Chert Beds Research Articles

A mid-Cretaceous carbon isotope reference curve for the SE Neo-Tethys region (Zagros, W Iran)

Stable carbon isotope chemostratigraphy and the associated reference curves have proved to be valuable tools for stratigraphic calibration and long-distance correlations. Nonetheless, the reference curves covering the Cretaceous have mostly been produced from localities located within the W Neo-Tethys. In order to establish a reference curve for the SE Neo-Tethys margin, an Aptian–Albian hemipelagic carbonate-rich succession deposited along the Zagros Basin (SW Iran) was examined for planktic foraminifera biostratigraphy, carbon isotope stratigraphy, and sedimentological characteristics. Eight biozones including Globigerinelloides ferreolensis, Globigerinelloides algerianus, Hedbergella trocoidea, Paraticinella bejaouaensis, Muricohedbergella planispira, Ticinella (T.) primula, Biticinella breggiensis, and Pseudothalmanninella (P.)ticinensis as well as two subzones enclosing T. praeticinensis and P. subticinensis assign the strata to the early late Aptian–late Albian age. A carbon isotope record constrained by the planktic foraminifera zonation scheme shows good concordance with existing composite reference curves from the W Neo-Tethys region. Several carbon isotope excursions (CIEs) characterizing global marine events including Oceanic Anoxic Event (OAE) 1a, OAE1b, OAE1c and associated sub-events can be identified in the studied section. Deoxygenated bottom waters associated with the formation of OAE1a and OAE1b are indicated by distinct lithological signatures including enrichment in pyrite and glauconite, nodular and stratiform chert beds, as well as enhanced organic matter contents. We integrate the here-studied interval with a previously published upper Albian−Turonian succession from the same outcrop section, forming a composite, stratigraphically well-constrained section. This results in a high-resolution carbon isotope record for the SE Neo-Tethys margin, considered to represent an expedient reference Aptian–Turonian curve for this region. Correlation of this new curve with previously published records from the Middle East has helped to address ambiguities regarding the stratigraphic positions of the early/late Aptian and Aptian/Albian boundaries identified by previous studies.

New insights into the origin and depositional setting of the Haerdaban Pb[sbnd]Zn deposit, Chinese western Tianshan: Evidence from geology, chert geochemistry, and detrital zircon U[sbnd]Pb geochronology

The Haerdaban PbZn deposit (with an ore reserve of 10.93 Mt. at 1.0–25.65 % Zn and 0.7–12.29 % Pb) is hosted in weakly metamorphosed clastic‑carbonate rocks from the Proterozoic Haerdaban Group. It represents a significant addition of the sediment-hosted PbZn deposits in the Yili block, Chinese western Tianshan. Currently, there are ongoing debates regarding its genesis, with a particular focus on the crucial metallogenic mechanism (syngenetic sedimentary exhalation or epigenetic reworking) responsible for the primary sulfide mineralization. Mineralization at Haerdaban primarily occurs as banded to stratiform ore layers or lenses conformably sandwiched in their host rocks. Vein and stockwork ores occur locally below the stratiform ore layers. A syn-sedimentary fault trending SN was identified based on abrupt lateral changes in lithofacies and thickness of the stratigraphic units. The ore mineralogy is dominated by sphalerite, galena, quartz, and dolomite, with a small amount of pyrite, barite, and organic matter. Detrital zircon LA-ICP-MS UPb dating of the Haerdaban siltstones obtained a maximum depositional age of about 604 Ma. Their geochemical composition similar to the passive continental margin signatures, with rare earth element (REE) patterns enriched in LREE and negative Eu anomalies (Eu/Eu* = 0.50–1.14). Stratiform beds of chert that host disseminated ores have relatively high contents of hydrothermal components (e.g., Ba, Zn), with apparent positive Eu anomalies (Eu/Eu* = 7.38–49.34) and negligible negative Ce anomalies (Ce/Ce* = 0.85–0.98). They are thus interpreted to be hydrothermal sedimentary rocks (exhalites) deposited in a suboxic-anoxic environment proximal to the hydrothermal vents. Integrated geological and geochemical evidence indicates that the Haerdaban PbZn deposit is a typical vent-proximal sedimentary exhalative (SEDEX) deposit formed in a Neoproterozoic Sinian (Ediacaran) passive continental margin rift basin. Post-depositional metamorphism and deformation in the Paleozoic may have caused partial remobilization of primary ores but did not significantly alter the morphology of the orebodies. Furthermore, establishing a genetic model for the Haerdaban deposit has important implications for the exploration of similar deposits preserved in the equivalent stratigraphy within the Chinese western Tianshan region.

