Chemical Weathering Research Articles

Intensive chemical weathering in the Arctic during the Miocene Climatic Optimum

The Arctic today has shallow, chemically immature, and frost-dominated weathering regimes. At Sokli, Finland (68°N), a 70 m deep palaeo-weathering profile is developed in a Devonian carbonatite pipe that represents fundamentally different past weathering environments. Formation of the apatite-francolite P-ore likely began under Palaeogene warm, humid climates. Later, cryptomelane (K-Mn oxide) crusts developed within the ore that have yielded peak 40Ar/39Ar ages of 16.20 ± 0.13 Ma (2σ)., The crusts formed at the redox front during the Miocene Climatic Optimum (∼16.9–14.7 Ma) under mean annual temperatures ∼12–14 °C warmer than today. The presence of the cryptomelane crust at shallow depth (15 m) indicates very low erosion rates since formation, consistent with its position on a tectonically stable Archaean craton and in the cold-based ice-divide zone of successive Fennoscandian ice sheets. The Miocene Climatic Optimum triggered a pulse of intensive weathering in mid- and low latitudes; the Sokli cryptomelane ages demonstrate that intensive chemical weathering extended into the Arctic.

Erosional modulation of the balance between alkalinity and acid generation from rock weathering

The balance between alkalinity generation by carbonate and silicate weathering and sulfuric acid generation by sulfide weathering controls the effect of weathering on atmospheric pCO2 over geologic timescales. How this balance varies across environmental gradients remains poorly constrained. Here, we analyze this balance across an erosional gradient of two orders of magnitude in the Three Rivers (Yangtze, Mekong, and Salween Rivers) Headwater Region (TRHR), eastern Qinghai-Tibet Plateau (QTP). By employing major element chemistry and multiple isotopes (δ34SSO4, δ18OSO4, and δ18OH2O) coupled with forward and inverse approaches, we unmix contributions of silicates, carbonates, evaporites, and sulfides to the total weathering budget. Across the TRHR, riverine SO42– is derived mainly from a mixture of an evaporite source with uniform values of δ34SSO4 and δ18OSO4, and a sulfide source that contributes highly variable values of δ34S (−12.2 ‰ to +4.1 ‰) and δ18O (−17.7 ‰ to −1.6 ‰). Contributions of sulfide oxidation to riverine SO42– vary from 16 % to 94 %, and sulfuric acid consumes 6 % to 63 % of the alkalinity produced by weathering. The fractions of weathering alkalinity derived from carbonate weathering range from 36 % to 98 % relative to silicate weathering. The combination of silicate, carbonate, and sulfide weathering suggests that the instantaneous weathering fluxes of most sampled catchments in the TRHR act as a sink of atmospheric CO2 over timescales shorter than marine carbonate burial (∼104 years), but as a carbon source over timescales longer than carbonate burial and shorter than sulfide burial (∼107 years). The spatial variability of the balance between alkalinity and acid generation, and, thus, the relationship between chemical weathering and atmospheric pCO2, are largely dependent on lithology. However, within comparable lithologic settings, sulfide and carbonate weathering rates rise with increasing erosion, whereas silicate weathering rates remain constant. Consequently, plateau weathering shifts from a sink to a source of atmospheric CO2 with increasing erosion. These findings suggest that sulfide weathering is more sensitive to erosion than carbonate and silicate weathering, and that it could play an important role in the long-term carbon cycle during mountain building.

Perspectives from modern hydrology and hydrochemistry on a lacustrine biodiversity hotspot: Ancient Lake Poso, Central Sulawesi, Indonesia

