Chloride Mass Balance Research Articles

Deciphering Groundwater-Surface water Interactions using Environmental Tracers in a Tropical Lake, Southwest India

This study focuses on identifying GW-SW interaction locations in a tropical lake - Vellayani Lake (VL), Southwest India, utilizing stable water isotopes (s18O, sD) and chloride mass balance approach. The northern lake region was identified as a critical groundwater discharge “hotspot” with pronounced discharge (2.14×106 - 3.82×106 m³/yr), prompting targeted management interventions. This reaffirms the critical role of groundwater inflow in sustaining the lake’s water balance. Additionally, the application of machine learning (ML) techniques refined the classification of Lacustrine Groundwater Discharge (LGD) and non-LGD sites while predictive modeling utilizing Sensitivity Indices enhanced the understanding of prominent factors influencing lake volume. K-means clustering and Random Forest (RF) classification, achieved high accuracy (90%) and a kappa value of 0.8 in distinguishing groundwater discharge and non-discharge sites. Predictive modeling and sensitivity analysis revealed precipitation as the most influential factor, with a ±20% change causing a 16.69% variation in lake volume. Groundwater discharge exhibited a sensitivity index of 0.5320, further emphasizing its critical role in maintaining lake hydrological balance. This integrated approach provided valuable insights into the critical role of nearshore groundwater recharge in maintaining lake hydrological balance and facilitates the identification of suitable areas for groundwater recharge structures. For practitioners and policymakers, this integrated approach offers a robust framework for identifying critical GW-SW interaction zones, prioritizing groundwater recharge areas, and designing sustainable water management strategies, especially in data-scarce regions, paving the way for improved resource management in similar tropical lake environments.

Hydrological Study of Mount Guna, a Shield Volcano on the Ethiopian Plateau

Abstract This dissertation investigated the hydrology and land cover change of Mount Guna using field data, remote sensing data and modelling. The hydrology of Mt Guna was studied by establishing meteorology, surface and groundwater monitoring stations on Mt Guna. The run-off generation and water balance of Mt Guna was investigated using the WetSpa hydrological model. The groundwater recharge of Mt Guna was investigated using the WetSpass model and the water table fluctuation and chloride mass balance methods. The land cover changes of Mt Guna over a span of 61 years were thoroughly analysed using Google Earth imagery and historical aerial photos using geographically weighted regression.

Estimation of Spatially Distributed Groundwater Recharge in Data-scarce Regions

Study RegionUpper Beles Basin, Ethiopia FocusData limitations significantly challenge accurate groundwater recharge estimation, especially in regions with sparse gauging stations and highly variable hydro-meteorological conditions, such as the Upper Beles Basin, Ethiopia. Using interpolated data often yields unreliable results. This study evaluates the use of remote sensing-based hydro-meteorological data to estimate spatially distributed groundwater recharge in such data-scarce regions, comparing it with point estimates derived from primary field data, using a case study of Upper Beles Basin. New Hydrological Insights for the RegionThe study employed TerraClimate and CHIRPS datasets to estimate spatially distributed recharge using the WetSpass model. Groundwater recharge was also estimated using the Water Table Fluctuation (WTF) and Chloride Mass Balance (CMB) methods, with data from 21 monitoring wells and 45 water samples. The estimated average annual recharge was 420mm (WTF), 308mm (CMB), and 365mm (WetSpass). The substantial variability in point estimates reflects the basin's recharge heterogeneity, indicating the risks of relying solely on point data. A strong correlation (72%) was found between the WTF-derived point estimates and WetSpass-generated values. Recharge variability is influenced by land use in the lowlands and by slope, soil, and rainfall in the highlands. This research demonstrates that remote sensing-based data can yield more reliable recharge estimates in regions with sparse gauging stations and highly variable hydro-meteorological conditions.

