Chemical Weathering Research Articles

Sensitive response of erosion and weathering to the Indian Summer Monsoon changes in South Asia during Dansgaard-Oeschger oscillations

Continental weathering plays a key role in regulating the long-term climate stability via negative feedback. However, whether and how erosion and weathering respond to rapid climate change (e.g millennial scale) in large river basins remains unclear, partly due to the lack of archives with robust age models and high sampling resolution. As one of the largest sediment source-to-sink systems, the Himalaya-Ganga/Brahmaputra River-Bay of Bengal system is considered as an ideal laboratory for examining the weathering-climate relationships over the past. Here we present the elemental and mineralogical data from well age-constrained core sediments in the Bay of Bengal, which document the erosion and weathering conditions in South Asia during the last glacial period. All proxies generally show larger values during glacial interstadials than the stadials, consistent with the millennial variabilities of regional sea surface temperature (SST) and the Indian Summer Monsoon (ISM) strength. We confirm that the erosion and chemical weathering signals in Ganga/Brahmaputra River basins, which sensitively respond to the ISM strength and/or temperature change, could be propagated through the large river systems and faithfully preserved in the South Asian marginal seas, without noticeable time lag on a millennial scale. Our findings provide valuable data for response of erosion and weathering dynamics in a large river basin to rapid climate changes, and highlight the immense potential of monsoon-driven continental silicate weathering in floodplains as a substantial short-term carbon sink, thus underscoring a pivotal natural carbon sequestration mechanism amidst the escalating threat of global warming.

Cenozoic tectono-sedimentary evolution of the external rif chain (Morocco) derived from mineralogical and geochemical analysis of mudrocks

A model of the Cenozoic tectono-sedimentary evolution of the External Rif Chain (Morocco) is provided by means of the study of the mineralogical and geochemical composition of mudrocks. To date there was a lack of homogeneous data and of a complete and extensive study of the whole External Rif Zone (ERZ). Therefore, this work shows the study of the whole ERZ where the most representative stratigraphic sections have been selected. This work provides important information about the geodynamic evolution and the variations in source-area provenance related to the growing of the Rif orogenic belt. Although there is still much work to be done, this study aims to improve the knowledge of the Cenozoic tectono-sedimentary evolution of the entire western ERZ with a homogeneous method, with a focus on the paleogeographic and paleotectonic evolution, the paleoweathering and the source areas deduced from mineralogical and geochemical data of the Cenozoic mudrocks. The bulk mineralogy is mainly characterized by the presence of calcite, quartz and dolomite plus ankerite. Feldspars have few percentages. The clay minerals are principally represented by mixed-layer illite/smectite (I/S). Illite and kaolinite are in little amount. Femic minerals, mixed-layer chlorite/smectite (C/S) and chlorite are the most abundant. The I/S features suggest a different thermal condition for the three domains. The chemical composition indicates that the mudrocks can be described as mixtures of carbonates with aluminosilicate components. The Al/Ti, Th/Cr, Th/Sc, La/Th and La/Sc ratios, the Cr/V vs. Y/Ni plot, the V-Ni-Th∗10 and La-Th-Sc ternary diagrams indicate a predominantly felsic source with a minor mafic input more evident in the Paleocene-Eocene samples of the External Intrarif and Mesorif. The External Rif Zones changed in the Cenozoic from a passive margin to a complex foreland system with the incoming of the Alpine tectonic phases. In general, the felsic contribution should be linked to the foreland area consisting in the Middle Atlas and Mesetas massifs made of a crystalline domain. This margin probably presented an intermediate narrow oceanic branch in the External Intrarif-Mesorif boundary that surprisingly should start to close during Paleogene times providing the mafic contribution. This Paleogene tectonic activity in these domains is corroborated by the thermal maturity indicating late diagenesis. The chemical weathering indices, such as the CIA (Chemical index of Alteration) and its modifications, show medium-high values and thus suggest generally moderate paleoweathering conditions in agreement with the predominant amount of I/S.