The highly biodiverse Lake Poso, located in Central Sulawesi, Indonesia, can be considered one of the least studied ancient lakes in the world. Here, we present a comprehensive analysis of Lake Poso's hydrology and hydrochemistry, shedding light on factors that may have contributed to the exceptional biodiversity. Riverine and lake water chemical compositions indicated a soft water lake and relative major cation and anion abundances of Ca2+ ≫ Mg2+ > Na+ > K+ and HCO3– ≫ SO42− > Cl−, primarily a result of the high annual precipitation and chemical weathering of calcareous-siliceous metamorphic bedrock. Lake Poso’s nutrient concentrations were low (average DIN/TDP mass ratio of 6.2 and 50.9 for the lake surface water and its tributaries, respectively), indicating that most of the inlets were P-limited and that the lake was likely P-limited as well. Metal pollutants indicated a minor to moderate impact of anthropogenic land use (∼32 % of the catchment area). Water isotopic compositions of the different tributaries clearly delineated rivers draining higher elevation catchments with lower δ2H and δ18O from those draining lower elevation catchments with higher δ2H and δ18O. Surface lake water isotopic compositions indicated detectable evaporation from the lake leading toward more enriched isotope compositions than the integrated source signal. Overall, the findings suggested that Lake Poso remains relatively resilient to anthropogenic land use and related nutrient and pollutant inputs. However, ongoing alterations to its hydrological balance due to significant changes in land use may drive the lake towards higher trophic levels in the future.

Evaluation of three prevalent global riverine nutrient transport models.

Global riverine nitrogen (N) and phosphorus (P) transport models offer important insights into basin nutrient cycling. However, appropriate model selection for a given research objective remains ambiguous. This study conducted a meta-analysis to evaluate the performance and applicability of three prevalent global riverine nutrient transport models: Global NEWS, IMAGE-GNM, and WorldQual. According to performance criteria (satisfactory: R2 > 0.50 and NSE > 0.50), the Global NEWS model performs satisfactorily in simulating dissolved organic nitrogen (DON; n = 101, R2 = 0.58, NSE = 0.57) and dissolved organic phosphorus loads (DOP; n = 80, R2 = 0.59, NSE = 0.59). The model falls short in simulating dissolved inorganic nitrogen (DIN; n = 644, R2 = 0.56, NSE = - 0.80) and dissolved inorganic phosphorus loads (DIP; n = 450, R2 = 0.33, NSE = - 0.12). The IMAGE-GNM model shows satisfactory accuracies in simulating riverine total nitrogen (TN; n = 831, R2 = 0.56, NSE = 0.53) and total phosphorus (TP; n = 902, R2 = 0.59, NSE = 0.48) concentrations, particularly in European basins. The WorldQual model presented unsatisfactory performance in simulating riverine TN (n = 11, R2 = 0.76, NSE = 0.34) and TP (n = 13, R2 = 0.71, NSE = - 0.25) concentrations. Using a two-segment linear model, we recommend the Global NEWS model for basins larger than 2.2 × 104 km2 for DIN and 3.2 × 104 km2 for DIP. The IMAGE-GNM model is best suited for basins with long-term datasets and high latitudes (TN > 21 years and > 53.8 °N; TP > 22 years and > 54.5 °N). For model improvements, both the Global NEWS and WorldQual models could benefit from enhanced in-stream nutrient retention/release modules. The Global NEWS model could be further improved with a better chemical weathering module. For the IMAGE-GNM model, refining the soil erosion module is warranted to enhance model performance. Addressing legacy nutrient effects is crucial for all three models. This study provides valuable guidance for selecting and improving nutrient transport models based on specific research needs.

Architecture of lacustrine deposits in response to early Carboniferous rifting and Gondwanan glaciation, Nova Scotia, south‐east Canada

AbstractUpper Palaeozoic lacustrine basin deposits not only record local tectonism but are also an archive to evaluate global palaeoclimate changes linked to the Late Palaeozoic Gondwanan ice age. The Tournaisian Horton Group of Nova Scotia, south‐east Canada, accumulated in rift basins following the final accretion of peri‐Gondwanan terranes to the Appalachians. Sedimentology, mineralogy and geochemistry of the well‐exposed sandstones and shales at the classic Blue Beach section (ca 353.5 to 352 Ma) reveal the interplay of local tectonism and global climatic controls on lacustrine sedimentation. The lacustrine depositional environment gradually transitioned from deep water offshore at the base of the section to wave‐dominated and fluvial‐dominated nearshore at the top. Multiple small transgressive–regressive sedimentation cycles have an average 21 ka duration, likely related to Milankovitch cyclicity. Unusually abundant soft‐sediment deformation structures and landslides are the sedimentary responses to frequent earthquakes during the most active phase of rift subsidence. The overall succession shows changes from a shallowing‐up balanced‐filled to an overfilled lacustrine basin. The chemical weathering intensity index and the Th/K ratio show a longer‐term trend from dry and cool conditions low in the section to humid and warm conditions near the top, with rapid change in the transition period. The section records the peak of the global mid‐Tournaisian carbon isotope excursion and the corresponding cooling event (354 Ma to approximately 351 Ma). The sedimentary succession is a response to long‐term and short‐term climatic cycles influencing lake level and sediment supply during the time of maximum rift basin subsidence recorded by the soft‐sediment deformation structures.