Diagenesis, compaction strain and deformation associated with chert and carbonate concretions in organic‐rich marl and phosphorite; Upper Cretaceous to Eocene, Jordan

ABSTRACTThis paper presents an integrated petrographic–geochemical–geomechanical study of the growth mechanisms of carbonate and chert concretions observed at outcrop and core from the Upper Cretaceous to Eocene organic‐rich carbonate mudrocks, central Jordan. It provides evidence for displacive and replacive concretion growth from the analysis of primary lithological characteristics, compaction strain and deformation structures associated with concretion growth. Concretions were analysed to determine the primary lithological controls on their development and the measurement of strain in the host rock to develop a method for constraining the growth mode and their paragenesis. Concretions exhibit either a replacive or displacive growth mode largely dependent on the original host lithology. Displacive concretions exhibit irregular shapes and semi‐fibrous internal structures in contrast to regular shapes and microcrystalline textures observed for replacive concretions. Cement fraction is high in both carbonate concretion types, indicating early formation in high‐porosity sediments at shallow burial depths. The strain field around displacive concretions is vertically asymmetrical. Conversely, it is symmetrical with uniform differential compaction for the replacive concretions. Evidence for displacive growth comes from triangular areas of chert at the lateral margins of some carbonate concretions, interpreted as areas of reduced strain. Another indicator is the forced asymmetrical folding of heterolithic host rocks around displacive concretions, with displacive carbonate units separated by trace laminae of the original (chert) beds. Enveloping chert beds exhibit early‐formed radial silica fractures with increased aperture size in the areas of maximum curvature. Carbon isotopic signatures of carbonate concretions show a strong correlation between concretion centres and host rock, suggesting a relatively shallow depth (first few tens of metres) of initial growth. Carbonate concretions are interpreted to have formed at shallow depths in the presence of alkaline pore waters rich in dissolved organic carbon in the presence of Mg2+ ions, available organic matter and redox‐sensitive metals such as U and Mo. A paragenetic history for the different concretion types is presented.

Provenance of lower Paleozoic sedimentary rocks in Tasmania and Waratah Bay, southern Victoria: constraints from detrital zircon hafnium isotopes and trace-element geochemistry

Nine Paleozoic sedimentary formations from western Tasmania and two from the Lachlan Orogen—one in northeast Tasmania and one in Waratah Bay in Victoria—contain detrital zircons that fall into major U–Pb age clusters at 2.0–1.4, 1.25–0.95 and 0.62–0.49 Ga. The zircon Th/U ratios and rare earth element (REE) patterns suggest a magmatic origin for detrital zircons in all these rock sequences. The REE geochemical signatures on bivariate discrimination diagrams indicate that most of the zircons originated in continental orogenic settings. The oldest group of zircons have a southwest Laurentian signature previously recognised from Proterozoic metasedimentary rocks in Tasmania. The 1.25–0.5 Ga zircons from all the samples have very similar εHfi values. They are not statistically different from those of typical Lachlan Orogen sandstones and resemble those in Rodinia and early Gondwana orogenic belts. The εHfi values of the Cambrian zircons within the Pioneer Sandstone are similar to the Mount Read Volcanics but cannot be distinguished on εHfi values from other sources in East Gondwana. The detrital zircon provenance of the Bear Gully Chert Bed at the base of the Digger Island Marlstone at Waratah Bay includes the west Tasmanian Proterozoic, the East Gondwana margin and the Macquarie Arc. This mixed provenance provides evidence for the late Cambrian docking of VanDieland with East Gondwana. KEY POINTS New zircon Hf isotope data are reported for early Paleozoic sedimentary rocks in Tasmania and Waratah Bay, southern Victoria. The western Tasmania basement was the dominant source for Tasmanian sandstones and a minor source for the Lachlan Orogen sandstones on the northeast margin of VanDieland. The mixed provenance of the Bear Gully Chert supports a late Cambrian accretion of VanDieland to the East Gondwana margin. The youngest zircons in the Bear Gully Chert at Waratah Bay were potentially sourced from the Macquarie Arc.