Coupled role of climate and tectonics in the deposition of the late Quaternary sedimentary sequence in the southern margin of the central Ganga Plain, India

ABSTRACT The Ganga Plain’s sedimentation is primarily controlled by Himalayan tectonics, variations in monsoon intensity, and glacier size. However, the significance of intrabasinal tectonics, which is an interplay of the Himalaya tectonics and basement tectonic configuration of the Ganga Plain, in comprehending the late Quaternary Ganga Plain sedimentation remains unclear. In this study, the sediment provenance and extent of weathering experienced by the sediments are studied using the mineralogical and geochemical (major, trace, and rare earth elements) composition of a sedimentary cliff sequence exposed at the Ramnagar locality near the cratonic peripheral bulge in the southern Ganga Plain. In the Ramnagar cliff sediment section, two sediment packages, designated SP-A and SP-B, are identified based on mineralogy, texture, and geochemistry. These packages of sediments show mild chemical weathering and distinct geochemical compositions. The lower part (SP-A) of the Ramnagar cliff section is characterized by higher contributions from mafic sources (pyroxene, feldspar, and mica as dominant minerals), while the upper part (SP-B) is predominately derived from felsic sources (mica and feldspar as dominant minerals), which are supplied via the peninsular and the Himalayan rivers, respectively. The southern part of the central Ganga Plain shows evidence of a shift in the sediment provenance from mafic to felsic source rock at 40 ka. This study demonstrates how weathering and sedimentation are controlled by both regional tectonics and climate in the southern margin of the central Ganga Plain.

Climatic significance of clay minerals in Cenozoic marine and lacustrine sediments

Abstract In sediments, clay minerals are mainly detrital. Formed by continental weathering, they are carried by surface transport predominantly by rivers, glaciers and, to a lesser extent, winds to the adjacent sedimentary basins and then are redistributed by oceanic currents. In a sedimentary core, the variability in the clay mineral assemblages reflects either variable physical and chemical weathering conditions in the watershed, typically with a significant link to climatic conditions, or changes in the mineral source, the latter being associated with various transport agents. When different sources are involved, a combination of mineralogical and geochemical proxies allows us to trace the detrital provenance, but they also indirectly provide valuable information on transport pathways and palaeocurrents. This manuscript reviews several examples from the literature and ongoing research on clay mineral variability in marine or lacustrine sedimentary records and interprets them in terms of: (1) climate control at different timescales, from the Neogene to the Quaternary; and (2) transport paths. Examples are selected to review the various clay-derived proxies in existence.

Sedimentological and geochemical proxies reveal changes in the South Atlantic Convergence Zone in Southeast South America during the Late-Holocene

Today, the South Atlantic Convergence Zone (SACZ), a convective band that extends across central Brazil to the western South Atlantic Ocean, modulates Southern Hemisphere summer rainfall in Southeastern Brazil. During the Holocene, however, the role of the SACZ over the rainfall regime in this part of South America is still under debate. This study aims to provide new insights into the SACZ Late-Holocene variability through analysis of the geochemical (XRF-based bulk sediment Metal/Metal ratios) and sedimentological (grain size and end-member modeling) variations along four cores retrieved in a coastal area (24–49 m water depth) located in the core of modern SACZ. Our records show an increase in Ti/Ca ratios, suggesting increased rainfall and that the terrigenous input to the Brazilian southeastern inner shelf changed in the Late-Holocene (last 4200 years). These changes are also followed by a decrease in the K/Ti ratio, indicative of an increase in chemical weathering in the sediment source, and an increase in the Mn/Ti, suggesting an increase in oxidation. Additionally, decadal-scale variability with periodicities of 25 and 55 years obtained by a time-series (Redfit) analysis highlights a potential role of the Pacific Decadal Oscillation and the Atlantic Multidecadal Oscillation, respectively, as drivers of the SACZ variability over the last 4200 years.

