Chemical Enrichment Research Articles

NGC 1856: Using Machine Learning Techniques to Uncover Detailed Stellar Abundances from MUSE Data

We present the first application of the novel approach based on data-driven machine learning methods applied to Multi-Unit Spectroscopic Explorer (MUSE) field data to derive stellar abundances of star clusters. MUSE has been used to target more than 10,000 fields, and it is unique in its ability to study dense stellar fields such as stellar clusters providing spectra for each individual star. We use MUSE data of the extragalactic young stellar cluster NGC 1856, located in the Large Magellanic Cloud (LMC). We present the individual stellar [Fe/H] abundance of 327 cluster members in addition to [Mg/Fe], [Si/Fe], [Ti/Fe], [C/Fe], [Ni/Fe], and [Cr/Fe] abundances of subsample sets. Our results match the LMC abundances obtained in the literature for [Mg/Fe], [Ti/Fe], [Ni/Fe], and [Cr/Fe]. This study is the first to derive [Si/Fe] and [C/Fe] abundances for this cluster. The revolutionary combination of integral-field spectroscopy and data-driven modeling will allow us to understand the chemical enrichment of star clusters and their host galaxies in greater detail expanding our understanding of galaxy evolution.

Peculiarities of the chemical enrichment of metal-poor stars in the Milky Way Galaxy

The oldest stars in the Milky Way are metal-poor with Fe/H $<$ -- 1.0, displaying peculiar elemental abundances compared to solar values. The relative variations in the chemical compositions among stars is also increasing with decreasing stellar metallicity, allowing for the pure signature of unique nucleosynthesis processes to be revealed. The study of the $r$-process is, for instance, one of the main goals of stellar archaeology and metal-poor stars exhibit an unexpected complexity in the stellar production of the $r$-process elements in the early Galaxy. In this work, we report the atmospheric parameters, main dynamic properties, and the abundances of four metal-poor stars: HE 1523-–0901, HD 6268, HD 121135, and HD 195636 (--1.5 $>$ Fe/H The abundances were derived from spectra obtained with the HRS echelle spectrograph at the Southern African Large Telescope, using both local and non-local thermodynamic equilibrium (LTE and NLTE) approaches, with the average error between 0.10 and 0.20 dex. Based on their kinematical properties, we show that HE 1523--0901 and HD 195636 are halo stars with typical high velocities. In particular, HD 121135 displays a peculiar kinematical behaviour, making it unclear whether it is a halo or an accreted star. Furthermore, HD 6268 is possibly a rare prototype of very metal-poor thick disk stars. The abundances derived for our stars are compared with theoretical stellar models and with other stars with similar metallicity values from the literature. HD 121135 is Al-poor and Sc-poor, compared to stars observed in the same metallicity range (--1.62 $>$ Fe/H $>$--1.12). The most metal-poor stars in our sample, HE 1523 -- 0901, HD 6268, and HD 195636, exhibit anomalies that are better explained by supernova models from fast-rotating stellar progenitors for elements up to the Fe group. Compared to other stars in the same metallicity range, their common biggest anomaly is represented by the low Sc abundances. If we consider the elements beyond Zn, HE 1523--0901 can be classified as an r-II star, HD 6268 as an r-I candidate, and HD 195636 and HD 121135 exhibiting a borderline $r$-process enrichment between limited-r and r-I star. Significant relative differences are observed between the $r$-process signatures in these stars.

Optimizing Echinodorus macrophyllus extracts: Assessing extraction conditions for chemical marker enrichment and evaluating inhibitory effects on cytokines release by THP-1 cells