Groundwater recharge in basement aquifers in subhumid drylands of sub-Saharan Africa

Characterising groundwater recharge is fundamental for sustainable groundwater management. This study focuses on assessing recharge in drylands using four experimental plots under different land-use practices in crystalline basement aquifers in three southern African countries (Chitedze in Malawi, Kabeleka and Liempe in Zambia, and Domboshawa in Zimbabwe). Several methods, including water-table fluctuation (WTF), chloride mass balance (CMB), water stable isotopes (δ18O and δ2H) and dissolved gases, were used to quantify annual recharge rates, recharge sources and groundwater residence times. This informed the development of a conceptual model of groundwater recharge in unpumped basement aquifers. Using WTF, across all sites/years, the range of annual median recharge was found to be in the range of 2.8–14.1% rainfall. Recharge was observed for most years across all sites and was controlled by hydrogeological settings, rainfall totals and antecedent conditions, i.e. the groundwater level at the end of the preceding dry season. Based on groundwater level observations and water stable isotope analysis, for sites where there has been extensive use of conservation agriculture (in time and space), there is some evidence of earlier and greater recharge compared to conventional agriculture at paired sites. Additionally, there is evidence of high lateral connectivity in shallow, permeable layers and high local connectivity in the aquifers which facilitate discharge to surface drainage. This leads to a lower proportion of modern recharge at these unpumped sites (typically <10%) compared to other studies using comparable methods in pumped boreholes, which highlights the importance of groundwater capture due to pumping.

To Investigate the Impact of Land Use Change on the Potential Groundwater Recharge on Hillslope With Deep Loess Deposits

ABSTRACTAccurately estimating groundwater recharge in hilly areas with limited water and thick vadose zones is challenging. This study investigated the impact of land use changes on groundwater recharge at a hillslope scale of Yuanzegou Watershed in China's Loess Plateau. Three adjacent hillslopes were selected for three different land uses: arbor (jujube, Ziziphus jujuba Mill.), subshrub (native grass, Artemisia gmelinii), and crop (millet, Setaria italica). Soil cores (as deep as 10–16/18 m) were collected at each of the three landscape positions on a hillslope. Reported tritium profiles in the watershed were used to estimate the net chloride input into vadose zone on hillslope associated with inverse chloride mass balance (CMB) method/chloride accumulation method (CAM). Soil water content and chloride profiles in the study were measured to determine recharge rates at each landscape position beneath different vegetation types. For the first time, we evaluated the actual chloride input into vadose zone on hillslopes as 540.2 ± 23.8 mg m−2 yr.−1, excluding the impact of runoff. Then, estimated recharge rates ranged from 42.7 ± 3.5 to 62.4 ± 4.7 mm yr.−1, consistent with nearby studies. Results showed that groundwater recharge does not change with landscape position except for higher value on upslope beneath subshrub hillslope. In contrast, groundwater recharge did significantly reduce by 12.9% ± 5.4% and 26.5% ± 4.5% after conversion from cropland to subshrub/arbor on the hillslope, respectively. Our findings contribute to understanding the ecohydrological effects of land use changes on groundwater recharge on hillslope and help to select suitable afforested vegetation for greening efforts in water‐limited hilly areas, with a priority on groundwater safety.

Groundwater Recharge Response to Reduced Irrigation Pumping: Checkbook Irrigation and the Water Savings Payment Plan

Ongoing investments in irrigation technologies highlight the need to accurately estimate the longevity and magnitude of water savings at the watershed level to avoid the paradox of irrigation efficiency. This paradox arises when irrigation pumping exceeds crop water demand, leading to excess water that is not recovered by the watershed. Comprehensive water accounting from farm to watershed scales is challenging due to spatial variability and inadequate socio-hydrological data. We hypothesize that water savings are short term, as prior studies show rapid recharge responses to surface changes. Precise estimation of these time scales and water savings can aid water managers making decisions. In this study, we examined water savings at three 65-hectare sites in Nebraska with diverse soil textures, management practices, and groundwater depths. Surface geophysics effectively identified in-field variability in soil water content and water flux. A one-dimensional model showed an average 80% agreement with chloride mass balance estimates of deep drainage. Our findings indicate that groundwater response times are short and water savings are modest (1–3 years; 50–900 mm over 10 years) following a 120 mm/year reduction in pumping. However, sandy soils with shallow groundwater show minimal potential for water savings, suggesting limited effectiveness of irrigation efficiency programs in such regions.