Re-Os geochronology and geochemical evolution of late Cambrian to Middle Ordovician Alum and Tøyen shales, Sweden

The limited number of accurate and precise radiometric ages through the ∼100 Myr span of the Cambrian and Ordovician impedes reliable age determinations for stage boundaries in these periods. Here, we fill significant gaps in the early Paleozoic chronostratigraphy by providing precise Re-Os time-pins. Sample selection is linked to a firm biostratigraphic framework built on the appearance and distribution of trilobites, graptolites, and conodonts. A Furongian (upper Cambrian) Alum Shale section (Andrarum-3 drill core, Scania, Sweden) at the onset of the Steptoean Positive Carbon Isotopic Excursion (SPICE) yields highly non-isochronous Re-Os isotopic data from a section with wildly fluctuating δ13Corg; however, selected data from a narrow sediment band with steady carbon isotope stratigraphy provides an imprecise Re-Os age of 497 ± 28 Ma (2σ; Model 3; n = 3), with an initial 187Os/188Os ratio (Osi) of 0.74 ± 0.05. Organic-rich Alum Shale (Tomten-1 drill core, Västergötland, Sweden) from ∼120 cm below the Cambrian-Ordovician boundary yields a Model 1 age of 488.6 ± 5.1 Ma (2σ; MSWD = 1.5; n = 25) and an Osi of 0.82 ± 0.04 for Stage 10, uppermost Cambrian. Biostratigraphic data indicate the dated Alum Shale is from an interval slightly below the Top Of Cambrian Excursion (TOCE) and slightly above the First Appearance Datum (FAD) of the agnostoid Lotagnostus americanus. Organic-rich Tøyen Shale (Lerhamn drill core, Scania, Sweden) yields a precise Model 1 Re-Os age of 469.7 ± 1.4 Ma (2σ; MSWD = 1.0; n = 10) and Osi of 0.802 ± 0.002 for the maximum age of the Floian–Dapingian stage boundary (Lower–Middle Ordovician boundary). The Os isotopic composition of seawater from the latest Ediacaran through the Cambrian to Early-Middle Ordovician hovers around 0.8 but falls to 0.54 by early Silurian. This significant decrease in seawater 187Os/188Os is consistent with reduced chemical weathering and cooler seawater temperatures through the Middle–Late Ordovician. Overall, Redox Sensitive Element (RSE; Re, Os, Mo, U) abundances correlate positively with Total Organic Carbon (TOC), suggesting efficient removal of these elements from an anoxic water column by organic matter. However, these relationships break down for high TOC (>10%) shales depositing under euxinic conditions. The RSE-TOC relationship breakdown supports enhanced metal drawdown from the water column with local pyrite accumulation. Geochemical data suggest the deposition of Alum and Tøyen shales under hydrographically restricted settings with increased primary productivity along the Baltica's margin during the latest Cambrian to Early-Middle Ordovician.

Composite Superhydrophobic Coating with Transparency and Thermal Insulation for Glass Curtain Walls.

In this paper, the preparation of a transparent superhydrophobic composite coating with a thermal insulation function using antimony-doped tin oxide (ATO) nanoparticles is proposed, which has advantages of being mass-producible and low-cost. In short, nanosilica and ATO are used as raw materials for constructing rough structures, and superhydrophobic coatings are obtained by mixing and adding binders after modification of each, which are then applied to the surface of various substrates by spraying to obtain a transparent superhydrophobic coating with a heat-insulating function. The specific role of each nanoparticle is discussed through comparative experiments that illustrate the mechanism by which the two particles construct rough structures. The coating achieves unique thermal insulation properties while possessing excellent superhydrophobicity (WCA of ∼163° and WSA of ∼3°) and high light transmission (∼70%). Heat-shielding experiments have demonstrated that the composite coating effectively reduces the room temperature by approximately 19% for the same irradiation time. The coating achieves a balanced improvement in visible transmittance, thermal insulation, and superhydrophobicity. In addition, the coating's self-cleaning properties, mechanical properties, chemical weathering resistance, high-temperature resistance, and anti-icing properties were verified through various experiments.