This study investigated various extractive methods and solvents with the goal of producing standardized extracts of Echinodorus macrophyllus for future industrial applications. Extracts were prepared through percolation, dynamic maceration, and static maceration, utilizing 96°GL ethanol (EtOH) and hydroethanolic solutions (90% EtOH, 70% EtOH, and 50% EtOH) as solvents. The highest extraction yields were achieved with 70% EtOH and 50% EtOH across all extractive methods. Both percolation and static maceration produced 50% and 70% EtOH extracts with elevated concentrations of chemical markers (cis- and trans-aconitic acids, homoorientin, chicoric acid, swertisin, caffeoyl-feruloyl-tartaric acid, and di-feruloyl-tartaric acid) and demonstrated superior inhibition rates of TNF and IL-1β release by LPS-stimulated THP-1 cells. Notably, these extracts were obtained in the form of fine powders, distinguishing them from extracts derived from 96°GL EtOH and 90% EtOH solutions. While the 50% EtOH and 70% EtOH extracts prepared by percolation or static maceration exhibited similar chemical composition and biological effects, percolation emerged as the preferred technique due to its ability to generate larger extract volumes. Principal component analysis (PCA) revealed robust correlations between these extracts and the contents of chemical markers but did not unveil significant correlations between higher marker contents and the inhibition of TNF and IL-1β release by THP-1 cells. These findings provide a basis for the future production of high-quality herbal preparations, emphasizing the critical role of extraction methods and solvent selection in pharmaceutical applications.

Contribution of very massive stars to the sulfur abundance in star-forming galaxies: Role of pair-instability supernovae

Context. Recent work presented increasing evidence of high non-constant S/O abundance ratios observed in star-forming metal-poor galaxies that deviated from the constant canonical S/O across a wide range of O/H abundances. Similar peculiarly high Fe/O ratios have also recently been detected. Aims. We investigate whether these high S/O ratios at low metallicities could be explained when the process of pair-instability supernovae (PISN) in chemical modelling is included, through which a similar behaviour of the Fe/O ratios was reproduced successfully. Methods. We used chemical evolution models that considered the stages of PISN in the previously published yields and adopted a suitable initial mass function (IMF) to characterize this evolutionary stage appropriately. Results. The peculiarly high values and the behaviour of the observed S/O versus O/H relation can be reproduced when the ejecta of very massive stars that go through the process of PISN are taken into account. Additionally, a bimodal top-heavy IMF and an initial strong burst of star formation are required to reach the reported high S/O values. Conclusions. We show that the role of very massive stars going through the process of PISN should be taken into account to explain the chemical enrichment of sulphur and oxygen in metal-poor star-forming regions.

X-Shooting ULLYSES: Massive stars at low metallicity. V. Effect of metallicity on surface abundances of O stars

Massive stars rotate faster, on average, than lower mass stars. Stellar rotation triggers hydrodynamical instabilities which transport angular momentum and chemical species from the core to the surface. Models of high-mass stars that include these processes predict that chemical mixing is stronger at lower metallicity. We aim to test this prediction by comparing the surface abundances of massive stars at different metallicities. We performed a spectroscopic analysis of single O stars in the Magellanic Clouds (MCs) based on the ULLYSES and XshootU surveys. We determined the fundamental parameters and helium, carbon, nitrogen, and oxygen surface abundances of 17 LMC and 17 SMC non-supergiant O6-9.5 stars. We complemented these determinations by literature results for additional MCs and also Galactic stars to increase the sample size and metallicity coverage. We investigated the differences in the surface chemical enrichment at different metallicities and compared them with predictions of three sets of evolutionary models. Surface abundances are consistent with CNO-cycle nucleosynthesis. The maximum surface nitrogen enrichment is stronger in MC stars than in Galactic stars. Nitrogen enrichment is also observed in stars with higher surface gravities in the SMC than in the Galaxy. This trend is predicted by models that incorporate chemical transport caused by stellar rotation. The distributions of projected rotational velocities in our samples are likely biased towards slow rotators. A metallicity dependence of surface abundances is demonstrated. The analysis of larger samples with an unbiased distribution of projected rotational velocities is required to better constrain the treatment of chemical mixing and angular momentum transport in massive single and binary stars.

