MIDAS represent an extension of the dust results of Rosetta to the micro- and nanometer scale. All micrometer-sized particles are hierarchical dust agglomerates of smaller subunits. The arrangement, appearance, and size distribution of the smallest determined surface features are reminiscent of those found in chondritic porous interplanetary dust particles. They represent the smallest directly detected subunits of comet 67P.

Inner Source Pickup Ions from Chondritic Smooth Interplanetary Dust Particles

Abstract Inner source pickup ions (PUIs) are thought to be produced by the interaction between solar wind ions and interplanetary dust particles (IDPs). The amount of PUIs produced and their velocity distribution depend on the composition, density, porosity, and size of the IDPs. Quinn et al. simulated the production of PUIs from chondritic porous (CP) IDPs. The study showed that the composition of PUIs produced from CP IDPs nearly resembled the solar wind. The purpose of this study is to expand upon Quinn et al. to chondritic smooth (CS) IDPs to get a more complete description of inner source PUI production. We simulate the production and transport of C+ and O+ PUIs using the Stopping and Range of Ions in Matter and the Energetic Particle Radiation Environment Module. We consider five production mechanisms: solar wind recycling, neutralization, backscattering, sputtering, and sputtering-induced recycling. Comparisons are made to observational studies that used the Charge-Time-Of-Flight instrument on board the SOlar and Heliospheric Observatory. Results indicate that sputtering is the dominant mechanism. This results in an inner source PUI composition that resembles the dust grains, which are rich in species such as C and O and poor in species such as Ne. However, studies by Ulysses show that inner source PUIs produced inside of ∼0.5 au have a composition similar to that of the solar wind. Thus, we conclude that the IDP population close to the Sun is dominated by CP IDPs rather than CS IDPs.

Comparison of GEMS in Interplanetary Dust Particles and GEMS-like Objects in a Stardust Impact Track in Aerogel.

Comet 81P/Wild 2 dust, the first comet sample of known provenance, was widely expected to resemble anhydrous chondritic porous (CP) interplanetary dust particles (IDPs). GEMS, distinctly characteristic of CP IDPs, have yet to be unambiguously identified in the Stardust mission samples despite claims of likely candidates. One such candidate is Stardust impact track 57 "Febo" in aerogel, which contains fine-grained objects texturally and compositionally similar to GEMS. Their position adjacent the terminal particle suggests that they may be indigenous, fine-grained, cometary material, like that in CP IDPs, shielded by the terminal particle from damage during deceleration from hypervelocity. Darkfield imaging and multi-detector energy-dispersive x-ray mapping were used to compare GEMS-like-objects in the Febo terminal particle with GEMS in an anhydrous, chondritic IDP. GEMS in the IDP are within 3× CI (solar) abundances for major and minor elements. In the Febo GEMS-like objects, Mg and Ca are systematically and strongly depleted relative to CI; S and Fe are somewhat enriched; and Au, a known aerogel contaminant is present, consistent with ablation, melting, abrasion and mixing of the SiOx aerogel with crystalline Fe-sulfide and minor enstatite, high-Ni sulfide and augite identified by elemental mapping in the terminal particle. Thus, GEMS-like objects in "caches" of fine-grained debris abutting terminal particles are most likely deceleration debris packed in place during particle transit through the aerogel.

Evolution of Morphological and Physical Properties of Laboratory Interstellar Organic Residues with Ultraviolet Irradiation

Abstract Refractory organic compounds formed in molecular clouds are among the building blocks of the solar system objects and could be the precursors of organic matter found in primitive meteorites and cometary materials. However, little is known about the evolutionary pathways of molecular cloud organics from dense molecular clouds to planetary systems. In this study, we focus on the evolution of the morphological and viscoelastic properties of molecular cloud refractory organic matter. We found that the organic residue, experimentally synthesized at ∼10 K from UV-irradiated H2O-CH3OH-NH3 ice, changed significantly in terms of its nanometer- to micrometer-scale morphology and viscoelastic properties after UV irradiation at room temperature. The dose of this irradiation was equivalent to that experienced after short residence in diffuse clouds (≤104 years) or irradiation in outer protoplanetary disks. The irradiated organic residues became highly porous and more rigid and formed amorphous nanospherules. These nanospherules are morphologically similar to organic nanoglobules observed in the least-altered chondrites, chondritic porous interplanetary dust particles, and cometary samples, suggesting that irradiation of refractory organics could be a possible formation pathway for such nanoglobules. The storage modulus (elasticity) of photo-irradiated organic residues is ∼100 MPa irrespective of vibrational frequency, a value that is lower than the storage moduli of minerals and ice. Dust grains coated with such irradiated organics would therefore stick together efficiently, but growth to larger grains might be suppressed due to an increase in aggregate brittleness caused by the strong connections between grains.

