Volume Expansion Research Articles

Ohmic baking of gluten free sponge cake: Analysis of technological and quality characteristics

The demand of gluten-free bakery products is worldwide increasing. Simultaneously, ohmic heating is an alternative heating technology that still deserves further research and development. Therefore, the aim of this work was assessing different technological and quality characteristics of gluten free sponge cake baked by ohmic heating. A custom ohmic system was designed and built and different electric field strengths (1500, 2000 and 2500 V/m) were tested. Conventional baking was performed for comparison purposes. The conventional baking time was 24 min, whilst the ohmic heating time ranged from 3.51 min at 2500 V/m to 7.93 min at 1500 V/m. The ohmic system achieved significantly higher energy efficiencies, reaching nearly 60%, compared to only 4.1% for conventional baking. Additionally, specific energy consumption was significantly lower for ohmic heating. Weight loss was higher for ohmically processed samples, showing larger number of pores in their inner spongy structure. Ohmic heating resulted in a larger volume expansion and a cake with lower density. The remaining quality characteristics, such as color, hardness, cohesiveness, and elasticity, were not significantly different. Results demonstrated that ohmic heating is a suitable technology for baking gluten-free sponge cakes and that it is a promising technology for fast industrial baking of such products.

Study on strength deterioration mechanism of foamed concrete under freeze-thaw cycles: Experiment and numerical simulation

In cold regions, freeze-thaw (F-T) cycles pose a severe challenge to the long-term durability and structural reliability of foamed concrete (FC). In response, this study proposes a comprehensive multi-level evaluation system integrating macro and micro scales, aiming to thoroughly investigate the decline mechanisms of compressive strength of FC under F-T cycles. Through macroscopic experiments, the extent of mass loss and strength degradation has been quantified. The evolution of internal damage, progression of surface displacements, and changes in pore structures have been effectively tracked and captured by using non-contact techniques. The findings reveal that after F-T cycles, the mass loss rate and strength loss rate of FC can be up to 6.62 % and 37.61 %, respectively. There is a marked acceleration in the expansion rate of non-stable internal cracks; peak displacements show significant growth, and the failure mode changed from brittle to brittle-ductile. Furthermore, the porosity and the proportion of irregular pore shapes have increased by 25.84 % and 18.39 %, respectively. Additionally, a discrete element model incorporating irregular pore characteristics has been established, elucidating the profound impact of F-T cycles from a microscopic physical perspective. Specifically, the weakening and the increased number of fracture events of the contact forces between cement particles lead to the deterioration of FC's strength.

3D Bismuth@N-Doped carbon microflowers for ultrahigh rate and stable sodium storage

Sodium-ion batteries (SIBs) are gaining attention in the energy storage market due to their high theoretical capacity and affordability. However, challenges such as volume expansion and sluggish dynamics during sodiation/desodiation hinder their practical application. A 3D bismuth@N-doped carbon microflowers (Bi@NC) anode was successfully prepared to address these issues. The Bi nanosheets expedite Na ions and electrons transport and inhibit particle pulverization, while the N-doped carbon layer maintains electrode stability and improves electronic conductivity. The Bi@NC anode exhibits ultrahigh rate (336.7 mAh/g at 20 A/g) and stable performance (92.9% capacity retention after 2500 cycles at 5 A/g).

Elucidating the role of magnesium in alkali-silica reaction: Performance and mechanisms

Alkali-silica reaction (ASR) is a major concrete deterioration causing volume expansion, cracking, and hence degradations in the strength and permeability of concrete structures. Despite a variety of ASR mitigation approaches having been investigated, the successful use of chemical admixture is limited to lithium salts, which have negative impacts on cement hydration and shrinkage behavior of concrete. To explore alternative substances for effective and economic ASR mitigation, the role of magnesium nitrate in mortars containing reactive aggregate is investigated at varying Mg/alkali ratios from 0 to 3.0 in terms of volume expansion, cracking behavior, silica dissolution, and modifications of ASR products. The results indicate that, at a Mg/alkali ratio of 0.74, the expansion and surface cracking density of the ASR-impacted mortar were decreased by 21.1 % and 39.1 %, respectively, which is superior to the efficacy of lithium nitrate. The 51.3 % less silica dissolution from aggregate, suppressed ASR gel formation, fewer Q3 polymerization sites in the silicate chains, less packed structure, and reduced alkali/Si ratio of the reaction products elucidate the underlying mechanisms across multiple length scales.