The α-element enrichment of gas in distant galaxies

Context. The chemical evolution of distant galaxies cannot be assessed from observations of individual stars, in contrast to the case of nearby galaxies. On the other hand, the study of the interstellar medium (ISM) offers an alternative way to reveal important properties of the chemical evolution of distant galaxies. The chemical enrichment of the ISM is produced by all the previous generations of stars and it is possible to precisely determine the metal abundances in the neutral ISM in galaxies. The chemical abundance patterns in the neutral ISM are determined by the gas metallicity, presence of dust (the depletion of metals into dust grains), and possible deviations due to specific nucleosynthesis, for example, α-element enhancements. Aims. We aim to derive the metallicities, dust depletion, and α-element enhancements in the neutral ISM of gas-rich mostly-metal-poor distant galaxies (Damped Lyman-α absorbers, DLAs). Furthermore, we aim to constrain the distribution of α-element enhancements with metallicity in these galaxies. Methods. We collected a literature sample of column density measurements of O, Mg, Si, S, Ti, Cr, Fe, Ni, Zn, P, and Mn in the neutral ISM of DLAs at redshifts of 0.60 < z < 3.40. We used this sample to define a golden sample of DLAs with constrained observations of Ti and at least one other α-element. By studying the abundance patterns, we determined the amount of dust depletion, solely based on the observed relative abundances of the α-elements. We then used the abundances of Fe-peak elements to determine the overall metallicity of each system, after correcting for dust depletion. In addition, we studied the deviations from the basic (linear) abundance patterns. We divided our sample into two groups of galaxies based on the widths of their absorption lines (Δv90 above or below 100 km s−1), which may be considered as a proxy for their dynamical mass. We characterised the distribution of the α-element enhancements as a function of metallicity for the galaxy population as a whole, by fitting a piecewise function (plateau, decline, plateau) to the data. Results. We observed systematic deviations from the basic abundance patterns for O, Mg, Si, S, Ti, and Mn, which we interpreted as α-element enhancements and a Mn underabundance. The distribution of the α-element enhancements with metallicity is different in the high-Δv90 and low-Δv90 groups of galaxies. We constrained the metallicity of the α-element knee for the high-Δv90 and low-Δv90 groups of galaxies to be −1.02±0.15 dex and −1.84±0.11 dex, respectively. The average α-element enhancement at the high-plateau is [α/Fe]=0.38±0.07 dex. On the other hand, Mn shows an underabundance in all DLAs in the golden sample of −0.36±0.07 dex, on average. Conclusions. We have constrained, for the first time, the distribution of the α-element enhancement with metallicity in the neutral ISM in distant galaxies. Less massive galaxies show an α-element knee at lower metallicities than more massive galaxies. This can be explained by a lower star formation rate in less massive galaxies. If this collective behaviour can be interpreted in the same way as it is for individual systems, this would suggest that more massive and metal-rich systems evolve to higher metallicities before the contribution of SN-Ia to [α/Fe] levels out that of core-collapse SNe. This finding may plausibly be supported by different SFRs in galaxies of different masses. Overall, our results offer important clues to the study of chemical evolution in distant galaxies.

GN-z11 in Context: Possible Signatures of Globular Cluster Precursors at Redshift 10

The first JWST spectroscopy of the luminous galaxy GN-z11 simultaneously established its redshift at z = 10.6 and revealed a rest-ultraviolet spectrum dominated by signatures of highly ionized nitrogen, which has so far defied clear interpretation. We present a reappraisal of this spectrum in the context of both detailed nebular modeling and nearby metal-poor reference galaxies. The N iv] emission enables the first nebular density measurement in an apparently predominantly star-forming galaxy at z > 10, revealing evidence for extremely high densities n e ≳ 105 cm−3. With a suite of photoionization models, we establish that regardless of the ionization mechanism and accounting for depletion and this density enhancement, gas substantially enriched in nitrogen ([N/O] = +0.52 assuming the nebular emission is dominated by star formation) is required to reproduce the observed lines. We compare the GN-z11 spectrum to local UV databases and highlight a unique nearby galaxy, Mrk 996, where a high concentration of Wolf–Rayet stars and their CNO-processed ejecta produce a UV spectrum remarkably similar in some respects to that of GN-z11 and the Sunburst Arc. Collating this evidence in the context of Galactic stellar abundances, we suggest that the peculiar nitrogenic features prominent in GN-z11 may be a unique signature of intense and densely clustered star formation in the evolutionary chain of the present-day globular clusters, consistent with in situ early enrichment with nuclear-processed stellar ejecta on a massive scale. Combined with insight from local galaxies, these and future JWST data open a powerful new window into the physical conditions of star formation and chemical enrichment at the highest redshifts.