Investigating the Role of Microclimate and Microorganisms in the Deterioration of Stone Heritage: The Case of Rupestrian Church from Jac, Romania

Natural stone can undergo disaggregation from various causes, including physical actions such as freeze–thaw cycles, temperature and humidity variations, chemical actions such as the solubilization of minerals by organic and inorganic acids, as well as biological actions due to the colonization of organisms that can produce biocorrosion and biomineralization. This research investigates the impact of microclimatic conditions and microbial activity on the physical and chemical integrity of stone heritage, particularly the biodeterioration caused by fungi in the case of a Romanian rock church. Various analytical techniques were employed, including macroscopic and optical microscopy, Raman spectroscopy, X-ray diffraction, and culture-based identification methods, to characterize the mineral composition and microbial contamination of the rock samples. The analyses revealed that the sandstone consists primarily of quartz (over 90%), muscovite (5–10%), and feldspars. The identified fungi included Cladosporium herbarium, Aspergillus niger, and Mortierella hyalina. The SEM images showed fungal hyphae and spores within the kaolinite–illite matrix, indicating significant microbial colonization and its role in rock deterioration. Additionally, microclimatic data collected over a 12-week period highlighted the substantial fluctuations in temperature and relative humidity within the church, which contribute to the physical and chemical weathering of the stone. This study also noted high levels of particulate matter (PM2.5 and PM10) and volatile organic compounds, which can exacerbate microbial growth and stone decay. The comprehensive analysis underscores the need for targeted preservation strategies that consider both microclimatic factors and microbial colonization to effectively conserve stone heritage sites, ensuring their longevity and structural integrity.

Increase in Paleoproductivity Driven by Strengthening of Indian Summer Monsoon During Past ~14kyrs: Evidenced by Biogenic Silica Accumulation Rates at Southeastern Arabian Sea

We analysed the BSi (Biogenic Silica) contents of the marine core SK-313/1 from the southeastern Arabian Sea which is dated up to ~14.5 kyr BP. Results show that the maximum and minimum BSi contents are 2.5 and 0.5%, respectively. This is because of the low supply of silica skeleton and the high dissolution and dilution of terrigenous materials. The BSi mass accumulation rates indicate a trend of reduced paleoproductivity during the late Glacial period and increase during the Holocene, with global climatic shifts. Insolation changes at low latitudes, which regulate temperatures, may affect nutrient availability and, consequently productivity variations on a glacial–interglacial timescale. Notably, millennial events like the Younger Dryas (YD) periods, exhibited lower paleoproductivity, in contrast to the Bølling/Allerød (B-A) period and the middle Holocene, which displayed elevated levels of paleoproductivity. These millennial-scale fluctuations in siliceous productivity may be due to the changes in nutrient supply caused by the Indian summer monsoon (ISM). The period of increased paleoproductivity could be influenced by intensified chemical weathering and a boosted nutrient supply, which are consequences of the strengthened ISM during periods of relatively higher temperature.

Boron Enrichment in Salinized Lacustrine Organic-Rich Shale of the Paleogene Biyang Depression, East China: Occurrence and Geological Controlling Factors

Although boron (B) is widely applied as a paleosalinity indicator for ancient lakes, the occurrence and geological controls of B enrichment in salinized lacustrine organic-rich shale (SLORS) are poorly understood. This study addresses this issue by comparing the mineral and element compositions of high-boron shale (HBS) and low-boron shale (LBS) from the Paleogene Biyang Depression, using integrated XRD, XRF, and ICP-MS analyses. The mineral composition of HBS is dominated by illite, whereas LBS primarily consists of albite; both are of detrital origin. Compared to the element composition of UCC, HBS is extremely enriched in Mo and W, whereas LBS is extremely enriched in W and U. Boron is positively correlated with Al2O3 and negatively correlated with Na2O, suggesting that B primarily occurs in illite. An enhanced extent of chemical weathering prevailed during the deposition of HBS, providing a greater supply of illite to the basin. Higher pH levels and greater reduction during HBS deposition encouraged illite absorption of B, ultimately leading to B enrichment in shale. Our findings suggest that pH and redox conditions, as well as the mineral compositions of shale, should be fully considered during the application of B and related ratios as paleosalinity indicators.