Red clays indicate sub-aerial exposure of the Rio Grande Rise during the Eocene volcanic episode

Autonomous underwater vehicle (AUV) mapping of the western Rio Grande Rise (RGR), South Atlantic, and subsequent exploration and photography of horizontal lava flows exposed in near vertical, faulted escarpments, showed occurrences of red clays/weathered volcanic tops trapped between successive alkaline lava flows. These red clays indicate a hiatus in successive volcanic eruptions. Here, we report detailed mineralogical, geochemical, and rock magnetic characteristics of one such distinct red clay dredged from ~ 650 m water depth in the western RGR. The mineral constituents of the red clay are kaolinite, magnetite, oxidized magnetite (/maghemite), hematite, and goethite, with biogenic calcite and halite occupying voids or precipitated on the surface of the red clay. The chemical index of alteration (CIA) has a value of 93, showing that red clay is a product of extreme chemical weathering of the lava flows. The alkaline volcanic rocks recovered from nearby show an age of ~ 44 Ma, indicating an Eocene age for the volcanism. We show that the red clays are a product of sub-aerial chemical weathering of these Eocene volcanic rocks, in a warm-wet climate, before the thermal subsidence of the RGR to its modern-day bathymetric depth.

Variations in Mid-Pleistocene glacial cycles: New insights from osmium isotopes

Reconstruction of Pleistocene glacial cycles from oxygen isotope records identifies dramatic changes in both global climate state and ice sheet size. The Mid-Pleistocene Transition (MPT) is an interval during which global ice sheets underwent a major transition from temporally symmetrical 41-thousand-year (kyr) cycles in the Early to Middle Pleistocene to asymmetrical 100-kyr cycles in the Middle to Late Pleistocene. The proposed timing of this transition and potential triggers remains contentious with possible mechanisms ranging from cryosphere dynamics to variations in Earth's energy balance. One suggested driver of the MPT involves the “Regolith Hypothesis”, which proposes that the Laurentide Ice Sheet (LIS) underwent fluctuations in ice sheet stability due to changes in subglacial substrate lithology. To empirically investigate this hypothesis, we use variations in seawater osmium (Os) isotope values from IODP sites U1302 and U1308 over an 800 kyr interval to evaluate changes in basal substrate across this transition. Our Os data identify a lithological shift beneath the LIS during the MPT that resulted in a marked change in the chemical weathering flux delivered to the ocean. We identify a pulse of glacially weathered material reaching the central North Atlantic, likely during the first Heinrich event at Marine Isotope Stage (MIS) 16, in response to increased ice sheet size post MPT. After MIS 16, the Os signal becomes less radiogenic which may correspond to a less extensive “missing glacial” which would have reduced overall weathering fluxes. Our Pleistocene Os isotope record (at ∼15 kyr resolution) contributes to our understanding of subglacial weathering of the LIS across the MPT and helps further constrain the flux of Os to the ocean during glacial-interglacial cycles.

Chemical weathering patterns driven by solar insolation and Indian monsoon in the southern Bay of Bengal since the last glaciation

Chemical weathering patterns driven by solar insolation and Indian monsoon in the southern Bay of Bengal since the last glaciation

Mineralogy and Provenance of Iron Sand Deposits from Cipatujah and Cikalong, Tasikmalaya, West Java, Indonesia