The implications of climate change on freshwater resources in the arid and semiarid Mediterranean environments using hydrological modeling, GIS tools, and remote sensing.

Precipitation partitioning in arid and semiarid environments is not well understood due to scanty precipitation, its temporal distribution, and the lack/absence of adequate measurements of the hydrometeorological components. Simulation methods have the potential to bridge the data gap, thereby providing a window to estimate the water balance components. The present investigation evaluates the water balance components of a typical watershed situated in the southeastern Mediterranean for the period 1979 through 2019 using daily meteorological data and a grid spacing of 250 m. Generated runoff results were commensurate with corresponding values obtained using the SWAT model. Computed groundwater recharge is also compatible with recharge values calculated using the chloride mass balance method. Results show that average runoff and groundwater recharge for the entire period was ⁓24 mm a-1 and 19 mm a-1, giving a precipitation ratio of 9.5% and 7.5%, respectively. Substantial interannual variability in the water balance components was observed during the study period which reflected the significant precipitation fluctuations typifying the Eastern Mediterranean. Results show that the period extending from 1998/1999 through 2018/2019 witnessed an 18% drop in annual precipitation, while surface runoff and groundwater recharge experienced a reduction of ⁓34% and ⁓67%, respectively. Although groundwater recharge is a complex function of numerous meteorological and geological factors, the NDVI can provide an excellent indicator of groundwater recharge in marginal Mediterranean environments. This is highly beneficial in areas where climate records are scanty or absent. The presented results emphasize the significant impacts of global warming and aridification on the future availability of water resources in the semiarid marginal climates in the Eastern Mediterranean and point out clearly that water resources in this area will become scarcer, leading to multiple security threats at national and regional levels.

Quantifying recharge mechanisms in low-hilly areas of a loess region: Implications for the quantity and quality of groundwater

Groundwater plays a crucial role in sustaining water supply and irrigation in arid regions with thick vadose zones; however, the recharge mechanisms and their impact on water quality remain contentious. For flood-irrigated areas, irrigation water amount is not well known to evaluate the effect of irrigation on the recharge. In this study, we employed multiple tracers to investigate recharge mechanisms in a low-hilly region with some flood-irrigated areas, where irrigation water recharge was estimated by the chloride mass balance method combined with the tritium peak method. Deep soil samples from irrigated lands in vadose zone and groundwater from unconfined aquifers were collected to determine the contents of the water isotopes (2H, 18O, and 3H), chlorides (Cl-), and nitrates (NO3−). The findings revealed unique tritium peaks preserved in the loess vadose zone, where the recharge rate under the non-irrigated site was estimated to be only 8.6 mm yr−1, 2.4 % of the average annual precipitation. According to the estimated irrigated recharge rates, irrigation water dominates the potential diffuse recharge in vadose zone. For the aquifer recharge, we then quantified diffuse recharge (62.2 ± 4.7 %, piston flow) and focused recharge (37.8 ± 4.7 %, preferential flow) via the line-conditioned excess (lc-excess) balance method. Focused recharge occurred in low depressions, where surface runoff carrying sediments with high solutes converged in large rainfall events during wet season. Subsequently, focused mode rapidly recharges groundwater with NO3− and Cl- elevated, deteriorating water quality of phreatic aquifer. Finally, we concluded focused recharge does not dominate aquifer recharge, but significantly affects groundwater quality. These findings underscore the implications for the sustainability of agricultural water and soil resources management, emphasizing the potential impacts of soil conservation on groundwater quality in low-hilly regions.