Si isotope ratio of radiolaria across Triassic–Jurassic transition in a pelagic deep-sea bedded chert (Inuyama, Japan)

The end-Triassic extinction event (ETE) marks one of the “Big five” mass extinction events of the Phanerozoic, yet the timing and nature of environmental changes on a global scale remain elusive. Here we report a mm-scale high-resolution δ30Si profile of sea surface-dwelling radiolaria, preserved as moulds, spanning the end-Triassic radiolarian turnover interval of the deep-sea succession at the Katsuyama section, Inuyama, Japan. The δ30Si of the Triassic-Jurassic radiolaria between − 0.6 ± 0.5‰ and 2.6 ± 0.3‰ overlap with available radiolarian δ30Si data for Triassic to Cenozoic, including modern samples. The mass balance of Si with dominant radiolaria up to 90% in chert supports negligible impact of diagenesis on δ30Si of radiolarian moulds. The cm-scale δ30Si variations up to 2 ‰ are overall associated with changes in silica contents. Here we hypothesize that the δ30Si of radiolarian reflect radiolarian productivity. We detected negative silicon isotope excursions within and above the end-Triassic radiolarian turnover interval, named here the SIE 1 and 2. The first SIE of 2 ‰ is detected from 0 mm to 10 mm above the base of purple chert interval, probably linked with the initial massive volcanism in the Central Atlantic magmatic provinces (CAMP) and associated deep-sea acidification and the onset of the end-Triassic radiolarian turnover. Subsequent positive SIE up to 2 ‰ ca. 10 mm above the first negative SIEs may record recovery of biosiliceous productivity, which could may be related with the first appearance of several Jurassic radiolarian taxa within the radiolarian turnover interval. We also detected data that is suggestive of SIE 2 in the lowermost dusky red chert bed, suggesting similar changes in productivity. These negative SIEs occurred within ~ 1 mm interval, implying the occurrence of kyr- or shorter-scale drastic environmental perturbations across the end-Triassic radiolarian turnover interval.

Formation of the massive bedded chert and coupled Silicon and Iron cycles during the Ediacaran-Cambrian transition

Direct inorganic silica precipitation was a major silicon sink in the Paleoproterozoic oceans, whereas the diagenetic silica replacement of peritidal carbonate rocks became an increasingly important sink for silica in Mesoproterozoic and Neoproterozoic. The unique widespread bedded chert documenting transition from platform margin to basinal environments in the Yangtze Block, South China, during the Ediacaran-Cambrian transition (ECT, 550-521 Ma), however, remains enigmatic. Here, we report consistently low Germanium/Silicon (Ge/Si) ratios (0.2-0.5 μmol/mol) of the ECT Liuchapo cherts. The low (Ge/Si) ratios, combined with rare earth elements (REE) analysis, point to normal seawater source for the Liuchapo cherts. The primary nature of the chert was verified by Oxygen isotopes (δ18O) of silica and thus the measured Ge/Si ratios of the cherts could represent the maximum estimate of seawater Ge/Si ratios during ECT. Seawater during ECT has a significantly lower Ge/Si ratio than that of the modern marine. Low Ge/Si requires a high fraction of seawater germanium to be buried by a non-SiO2 sink. We speculate that germanium removal may be associated with a very active iron cycle driven by oscillating redox during ECT. The iron redox cycle may also effectively shuttle seawater silicon to sediments, causing bedded cherts precipitation. This study suggests that silica precipitation may be directly linked to the redox cycling of iron, and that this linkage favors silica precipitation regardless of its saturation state in the ocean.

Field Description and Lithostratigraphic Study of Sargelu Formation in Rania and Sargelu sections, Northern Iraq

The Sargule Formation was deposited during the Middle Jurassic, representing one of the most important source rocks in Iraq and surrounding areas.
 Jurassic successions are commonly exposed as an isolated patch at some eroded anticline’s cores and limbs in the High Folded Zone, Imbricate Zone, and Thrust Zones of northern Iraq. The Sargelu section is located in Sargelu village at Surdash anticline, while the Rania section is located in Rania city near Hanjira village at Shaweri anticline. Fieldwork in Rania and Sargelu Sections allow to divide Sargelu Formation lithostratigraphically into many subdivisions as follow:
 The Sargelu Formation in the Rania section is about 40 m and can be divided into two lithologic units; the upper thin to medium bituminous limestone beds alternated with thin chert beds, and the lower thin to medium bituminous limestone beds alternated with fissile gray shale beds.
 the The Sargelu section comprises 180m and is divided into three units; the upper unit consists of dark gray limestone beds and thin brownish-black of laminated shale. The middle unit includes dark chert alternated with dark gray bituminous limestone and brownish-black laminated shale. At the same time, the lower unit consists of dark gray bituminous limestone beds alternated with medium brownish-black laminated shale beds.