Provenance, paleoweathering, and tectonic environment were studied on the iron sand samples taken from Cipatujah and Cikalong areas in Tasikmalaya, West Java, Indonesia using their mineralogical and geochemical data. These data were obtained from mineralogy grain analysis, X-ray fluorescence, dan ICP MS. From this study, iron sand deposits in both areas vary in grain sizes from very coarse to fine sand. Various minerals, such as magnetite, ilmenite, hematite, pyroxene, amphibole, garnet, quartz, ankerite, plagioclase, and zircon were identified. In addition, rock fragments, fossils, and clay are also found. In term of grain size, the placer deposit is geochemically classified as Fe shale (clay-silt grain size). The provenance shows that the basic rocks act as the source rock based on REE values, heavy mineral assemblage, and elemental ratios. Based on the provenance characteristics, regional geological framework, and catchment area pattern, the Jampang Formation and Young Formation of Mount Cikuray are the most possible sources of iron sand. The chemical index of alteration calculated from major oxide values indicates that the source area had intense chemical weathering. Heavy minerals contained in iron sand deposits reveal a low maturity based on compositional variability (16.58–36.55). Both iron sand deposits from Cipatujah and Cikalong originated in a continental arc setting, which coincides with the current tectonic setting of western Java.

Origins and evolution of two types of Late Triassic granitic magmas in the Caolong-Xiangkariwa area of central-eastern Songpan-Ganze terrane, northern Tibet: Implications for pegmatite lithium mineralization

Pegmatite-type lithium (Li) deposits are an important source of the low-carbon energy metal, which is generally considered to be formed by the high degrees of differentiation of strongly peraluminous granitic magma. However, the question of whether the parental rocks of these peraluminous magmas are igneous or sedimentary has been widely debated. Recent studies have identified a world-class pegmatite-type Li deposit belt (up to 2800 km long) closely associated with the Late Triassic granitoids and (meta)sedimentary rocks along the West Kunlun and Hoh Xil-Songpan-Ganze terranes in northern Tibet. This study presents a comprehensive petrological, geochronological, and geochemical study on the two types of Late Triassic granitoids in the Caolong-Xiangkariwa area of the Yushu region of central-eastern Hoh Xil-Songpan-Ganze terrane in northern Tibet: type A includes the Tongtianhe-Zhenqin-Zhaduo-Zhaya-Xiangkariwa (TZX) diorites and granodiorites (218−212 Ma), and type B includes the Caolong two-mica and muscovite granites (213−205 Ma), as well as ore-barren, beryl-bearing, and spodumene-bearing pegmatite dikes (209−196 Ma). The TZX diorites and granodiorites contain variable amounts of amphibolite and biotite. They are metaluminous to slightly peraluminous with variable SiO2 (54.4−71.3 wt%), MgO (0.72−7.26 wt%) contents, and Mg# values (40−70). Some samples with low SiO2 (54.4−58.5 wt%) contents have geochemical features similar to high-Mg andesites: e.g., high MgO contents (5.24−7.26 wt%) and Mg# values (61−70). The TZX diorites and granodiorites exhibit less enriched (86Sr/87Sr)i (0.7080−0.7118) and εNd(t) (−4.8 to −8.0). By contrast, the Caolong two-mica and muscovite granites are characterized by the occurrence of abundant muscovite (plus tourmaline and garnet) and are strongly peraluminous. The Caolong granites and pegmatites are geochemically characterized by high SiO2 contents (68.8−79.8 wt%) and low MgO contents (0.01−0.10 wt%) and Mg# values (4−23). They have εNd(t) values (−8.8 to −11.4; granites: −8.8 to −10.8; pegmatites: −9.2 to −11.4) that are more enriched than the TZX diorites and granodiorites but similar to those of Songpan-Ganze (meta)sedimentary rocks (−7.4 to −12.9), and the Caolong two-mica granites have high zircon δ18O values (11.6−12.1). In addition, decreasing K/Rb ratios correspond to increasing Cs contents in K-feldspar and muscovite from the Caolong granites and pegmatites. Taking into account the Late Triassic granitoids and (meta)sedimentary rocks in the Hoh Xil-Songpan-Ganze terrane, we suggest that the TZX diorites and granodiorites were most probably formed by the partial melting of metasomatized lithospheric mantle that subsequently underwent extensive fractional crystallization. Conversely, the Caolong two-mica and muscovite granites were likely generated purely by the partial melting of (meta)sedimentary rocks rather than via the evolution of dioritic-granodioritic magmas. In summary, there were two kinds of granitic magmas with different sources in the Caolong-Xiangkariwa area. Finally, the Caolong pegmatites were most likely formed by the extreme differentiation of two-mica granitic magmas rather than the dioritic-granodioritic magmas. Therefore, the evolution of magmas derived from (meta)sedimentary rocks were most likely to have formed the Li-rich pegmatites. Moreover, these (meta)sedimentary rocks representing the ultimate Li source must have undergone strong chemical weathering, resulting in significant Li enrichment.