New modified chloride mass balance for hydrogeological applications

New modified chloride mass balance for hydrogeological applications

Discrepancy and estimates of groundwater recharge under different land use types on the Loess Plateau

Study regionThe Dongzhi tableland on the loess plateau, China. Study focusThis study investigates how various land use types on the Loess Plateau affect groundwater recharge using the chloride mass balance method (CMB). By integrating data from Cl–, NO3/Cl–, and stable isotopes (δ18O and δ2H), the research develops a new approach to estimate the average ion concentration rates in soil profiles. This methodology provides a nuanced understanding of how precipitation infiltration recharges groundwater under different land use scenarios and the impact of land use changes on these processes. New hydrological insights for the regionThe research findings highlight significant variations in groundwater recharge rates among different land uses. Grasslands show the highest recharge rate at 26 mm/yr, followed by forests at 23 mm/yr, while shrublands have the lowest at 5 mm/yr. Agricultural lands have moderate recharge rates ranging from 14 to 16 mm/yr. Transitioning from agricultural land to other land uses like shrublands and forests results in dramatic changes in recharge rates, with decreases and increases in recharge of 72% and 61%, respectively. These insights are crucial for developing strategic land-use planning to optimize groundwater recharge and enhance water security on the Loess Plateau. The study emphasizes the need for policies that balance hydrological science and land management to sustain both human livelihoods and ecological continuity.

A high-resolution map of diffuse groundwater recharge rates for Australia

Abstract. Estimating groundwater recharge rates is important to understand and manage groundwater. Numerous studies have used collated recharge datasets to understand and project regional- or global-scale groundwater recharge rates. However, recharge estimation methods all have distinct assumptions, quantify different recharge components and operate over different temporal scales. We use over 200 000 groundwater chloride measurements to estimate groundwater recharge rates using an improved chloride mass balance (CMB) method across Australia. Groundwater recharge rates were produced stochastically using gridded chloride deposition, runoff and precipitation datasets. After filtering out groundwater recharge rates where the assumptions of the method may have been compromised, 98 568 estimates of recharge were produced. The resulting groundwater recharge rates and 17 spatial datasets were integrated into a random forest regression algorithm, generating a high-resolution (0.05°) model of groundwater recharge rates across Australia. The regression reveals that climate-related variables, including precipitation, rainfall seasonality and potential evapotranspiration, exert the most significant influence on groundwater recharge rates, with vegetation (the normalised difference vegetation index or NDVI) also contributing significantly. Importantly, the mean values of both the recharge point dataset (43.5 mm yr−1) and the spatial recharge model (22.7 mm yr−1) are notably lower than those reported in previous studies, underscoring the prolonged timescale of the CMB method, the potential disparities arising from distinct recharge estimation methodologies and limited averaging across climate zones. This study presents a robust and automated approach to estimate recharge using the CMB method, offering a unified model based on a single estimation method. The resulting datasets, the Python script for recharge rate calculation and the spatial recharge models collectively provide valuable insights for water resource management across the Australian continent, and similar approaches can be applied globally.

Uncertainties in physical and tracer methods in actual groundwater recharge estimation in the thick loess deposits of China

Groundwater recharge (GR) can be estimated with physical, tracer techniques and numerical modelling; however, the uncertainties in these methods have not been fully interpreted. This study selected six methods for actual GR estimation in the saturated zones with different data requirements and method assumptions, including two physical methods (i.e., water table fluctuation WTF and Darcy's law DL) and four tracer techniques (i.e., chloride mass balance CMB, tritium renewal rate TRR, chlorofluorocarbons CFC and 14C dating method CBD). Taking the loess tablelands of China as an example study area, we first analyzed the uncertainties in these methods and then recommended the appropriate methods for GR estimation in regions with thick vadose zones. Overall, the recharge rates from WTF, CMB and CFC (88 ± 24, 98 ± 33 and 53 ± 9 mm/year) were much greater than those from DL, TRR and CBD (10 ± 3, 14 ± 3 and 7 ± 5 mm/year). The differences in estimated GR are closely related to the method parameters, assumptions and temporal scales. Specifically, the model parameters (e.g., specific yield, hydraulic conductivity) exhibit large ranges due to spatiotemporal heterogeneity, and the physical methods are more sensitive to hydrogeological parameters compared with the tracer techniques. The uncertainties related to model assumptions originate from the simplified water/solute movement processes. The lag effect of the thick vadose zone largely limits WTF and TRR, but contributes to CMB. Ignoring the mixing and dispersion effect may overestimate recharge by 36–48 % for CFC, and the heterogeneity of the aquifer reduces the potential of CBD for recharge estimation. Overall, CMB is considered as the most optimal method for estimating GR in the thick loess deposits. This study deepens the understanding of the uncertainties in GR assessment methods in regions with thick vadose zones.