Dust particle flux and size distribution in the coma of 67P/Churyumov-Gerasimenko measured in situ by the COSIMA instrument on board Rosetta

Context. The COmetary Secondary Ion Mass Analyzer (COSIMA) on board Rosetta is dedicated to the collection and compositional analysis of the dust particles in the coma of 67P/Churyumov-Gerasimenko (67P). Aims. Investigation of the physical properties of the dust particles collected along the comet trajectory around the Sun starting at a heliocentric distance of 3.5 AU. Methods. The flux, size distribution, and morphology of the dust particles collected in the vicinity of the nucleus of comet 67P were measured with a daily to weekly time resolution. Results. The particles collected by COSIMA can be classified according to their morphology into two main types: compact particles and porous aggregates. In low-resolution images, the porous material appears similar to the chondritic-porous interplanetary dust particles collected in Earth’s stratosphere in terms of texture. We show that this porous material represents 75% in volume and 50% in number of the large dust particles collected by COSIMA. Compact particles have typical sizes from a few tens of microns to a few hundreds of microns, while porous aggregates can be as large as a millimeter. The particles are not collected as a continuous flow but appear in bursts. This could be due to limited time resolution and/or fragmentation either in the collection funnel or few meters away from the spacecraft. The average collection rate of dust particles as a function of nucleo-centric distance shows that, at high phase angle, the dust flux follows a 1/ d 2 comet law, excluding fragmentation of the dust particles along their journey to the spacecraft. At low phase angle, the dust flux is much more dispersed compared to the 1/ d 2 comet law but cannot be explained by fragmentation of the particles along their trajectory since their velocity, indirectly deduced from the COSIMA data, does not support such a phenomenon. The cumulative size distribution of particles larger than 150 μ m follows a power law close to r − 0.8 ± 0.1 , confirming measurements made by another Rosetta dust instrument Grain Impact Analyser and Dust Accumulator (GIADA). The cumulative size distribution of particles between 30 μ m and 150 μ m has a power index of −1.9 ± 0.3. The excess of dust in the 10–100 μ m range in comparison to the 100 μ m–1 mm range together with no evidence for fragmentation in the inner coma, implies that these particles could have been released or fragmented at the nucleus right after lift-off of larger particles. Below 30 μ m, particles exhibit a flat size distribution. We interprete this knee in the size distribution at small sizes as the consequence of strong binding forces between the sub-constitutents. For aggregates smaller than 30 μ m, forces stronger than Van-der-Waals forces would be needed to break them apart.

Variations in cometary dust composition fromGiottotoRosetta, clues to their formation mechanisms

This paper reviews the current knowledge on the composition of cometary dust (ice, minerals and organics) in order to constrain their origin and formation mechanisms. Comets have been investigated by astronomical observations, space missions (Giotto to Rosetta), and by the analysis of cometary dust particles collected on Earth, chondritic porous interplanetary dust particles (CP-IDPs) and ultracarbonaceous Antarctic micrometeorites (UCAMMs). Most ices detected in the dense phases of the interstellar medium (ISM) have been identified in cometary volatiles. However, differences also suggest that cometary ices cannot be completely inherited from the ISM. Cometary minerals are dominated by crystalline Mg-rich silicates, Fe sulphides and glassy phases including GEMS (glass with embedded metals and sulphides). The crystalline nature and refractory composition of a significant fraction of the minerals in comets imply a high temperature formation/processing close to the proto-Sun, resetting a possible presolar signature of these phases. These minerals were further transported up to the external regions of the disc and incorporated in comet nuclei. Cometary matter contains a low abundance of isotopically anomalous minerals directly inherited from the presolar cloud. At least two different kinds of organic matter are found in dust of cometary origin, with low or high nitrogen content. N-poor organic matter is also observed in primitive interplanetary materials (like carbonaceous chondrites) and its origin is debated. The N-rich organic matter is only observed in CP-IDPs and UCAMMs and can be formed by Galactic cosmic ray irradiation of N2- and CH4-rich icy surface at large heliocentric distance beyond a ‘nitrogen snow line’.

Aggregate dust particles at comet 67P/Churyumov-Gerasimenko.