Controls on long-term denudation rate of carbonate terrains in the Eastern Mediterranean

Quantifying denudation rates under different climatic and tectonic settings is fundamental to understanding landscape evolution. Carbonate rocks may respond differently to climatic and tectonic forcings than other rock types because of their tendency to dissolve congruently. Yet, there is little information on the long-term denudation rate of carbonates and their controlling factors in different settings. Here, we present the first long-term denudation rates for carbonates in the south of the Central Anatolian Plateau. We quantified the outcrop denudation rates using in-situ cosmogenic 36Cl measured in 13 rock samples to evaluate spatial variations and potential controls on the style and rate of denudation. 36Cl-derived denudation rates range from 1.92 ± 0.31 to 45.77 ± 3.91 mm/ka. On the plateau, denudation rates are strongly correlated with precipitation and are lower than the theoretical maximum dissolution rates predicted assuming zero evaporation, implying that climate exerts the major control on carbonate denudation. These results indicate that chemical weathering is the prevalent denudation style. The denudation pattern shows spatial variability with a decreasing trend from SW to NE consistent with climate zones. High-to-moderate denudation rates occur in the continental climate, while the lowest denudation rates occur in the arid plateau interior. In the Mediterranean coastal region, measured denudation rates are higher than the predicted maximum dissolution rates, reflecting the mechanical removal of overlying rock or soil. The low denudation rates in the plateau interior indicate a slowly evolving landscape with an arid climate. The physical properties of rocks showed the weakest control on carbonate denudation.In the Central Taurides, significant infiltration of surface runoff resulted in strong subsurface karstification at the expense of surface drainage. This process caused disequilibrium between uplift and denudation and resulted in the preservation of high-elevation topography. Therefore, in the actively uplifting plateau margin, the influence of tectonics on carbonate denudation has been interfered with the impact of precipitation and subsurface karstification.

Provenance Indication of Rare Earth Elements in Lake Particulates from Environmentally Sensitive Regions

The provenance of lake particulate matter in environmentally sensitive areas is crucial to understanding regional environmental and climatic changes. This study investigated two regions in the Northeast Tibetan Plateau, China: Region I (Keluke, Tuosu, and Gahai Lakes) and Region II (Qinghai Lake and nearby rivers). The results showed that: (1) The two regions have greater differences in the enrichment of rare earth elements (REEs) and heterogeneity in spatial distribution, both of which are characterized by relative enrichment of LREE and depletion of HREE, but to different degrees; (2) the source and formation of particulate matter in two regions are consistent. Particulate matter in Region I (Keluke and Tuosu Lakes) predominantly originates from granite rocks, which undergo weathering and transportation through rivers. Region II (Qinghai Lake and nearby rivers) particulate matter is affected by chemical weathering and partial recycling of detrital material. Diagenesis had a minimal impact on the particulate REEs. (3) This study primarily provides a preliminary understanding of REEs in lake particles, assessing particle changes during the water-to-sediment process and their provenance indication. Future studies will incorporate the solid fugacity (solid speciation) of REEs in particles, contributing to a comprehensive understanding of rare earth element geochemical processes. This study provides valuable insights into REEs distribution, source, and geochemical behavior in the Tibetan Plateau, underscoring the importance of REEs in understanding provenance processes, and is indicative of provenance studies in other climate change-sensitive regions of the world.