Provenance Analysis of the Northern Offshore Mud Area of the Shandong Peninsula, China, Spanning the Last 2000 Years

The mud area in the northern offshore of the Shandong Peninsula constitutes a dynamic source–sink system in China’s continental shelf and is a hotspot for research. However, the provenance of the sediments remains controversial, and the depositional environment is not yet fully understood. This paper performed accelerator mass spectrometry 14C dating, grain-size analysis, clay mineralogic analysis, and geochemical analysis of the ZZ04 sediment core. The results showed that this core primarily comprises silt and clay, reflecting weak sedimentary hydrodynamic conditions and stable deposition. The clay mineral assemblage—illite, smectite, chlorite, and kaolinite—indicates strong physical weathering. The provenance of the mud area was mainly from the Yellow River, Shandong Peninsula rivers, and Yangtze River, highlighting its multi-source characteristics. The smectite/(illite + chlorite) ratio in the ZZ04 core serves as a mineralogical indicator of the East Asian summer monsoon (EASM). Eight significant East Asian winter monsoon (EAWM) intensifications were identified, correlating with global cooling events similar to those at 1.89, 1.4, 1.03, and 0.62 thousand years ago. During the EAWM period, the coastal current and the Yellow Sea warm current play crucial roles in the transportation of matter and heat flux in the mud area. In contrast, during the EASM period, the sediments are predominantly sourced from the Shandong Peninsula rivers, contributing terrigenous materials shaped by chemical weathering.

Denudation and Weathering Rates of Carbonate Landscapes From Meteoric 10Be/9Be Ratios

AbstractKnowledge of the rates of carbonate rock denudation, the relative apportionment of chemical weathering versus physical erosion, and their sensitivity to climate, vegetation, and tectonics is essential for disclosing feedbacks within the carbon cycle and the functioning of karst landscapes that supply important services to humans. Currently, however, for carbonate lithologies, no method exists that allows to simultaneously partition denudation into erosion and weathering fluxes at spatial scales ranging from soil to watersheds. To determine total denudation rates in carbonate landscapes from an individual soil or river sample, we adapted a published framework that combines cosmogenic meteoric 10Be as an atmospheric flux tracer with stable 9Be that is released from rocks by weathering, to the limestone‐dominated French Jura Mountains. By analyzing water, soil, sediment, travertine, and bedrock for 10Be/9Be, major and trace elements, carbon stable isotopes and radiogenic strontium, we quantified contributions of Be from primary versus secondary carbonate phases and its release during weathering from carbonate bedrock versus silicate impurities. We calculated partitioning of Be between solids and solutes, and rates of catchment‐wide (from sediment) and point source (from soil) denudation, weathering and erosion. Our results indicate that average denudation rates are 300–500 t/km2/yr. Denudation is dominated by weathering intensity (W/D) ratios of >0.92, and a non‐negligible contribution from deeper (below soil) weathering. Our rates agree to within less than a factor of two with decadal‐scale denudation rates from combined suspended and dissolved fluxes, highlighting the substantial potential of this method for future Earth surface studies.

