Chemical Corrosion Resistance Research Articles

Interface engineering in CF/Al matrix composites for enhancement in mechanical strength and anti-corrosion properties

Metal matrix composites (MMCs), renowned for their lightweight and exceptional mechanical properties, are currently in high demand. Herein, carbon fiber‑aluminum metal matrix composites (CF/Al MMCs) modified with 4 types of corrosion-barrier interface coatings (CBCs), respectively, including Ni, TiO2, ZnO, and Al2O3 were investigated, and the composites were prepared by squeeze casting technique. The effects of these CBCs on the CF/Al interface reaction and the mechanical properties and electrochemical corrosion resistance of the composites are revealed and discussed thoroughly. It is observed that T300‑carbon fiber reinforced MMCs without any CBCs exhibit low mechanical strength due to the formation of Al4C3 phase induced by strong interaction between fiber and matrix. With CBCs, the formation of Al4C3 was significantly suppressed. Comparatively, the ZnO-coated CF/Al MMCs exhibit the most remarkable enhancement in the mechanical properties with a flexural strength of 796.4 MPa and a modulus of 105.3 GPa, which are approximately 114% and 52.2% higher than those of the counterparts without CBCs, respectively. More importantly, the CF/Al MMCs with CBCs demonstrate superior chemical corrosion resistance, retaining their mechanical performance even after a 7-day immersion in salt solutions. These results provide an important guideline in interface engineering for MMCs with enhanced mechanical properties and electrochemical corrosion resistance.

Nanodiamond Coating in Energy and Engineering Fields: Synthesis Methods, Characteristics, and Applications.

Nanodiamonds are metastable allotropes of carbon. Based on their high hardness, chemical inertness, high thermal conductivity, and wide bandgap, nanodiamonds are widely used in energy and engineering applications in the form of coatings, such as mechanical processing, nuclear engineering, semiconductors, etc., particularly focusing on the reinforcement in mechanical performance, corrosion resistance, heat transfer, and electrical behavior. In mechanical performance, nanodiamond coatings can elevate hardness and wear resistance, improve the efficiency of mechanical components, and concomitantly reduce friction, diminish maintenance costs, particularly under high-load conditions. Concerning chemical inertness and corrosion resistance, nanodiamond coatings are gradually becoming the preferred manufacturing material or surface modification material for equipment in harsh environments. As for heat transfer, the extremely high coefficient of thermal conductivity of nanodiamond coatings makes them one of the main surface modification materials for heat exchange equipment. The increase of nucleation sites results in excellent performance of nanodiamond coatings during the boiling heat transfer stage. Additionally, concerning electrical properties, nanodiamond coatings elevate the efficiency of solar cells and fuel cells, and great performance in electrochemical and electrocatalytic is found. This article will briefly describe the application and mechanism analysis of nanodiamonds in the above-mentionedfields.

Preparation and performance study of highly durable silicone rubber superhydrophobic surfaces

Superhydrophobic coatings are widely applied in aerospace and other fields to address issues such as surface drag reduction, anti-icing, and corrosion resistance. Due to the poor durability and unstable performance encountered in the application of most superhydrophobic coatings, we have combined the template method with the spray method to prepare a superhydrophobic surface with excellent durability. Experimental results demonstrate that the contact angle and sliding angle of the prepared surface reached 160.9° and 2.5°, respectively. Importantly, even after undergoing tests such as high-load sandpaper abrasion, tape peeling, and high-speed steel ball impact, the surface maintained outstanding hydrophobic performance. Furthermore, the surface exhibited not only excellent chemical corrosion resistance and self-cleaning effects but also, after experiencing high-load mechanical wear, extended the ice formation delay time to 201 seconds compared to a silicone rubber surface. This study employed a simple and environmentally friendly preparation process, providing robust guidance for the theoretical analysis and practical operation of designing and preparing superhydrophobic surfaces with outstanding durability.

Research Progress of Carbon-Silicone Composite Materials

Silicone is a kind of polymer material with high cross-linked structure, which is composed by Si-O-Si main chain. Due to the special molecular chain structure, silicone materials are characterized by oxidation resistance, aging resistance, high and low temperature resistance and chemical corrosion resistance. Moreover, silicone materials have processable properties, simple forming process, good mechanical property, non-toxic and pollution-free. Therefore, silicone has been widely concerned by researchers at home and abroad. In this paper, the main research progress and application directions of carbon-silicone composite at home and abroad in recent years are reviewed.