The Star Formation History in Local Group Galaxies. I. Ten Dwarf Galaxies

The star formation histories (SFHs) of galaxies provide valuable insights into galaxy evolution and stellar physics. Understanding the SFHs enables the study of chemical enrichment of galaxies, star formation triggered by interactions, and the behavior of various stellar populations. This work investigates the SFHs of ten dwarf galaxies in the Local Group (LG), which spans a wide range of types, masses, luminosities, and metallicities. The analysis is based on our new sample of the member stars in the LG after removing foreground dwarf stars by using information from the near-infrared color–color diagram and Gaia astrometry. The sample includes the most complete and pure red supergiants and asymptotic giant branch stars to gain valuable insights into the recent SFHs of the galaxies. A fitting method based on the color–magnitude diagram (CMD) is introduced to measure the SFH. The Padova isochrones are used to generate initial model CMDs, accounting for photometric errors and completeness through star-field simulations to match the completeness and error distributions of the observed CMDs. Subsequently, the SFHs, distance modulus, and metallicity of the ten dwarf galaxies are determined by fitting the CMDs. The results indicate that the star formation rates of dwarf irregulars show a gradual increase, while those of dwarf ellipticals exhibit a gradual decrease from the past to the present. Furthermore, this work shows that the star formation activity in dwarf ellipticals persisted up to 30 Myr ago. A significant increasing feature in the SFH of NGC 6822 reveals star formation activity triggered by an interaction event.

GHOST commissioning science results III: Characterizing an iron-poor damped Lyman α system

Abstract The Gemini High-resolution Optical SpecTrograph (GHOST) is a new echelle spectrograph available on the Gemini-South telescope as of Semester 2024A. We present the first high resolution spectrum of the quasar J1449−1227 (redshift zem = 3.27) using data taken during the commissioning of GHOST. The observed quasar hosts an intervening iron-poor ([Fe/H] =−2.5) damped Lyman α (DLA) system at redshift z = 2.904. Taking advantage of the high spectral resolving power of GHOST (R ≈ 55000), we are able to accurately model the metal absorption lines of the metal-poor DLA and find a supersolar [Si/Fe], suggesting the DLA gas is in an early stage of chemical enrichment. Using simple ionization models, we find that the large range in the C iv/Si iv column density ratio of individual components within the DLA’s high ionization absorption profile can be reproduced by several metal-poor Lyman limit systems surrounding the low-ionization gas of the DLA. It is possible that this metal-poor DLA resides within a complex system of metal-poor galaxies or filaments with inflowing gas. The high spectral resolution, wavelength coverage and sensitivity of GHOST makes it an ideal spectrograph for characterizing the chemistry and kinematics of quasar absorption lines.

Mapping the intracluster medium in the era of high-resolution X-ray spectroscopy

ABSTRACT High-resolution spectroscopy in soft X-rays will open a new window to map multiphase gas in galaxy clusters and probe physics of the intracluster medium (ICM), including chemical enrichment histories, circulation of matter and energy during large-scale structure evolution, stellar and black hole feedback, halo virialization, and gas mixing processes. An eV-level spectral resolution, large field of view, and effective area are essential to separate cluster emissions from the Galactic foreground and efficiently map the cluster outskirts. Several mission concepts that meet these criteria have been proposed recently, e.g. LEM, HUBS, and Super DIOS. This theoretical study explores what information on ICM physics could be recovered with such missions and the associated challenges. We emphasize the need for a comprehensive comparison between simulations and observations to interpret the high-resolution spectroscopic observations correctly. Using Line Emission Mapper (LEM) characteristics as an example, we demonstrate that it enables the use of soft X-ray emission lines (e.g. O vii/viii and Fe-L complex) from the cluster outskirts to measure the thermodynamic, chemical, and kinematic properties of the gas up to r200 and beyond. By generating mock observations with full backgrounds, analysing their images/spectra with observational approaches, and comparing the recovered characteristics with true ones from simulations, we develop six key science drivers for future missions, including the exploration of multiphase gas in galaxy clusters (e.g. temperature fluctuations, phase-space distributions), metallicity, ICM gas bulk motions and turbulence power spectra, ICM-cosmic filament interactions, and advances for cluster cosmology.

Untargeted metabolomic analysis reveals different metabolites associated with response to mepolizumab and omalizumab in asthma.