Geochemical Characterization and Constraints on Provenance, Tectonic setting and Paleoweathering of the Miocene Bhuban Sandstone Exposed in Sakhan Anticline, Tripura Fold Belt, Surma Basin, India

ABSTRACT The petrography of sandstone, major oxides, trace and REE compositions of the Bhuban formation, exposed in the Sakhan Anticline of Tripura Frontal Fold Belt have been studied to determine the source rock, depositional tectonic setup and paleoweathering conditions. The average modal composition of the Bhuban Sandstone (Q89.27F4.40L6.33) classified them as quartz arenite and sub litharenite types. The modal composition data (Q-F-L) indicates a craton interior and recycled source for these sediments and deposited in an active continental basin margin as suggested by the bivariate plot of SiO2 vs. K2O/Na2O. The binary discrimination plot of Hf vs. La/Th suggests acidic and older sedimentary component as source for the studied sandstone. The ternary plot of V-Ni-Th×10 pointed towards felsic igneous provenance. Trace and rare earth elemental ratios, chondrite-normalize REE plot suggests the source of the Bhuban sediments are derived from felsic terrain. The CIA values (66.48-75.41), A-CN-K plot (A=Al2O3, CN=CaO+ Na2O, K=K2O) and distinct depletion of Na2O, CaO, U, Sr and Ba suggests moderate degree of chemical weathering of the source rocks which may indicate humid climatic conditions in the source area.

Provenance and tectonic setting of sandstones of the Lomas Coloradas Formation, Cabullona Group, Sonora, México: Constraints on petrography and geochemistry

The sedimentary rocks of the Cabullona Group are well exposed in the Cabullona Basin of northeastern Sonora, México, which represent syntectonic sedimentation associated with Laramide-style deformation during the Campanian−early Maastrichtian. The sandstones of the Lomas Coloradas Formation deposited at the upper part of the Cabullona Group. Petrography and geochemical (major, trace, and rare earth elements) studies were carried out on the sandstones to interpret the palaeoweathering, provenance, and tectonic setting of the Lomas Coloradas Formation sandstones. Most of the sandstone modal analysis data plotted in the QFL and QmFLt ternary diagrams fall into the fields of dissected arcs and recycled orogens, respectively. Geochemically the sandstones are classified as litharenites while few samples plot into the arkosic field. The chondrite-normalized REE diagrams for sandstones have LREE-enriched, relatively flat HREE patterns with negative Eu anomalies. CIA values and the A‒CN‒K diagram indicate a low intensity of chemical weathering in the source area. The tectonic setting diagram suggests both arc and rift settings for the studied sandstones. The bivariate and ternary diagrams and elemental ratios suggest a felsic source for the Lomas Coloradas Formation. The average REE patterns of the studied sandstones are comparable with REE patterns of the granite from the Caborca block, the rhyolite and granite of the Tarahumara Formation, and the Mesozoic felsic volcanic rocks. The modeled mixture of 40% Proterozoic granite, 30% Triassic arc, 10% Jurassic arc, and 20% Laramide arc represents the probable source rocks for the Lomas Coloradas Formation.

The Hydrochemistry Characteristics and Chemical Weathering Intensity of an Anthropogenically Involved Catchment, South China

The hydrochemical characteristics of watersheds are influenced by many factors, with chemical weathering and human activities exerting the most substantial influence. Performing a quantitative evaluation of the factors contributing to the chemical weathering of rocks is of significant scientific importance. This research zeroes in on the Qingtang River basin to elaborate on the hydrochemical characteristic, explore the origins of ions, and quantify the influence of anthropogenic discharges amidst cation interferences, thus improving the accuracy of chemical weathering rate estimations. The samples encompassed surface water, groundwater, and water from dripping in karst caves. The findings indicate that human-induced alterations significantly influence hydrogeochemical dynamics, although chemical weathering of rocks in their natural state is the controlling factor. The mean contributions of cations from atmospheric deposition, human inputs, carbonate weathering, and silicate weathering were 17.56%, 21.05%, 51.77%, and 9.54%, respectively. The chemical weathering rate for carbonate rocks was 62.4 t·km−2·a−1, which increased by 27.87% due to the influence of exogenous acids. The anthropogenic impact is predominantly evident in two aspects: (1) the alteration of hydrochemical processes within the watershed through direct input of ions, and (2) the acceleration of rock weathering rates in the watershed due to the exogenous acids.