Quantifying water loss in leaky micro-dam reservoir through water balance analysis and high-resolution water level data modeling

Abstract This study aimed to assess the runoff, recharge, and response of a shallow aquifer to leakage from the Arato micro-dam reservoir (MDR). The assessment was conducted using the Soil Conservation Service Curve Number (SCS-CN), soil moisture balance (SMB), and diver (automatic data logger) measurements in both the MDR and a shallow hand-dug well. Recharge was estimated using the chloride mass balance (CMB) and water table fluctuation (WTF) methods. The results revealed that the annual runoff from the catchment was 48.8 mm, which accounted for approximately 0.71 million m3. The yearly groundwater recharge was estimated to be 104, 92.8, and 100 mm using the SMB, CMB, and WTF methods, respectively. Furthermore, the water balance model of the Arato MDR indicated a leakage rate of 13.2 mm/day. It is noteworthy that the estimated leakage exceeded the seepage initially anticipated during the project's design phase (9,965 m3/year). This research project highlights the significance of utilizing local climatic and physical data from the specific watershed under investigation when planning reservoirs and other water resources. It also underscores the importance of conducting thorough site investigations to accurately quantify hydraulic conductivity for leakage estimation purposes.

Road Salt Legacies: Quantifying Fluxes of Chloride to Groundwater and Surface Water Across the Chicago Metropolitan Statistical Area

AbstractFreshwater chloride concentrations have been increasing in North American surface waters for decades, largely driven by increases in the use of road salt, which is commonly applied as a deicer. In Chicago, thousands of tons of road salt are applied to roadways each winter, and increases in surface water chloride concentrations have been noted across the region since the mid‐1960s. While much of the applied salt runs directly off to nearby waterways during snowmelt events, some percolates to groundwater, affecting public supply wells and increasing the amount of chloride released to streams as baseflow during the non‐salting season. In the present study we have developed a spatially distributed chloride mass balance across the Chicago Metropolitan Statistical Area (CMSA) for a 30‐year period (1990–2020) to better our understanding of long‐term chloride fluxes and storage. Our results show that inputs of road salt to the region increased by 33% between 1990 and 2020. During this same period, riverine chloride loads across the region increased by 60%. Despite these increases in riverine chloride export, we find that chloride is accumulating in CMSA groundwater at a rate of ∼480 ktons year−1. We show that shallow aquifers, &lt;30 m, exhibit only seasonal chloride storage, without long‐term accumulation. In contrast, at depths below 30 m, we find chloride concentrations to be increasing over time, indicating that legacy chloride is accumulating at deeper depths in CMSA groundwater. The present results highlight the importance of legacy chloride to long‐term water quality dynamics in North American cities.

Estimation of Annual and Seasonal Groundwater Recharge by Using Wetspass‐M and Chloride Mass‐Balance Methods, Upper Bilate Catchment, Rifty Valley Basin, Ethiopia

It is difficult to estimate groundwater recharge (GWR) since it cannot be measured directly. Numerous physical and empirical models may be used to calculate the components of the groundwater (GW) balance of a given basin. This study’s goal is to compute the annual and seasonal GWR rates in the upper Bilate catchment using the chloride mass‐balance (CMB) approach and water and energy transfer between soil, plants, and atmosphere under the quasi‐steady state (WetSpass)‐modular three‐dimensional finite‐difference groundwater flow model (MODFLOW). Grid maps were prepared as the input data for the model, and to reflect the catchment condition, the parameter attribute tables were arranged. The water balance (WB)’s constituents for each season and year were simulated by the WetSpass‐M model. As well, the CMB technique was applied; the samples were obtained from wells and around rain gauges of the study area, tested in the Arba Minch University water quality laboratory, and then chloride concentrations were evaluated. The recharge was calculated using the precipitation‐weighted average chlorine content in the rainfall and GW. The mean annual GWR values calculated by using WetSpass‐M and CMB were 157.6 and 147.69 mm, respectively, representing 12.7% and 11.91% of the mean precipitation received in the catchment, respectively. WetSpass‐M, the seasonal average recharge values in winter, spring, summer, and autumn were 29.39, 58.87, 1.92, and 56.28 mm; from the total annual recharge, 2.38%, 4.9%, 0.17%, and 4.55% occurred, respectively. CMB, during the dry and wet seasons are 24.08 and 52.16 mm/year, respectively. This result showed that the recharge estimated by the WetSpass‐M model was slightly higher as compared to the CMB method, and both were in a comparable range and both models are with good performance.