Growth and properties of tantalum carbide coatings on graphite by TRD technique

The tantalum carbide-coated graphite material exhibits remarkable chemical stability, corrosion resistance, and heat shock resistance, enabling it to demonstrate excellent stability during the growth of wide bandgap semiconductors. Its application significantly enhances the quality of third-generation semiconductor crystals. Nevertheless, the high cost of this material hinders its widespread utilization in the field of wide bandgap semiconductors. To address this challenge, this study employs the Thermo-reaction deposition and diffusion (TRD) technique to successfully fabricate a tantalum carbide coating on the surface of graphite. Through thermodynamic analysis, this article validate the thermodynamic feasibility of preparing tantalum carbide coatings using the TRD process. To achieve a dense and uniform TaC coating on the graphite surface, we systematically investigate the effects of reducing agent content, reaction temperature, and reaction time on the microstructure of the coating. Experimental research has found that a molar ratio of B4C to Ta2O5 of 1:0.64 optimizes the coating uniformity. Deviations from this ratio, either higher or lower, can lead to coating inhomogeneity or even failure in coating formation. Additionally, this article determine that a reaction temperature range of 1200–1400 °C, coupled with a reaction time not exceeding 6 h, represents the most suitable conditions for preparing TaC coatings on the graphite surface. Finally, to evaluate the practical performance of the coated graphite, this article simulate the corrosive environment encountered during the physical vapor transport method for growing aluminum nitride single crystals. The results demonstrate a significant improvement in the corrosion resistance of the coated graphite. This enhancement is primarily attributed to the formation of a dense TaC coating on the graphite surface, which exhibits remarkable stability at elevated temperatures.

Coupled amorphous NiFeP/cystalline Ni3S2 nanosheets enables accelerated reaction kinetics for high current density seawater electrolysis

Rational designing efficient, low-cost and corrosion resistant electrocatalysts is a crucial priority for seawater electrolysis to give impetus to the development of hydrogen energy and carbon neutrality. Herein, an amorphous NiFeP/crystalline Ni3S2 (NiFeP/Ni3S2) heterojunction catalyst is legitimately constructed for seawater electrolysis. Such structure improves the conductivity of amorphous NiFeP and optimizes the electronic structure by keeping the metal active sites in a relatively high valence state. In situ/ex situ experimental and theoretical calculation results reveal that the amorphous/crystal heterostructure accelerates the reconstruction and reaction kinetics of catalysts, reducing the energy barrier for potential-determining step and leading to improved intrinsic activity. The constructed NiFeP/Ni3S2 shows the overpotential of 354 mV to drive current density of 800 mA cm−2 in the alkaline medium. Besides, under 100 mA cm−2, NiFeP/Ni3S2 can run stably for 600 hours in seawater electrolyte without any hypochlorite production, demonstrating its excellent chemical stability and corrosion resistance.

Crystalline to Amorphous: Unveiling the Potential of Transition Metal Oxide‐based Electrocatalysts for Facile Oxygen Evolution Reaction in Alkaline Media

AbstractTransition metal oxides/hydroxides exhibit reasonable oxygen activity in alkaline electrolytes and have been identified as potential electrocatalysts. Some highly active transition metal oxides or hydroxides can alter their surface chemistry in response to the electrolyte environment. This review presents the performance of some of the recently developed transition metal‐based oxides in electrocatalytic oxygen evolution reaction (OER). Despite the promising catalytic activity of many transition metals and their alloys due to their incompletely filled d orbitals, their low corrosion resistance in alkaline media barriers their use as electrocatalysts. Metallic glasses (MGs), with their disordered atomic structure, have many unique and exciting properties that cannot be found in crystalline metals. Metallic glasses′ unique chemical activity and corrosion resistance stem from their metastable and defective nature, as well as their structural and chemical homogeneity. In the case of Zr‐based MGs, the presence of MG−OHads and MG−Ox species on the surface for oxygen evolution enables rapid electron transfer to chemisorbed OH− with an “activated” MG surface leading to the generation of an amorphous Zr‐rich layer. Zr‐rich oxide layer formation favors the OER understood by decreased Tafel slope and highly stable nature during open circuit potential measurements in the alkaline solution. Unlike the as‐spun counterpart, the relatively small impedance magnitude and characteristic frequency for the post‐OER electrode corroborate the enhancement of oxygen evolution kinetics after electrochemistry. Compared with the early discovered electrodes, the MG‐oxide assembly outperforms many transition and precision metal‐based oxides and their composite forms regarding oxygen electroactivity and stability.