Comets are thought to preserve almost pristine dust particles, thus providing a unique sample of the properties of the early solar nebula. The microscopic properties of this dust played a key part in particle aggregation during the formation of the Solar System. Cometary dust was previously considered to comprise irregular, fluffy agglomerates on the basis of interpretations of remote observations in the visible and infrared and the study of chondritic porous interplanetary dust particles that were thought, but not proved, to originate in comets. Although the dust returned by an earlier mission has provided detailed mineralogy of particles from comet 81P/Wild, the fine-grained aggregate component was strongly modified during collection. Here we report in situ measurements of dust particles at comet 67P/Churyumov-Gerasimenko. The particles are aggregates of smaller, elongated grains, with structures at distinct sizes indicating hierarchical aggregation. Topographic images of selected dust particles with sizes of one micrometre to a few tens of micrometres show a variety of morphologies, including compact single grains and large porous aggregate particles, similar to chondritic porous interplanetary dust particles. The measured grain elongations are similar to the value inferred for interstellar dust and support the idea that such grains could represent a fraction of the building blocks of comets. In the subsequent growth phase, hierarchical agglomeration could be a dominant process and would produce aggregates that stick more easily at higher masses and velocities than homogeneous dust particles. The presence of hierarchical dust aggregates in the near-surface of the nucleus of comet 67P also provides a mechanism for lowering the tensile strength of the dust layer and aiding dust release.

Planetary science: Cometary dust under the microscope.

The Rosetta spacecraft made history by successfully orbiting a comet. Data from the craft now reveal the structure of the comet's dust particles, shedding light on the processes that form planetary systems. See Letter p.73 Mark Bentley et al. report in situ measurements of dust particles at comet 67P/Churyumov–Gerasimenko, obtained using the MIDAS instrument on the Rosetta spacecraft, the first atomic force microscope to be launched into space. The particles are revealed to be aggregates of smaller, elongated grains, with structures at distinct sizes indicating hierarchical aggregation. The dust particles show a variety of morphologies, from compact single grains to large porous aggregate particles, similar to chondritic porous interplanetary dust particles, supporting the suggestion that the latter are of cometary origin.

In situ 3‐D mapping of pore structures and hollow grains of interplanetary dust particles with phase contrast X‐ray nanotomography

AbstractUnlocking the 3‐D structure and properties of intact chondritic porous interplanetary dust particles (IDPs) in nanoscale detail is challenging, which is also complicated by atmospheric entry heating, but is important for advancing our understanding of the formation and origins of IDPs and planetary bodies as well as dust and ice agglomeration in the outer protoplanetary disk. Here, we show that indigenous pores, pristine grains, and thermal alteration products throughout intact particles can be noninvasively visualized and distinguished morphologically and microstructurally in 3‐D detail down to ~10 nm by exploiting phase contrast X‐ray nanotomography. We have uncovered the surprisingly intricate, submicron, and nanoscale pore structures of a ~10‐μm‐long porous IDP, consisting of two types of voids that are interconnected in 3‐D space. One is morphologically primitive and mostly submicron‐sized intergranular voids that are ubiquitous; the other is morphologically advanced and well‐defined intragranular nanoholes that run through the approximate centers of ~0.3 μm or lower submicron hollow grains. The distinct hollow grains exhibit complex 3‐D morphologies but in 2‐D projections resemble typical organic hollow globules observed by transmission electron microscopy. The particle, with its outer region characterized by rough vesicular structures due to thermal alteration, has turned out to be an inherently fragile and intricately submicron‐ and nanoporous aggregate of the sub‐μm grains or grain clumps that are delicately bound together frequently with little grain‐to‐grain contact in 3‐D space.