Interlayer Structure Manipulation of FeOCl/MXene with Soft/Hard Interface Design for Safe Water Production Using Dechlorination Battery Deionization

AbstractSuffering from the susceptibility to decomposition, the potential electrochemical application of FeOCl has greatly been hindered. The rational design of the soft‐hard material interface can effectively address the challenge of stress concentration and thus decomposition that may occur in the electrodes during charging and discharging. Herein, interlayer structure manipulation of FeOCl/MXene using soft‐hard interface design method were conducted for electrochemical dechlorination. FeOCl was encapsulated in Ti3C2Tx MXene nanosheets by electrostatic self‐assembly layer by layer to form a soft‐hard mechanical hierarchical structure, in which Ti3C2Tx was used as flexible buffer layers to relieve the huge volume change of FeOCl during Cl− intercalation/deintercalation and constructed a conductive network for fast charge transfer. The CDI dechlorination system of FeOCl/Ti3C2Tx delivered outstanding Cl− adsorption capacity (158.47 ± 6.98 mg g−1), rate (6.07 ± 0.35 mg g−1 min−1), and stability (over 94.49 % in 30 cycles), and achieved considerable energy recovery (21.14 ± 0.25 %). The superior dechlorination performance was proved to originate from the Fe2+/Fe3+ topochemical transformation and the deformation constraint effect of Ti3C2Tx on FeOCl. Our interfacial design strategy enables a hard‐to‐soft integration capacity, which can serve as a universal technology for solving the traditional problem of electrode volume expansion.

A gradient-distributed binder with high energy dissipation for stable silicon anode

Silicon is considered as a promising alternative to traditional graphite anode for lithium-ion batteries. Due to the dramatic volume expansion of silicon anode generated from the insertion of Li+ ions, the binder which can suppress the severe volume change and repeated massive stress impact during cycling is required greatly. Herein, we design a gradient-distributed two-component binder (GE-PAA) to achieve excellent cyclic stability, and reveal the mechanism of high energy dissipative binder stabilized silicon electrodes. The inner layer of the electrode is the polyacrylic acid polymer (PAA) with high Young’s modulus, which is used as the skeleton binder to stabilize the silicon particle interface and the electrode structure. The outer layer is the gel electrolyte polymer (GE) with lower Young’s modulus, which releases the stress generated during the lithiation and de-lithiation process effectively, achieving the high structural stability at the molecular level and silicon particles. Due to the synergistic effect of the gradient binder design, the silicon electrode retains a reversible capacity of 1557.4 mAh g-1 after 200 cycles at the current density of 0.5 C and 1539.2 mAh g-1 at a high rate of 1.8 C. This work provides a novel binder design strategy for Si anode with long cycle stability.

Interlayer Structure Manipulation of FeOCl/MXene with Soft/Hard Interface Design for Safe Water Production Using Dechlorination Battery Deionization.

Suffering from the susceptibility to decomposition, the potential electrochemical application of FeOCl has greatly been hindered. The rational design of the soft-hard material interface can effectively address the challenge of stress concentration and thus decomposition that may occur in the electrodes during charging and discharging. Herein, interlayer structure manipulation of FeOCl/MXene using soft-hard interface design method were conducted for electrochemical dechlorination. FeOCl was encapsulated in Ti3C2Tx MXene nanosheets by electrostatic self-assembly layer by layer to form a soft-hard mechanical hierarchical structure, in which Ti3C2Tx was used as flexible buffer layers to relieve the huge volume change of FeOCl during Cl- intercalation/deintercalation and constructed a conductive network for fast charge transfer. The CDI dechlorination system of FeOCl/Ti3C2Tx delivered outstanding Cl- adsorption capacity (158.47 ± 6.98 mg g-1), rate (6.07 ± 0.35 mg g-1 min-1), and stability (over 94.49% in 30 cycles), and achieved considerable energy recovery (21.14 ± 0.25%). The superior dechlorination performance was proved to originate from the Fe2+/Fe3+ topochemical transformation and the deformation constraint effect of Ti3C2Tx on FeOCl. Our interfacial design strategy enables a hard-to-soft integration capacity, which can serve as a universal technology for solving the translational problem of electrode volume expansion.