WetSpass model and chloride mass balance based groundwater recharge estimation: the Case of Golina River Basin, northern Ethiopia

WetSpass model and chloride mass balance based groundwater recharge estimation: the Case of Golina River Basin, northern Ethiopia

Groundwater flow modeling and recharge estimation of heterogeneous aquifer: Applied to Matmata aquifer, southeastern, Tunisia

Groundwater is an important source of water supply for several socioeconomic sectors. In particular, heterogeneous carbonate aquifers are an important potential reservoir of groundwater resources. The Matmata carbonate aquifer, located in southern Tunisia, suffers from over abstraction and severe anthropogenic pressure. This study aims to estimate diffusive recharge rates using climate and soil datasets, and proposes a combination of CMB techniques and numerical simulation methods. Groundwater chloride mass balance and numerical simulations were best practices for achieving these goals. The Hydrus-1D model was applied, calibrated and validated with soil water content measured at different depths and using long-term, diurnal-scale field and climate data. The results highlight that Richard's retention parameters give a close correlation with the observed saturated moisture content with RMSE of 0.07. The calculated evaporation is around 22.5 mm for the entire study period, and the contribution of rainfall to infiltration, which was estimated at 9.8 mm as 8.4%. The CMB model shows a recent recharge rate 4.83 mm. yr−1, corresponding to a groundwater recharge rate of 5.84 % of precipitation. Groundwater recharge estimation is one of the most important concepts of water balance, and its assessment is crucial for groundwater management and protection.

Stable Isotopes and Water Level Monitoring Integrated to Characterize Groundwater Recharge in the Pra Basin, Ghana

In the Pra Basin of Ghana, groundwater is increasingly becoming the alternative water supply due to the continual pollution of surface water resources through illegal mining and indiscriminate waste discharges into rivers. However, our understanding of hydrogeology and the dynamics of groundwater quality remains inadequate, posing challenges for sustainable water resource management. This study aims to characterize groundwater recharge by determining its origin and mechanism of recharge prior to entering the saturated zone and to provide spatial estimates of groundwater recharge using stable isotopes and water level measurements relevant to groundwater management in the basin. Ninety (90) water samples (surface water and groundwater) were collected to determine stable isotope ratios of oxygen (δ18O) and hydrogen (δ2H) and chloride concentration. In addition, ten boreholes were installed with automatic divers to collect time series data on groundwater levels for the 2022 water year. The Chloride Mass Balance (CMB) and the Water Table Fluctuation (WTF) methods were employed to estimate the total amount and spatial distribution of groundwater recharge for the basin. Analysis of the stable isotope data shows that the surface water samples in the Pra Basin have oxygen (δ18O) and hydrogen (δ2H) isotope ratios ranging from −2.8 to 2.2‰ vrs V-SMOW for δ18O and from −9.4 to 12.8‰ vrs V-SMOW for δ2H, with a mean of −0.9‰ vrs V-SMOW and 0.5‰ vrs V-SMOW, respectively. Measures in groundwater ranges from −3.0 to −1.5‰ vrs V-SMOW for δ18O and from −10.4 to −2.4‰ vrs V-SMOW for δ2H, with a mean of −2.3 and −7.0‰ vrs V-SMOW, respectively. The water in the Pra Basin originates from meteoric source. Groundwater has a relatively depleted isotopic signature compared to surface water due to the short residence time of infiltration within the extinction depth of evaporation in the vadose zone. Estimated evaporative losses in the catchment range from 51 to 77%, with a mean of 62% for surface water and from 55 to 61% with a mean of 57% for groundwater, respectively. Analysis of the stable isotope data and water level measurements suggests a potential hydraulic connection between surface water and groundwater. This hypothesis is supported by the fact that the isotopes of groundwater have comparatively lower values than surface water. Furthermore, the observation that the groundwater level remains constant in months with lower rainfall further supports this conclusion. The estimated annual groundwater recharge in the catchment ranges from 9 to 667 mm (average 165 mm) and accounts for 0.6% to 33.5% (average 10.7%) of mean annual precipitation. The total estimated mean recharge for the study catchment is 228 M m3, higher than the estimated total surface water use for the entire Pra Basin of 144 M m3 for 2010, indicating vast groundwater potential. Overall, our study provides a novel insight into the recharge mechanism and spatial quantification of groundwater recharge, which can be used to constrain groundwater flow and hydrogeochemical evolution models, which are crucial for effective groundwater management within the framework of the Pra Basin’s Integrated Water Resources Management Plan.