Diagenetic controls on porosity evolution and reservoir quality of an outcrop analogue of the Jurassic carbonate reservoirs in the Arabian Plate: An example from the Middle Jurassic Tuwaiq Mountain Formation, Central Saudi Arabia

The Middle Jurassic Tuwaiq Mountain Formation (TMF; formed of three members, from bottom to top T1, T2, and T3) represents one of the primary conventional and unconventional reservoirs to be assessed in Saudi Arabia. It is considered as a tight carbonate reservoir in the Jafurah Basin and conventional reservoir in the Arabian Basin. Here, we investigate the depositional, diagenetic, and stratigraphic impact on reservoir quality and porosity evolution of the TMF through an integrated petrographical, geochemical and petrophysical analyses on outcrop samples. The TMF has a complex diagenetic history including micritization, dissolution, recrystallization and neomorphism, meteoric cementation, evaporite precipitation, dolomitization, silicification, dolomite dissolution and calcitization. Dolomitization occurred via a hypersaline fluid mechanism, based on texture, association with evaporites, and Sr concentration. X-ray diffraction results support chert replacing evaporite as the mechanism of the two chert beds in the T3 member due to the presence of anhydrite relics in their samples. This replacement formed the necessary Ca 2+ rich fluid for dolomite dissolution and calcitization. Therefore, dolomite calcitization occurs locally and is stratigraphically controlled based on its position relative to chert beds in T3. T3 and the upper part of the T2 member contain calcitized dolomites, while the lower part of T2 and T1 contain only dissolved dolomite. As the fluid went deeper in the TMF, it became weaker. Therefore, the fluid was too weak to develop dolomite calcitization process and instead only affected T1 and the lower part of T2 by dolomite dissolution. Overall, dolomite dissolution and dolomite calcitization didn't have a high impact on porosity evolution as the TMF isn't a highly dolomitized formation. The distribution of porosity (ø), permeability (K), and reservoir-quality-index (RQI) of the TMF are stratigraphically controlled. The TMF represents the regressive system tract of a 3rd order depositional sequence, which is composed of seven 4th order cycles (i.e. deep lagoon cycles (DLC) and shallow lagoon cycles (SLC)). RQI, Ø, and K plots showed great fitting with the 4th order depositional-cycles as DLC has very poor reservoir properties (average ø = 7.7%, average K = 0.17 mD, average RQI = 0.03), while SLC has fair reservoir properties (average ø = 15.4%, average K = 2.64 mD, average RQI = 0.11). Reservoir quality contrast is controlled by two factors: (1) the reduced mud-content and increased grain-content in SLC compared with DLC resulted in increased primary interparticle porosity, and is governed by depositional energy; and (2) the higher primary interparticle porosity in SLCs compared with DLCs preferentially facilitated more infiltration of undersaturated meteoric fluids, resulting in enhanced grain dissolution. This is reflected on the higher proportion of moldic and vuggy porosity in SLCs compared with DLCs. The accurate assessment of the TMF micro-scale attributes and controls on reservoir quality in an outcrop analogue that occurs in close proximity to subsurface hydrocarbon producing intervals can provide important input for oilfield appraisal and enhanced oil recovery performance. • Cementation was the main destructive diagenetic feature of the reservoir quality. • Depositional texture controlled primary porosity and dissolution related secondary porosity. • Dolomite-Calcitization and meteoric-dissolution had a stratigraphically controlled distribution. • Dolomitization happened through hypersaline fluids like many Jurassic carbonates in the Arabian Plate. • Dedolomitization mechanism was related to the process of chert replacing evaporites.

Radiolarian evidence for Middle Bathonian radiolarites in the Episkopi Formation (Ayios Photios Group, Mamonia Complex, SW Cyprus).

The Ayios Photios Group in SW Cyprus represents a deep-water slope or base of slope sequence that was accumulated on a Mesozoic margin of the Mediterranean Tethys. The Episkopi Formation is an essentially radiolaritic sequence, the age of which was previously considered to range between the Callovian and the Valanginian. A moderately well preserved (PI 4-5) radiolarian assemblage was extracted after laboratory leaching with diluted hydrofluoric acid of a radiolarian chert bed south of the village of Episkopi. Based on the co-occurrence of Bernoullius rectispinus leporinus Conti & Marcucci, Hexasaturnalis tetraspinus (Yao) and Theocapsommella cucurbiformis (Baumgartner), the assemblage is correlated with the Middle Bathonian (Unitary Association Zone 6). Our results extend downwards the known age range of radiolarites of the Episkopi formation and reduce the previously known range of depositional hiatus with the underlying Upper Triassic formations of the Ayios Photios Group.