Gradient lithiophilic structure for the homogenized electric field strength to achieve dendrite-free lithium metal anode

Uncontrolled dendrite growth restricts the application of lithium metal battery as next-generation batteries. Herein, a 3D gradient lithiophilic framework (CuxO-Ag@CNFs) was constructed by multi-step electrochemical deposition. The symmetric cell can work steadily for 1000 h under low voltage hysteresis conditions at high current and large capacity (10 mA cm−2, 10 mAh cm−2). DFT calculation confirms the difference of lithiophilicity between CuxO, Ag and CuxO-Ag. The gradient structure of CuxO-Ag@CNFs was demonstrated by multiple structural characterization. COMSOL was used to simulate the distribution trend of Li+ concentration and electric field strength on the surface of the framework and verify the role of the composite material in homogenizing the electric field strength. The excellent performance of Li metal composite anode was attributed to the gradient distribution of CuxO and Ag on the CNFs with good lithiophilic property, which can achieve uniform local current density, form a stable SEI layer of Li2O and confine volume expansion ability of Li. Finally, LiFePO4 and CuxO-Ag@CNFs-Li were used as cathode and anode respectively, in full cell, which exhibited the potential for practical applications with superior cycling stability and good rate performance.

Sound waves and solutions: Point-of-care ultrasonography for acute kidney injury in cirrhosis

This article delves into the intricate challenges of acute kidney injury (AKI) in cirrhosis, a condition fraught with high morbidity and mortality. The complexities arise from distinguishing between various causes of AKI, particularly hemodynamic AKI, in cirrhotic patients, who experience hemodynamic changes due to portal hypertension. The term "hepatocardiorenal syndrome" is introduced to encapsulate the intricate interplay among the liver, heart, and kidneys. The narrative emphasizes the often-overlooked aspect of cardiac function in AKI assessments in cirrhosis, unveiling the prevalence of cirrhotic cardiomyopathy marked by impaired diastolic function. The conventional empiric approach involving volume expansion and vasopressors for hepatorenal syndrome is critically analyzed, highlighting potential risks and variable patient responses. We advocate for a nuanced algorithm for AKI evaluation in cirrhosis, prominently featuring point-of-care ultrasonography (POCUS). POCUS applications encompass assessing fluid tolerance, detecting venous congestion, and evaluating cardiac function.

A hybrid thermo-mechanical phase-field model for anisotropic brittle fracture

The phase-field modeling approach is integrated with the isogeometric-meshfree approach to investigate the coupled thermo-mechanical fracture behaviors of composite materials, accounting for material anisotropy. The present approach is formulated within a thermodynamic framework, exploring the effects of both thermal and mechanical factors on crack evolution. The crack driving force in composites is determined by the collective contributions from both fibers and the matrix. Moreover, a hybrid computational framework, enhanced with an adaptive mesh refinement technique, is proposed for the efficient implementation of thermo-mechanical fracture. Finally, simulations of the thermal deformation and fracture processes in both homogeneous and composite materials are implemented to verify the present approach. The impact of the weak material anisotropy, such as anisotropic thermal conductivity and material strength, along with the strong anisotropy coefficient on fracture patterns in orthotropic composites is also investigated. The simulation results demonstrate that the developed approach can predict complex failure patterns in composites under thermo-mechanical loading, thus offering insights for the design of composites.

Epigenetic and proteomic signatures associate with clonal hematopoiesis expansion rate.