Purple soil inheritance and source of parent rock material and tectonic background in the Sichuan Basin, China

ABSTRACT The parent rock inheritance of the purple soils in the Sichuan Basin is evident, and this is due to factors that are directly related to the parent rocks’ characteristics. Fundamentally, the nature of purple soils is determined by the lithology, chemical composition, weathering, and soil formation of parent rocks, whereas the provenance, and tectonic context of rocks during their diagenesis have a significant influence on their rock attributes. In this study, rocks from four sedimentary layers of the Cretaceous and Jurassic eras – k1c, J3p, J3s, J2s in the Sichuan Basin – as well as the overlying soils were examined, and experimental determinations of the samples’ physical characteristics and chemical elemental composition were made to confirm the parent rock inheritance of purple soils. The essential weathering indices ICV, CIAcorr, WIP, and Na/K were used to study the weathering characteristics of the rocks and soils, and the A-CN-K ternary diagram was used to assess the weathering trends of the rocks. The findings demonstrate that purple soil exhibits significant parent rock inheritance due to its rapid physical soil formation process and weak chemical weathering process. That the rocks of the four sedimentary layers in the study area have all reached a moderate degree of weathering, their original source components are quartzose sedimentary which may have been derived from feldspar source rocks. The tectonic background of the source rocks may be mainly continental arc and active continental margin environment, there may be an oceanic arc tectonic environment.

Dynamic redox and nutrient cycling response to climate forcing in the Mesoproterozoic ocean

Controls on Mesoproterozoic ocean redox heterogeneity, and links to nutrient cycling and oxygenation feedbacks, remain poorly resolved. Here, we report ocean redox and phosphorus cycling across two high-resolution sections from the ~1.4 Ga Xiamaling Formation, North China Craton. In the lower section, fluctuations in trade wind intensity regulated the spatial extent of a ferruginous oxygen minimum zone, promoting phosphorus drawdown and persistent oligotrophic conditions. In the upper section, high but variable continental chemical weathering rates led to periodic fluctuations between highly and weakly euxinic conditions, promoting phosphorus recycling and persistent eutrophication. Biogeochemical modeling demonstrates how changes in geographical location relative to global atmospheric circulation cells could have driven these temporal changes in regional ocean biogeochemistry. Our approach suggests that much of the ocean redox heterogeneity apparent in the Mesoproterozoic record can be explained by climate forcing at individual locations, rather than specific events or step-changes in global oceanic redox conditions.

Comparative C, N, and S cycling along a Californian grassland chronosequence

Carbon (C), nitrogen (N), and sulfur (S) are elements strongly influenced by biological cycling and redox reactions in soils, but few comparative analyses have investigated the behaviors of these elements with time. Thus, we examined changes in content and isotope composition of soil profiles along a chronosequence (58–212 kyr) of marine terraces on the central California coast, in an area with significant background geochemical research. Unlike in other chronosequences in more humid locations, the total C, N, and S in these soils did not vary strongly with age, possibly due to the retention of phosphorus (P). The total pools of soil N and S cannot be explained by wet deposition of NO3 and SO4 alone, suggesting other sources of atmospheric inputs such as NH4+ and dimethyl sulfide. Total C and N declined in a characteristic logarithmic pattern with depth, while S did not. The ratio of extractable soil nitrate (NO3) to total N declined with depth, suggesting strong biological demand via various avenues. In contrast, the ratio of extractable sulfate (SO4) to total S increased with depth, suggesting that S was in biological excess. We used a simple reactive transport model to integrate the depth profiles of total C and N and their isotope values. The depth trends of total concentrations suggested one-pool residence times of approximately 500 to 1000 y, consistent with turnover times calculated by mass balance. Depth trends of stable isotope values indicated that N is isotopically fractionated at a magnitude twice that of C, consistent with observed 15N-depleted nitrous oxide (N2O) emissions during the dry summer months. The isotope composition of S (total and SO4) suggests some isotope enrichment during biogeochemical cycling, but far less than observed for N. Thus, despite significant chemical weathering and elemental loss over time, the biogeochemical cycles of C, N, and S remain relatively unaffected by soil age in this climatic setting.

Spatial and temporal distribution of geochemical elements and their processes in different size fractions–Miri River (NW Borneo)