Physical and chemical depositional processes when volcanoes meet lacustrine environments: the Cretaceous Imjado Volcanics, Jeungdo, southwestern Korea

Abstract A Cretaceous volcano-sedimentary succession (Imjado Volcanics, Jeungdo, SW Korea) was analysed to understand volcanic influences on physical and chemical depositional processes of a shallow alkaline lake during and after explosive eruptions. The succession is composed of primary and resedimented volcaniclastic deposits interbedded with fine-grained sediments and a bedded chert. The primary volcaniclastic deposits are characterized by two end-members: thick (20 m), welded lapilli tuff and thin (0.9 m), planar stratified tuff deposits. The first member deposits were accumulated by steady pyroclastic density currents that displaced the lake water from the shoreline. The second end-member deposits were accumulated by unsteady pyroclastic density currents that rapidly disintegrated at the shoreline and transformed into turbidity currents. The reverse to normally graded volcaniclastic sandstone is one of the resedimented volcaniclastic deposits accumulated by hyperpycnal flows originating from subaerial discharge. On top of this deposit, a bedded chert is exposed and composed of microcrystalline texture without biogenic remains. The microscopic analysis and stratigraphic relationship suggest that the chert bed was formed by chemical precipitation as a result of changes in the hydrochemistry of lake water by interaction between fresh water (hyperpycnal flows) and the alkaline bottom water of the lake.

Structural and chemical heterogeneity of Proterozoic organic microfossils of the ca. 1 Ga old Angmaat Formation, Baffin Island, Canada.

Organic microfossils in Meso- and Neoproterozoic rocks are of key importance to track the emergence and evolution of eukaryotic life. An increasing number of studies combine Raman spectroscopy with synchrotron-based methods to characterize these microfossils. A recurring observation is that Raman spectra of organic microfossils show negligible variation on a sample scale and that variation between different samples can be explained by differences in thermal maturation or in the biologic origin of organic precursor material. There is a paucity of work, however, that explores the extent to which the petrographic framework and diagenetic processes might influence the chemical structure of organic materials. We present a detailed Raman spectroscopy-based study of a complex organic microfossil assemblage in the ca. 1Ga old Angmaat Formation, Baffin Island, Canada. This formation contains abundant early diagenetic chert that preserves silicified microbial mats with numerous, readily identifiable organic microfossils. Individual chert beds show petrographic differences with discrete episodes of cementation and recrystallization. Raman spectroscopy reveals measurable variation of organic maturity between samples and between neighboring organic microfossils of the same taxonomy and taphonomic state. Scanning transmission X-ray microscopy performed on taphonomically similar coccoidal microfossils from the same thin section shows distinct chemical compositions, with varying ratios of aromatic compounds to ketones and phenols. Such observations imply that geochemical variation of organic matter is not necessarily coupled to thermal alteration or organic precursor material. Variation of the Raman signal across single samples is most likely linked to the diagenetic state of analyzed materials and implies an association between organic preservation and access to diagenetic fluids. Variation in the maturity of individual microfossils may be a natural outcome of local diagenetic processes and potentially exceeds differences derived from precursor organic material. These observations stress the importance of detailed in situ characterization by Raman spectroscopy to identify target specimens for further chemical analysis.

U–Pb geochronology and trace-element composition of zircons from the Jinchang Au–Ni deposit, SW China, and their implications for tectonics

AbstractSituated between the South China Block and the Simao Block, the Ailaoshan Belt is a significant component of the Jinshajiang–Ailaoshan tectonic-magmatic-metallogenic belt of southwestern China. The formation of the Ailaoshan Belt is closely related to the evolution of the Palaeo-Tethys Ocean. In this study, we constrain ages of sedimentation in the Jinchang Au–Ni deposit in the Ailaoshan Belt, using laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) U–Pb ages of the youngest populations of detrital zircons separated from a chert layer and two uncomfortably overlying meta-sandstones. The combined data of the meta-sandstone samples from the Yiwanshui Formation yielded a concordant age of 250.8 ± 0.6 Ma (mean square weighted deviation (MSWD), 2.8; n = 26). The chert sample from the Jinchangyan Formation yielded a concordant age of 347.0 ± 1.5 Ma (MSWD, 2.8; n = 16). Detrital zircons from the meta-sandstone are characterized by low rare earth element contents (∑REE) and low Y, and high U and U/Yb ratio, suggesting a continental crustal origin. Zircons in the meta-sandstones were derived mainly from pre-collision subduction zone magmatic rocks related to the closure of the Palaeo-Tethys Ocean. In contrast, detrital zircons from the chert contain relatively high ∑REE and Y, and low U and U/Yb ratio, suggesting an oceanic crust origin. Zircons in the chert bed were derived mainly from ophiolites related to seafloor spreading in a branch of the Palaeo-Tethys Ocean.