Solid Earth forcing of Mesozoic oceanic anoxic events

Oceanic anoxic events are geologically abrupt phases of extreme oxygen depletion in the oceans that disrupted marine ecosystems and brought about evolutionary turnover. Typically lasting ~1.5 million years, these events occurred frequently during the Mesozoic era, from about 183 to 85 million years ago, an interval associated with continental breakup and widespread large igneous province volcanism. One hypothesis suggests that anoxic events resulted from enhanced chemical weathering of Earth’s surface in a greenhouse world shaped by high volcanic carbon outgassing. Here we test this hypothesis using a combination of plate reconstructions, tectonic–geochemical analysis and global biogeochemical modelling. We show that enhanced weathering of mafic lithologies during continental breakup and nascent seafloor spreading can plausibly drive a succession of anoxic events. Weathering pulses collectively gave rise to substantial releases of the nutrient phosphorus to the oceans, stimulating biological primary production. This, in turn, enhanced organic carbon burial and caused widespread ocean deoxygenation on a scale sufficient to drive recurrent anoxia. This model complements volcanic outgassing-centred hypotheses for triggering these events by demonstrating well-quantified basaltic sources of phosphorus release during periods of intense weathering related to climate warmth. Our study highlights a close coupling between the solid Earth and biosphere during continental reorganization.

Mineralogical Characterization and Geochemical Signatures of Supergene Kaolinitic Clay Deposits: Insight of Ropp Complex Kaolins, Northcentral Nigeria

This study presents the chemical and mineralogical composition of clay deposits and associated rock types within the Ropp Complex in order to assess the influence of parent lithology on the kaolinization, genesis, and utility of the deposit. Representative kaolin samples from E horizons of the weathering profiles and their bedrocks were collected from six sites in the Ropp Complex. Clay mineralogy was determined via the XRD technique, while a geochemical analysis was conducted using XRF, SEM coupled with EDS, and ICP-MS. The results showed that all kaolins dominantly contain kaolinite with a content of 77%–98% except for the AS1 kaolin with only minor kaolinite (20%) but mainly illite (65%). The notably lower crystallinity of kaolinite (HI value of 0.53–1.1) as well as its markedly small grain size is consistent with the formation of kaolinite from intensive chemical weathering of igneous rocks. The AS1 kaolin was probably formed from hydrothermal alteration in the burial stage due to the heating of groundwater by the late volcanism. Mobile trace elements (Sr, Ba, and Eu) exhibited a depletion trend, while immobile elements (Hf, Ta, Th) showed enrichment. The relatively more zirconium in kaolins implies the formation of low-temperature kaolinization. The notably high kaolinite content, accompanied by reasonable levels of Fe2O3 and TiO2, signifies a medium-grade quality. Furthermore, chondrite-normalized rare earth element (REE) patterns exhibit congruent trends in rocks and kaolin samples, indicating a relative enrichment in light rare earth elements (LREEs) alongside a discernible negative Eu anomaly. The abundant kaolinite and silicon–aluminum composition make the kaolins suitable for refractories, pharmaceutics, cosmetics, and supplementary cementitious material (SCM).

Enhanced erosion and silicate weathering of the West African craton during the late Cretaceous cooling evidenced by mineralogical and Hf[sbnd]Nd isotope proxies