Compositional characterisation of the Themis family

Context. It has recently been proposed that the surface composition of icy main-belt asteroids (B-,C-,Cb-,Cg-,P-,and D-types) may be consistent with that of chondritic porous interplanetary dust particles (CPIDPs). Aims. In the light of this new association, we re-examine the surface composition of a sample of asteroids belonging to the Themis family in order to place new constraints on the formation and evolution of its parent body. Methods. We acquired NIR spectral data for 15 members of the Themis family and complemented this dataset with existing spectra in the visible and mid-infrared ranges to perform a thorough analysis of the composition of the family. Assuming end-member minerals and particle sizes (<2\mum) similar to those found in CPIDPs, we used a radiative transfer code adapted for light scattering by small particles to model the spectral properties of these asteroids. Results. Our best-matching models indicate that most objects in our sample possess a surface composition that is consistent with the composition of CP IDPs.We find ultra-fine grained Fe-bearing olivine glasses to be among the dominant constituents. We further detect the presence of minor fractions of Mg-rich crystalline silicates. The few unsuccessfully matched asteroids may indicate the presence of interlopers in the family or objects sampling a distinct compositional layer of the parent body. Conclusions. The composition inferred for the Themis family members suggests that the parent body accreted from a mixture of ice and anhydrous silicates (mainly amorphous) and subsequently underwent limited heating. By comparison with existing thermal models that assume a 400km diameter progenitor, the accretion process of the Themis parent body must have occurred relatively late (>4Myr after CAIs) so that only moderate internal heating occurred in its interior, preventing aqueous alteration of the outer shell.

GEMS-like material in the matrix of the Paris meteorite and the early stages of alteration of CM chondrites

The Paris meteorite is a weakly altered CM chondrite that has been discovered recently (Hewins et al., 2014). Its matrix offers the opportunity to search for well-preserved pristine pre-accretional material, as well as to study the earliest stages of aqueous alteration in the CM parent body. The study of the matrix of Paris has been conducted by analytical transmission electron microscopy on focused ion beam sections extracted from matrix areas showing different degrees of aqueous alteration.The least altered matrix sample consists of amorphous silicate grains, a few hundreds of nm in size, separated from one another by an abundant porosity. The amorphous silicates enclose numerous Fe-sulfide nanograins and their average composition is close to the chondritic composition. They share many similarities with GEMS (glass with embedded metal and sulfides) grains present in chondritic-porous interplanetary dust particles and with primitive type 3.0 carbonaceous chondrites. This first discovery of GEMS-like texture in a CM chondrite suggests that GEMS grains could have been the building blocks of the CM matrices.In more aqueously altered samples, pronounced microstructural heterogeneities were detected at the micrometer scale. The matrix consists mostly of a mixture of amorphous material and Fe-rich, spongy to fine-fibrous, poorly crystalline phyllosilicates. The porosity fraction is significantly reduced and the mixed amorphous-fibrous material frequently forms a continuous groundmass. The close association between these two material types suggests a replacement mechanism due to aqueous alteration. Chemical compositions correlate strongly with the microstructure. The amorphous material has a composition close to the chondritic value while the fine-fibrous phyllosilicate material is Fe-enriched. This Fe enrichment is found to be continuous from weakly to more heavily altered areas, in which the fibrous morphology is coarser and better crystalline. Cronstedtite with intercalated tochilinite is also found, but in pore spaces. This chemical evolution, concomitant with the maturation of the phyllosilicates, demonstrates that the early aqueous fluids that interacted with silicates in the matrix were enriched in Fe. This composition is probably the consequence of the preferential dissolution of metal and iron sulfides during the first stages of alteration. The enrichment of phyllosilicates in Mg seen in more altered CM chondrites is not observed in Paris.

The asteroid-comet continuum from laboratory and space analyses of comet samples and micrometeorites

AbstractComets are probably the best archives of the nascent solar system, 4.5 Gyr ago, and their compositions reveal crucial clues on the structure and dynamics of the early protoplanetary disk. Anhydrous minerals (olivine and pyroxene) have been identified in cometary dust for a few decades. Surprisingly, samples from comet Wild2 returned by the Stardust mission in 2006 also contain high temperature mineral assemblages like chondrules and refractory inclusions, which are typical components of primitive meteorites (carbonaceous chondrites - CCs). A few Stardust samples have also preserved some organic matter of comet Wild 2 that share some similarities with CCs. Interplanetary dust falling on Earth originate from comets and asteroids in proportions to be further constrained. These cosmic dust particles mostly show similarities with CCs, which in turn only represent a few percent of meteorites recovered on Earth. At least two (rare) families of cosmic dust particles have shown strong evidences for a cometary origin: the chondritic porous interplanetary dust particles (CP-IDPs) collected in the terrestrial stratosphere by NASA, and the ultracarbonaceous Antarctic Micrometeorites (UCAMMs) collected from polar snow and ice by French and Japanese teams. Analyses of dust particles from the Jupiter family comet 67P/Churyumov-Gerasimenko by the dust analyzers on Rosetta orbiter (COSIMA, GIADA, MIDAS) suggest a relationship to interplanetary dust/micrometeorites. A growing number of evidences highlights the existence of a continuum between asteroids and comets, already in the early history of the solar system.