There is limited evidence on biomarkers associated with response to the monoclonal antibodies currently approved for asthma treatment. We sought to identify circulatory metabolites associated with response to treatment with mepolizumab or omalizumab. We conducted global metabolomic profiling of pre-treatment plasma samples from 100 patients with moderate-to-severe asthma who initiated mepolizumab (n=31) or omalizumab (n=69). The primary outcome was the change in exacerbations within 12 months of therapy. Negative binomial models were used to assess the association between each metabolite and exacerbations, adjusting for age, sex, body mass index, baseline exacerbations and inhaled corticosteroid use. Chemical similarity enrichment analysis (ChemRICH) was conducted to identify chemical subclasses associated with treatment response. The mean age of the mepolizumab group was 58.7 years with on average 2.9 exacerbations over the year prior to initiation of biologic therapy. The mean age in the omalizumab group was 48.8 years with 1.5 exacerbations in the preceding year. Patients with higher levels of two tocopherol metabolites were associated with more exacerbations on mepolizumab (δ-carboxyethyl hydroxychroman (CEHC) (p=2.65E-05, false discovery rate (FDR=0.01) and δ-CEHC glucuronide (p=2.47E-06, FDR=0.003)). Higher levels of six androgenic steroids, three carnitine metabolites and two bile acid metabolites were associated with decreased exacerbations in the omalizumab group. In enrichment analyses, xanthine metabolites (cluster FDR=0.0006) and tocopherol metabolites (cluster FDR=0.02) were associated with worse mepolizumab response, while androgenic steroids (cluster FDR=1.9E-18), pregnenolone steroids (cluster p=3.2E-07, FDR=1.4E-05) and secondary bile acid metabolites (cluster p=0.0003, FDR=0.006) were the top subclasses associated with better omalizumab response. This study identifies distinct metabolites associated with response to mepolizumab and omalizumab, with androgenic steroids associated with response to both mepolizumab and omalizumab.

FAUST

Context. The origin of the chemical diversity observed around low-mass protostars probably resides in the earliest history of these systems. Aims. We aim to investigate the impact of protostellar feedback on the chemistry and grain growth in the circumstellar medium of multiple stellar systems. Methods. In the context of the ALMA Large Program FAUST, we present high-resolution (50 au) observations of CH3OH, H2CO, and SiO and continuum emission at 1.3 mm and 3 mm towards the Corona Australis star cluster. Results. Methanol emission reveals an arc-like structure at ∼1800 au from the protostellar system IRS7B along the direction perpendicular to the major axis of the disc. The arc is located at the edge of two elongated continuum structures that define a cone emerging from IRS7B. The region inside the cone is probed by H2CO, while the eastern wall of the arc shows bright emission in SiO, a typical shock tracer. Taking into account the association with a previously detected radio jet imaged with JVLA at 6 cm, the molecular arc reveals for the first time a bow shock driven by IRS7B and a two-sided dust cavity opened by the mass-loss process. For each cavity wall, we derive an average H2 column density of ∼7 × 1021 cm−2, a mass of ∼9 × 10−3 M⊙, and a lower limit on the dust spectral index of 1.4. Conclusions. These observations provide the first evidence of a shock and a conical dust cavity opened by the jet driven by IRS7B, with important implications for the chemical enrichment and grain growth in the envelope of Solar System analogues.

A Perspective on the Milky Way Bulge Bar as Seen from the Neutron-capture Elements Cerium and Neodymium with APOGEE

This study probes the chemical abundances of the neutron-capture elements cerium and neodymium in the inner Milky Way from an analysis of a sample of ∼2000 stars in the Galactic bulge bar spatially contained within ∣X Gal∣ < 5 kpc, ∣Y Gal∣ < 3.5 kpc, and ∣Z Gal∣ < 1 kpc, and spanning metallicities between −2.0 ≲ [Fe/H] ≲ +0.5. We classify the sample stars into low- or high-[Mg/Fe] populations and find that, in general, values of [Ce/Fe] and [Nd/Fe] increase as the metallicity decreases for the low- and high-[Mg/Fe] populations. Ce abundances show a more complex variation across the metallicity range of our bulge-bar sample when compared to Nd, with the r-process dominating the production of neutron-capture elements in the high-[Mg/Fe] population ([Ce/Nd] < 0.0). We find a spatial chemical dependence of Ce and Nd abundances for our sample of bulge-bar stars, with low- and high-[Mg/Fe] populations displaying a distinct abundance distribution. In the region close to the center of the MW, the low-[Mg/Fe] population is dominated by stars with low [Ce/Fe], [Ce/Mg], [Nd/Mg], [Nd/Fe], and [Ce/Nd] ratios. The low [Ce/Nd] ratio indicates a significant contribution in this central region from r-process yields for the low-[Mg/Fe] population. The chemical pattern of the most metal-poor stars in our sample suggests an early chemical enrichment of the bulge dominated by yields from core-collapse supernovae and r-process astrophysical sites, such as magnetorotational supernovae.