The toxicity, persistence, and propensity for accumulation of metals in aquatic environments have raised significant concerns globally. Expansion of urbanization with the growth of industrial and agricultural sectors in Miri City results in a high concentration of pollutants that flow directly into the Miri River. Hence, this study provides a comprehensive analysis of the Miri River water quality, focusing on spatial and temporal variations. River water samples were collected in two different time periods and analysed for physico-chemical parameters includes major ions, nutrients, metals and isotopes. Particularly, the metals were analysed in different size fractions (particulate and colloid) of the suspended solids. Geochemical plots, pollution index, geochemical modelling and factor analysis were used for the data analysis. Interpretation of data reveals that the mean concentration of metals in river water were increased from downstream to the upstream of the river irrespective of the seasons. Major ions were mostly derived from the chemical weathering of source rocks, which was supported by the Gibbs plot. Piper plot indicates the seasonal shifting of water types from Ca–Mg to Na–Cl. Isotopic signatures reveal direct atmospheric precipitation and evaporation were the major origins of river water. Fe was the dominant metal concentration in river water irrespective of the seasons (mean concentration 1.05 mg/L). Fe and Zn were the dominant metal concentration observed in all the 3 size fractions of suspended solids. Industrial activities and seawater influx dominate in the downstream, whereas weathering and agricultural inputs are significant in the upstream of the river. Particulate and colloidal fractions are the major contributors for the metal transport in the midstream and downstream of the river. The outcome of this study offer a thorough understanding of the seasonal elemental distribution at different size fractions, geochemical behaviour and the pollution status of the Miri River. With this knowledge, sustainable management strategies can be developed for this crucial water resource to the benefit of Miri community.

Genetic implications of Th/U, Th/K, and U/K ratios for U mineralizations: A case study from El-Missikat and El-Erediya shear zones, Eastern Desert, Egypt

The current work is an attempt to reveal the possible utilization of the radiometric measurements to build-up a complete genetic scenario for magmatic, hydrothermal, and supergene uranium mineralization. For this purpose, ground gamma-ray survey was performed through the exploratory tunnels dug perpendicular to El-Missikat and El-Erediya shear zones, the Central Eastern Desert of Egypt. Contents of U, Th, and K were measured for the host pink granite (e.g., avg.15.94 U ppm, 35.62 Th ppm, and 6.63% K), alteration zones (brecciation, silicification, greisenization, kaolinization and hematitization) (e.g., avg. 124.01 U ppm, 63.67 Th ppm, and 3.13% K), and mineralized silica veins (e.g., avg. 312.65 U ppm, 92.22 Th ppm, and 2.62% K). All of these data were graphically represented as correlation plots of Th vs. U, Th/U vs. U, Th vs. K, and U/K vs. Th/K. The overall results indicate magmatic, hydrothermal, and supergene sources of El-Missikat and El-Erediya U mineralization. The magma-derived U contents are enclosed mainly in the pink granite that is mostly characterized by normal Th/U (2.5–5) and Th/K ratios (3–5*10–4). The hydrothermal processes through the alteration zones and mineralized silica veins are reflected by the weak correlation of Th with U (e.g. r = 0.13 and − 0.39), the strong negative correlation of Th/U ratio with U (e.g. r = − 0.82), 2.5˃Th/U˃0.1, Th/K˃5*10–4, Th/K < 3*10–4, and the strong positive correlation of U/K with Th/K (e.g. r = 0.91) as well as the occurrence of thorite, columbite, xenotime and hydrothermal zircon (0.5 > Th/U ≤ 0.1). Afterwards, the hydrothermal mineralization underwent some degrees of chemical weathering that resulted in supergene U mineralization whose fingerprints can be traced by the occurrence of secondary U minerals (e.g. kasolite and uranophane), Th/U ratios ≤ 0.1, and the weak correlation between Th/K and U/K (e.g. r = 0.39 and − 0.11).

Anomalous weathering trends during the Early Silurian warming: Implications for the biotic crisis and recovery

The Late Ordovician mass extinctions were divided into two distinct stages, with the second stage occurring during the Late Hirnantian. However, biotic recovery was delayed until the Aeronian and the triggering factors are still unknown. To comprehend the connections between paleoclimate, marine redox states, and biotic recovery in the Early Silurian, we analyzed temporal variations in chemical weathering intensity using multi-geochemical proxies for the shales of the Longmaxi Formation in South China. The results reveal a significant increase in chemical weathering intensity from the Rhuddanian warming phase to the Aeronian cooling phase. This increase is anomalous, considering it coincides with the Early Silurian's climate cooling. This study posits that Rhuddanian sediments exhibited low chemical weathering intensity and more congruent weathering, while Aeronian sediments were characterized by intermediate chemical weathering intensity and incongruent weathering. Given that the gradual enrichment of oxygen within bottom waters can be supported by Corg/P and Corg-S-Fe, this study suggests that congruent weathering-induced high paleoproductivity is the primary factor accelerating anoxia in the Rhuddanian. In summary, the persistent marine anoxia of seawater thus triggered the deposition of organic-rich shales and delayed biotic recovery in the Rhuddanian.