Clonal hematopoiesis of indeterminate potential (CHIP), whereby somatic mutations in hematopoietic stem cells confer a selective advantage and drive clonal expansion, not only correlates with age but also confers increased risk of morbidity and mortality. Here, we leverage genetically predicted traits to identify factors that determine CHIP clonal expansion rate. We used the passenger-approximated clonal expansion rate method to quantify the clonal expansion rate for 4,370 individuals in the National Heart, Lung, and Blood Institute (NHLBI) Trans-Omics for Precision Medicine (TOPMed) cohort and calculated polygenic risk scores for DNA methylation aging, inflammation-related measures and circulating protein levels. Clonal expansion rate was significantly associated with both genetically predicted and measured epigenetic clocks. No associations were identified with inflammation-related lab values or diseases and CHIP expansion rate overall. A proteome-wide search identified predicted circulating levels of myeloid zinc finger 1 and anti-Müllerian hormone as associated with an increased CHIP clonal expansion rate and tissue inhibitor of metalloproteinase 1 and glycine N-methyltransferase as associated with decreased CHIP clonal expansion rate. Together, our findings identify epigenetic and proteomic patterns associated with the rate of hematopoietic clonal expansion.

Soft-in-Rigid Strategy Promoting Rapid and High-Capacity Lithium Storage by Chemical Scissoring.

Large and rapid lithium storage is hugely demanded for high-energy/power lithium-ion batteries; however, it is difficult to achieve these two indicators simultaneously. Sn-based materials with a (de)alloying mechanism show low working potential and high theoretical capacity, but the huge volume expansion and particle agglomeration of Sn restrict cyclic stability and rate capability. Herein, a soft-in-rigid concept was proposed and achieved by chemical scissoring where a soft Sn-S bond was chosen as chemical tailor to break the Ti-S bond to obtain a loose stacking structure of 1D chain-like Sn1.2Ti0.8S3. The in situ and ex situ (micro)structural characterizations demonstrate that the Sn-S bonds are reduced into Sn domains and such Sn disperses in the rigid Ti-S framework, thus relieving the volume expansion and particle agglomeration by chemical and physical shielding. Benefiting from the merits of large-capacity Sn with an alloying mechanism and high-rate TiS2 with an intercalation mechanism, the Sn1.2Ti0.8S3 anode offers a high specific capacity of 963.2 mA h g-1 at 0.1 A g-1 after 100 cycles and a reversible capacity of 250 mA h g-1 at 10 A g-1 after 3900 cycles. Such a strategy realized by chemical tailoring at the structural unit level would broaden the prospects for constructing joint high-capacity and high-rate LIB anodes.

Nano-cutting mechanism of ion implantation-modified SiC: reducing subsurface damage expansion and abrasive wear

This study utilized ion implantation to modify the material properties of silicon carbide (SiC) to mitigate subsurface damage during SiC machining. The paper analyzed the mechanism of hydrogen ion implantation on the machining performance of SiC at the atomic scale. A molecular dynamics model of nanoscale cutting of an ion-implanted SiC workpiece using a non-rigid regular tetrakaidecahedral diamond abrasive grain was established. The study investigated the effects of ion implantation on crystal structure phase transformation, dislocation nucleation, and defect structure evolution. Results showed ion implantation modification decreased the extension depth of amorphous structures in the subsurface layer, thereby enhancing the surface and subsurface integrity of the SiC workpiece. Additionally, dislocation extension length and volume within the lattice structure were lower in the ion-implanted workpiece compared to non-implanted ones. Phase transformation, compressive pressure, and cutting stress of the lattice in the shear region per unit volume were lower in the ion-implanted workpiece than the non-implanted one. Taking the diamond abrasive grain as the research subject, the mechanism of grain wear under ion implantation was explored. Grain expansion, compression, and atomic volumetric strain wear rate were higher in the non-implanted workpiece versus implanted ones. Under shear extrusion of the SiC workpiece, dangling bonds of atoms in the diamond grain were unstable, resulting in graphitization of the diamond structure at elevated temperatures. This study established a solid theoretical and practical foundation for realizing non-destructive machining at the atomic scale, encompassing both theoretical principles and practical applications.