Groundwater recharge estimation using chloride mass balance method on the southern slope of Merapi Volcano, Indonesia

Groundwater is a main resource for the majority of Indonesian people as a source of clean water to meet their daily needs. The increase in groundwater use is unavoidable due to increasing development in Indonesia, especially in Yogyakarta. Groundwater recharge is important in the hydrological cycle to meet groundwater needs. Therefore, this study aims to estimate groundwater recharge by the chloride mass balance (CMB) method on the southern slope of Merapi Volcano in Yogyakarta, Indonesia. This research was conducted in the rainy and dry seasons from August 2022 until January 2023. This research collects annual rainfall near the study area from the Meteorology, Climatology, and Geophysics Agency (BMKG) Yogyakarta station, monthly data collected from eighteen samples of groundwater station, and monthly data collected from fifteen samples of rainwater in the study area. The chemical content of groundwater and rainwater samples is analyzed using argentometry to obtain chloride concentration. The result of annual rainfall in the study area is 3,603.878 mm/year. The average chloride concentration in rainwater is 1.1 mg/L, while the average chloride concentration in groundwater is 8.015 mg/L. The CMB method calculation showed that the recharge in the study area ranges from 171.65 to 1,711.29 mm/year. The groundwater recharge has a positive correlation with elevation and rainfall. High groundwater recharge is also found in the northern area due to fractured lava aquifer.

A Framework to Assess Natural Chloride Background in Coastal Aquifers Affected by Seawater Intrusion in Eastern Spain

The protection of groundwater resources in coastal aquifers is an increasingly important issue worldwide. To establish threshold values and remediation objectives, it is essential to know the natural background concentrations of relevant ions in groundwater. The rationale is to define the Natural Background Level (NBL) of chemical species determined by atmospheric and lithological forces. In many coastal aquifers, this evaluation worsens since atmospheric and lithological salinity combines with many other anthropogenic sources of salinity, including exogenous salinity induced by seawater intrusion (SWI). This paper presents a combination of six well-known statistical techniques and a new methodology (i.e., SITE index) in eight GWBs affected by SWI in Eastern Spain. The chloride ion was the selected conservative chemical specie to assess the qualitative status due to the variable SWI affection. The Natural Chloride Background (NCB) obtained from these methodologies at the GWB scale was compared with regional NCB data calculated with the Atmospheric Chloride Mass Balance (CMB) method in Continental Spain. The CMB method provides atmospherically derived NCB data that are not influenced by SWI or anthropogenic activities or lithological forces. This external evaluation can be considered the atmospheric fraction of NCB, which serves as a regional criterion to validate the more detailed statistical methodologies applied at the GWB scale. As a result, a conceptualization of NCB is obtained by means of a range of values between 115 mg L−1 and 261 mg L−1 in the studied coastal GWBs affected by SWI in Eastern Spain.