Development of a lateral topographic weathering gradient in temperate forested podzols

Mineral weathering is an important soil-forming process driven by the interplay of water, organisms, solution chemistry, and mineralogy. The influence of hillslope-scale patterns of water flux on mineral weathering in soils is still not well understood, particularly in humid postglacial soils, which commonly harbor abundant weatherable primary minerals. Previous work in these settings showed the importance of lateral hydrologic patterns to hillslope-scale pedogenesis. In this study, we hypothesized that there is a corresponding relationship between hydrologically driven pedogenesis and chemical weathering in podzols in the White Mountains of New Hampshire, USA. We tested this hypothesis by quantifying the depletion of plagioclase in the fine fraction (≤2 mm) of closely spaced, similar-age podzols along a gradient in topography and depth to bedrock that controls lateral water flow. Along this gradient, laterally developed podzols formed through frequent, episodic flushing by upslope groundwater, and vertically developed podzols formed through characteristic vertical infiltration. We estimated the depletion of plagioclase-bound elements within the upper mineral horizons of podzols using mass transfer coefficients (τ) and quantified plagioclase losses directly through electron microscopy and microprobe analysis. Elemental depletion was significantly more pronounced in the upslope lateral eluvial (E horizon-dominant) podzols relative to lateral illuvial (B horizon-dominant) and vertical (containing both E and B horizons) podzols downslope, with median Na losses of ∼74 %, ∼56 %, and ∼40 %, respectively. When comparing genetic E horizons, Na and Al were significantly more depleted in laterally developed podzols relative to vertically developed podzols. Microprobe analysis revealed that ∼74 % of the plagioclase was weathered from the mineral pool of lateral eluvial podzols, compared to ∼39 % and ∼23 % for lateral illuvial podzols and vertically developed podzols, respectively. Despite this intense weathering, plagioclase remains the second most abundant mineral in soil thin sections. These findings confirm that the concept of soil development as occurring vertically does not accurately characterize soils in topographically complex regions. Our work improves the current understanding of pedogenesis by identifying distinct, short-scale gradients in mineral weathering shaped by local patterns of hydrology and topography.

Effect of damming on hydrogeochemical characteristics and potential environmental risks in a large reservoir: Insights from different vertical layer sampling

The water environment of large reservoirs is fragility due to effects from hydrological regulation of damming and anthropogenic inputs. As a critical path to quantify the natural chemical weathering and assess environmental risks, solute chemistry of river has been widely focused on. However, the complexed hydrological conditions of large reservoir affect the chemical compositions, and the significance of solute vertical geochemistry as an indicator of chemical weathering and water quality health remains explore. Therefore, the Three Gorges Reservoir (TGR) was selected as a typical study area, which is the world's largest hydropower project and subject to frequent water quality problems. Then, the chemical compositions in stratified water were determined. Ca2+ (52.8 ± 4.3 mg/L) and HCO3− (180.9 ± 8.9 mg/L) were the most abundant ions among cations and anions, respectively. Incremental mean concentration of total major ions followed with the increase of riverine depth and flow direction. An improved inversion model was used to quantify the source contribution, which weathering of dolomite (34%) and calcite (38%) contributed the most to total cations, and the influences of agriculture and sewage discharge were limited. Additional contributions of evaporite and pyrite oxidation were found in analysis of deeper water samples, which also results in 2%–67% difference in estimated CO2 release flux using data from different depth, indicating additional information about sulfuric acid driven weathering was contained. Finally, the water quality of the reservoir was assessed for irrigation and non-carcinogenic risks. Results showed the stratified water of TGR can be used as a good water source of irrigation. However, NO3− (5.1 ± 1.1 mg/L) may have a potential non-carcinogenic risk to children, especially in surface water. To sum up, this study provided an indispensable supplement to the water chemistry archives in the TGR basin, serving as theoretical references for environmental management of large reservoirs.