Statistical analysis of geological factors controlling bed-bounded fracture density in heterolithic shale reservoirs: The example of the Woodford Shale Formation (Oklahoma, USA)

The geological controlling factors of natural fracture distribution and density in the Woodford Shale Formation are quantitatively investigated in this study. The Upper Woodford Shale member in southern Oklahoma, is exceptionally brittle due to the abundance of recrystallized radiolaria chert beds that alternate with siliceous shale beds. Bed-bounded compressional fractures are well developed in the structural-active region. Two areas were characterized and compared to represent low and high confining pressure conditions respectively. A statistical analysis workflow consisting of Principal Component Analysis (PCA) and Partial Least Square Regression (PLS) was proposed to quantify the controlling factors' relationship and their Variable Importance in Projection (VIP) which reveals the contribution of each controlling factor to the fracture density. The result indicated that natural fractures' occurrence in shale reservoirs are impacted by three controlling factors: rock hardness, hard bed ratio (thickness percentage of hard beds within a stratigraphic unit interval) and bed frequency (number of beds within a unit interval). The contributions from these individual controlling factors are different under different reservoir conditions. Bed frequency (layering anisotropy) is the dominant controlling factor that contributes on average three times more than the hard bed ratio and hardness to fracture density. Hardness's contribution to fracture density in the subsurface scenario is lower by 22% than the surface scenario due to the increase in confining pressure. The analytical results highlight the importance of the layering effect on fracture density which has often been overlooked in geomechanical modeling workflow. A new concept of Fracture Density Index (FDI) is defined and can be further applied to predict fracture density in other unconventional reservoirs.

Development of a greenalite-silica shuttle during incursions of hydrothermal vent plumes onto Neoarchean shelf, Hamersley region, Australia

Deep-water cherts are common in early Precambrian successions. Their mode of formation is unclear but proposed mechanisms include seawater silica precipitation, silica adsorption onto iron oxide particles and silica replacement of seafloor sediments. Here we document ≥80 laminated chert beds (0.02–7 m thick) in 2.56–2.49 Ga shelf sequences in drill-hole ABDP9 from the Hamersley Group, Australia. The laminated chert beds, including thin intervals of banded iron formation (BIF), are concentrated in six major intervals that first appear ca. 75 m.y. before deposition of the 2.49 Ga Brockman Iron Formation. The chert beds do not preserve textures indicative of seafloor replacement of precursor grains but of a chemical sediment comprising greenalite nanoparticles enclosed in silica cement with syneresis cracks that truncate sedimentary lamination. The greenalite is interpreted to have precipitated from dissolved Fe(II) and SiO2(aq) transported by hydrothermal plumes. Its ubiquity in laminated chert cement and the capacity of clay minerals to sorb silica, suggest the operation of a greenalite-silica shuttle by which excess dissolved silica in the seawater-plume mixture adsorbed onto settling Fe(II)-silicate nanoparticles. Upon deposition, pore-water silica concentrations surpassed the threshold for cementation due to the drawdown of silica into sediment pore waters and dewatering of underlying siliceous muds. In contrast, the lack of non-ferruginous chert beds in deep-water shelf sediments suggests that silica concentrations were lower in non-plume seawater. The appearance and disappearance of ferruginous cherts in shelf sequences is interpreted to record the waxing and waning of distal vent plumes. Deposition of chert beds starting at 2.56 Ga culminated with the development of thick, laterally extensive BIFs after 2.49 Ga, signalling enhanced ocean ridge volcanism and the transgression of vent plumes across a drowned shelf. The disappearance of basinal cherts and major BIFs after the Great Oxidation Event (2.45–2.3 Ga) may record the disruption or shutdown of the oceanic greenalite-silica shuttle.

Sedimentary Paleoenvironment of the Eastern Hexi Corridor, NW China: Constraints from Chert Geochemistry and Sedimentary Analysis of Early Paleozoic Strata

AbstractThe eastern Hexi Corridor, northwest China, is located at the tectonic junction of the Alxa Block, the North China Craton, and the Qinling‐Qilian Orogen. The early Paleozoic Xiangshan Group record critical information regarding paleoenvironment, paleoclimate and paleotectonic setting, from which we here present a focused study on the chert beds within the Xiangshan Group. Through field mapping, microstructural observation, whole‐rock geochemistry analyses and detrital zircon dating, we suggest that the Xiangshan Group chert was deposited along a passive continental margin, formed primarily through biological activity with minor hydrothermal influence and terrestrial input. The characteristics of the chert support a low latitude sedimentary paleoenvironmental origin, and reveal the fact that the Alxa Block was separated from the North China craton, while emerged some paleogeographic affinity with the Qilian region in the Middle‐Late Cambrian.