Thermal spalling failure mechanism of heterogeneous granite under moving heat source

The conventional mechanical methods employed for rock breaking encounter substantial challenges in deep, hard formation drilling, characterized by low penetration rates and exorbitant drilling costs. Consequently, there exists an urgent necessity to explore novel drilling methods and technologies. Thermal spallation drilling, as a non-contact rock breaking technique, offers high efficiency in rock fragmentation and substantially reduces drilling costs. However, the mechanism underlying rock fragmentation induced by thermal spallation remains unclear. Therefore, this study establishes a thermo-mechanical coupling model based on heterogeneous granite subjected to a high-temperature moving heat source. The model comprehensively considers the geometric shape, contact, and strength heterogeneity of rock minerals, and analyzes the effects of heating source speed, radius, mineral composition, heterogeneity index, and grain size on the thermal spallation mechanism of rock. The research findings indicate that lower heating source speeds and larger radii result in higher surface temperatures and greater damage volumes, whereas increasing speed and reducing radius enhance fragmentation efficiency, with speed exerting a more significant influence. Thermal spallation primarily results in tensile damage to rocks, with the surface damage and depth of damage being respectively influenced by the heating source speed and radius. Particle size exhibits minimal impact on thermal spallation, while increased quartz content enhances the rock's thermal properties, resulting in significant thermal spallation effects. Additionally, the location of rock damage is closely correlated with thermal parameters. These findings significantly contribute to a better understanding of the thermal spallation fracture mechanism in granite and facilitate the development of technical solutions for thermal spallation drilling methods.

Ultrastable Organic Anode Enabled by Electrochemically Active MXene Binder toward Advanced Potassium Ion Storage.

Conjugated carbonyl compounds are regarded as promising organic anode materials for potassium ion batteries (PIBs) due to their rich redox sites, excellent reversibility, and structural tunability, but their low electrical conductivity and severe solubility in organic electrolytes have substantially restricted their practical application. Herein, 2D MXene is utilized as an electrochemically active binder to fabricate perylene-3,4,9,10-tetracarboxylic dianhydride (PTCDA) electrodes for high-performance PIBs. MXene, coupled with Super-P particles, served as a binder and conductive matrix to facilitate rapid ion and electron transport, restrain the solubility of PTCDA, promote potassium adsorption, and alleviate the volume expansion of PTCDA during potassiation. Consequently, the PTCDA electrode bonded by the MXene/Super-P system delivers excellent potassium storage performance in terms of a high capacity of 462 mAh g-1 at 50 mA g-1, superior rate capability of 116.3 mAh g-1 at 2000 mA g-1, and stable cycle performance over 3000 cycles with a low capacity decay rate of ∼0.0033% per cycle. When configured with the PTCDA@450 cathode, an all-PTCDA potassium ion full cell delivers a maximum energy density of 179.5 Wh kg-1, indicating the superiority of MXene as an electrochemically active binder to promote the practical application of organic anodes for PIBs.

Exploring the influence of carbonate minerals on the performance, volume stability, and phase composition of alkali‐activated waste glass binder at high temperatures

AbstractAlkali‐activated waste glass (AA‐WG) has received much attention because to its high mechanical properties achieved with low energy demand. However, AA‐WG exhibits low stability, including volume expansion, porosity increment, and a reduction in compressive strength. Enhancing the stability of AA‐WG could improve its commercial viability and expand its range of applications. Therefore, this study aims to evaluate the role of calcite CaCO3 (CC) and magnesite MgCO3 (MC) in enhancing the physicomechanical properties and phase composition of AA‐WG at elevated temperatures. The proposed strategy includes replacing WG with different contents of CC and MC, followed by activation with a 4 M NaOH solution and curing at 100°C for 24 h. The hardened samples were then exposed to 800°C for a 2 h holding time to evaluate the thermal stability of the AA‐WG, AA‐WG‐CC, and AA‐WG‐MC mixtures. The results demonstrated that increasing the CC content up to 50 wt.% significantly enhanced the compressive strength of the AA‐WG when cured at 100°C, while the incorporation of MC caused a negative effect. Surprisingly, an opposite trend was observed at a higher temperature of 800°C, where the samples containing MC exhibit better mechanical and physical performance compared to those with CC. The variation in the type, composition, and weight loss upon ignition of the carbonate‐based minerals significantly influenced the stability and phase composition of the thermally exposed AA‐WG. Although the sample with 50 wt.% MC showed higher volume shrinkage, it demonstrated higher compressive strength (~82 MPa) at 800°C than the sample with 50 wt.% CC (~7 MPa). This difference can be attributed to the formation of diopside CaMgSi2O6 and forsterite Mg2SiO4, which have higher crystallinity, specific gravity, and hardness compared to wollastonite CaSiO3 and the tri‐calcium silicate phases Ca3SiO4.