The evolution of oceanic temperatures between the Turonian and the K/T boundary indicates a long-term cooling coincident with a decrease of atmospheric CO2 levels, yet the cause of climate cooling at that time still remains debated. In this study, we evaluated the possible implication of enhanced silicate weathering as a sink for atmospheric CO2 by applying paired NdHf isotope measurements to detrital clay records from the West African margin. The use of this novel proxy for chemical weathering intensity (ΔɛHf(t)clay) was complemented by additional mineralogical and major-trace element analyses in order to investigate the variability of mechanical erosion patterns and further explore potential linkages between tectonics, weathering and climate during the late Cretaceous.Our ΔɛHf(t)clay data suggest more intense silicate weathering on the West African Craton during the Santonian to the middle Campanian period, coincident with enhanced physical erosional inputs as inferred from higher Quartz/Clays and Feldspar/Clays ratios. This observation suggests that the shift towards intensified chemical weathering at that time was driven by enhanced mechanical erosion, possibly related to a moderate tectonic event on the West African craton. Evidence for increasing kaolinite contents and higher ΔɛHf(t)clay values during the Maastrichtian point towards more hydrolysing conditions, inducing either destabilization of older Mesozoic lateritic material or favouring the development of kaolinite-rich soils.Overall, this study was compared with several new data of chemical weathering evolution along the south Atlantic margins, adding new insights on tectonic-weathering-climate interactions during the late Cretaceous, suggesting a possible link between silicate weathering feedbacks and global cooling at that time.

Middle Pleistocene weakening of the Indian summer monsoon driven by global cooling

The Indian Monsoon profoundly impacts the climate, agriculture, and economy of the Indian subcontinent and southwestern China. However, the long-term variability of the Indian summer monsoon (ISM) and its forcing mechanism in the context of the stepwise Pleistocene cooling trend are poorly understood, due to the lack of high-quality terrestrial paleoclimate records. Quaternary loess and paleosol deposits in SW China provide the opportunity to study the long-term evolution of the ISM. Based on analyses of magnetic properties and chemical weathering indices, we found that decreased chemical weathering and pedogenic intensity occurred in SW China since the Middle Pleistocene. Comparison of our results with published paleoclimate records from the Indian Ocean and SW China suggest that substantial ISM weakening occurred after ∼0.7–0.6 Ma, coincident with the Mid-Pleistocene climatic transition. We conclude that decreasing global surface temperatures associated with the major growth of Northern Hemisphere ice sheets caused the Middle Pleistocene weakening of the ISM, leading to changes in precipitation regimes in the southern Asian continent and SW China. Our results suggest that global cooling is strongly linked with the South Asian monsoon climate system, and they provide clues for predicting future climate changes in its area of influence.

Geochemistry of Quaternary sediments in the northwestern South China Sea: Sediment provenance and mid-Pleistocene transition

The Quaternary sediments in the northwestern South China Sea (NW-SCS) provide valuable information about provenance, climate and sea level changes. However, the correlation between the geochemical records in marine sediments and these influencing factors remains less understood in the NW-SCS. Two wells penetrated Quaternary sediments on the shelf and shelf margin of the NW-SCS and provide an excellent dataset. In this study, the major, trace, and rare earth elements in the sediments were analyzed to reveal the Quaternary provenance changes that correlate with the climatic Middle Pleistocene transition (MPT). These results indicate that the core sediments were mainly derived from felsic source rocks and the degree of chemical weathering in the source areas is relatively low (CIA averaged at 58). The Quaternary provenance of the NW-SCS did not undergo significant changes, recording mixed sedimentation from the Red River, Hainan Island, and central Vietnamese sources. The felsic source rocks and negative Eu anomaly indicated the shelf area received sediments primarily from the Red River and Hainan Island. However, a positive Eu anomaly on the shelf margin suggests additional contributions from mafic rocks sourced from central Vietnam. During the MPT (1.3–1.4 to 0.8–0.9 Ma), the dominant periodicity of climate cycles changed from a 40 kyr obliquity cycle to a 100 kyr eccentricity cycle; the cooling climate led to a slight weaking in chemical weathering and a minor decrease in sediment supply from terrestrial sources. After the MPT, the mixed sourced sediments in the shelf and shelf margin areas of the NW-SCS likely suffered from multiple hydrodynamic forces under the influence of the Pleistocene high-frequency and high-amplitude sea level fluctuations. These climate induced changes led to significant fluctuations in element content that provide new insights into Quaternary sources and climatic events in the NW-SCS.