Identification of Proton Populations in Cherts as Natural Analogues of Pure Silica Materials by Means of Low Field NMR.

Recent theories about the sources of silica in bedded and nodular cherts do not fit the origin of cherts from the Kraków–Częstochowa Upland. Since siliceous sponges as a single source of silica is questionable, assumptions about additional sources have to be verified. In order to do so, three samples of nodular cherts and one representative sample of bedded chert were studied by means of 1H LF-NMR 1D and 2D relaxometry and complementary geochemical methods. The results were compared with the literature and standard silica materials which helped to identify five types of 1H signal. The very distinct 1D-T2 spectra of the dried samples indicated the existence of closed pores which, after comprehensive analysis, were identified as inclusions filled with different types of siliceous materials. Saturation revealed the differences between nodular and bedded cherts that were visible mainly in the amount and size of open porosity. The principal component analysis of NMR parameters showed the excellent separation of these two groups of samples and this is well visible on the biplots. Additionally, the estimated pore size distribution revealed that the total porosity of around 2% consisted primarily of mesopores (2–50 nm in diameter) and macropores (diameter >50 nm). In bedded cherts, open porosity is dominated by macropores, while the share of mesopores and macropores is similar in nodular cherts.

Chert geochemistry, depositional setting, stratigraphic and structural significance for the Permian Nong Pong Formation, Khao Khwang Fold and Thrust Belt, Saraburi, Thailand

The deepwater chert-shale-limestone-tuff Permian Nong Pong Formation (NPF) of the Saraburi Group is a major unit within the Triassic (Indosinian Orogeny) Khao Khwang Fold and Thrust Belt (KKFTB). Whether the NPF was deposited in a continental margin or ocean basin remains uncertain and impacts structural, sedimentary and stratigraphic interpretations of the KKFTB. This study investigates chert geochemistry from a 60 m section of the formation, near Muak Lek town, to determine its depositional environment. Radiolarian fauna from the chert beds includes Follicucullus porrectus Rudenko, (probable late Guadalupian, late middle Permian), indicating the NPF is time-equivalent to adjacent carbonate platform deposition (Khao Khwang and Khao Khad formations). High ratios of SiO2/(SiO2 + Al2O3 + Fe2O3) and Fe-Al-Mn plots indicate a biogenic origin (radiolarians, sponge spicules) for the cherts, far from a hydrothermal source. Trace element ratios for U/Th, Sc/Th and Sr/Ba and Ce anomalies in the NASC-normalized REE distribution are ambiguous, and range between shallow to deep ocean basin, and continental margin settings. Major elements analysis of cherts show: (1) high ratios of SiO2/(SiO2 + Al2O3 + Fe2O3), range: 0.60–0.82 (0.76 average), (2) Al/(Al + Fe + Mn), range: 0.67–0.82 and (3) average MnO/TiO2 = 0.14. The MnO/TiO2 and Al2O3/(Al2O3 + Fe2O3) ratio, 100 × Fe2O3/SiO2 vs. 100 × Al2O3/SiO2 and Fe2O3/(100-SiO2) vs. Al2O3/(100-SiO2) diagrams indicate deposition on a continental margin. The Lan/Cen versus Al2O3/(Al2O3 + Fe2O3) discrimination diagram indicates a pelagic, continental margin setting. Combined geochemical, structural and sedimentary facies analyses suggests the NPF was deposited in a deep marine, normal fault-bounded basin on a rifted, ribbon continent margin where carbonate platforms grew on structural highs.

Diagenetic formation of bedded chert: Implications from a rock magnetic study of siliceous precursor sediments