Towards Cosmography of the Local Universe

Anisotropies in the distance-redshift relation of cosmological sources are expected due to large-scale inhomogeneities in the local Universe. When the observed sources are tracing a large-scale matter flow in a general spacetime geometry, the distance-redshift relation with its anisotropies can be described with a geometrical prediction that generalises the well-known Friedmann-Lemaître-Robertson-Walker result. Furthermore, it turns out that a finite set of multipole coefficients contain the full information about a finite-order truncation of the distance-redshift relation of a given observer. The multipoles of the distance-redshift relation are interesting new cosmological observables that have a direct physical interpretation in terms of kinematical quantities of the underlying matter flow. Using light cones extracted from N-body simulations we quantify the anisotropies expected in a Λ cold dark matter cosmology by running a Markov chain Monte Carlo analysis on the observed data. In this observational approach the survey selection implements an implicit smoothing scale over which the effective rest frame of matter is fitted. The perceived anisotropy therefore depends significantly on the redshift range and distribution of sources. We find that the multipoles of the expansion rate, as well as the observer’s velocity with respect to the large-scale matter flow, can be determined robustly with our approach.

Tuning Perovskites’ Hydration-Induced Chemical Expansion with Octahedral Tilt Angles

Tuning Perovskites’ Hydration-Induced Chemical Expansion with Octahedral Tilt Angles

Multiscale structural engineering of Co0.85Se@porous carbon composite enables highly reversible lithium/sodium storage

Cobalt selenide (Co0.85Se) has been regarded as the most potential anode material for both lithium/sodium ion batteries (LIBs and SIBs) due to its high specific capacity and excellent pseudocapacitive effect. However, the inevitable volume expansion during conversion reaction and grievous dissolution of Se in electrolytes seriously undermine its reversibility and cycling stability. Combining the transition-metal chalcogenides with stable porous carbon networks is considered as one of the most effective strategies to improve electrochemical stability and conductivity of transition-metal chalcogenides. Here, we proposed a multiscale structural engineering strategy to encapsulate selenide nanoparticles in N-doped porous carbon to enable high-performance Co0.85Se@porous carbon composite for highly reversible lithium/sodium storage. Specifically, the Co0.85Se nanoparticles are tightly anchored to carbon network through substantial SeC bond, which effectively buffer volume expansion and inhibit the dissolution of Se in electrolytes. Additionally, the carbon pores with multilevel size help achieving the fast ions diffusion. The unique structure enables the Co0.85Se composite anode to exhibit excellent discharge capacities of 955.1 mAh g−1 at 100 mA g−1 after 100 cycles, 305.6 mAh g−1 at 1 A g−1 of full cells after 550 cycles in LIBs and 491.3 mAh g−1 at 100 mA g−1 after 100 cycles in SIBs.

Facile synthesis of SiOx/C as high-performance anodes for lithium-ion batteries

Despite its high capacity (∼2615 mAh·g−1), silicon oxide (SiOx) suffers from low electrical conductivity and volume expansion during cycling, leading to capacity fading. In this work, a SiOx/C composite was synthesized by magnesium thermal reduction using co-assembled mesoporous SiO2 and graphitic carbon nitride (g-C3N4) as precursors. The SiOx/C composite displays a sheet-like nanostructure with highly dispersed SiOx. The presence of carbon enhances the conductivity and structural stability of the composite, leading to a low charge resistance (94.0 Ω), fast lithium diffusion (DLi+ = 5.15 × 10−14 cm2·s−1), and excellent cycling capability (863 mAh·g−1 after 160 cycles).