FAUST

Aims. Interstellar complex organic molecules (iCOMs) are species commonly found in the interstellar medium. They are believed to be crucial seed species for the build-up of chemical complexity in star forming regions as well as our own Solar System. Thus, understanding how their abundances evolve during the star formation process and whether it enriches the emerging planetary system is of paramount importance. Methods. We use data from the ALMA Large Program FAUST (Fifty AU STudy of the chemistry in the disk and envelope system of solar protostars) to study the compact line emission towards the [BHB2007] 11 proto-binary system (sources A and B), where a complex structure of filaments connecting the two sources with a larger circumbinary disk has previously been detected. More than 45 methyl formate (CH3OCHO) lines are clearly detected with upper energies in the [123, 366] K range, as well as 8 dimethyl ether transitions (CH3OCH3) in the [93, 191] K range, 1 ketene transition (H2CCO) and 4 formic acid transitions (t-HCOOH). We compute the abundance ratios with respect to CH3OH for CH3OCHO, CH3OCH3, H2CCO, t-HCOOH (as well as an upper limit for CH3CHO) through a radiative transfer analysis. We also report the upper limits on the column densities of nitrogen bearing iCOMs, N(C2H5CN) and N(C2H3CN). Results. The emission from the detected iCOMs and their precursors is compact and encompasses both protostars, which are separated by only 0.2″ (~28 au). The integrated intensities tend to align with the Southern filament, revealed by the high spatial resolution observations of the dust emission at 1.3 mm. A Position-Velocity and 2D analysis are performed on the strongest and uncontaminated CH3OCH3 transition and show three different spatial and velocity regions, two of them being close to 11B (Southern filament) and the third one near 11A. Conclusions. All our observations suggest that the detected methanol, as well as the other iCOMs, are generated by the shocked gas from the incoming filaments streaming towards [BHB2007] 11A and 11B, respectively, making this source one of the few where chemical enrichment of the gas caused by the streaming material is observed.

Charting circumstellar chemistry of carbon-rich asymptotic giant branch stars

Context. Asymptotic giant branch (AGB) stars are major contributors to the chemical enrichment of the interstellar medium through nucleosynthesis and extensive mass loss. Direct measures of both processes can be obtained by studying their circumstellar envelopes in molecular line emission. Most of our current knowledge of circumstellar chemistry, in particular in a C-rich environment, is based on observations of the carbon star IRC +10216. Aims. We aim to obtain a more generalised understanding of the chemistry in C-rich AGB circumstellar envelopes by studying a sample of three carbon stars, IRAS 15194–5115, IRAS 15082–4808, and IRAS 07454–7112, and to observationally test the archetypal status often attributed to IRC +10216. Methods. We performed spatially resolved, unbiased spectral surveys in ALMA Band 3 (85–116 GHz). We estimated the sizes of the molecular emitting regions using azimuthally averaged radial profiles of the line brightness distributions. We derived abundance estimates, using a population diagram analysis for molecules with multiple detected lines, and using single-line analytical calculations for the others. Results. We identify a total of 132 rotational transitions from 49 molecular species. There are two main morphologies of the brightness distributions: centrally peaked (CS, SiO, SiS, HCN) and shell-like (CN, HNC, C2H, C3H, C4H, C3N, HC5N, c-C3H2). The brightness distributions of HC3N and SiC2 have both a central and a shell component. The qualitative behaviour of the brightness distributions of all detected molecules, in particular their relative locations with respect to the central star, is the same for all three stars, and consistent with those observed towards IRC +10216. Of the shell distributions, the cyanopolyynes peak at slightly smaller radii than the hydrocarbons, and CN and HNC show the most extended emission. The emitting regions for each species are the smallest for IRAS 07454–7112, consistent with this object having the lowest circumstellar density within our sample. We find that, within the uncertainties of the analysis, the three stars present similar abundances for most species, and also compared to IRC +10216. We find, tentatively, that SiO is more abundant in our three stars compared to IRC+10216, and that the hydrocarbons are under-abundant in IRAS 07454–7112 compared to the other stars and IRC +10216. Our estimated 12C/13C ratios match well the literature values for the three sources and our estimated silicon and sulphur isotopic ratios are very similar across the three stars and IRC +10216. Conclusions. The observed circumstellar chemistry appears very similar across our sample and compared to that of IRC +10216, both in terms of the relative location of the emitting regions and molecular abundances. This implies that, to a first approximation, the chemical models tailored to IRC +10216 are, at least, able to reproduce the observed chemistry in C-rich envelopes across roughly an order of magnitude in wind density.