Bedded chert is a distinctive rock type characterized by a rhythmic alternation of quartz-rich chert beds and clay-rich interbeds. The origin of the lithologic variations is not well understood. A rock magnetic study of a sequence of alternating bands of radiolarian-rich and clay-rich bands recovered by ODP leg 129, which is considered to be the best-known analog for the bedded chert precursor sediments, shows that the relative abundances and characteristics of magnetic phases are similar in both sediment types, with only a minor (1.5 times on average) increase in bulk concentration in clay-rich bands. Comparison with magnetic properties of the diagenetically mature chert-shale couplets suggests that siliceous precursor sediments undergo strong differential diagenetic modification. A simple silica transfer model, with dissolution of silica in proto-shale donor beds and deposition in proto-chert receiver beds, indicate that the known features of the bedded chert sequences, such as the difference in thickness, cosmic dust content between chert and shale, can be reproduced in case of donor beds having initially lower clay (higher biogenic silica) content compared to receiver beds. While contrary to the current depositional model explaining chert beds formation by episodic radiolarian bloom on a background of slow accumulation of clays, an association of proto-shale beds with high productivity episodes is supported by an independent paleoproductivity proxy – their higher Al/Ti values, and is in full agreement with the known silica diagenesis trends, particularly, with the retarding influence of detrital minerals on silica transformations. The impetus for diagenetic silica segregation is provided by initial variability in clay content within a siliceous sedimentary succession. Silica dissolution starts in clay-poor intervals. When diffusing silica encounters clay-rich beds, adsorption to clay lowers dissolved silica content below the saturation level of the higher solubility phases and leads to deposition of low solubility quartz. Early deposition of quartz cement prevents significant compaction of chert layers, while the loss of silica in donor beds leads to their compaction and concomitant increase in non-reactive clay and cosmic dust particles. Severe distortion of primary environmental signals during differential diagenesis questions the use of bedded chert sequences for cyclostratigraphic studies.

Managing and Surveying the Geological Garden at Tata (Northern Transdanubia, Hungary)

The Geological Garden at Tata is an open-air geological museum where a spectacular succession of Tethyan Mesozoic sedimentary rocks, characteristic of the Alpine-Carpathian region, is finely exposed in abandoned quarries and cleaned rock surfaces. In addition to geological values, the area houses copper-age chert mines, the only ones accessible to the wider public in Hungary. Due to financial problems, however, maintenance of the site was more or less confined to mowing for more than 20 years. Renewal of the Geological Garden began in 2015 when large-scale cleaning as well as detailed surveying was carried out. Removing the soil and loose rock debris provided opportunity to study the effects of weathering and growth of vegetation. Near 60 m3 of rock debris and soil had been accumulated on approx. 5000 m2 rock surface over the decades of obligate deterioration. Lower Jurassic marl and Middle Jurassic radiolarite chert beds as well as Middle Jurassic limestones proved to be especially deeply weathered. The cleaning action raised the question whether the sub-horizontal rock surfaces can be conserved for a long time in their present state or not. Lessons drawn from the latter can serve as a basis for future maintenance activities as well as for plans aiming at developing geosites.

THE OLIGOCENE–MIOCENE MENILITE FORMATION IN THE UKRAINIAN CARPATHIANS: A WORLD‐CLASS SOURCE ROCK

This study investigates the hydrocarbon potential of Oligocene–Miocene shales in the Menilite Formation, the main source rock in the Ukrainian Carpathians. The study is based on the analysis of 233 samples collected from outcrops along the Chechva River in western Ukraine in order to analyse bulk parameters (TOC, Rock‐Eval), biomarkers and maceral composition.In Ukraine, the Menilite Formation is conventionally divided into Lower (Lower Oligocene), Middle (Upper Oligocene) and Upper (Lower Miocene) Members. The Early Oligocene and Early Miocene ages of the lower and upper members are confirmed by new nannoplankton data. The Lower Menilite Member is approximately 330 m thick in the study area and contains numerous chert beds and turbidite sandstones in its lower part together with organic‐rich black shales. The shales have a high content of silica which was probably derived from siliceous micro‐organisms. The TOC content of the shales frequently exceeds 20 wt.% and averages 9.76 wt.%. HI values range between 600 and 300 mgHC/gTOC (max. 800 mgHC/gTOC). The Middle Member contains thin black shale intervals but was not studied in detail. The Upper Member is about 1300 m thick in the study area and is composed mainly of organic‐rich shales. Chert layers are present near the base of the Member, and a prominent tuff horizon in the upper part represents a volcanic phase during shale deposition. The member grades into overlying molasse sediments. The average TOC content of the Upper Menilite succession is 5.17 wt.% but exceeds 20 wt.% near its base.Low Tmax and vitrinite reflectance measurements for the Lower (419°C and 0.24–0.34 %Rr, respectively) and Upper (425°C and 0.26–0.32 %Rr, respectively) Menilite Member successions indicate thermal immaturity. Biomarker and maceral data suggest a dominantly marine (Type II) organic matter input mixed with varying amounts of land‐plant derived material, and indicate varying redox and salinity conditions during deposition.Determination of the Source Potential Index (SPI) shows that the Menilite Formation in the study area has the potential to generate up to 74.5 tons of hydrocarbons per m2. The Chechva River outcrops therefore appear to have a significantly higher generation potential than other source rocks in the Paratethys realm. These very high SPI values for the Menilite Formation may explain why a relatively small area in Ukraine hosts about 70% of the known hydrocarbon reserves in the northern and eastern Carpathian fold‐thrust belt.