E-XQR-30: The evolution of Mg ii, C ii, and O i across 2 &amp;lt; z &amp;lt; 6

ABSTRACT Intervening metal absorbers in quasar spectra at z &amp;gt; 6 can be used as probes to study the chemical enrichment of the Universe during the Epoch of Reionization. This work presents the comoving line densities (dn/dX) of low-ionization absorbers, namely, Mg ii (2796 Å), C ii (1334 Å), and O i (1302 Å) across 2 &amp;lt; z &amp;lt; 6 using the E-XQR-30 metal absorber catalogue prepared from 42 XSHOOTER quasar spectra at 5.8 &amp;lt; z &amp;lt; 6.6. Here, we analyse 280 Mg ii (1.9 &amp;lt; z &amp;lt; 6.4), 22 C ii (5.2 &amp;lt; z &amp;lt; 6.4), and 10 O i (5.3 &amp;lt; z &amp;lt; 6.4) intervening absorbers, thereby building up on previous studies with improved sensitivity of 50 per cent completeness at an equivalent width of W &amp;gt; 0.03 Å. For the first time, we present the comoving line densities of 131 weak (W &amp;lt; 0.3 Å) intervening Mg ii absorbers at 1.9 &amp;lt; z &amp;lt; 6.4 which exhibit constant evolution with redshift similar to medium (0.3 &amp;lt; W &amp;lt; 1.0 Å) absorbers. However, the cosmic mass density of Mg ii – dominated by strong Mg ii systems – traces the evolution of global star formation history from redshift 1.9 to 5.5. E-XQR-30 also increases the absorption path-length by a factor of 50 per cent for C ii and O i whose line densities show a rising trend towards z &amp;gt; 5, in agreement with previous works. In the context of a decline in the metal enrichment of the Universe at z &amp;gt; 5, the overall evolution in the incidence rates of absorption systems can be explained by a weak – possibly soft fluctuating – ultraviolet background. Our results, thereby, provide evidence for a late reionization continuing to occur in metal-enriched and therefore, biased regions in the Universe.

Whole-Genome Mapping of Epigenetic Modification of 5-Formylcytosine at Single-Base Resolution by Chemical Labeling Enrichment and Deamination Sequencing.

DNA cytosine methylation (5-methylcytosine, 5mC) is a predominant epigenetic modification that plays a critical role in a variety of biological and pathological processes in mammals. In active DNA demethylation, the 10-11 translocation (TET) dioxygenases can sequentially oxidize 5mC to generate three modified forms of cytosine, 5-hydroxymethylcytosine (5hmC), 5-formylcytosine (5fC), and 5-carboxylcytosine (5caC). Beyond being a demethylation intermediate, recent studies have shown that 5fC has regulatory functions in gene expression and chromatin organization. While some methods have been developed to detect 5fC, genome-wide mapping of 5fC at base resolution is still highly desirable. Herein, we propose a chemical labeling enrichment and deamination sequencing (CLED-seq) method for detecting 5fC in genomic DNA at single-base resolution. The CLED-seq method utilizes selective labeling and enrichment of 5fC-containing DNA fragments, followed by deamination mediated by apolipoprotein B mRNA-editing catalytic polypeptide-like 3A (APOBEC3A or A3A) and sequencing. In the CLED-seq process, while all C, 5mC, and 5hmC are interpreted as T during sequencing, 5fC is still read as C, enabling the precise detection of 5fC in DNA. Using the proposed CLED-seq method, we accomplished genome-wide mapping of 5fC in mouse embryonic stem cells. The mapping study revealed that promoter regions enriched with 5fC overlapped with H3K4me1, H3K4me3, and H3K27ac marks. These findings suggest a correlation between 5fC marks and active gene expression in mESCs. In conclusion, CLED-seq is a straightforward, bisulfite-free method that offers a valuable tool for detecting 5fC in genomes at a single-base resolution.

Enrichment of Iron-containing Concentrate with Ammonium Hydrofluoride

The rationality of using ash and slag waste from coal-fired TPP to obtain high-quality iron-containing concentrate (FC) is demonstrated. Using the method of wet magnetic separation of ash and slag waste from TPP, FC is extracted with Fe2O3 content of 59.2 %. It has been established that the method of chemical enrichment with ammonium hydrofluoride can increase the Fe2O3 content in FC to 79 %; a by-product of the reaction between FC and NH4F•HF is high-quality amorphous silica (white soot). The effect of process temperature on the composition of the resulting FC has been studied, at that the phase composition of iron oxides remains virtually unchanged. Optimal modes of the process are proposed.

Metal enrichment: the apex accretor perspective

The goal of this work is to devise a description of the enrichment process in large-scale structure that explains the available observations and makes predictions for future measurements. We took a spartan approach to this study, employing observational results and algebra to connect stellar assembly in star-forming halos with metal enrichment of the intra-cluster and group medium. On one hand, our construct is the first to provide an explanation for much of the phenomenology of metal enrichment in clusters and groups. It sheds light on the lack of redshift evolution in metal abundance, as well as the small scatter of metal abundance profiles, the entropy versus abundance anti-correlation found in cool core clusters, and the so-called Fe conundrum, along with several other aspects of cluster enrichment. On the other hand, it also allows us to infer the properties of other constituents of large-scale structure. We find that gas that is not bound to halos must have a metal abundance similar to that of the ICM and only about one-seventh to one-third of the Fe in the Universe is locked in stars. A comparable amount is found in gas in groups and clusters and, lastly and most importantly, about three-fifths of the total Fe is contained in a tenuous warm or hot gaseous medium in or between galaxies. We point out that several of our results follow from two critical but well motivated assumptions: 1) the stellar mass in massive halos is currently underestimated and 2) the adopted Fe yield is only marginally consistent with predictions from synthesis models and SN rates. One of the most appealing features of the work presented here is that it provides an observationally grounded construct where vital questions on chemical enrichment in the large-scale structure can be addressed. We hope that it may serve as a useful baseline for future works.

Explaining the high nitrogen abundances observed in high-z galaxies via population III stars of a few thousand solar masses

The chemical enrichment of the early Universe is a crucial element in the formation and evolution of galaxies, and Population III (Pop III) stars must play a vital role in this process. In this study, we examine metal enrichment from massive stars in the early Universe’s embryonic galaxies. Using radiation hydrodynamic simulations and stellar evolution modelling, we calculated the expected metal yield from these stars. Specifically, we applied accretion rates from a previous radiation-hydrodynamic simulation to inform our stellar evolution modelling, executed with the Geneva code, across 11 selected datasets, with final stellar masses between 500 and 9000 M⊙. Our results demonstrate that the first generation of Pop III stars within a mass range of 2000−9000 M⊙ result in N/O, C/O and O/H ratios compatible with the values observed in very high-z galaxies GN-z11 and CEERS 1019. The ejecta of these Pop III stars are predominantly composed of 4He, 1H, and 14N. Our Pop III chemical enrichment model of the halo can accurately reproduce the observed N/O and C/O ratios, and, by incorporating a hundred times more zero-metallicity interstellar material with the stellar ejecta, it accurately attains the observed O/H ratio. Thus, a sub-population of extremely massive Pop III stars, with masses surpassing approximately 2000 M⊙, effectively reproduces the CNO elemental abundances observed in high-z JWST galaxies to date. We closely reproduced the observed Ne/O ratio in CEERS 1019 employing a model with several thousand solar masses and non-zero metallicity, and we projected a 12C/13C ratio of 7, substantially lower than the solar ratio of around 90. The significant nitrogen enrichment predicted by Pop III stars with a few thousand solar masses not only reinforces the argument for a heavy seed formation pathway for massive black holes at redshifts as high as z = 10.6 but it also accentuates the need for deeper investigations into their complex nature and pivotal role in the early Universe.