The influence of different water glass moduli on the chemical corrosion resistance of alkali-activated porous concrete

The high porosity characteristic of porous concrete makes its cementitious materials susceptible to strength degradation due to external chemical corrosion. Currently, research on its resistance to chemical corrosion is relatively limited, primarily employing silicate cement as the main binder. Therefore, this study investigates the impact of different sodium silicate moduli on the chemical corrosion resistance of alkali-activated porous concrete. The experiment evaluates its performance under conditions of sulfate ion corrosion, accelerated carbonation, and coupled corrosion. The results indicate that the developed porous concrete maintains sufficient strength and porosity after chemical corrosion, meeting the minimum standards of relevant industry standards (JIS A, 17 MPa). Lower alkali activator moduli enhance corrosion resistance, likely attributed to increased hydration and a denser microstructure. This research provides necessary groundwork and theoretical support for the practical application of alkali-activated porous concrete in warm coastal regions.

Review on Abrasive Machining Technology of SiC Ceramic Composites.

Ceramic matrix composites have the advantages of low density, high specific strength, high specific die, high-temperature resistance, wear resistance, chemical corrosion resistance, etc., which are widely used in aerospace, energy, transportation, and other fields. CMCs have become an important choice for engine components and other high-temperature component manufacturing. However, ceramic matrix composite is a kind of multi-phase structure, anisotropy, high hardness material, due to the brittleness of the ceramic matrix, the weak bonding force between fiber and matrix, and the anisotropy of composite material. Burr, delamination, tearing, chips, and other surface damage tend to generate in the machining, resulting in surface quality and strength decline. This paper reviewed the latest abrasive machining technology for SiC ceramic composites. The characteristics and research directions of the main abrasive machining technology, including grinding, laser-assisted grinding, ultrasonic-assisted grinding, and abrasive waterjet machining, are introduced first. Then, the commonly used numerical simulation research for modeling and simulating the machining of ceramic matrix composites is briefly summarized. Finally, the processing difficulties and research hotspots of ceramic matrix composites are summarized.

Synthesis and Characterization of Silica and Silica Cellulose from Natural Materials as Matrix for Various Sensor Applications: A Mini Review

Sensors play a crucial role in various fields by enabling the detection and analysis of a wide range of substances, including hazardous substance detection, environmental and food safety monitoring, pharmaceutical industry, gas analysis, and others. Research continues to identify and develop sensor matrix materials that can increase the sensitivity, selectivity and responsiveness of sensors. Silica, an oxide mineral is a potential matrix material for sensor applications because of its unique characteristics. It has a large pore structure and modifiable pore size distribution. Silica’s stable chemical properties, high-temperature resistance and corrosion resistance make it an ideal matrix material for a wide range of sensor applications. In recent years, silica cellulose also become a potential material for sensor applications. Silica cellulose is produced by combining silica with cellulose components from natural materials, such as rice husk ash, bamboo leaf ash, rice straw ash, and other plant fibers. This article provides a comprehensive exploration of various methods of synthesis and characterization of silica and silica cellulose materials. The methods include sol-gel, acid leaching, alkaline extraction, and other techniques for extracting cellulose from natural sources. In addition, sensor applications that have been tested using this material are also discussed, including its use in detecting molecular compounds, food and environmental applications. The development of silica and silica cellulose materials based on natural materials is considered because of their sustainability. By continuing to explore the potential of these materials, it is hoped that it can make a significant contribution in the development of sensor technology that is more innovative, environmentally friendly and sustainable.

Enhancement of hardness and corrosion resistance of Al-Si-N multilayer color coating via SiN/AlSiN/AlN compositional gradient interlayer

The color of AlN/Si/Al coating can be controlled by the thickness of the AlN layer according to the interference effect. However, the loading capacity is affected by the large hardness difference between the Si and Al layers. Corrosion resistance is relatively weak due to penetration defects in the AlN surface layer. In this work, therefore, a SiN/AlSiN/AlN interlayer is sputtered in between the Si/Al layer in the AlN/Si/Al coating as the transition layer. The chemical state, structure, morphology, color, hardness, and corrosion resistance of the as-deposited Al-Si-N coating are carefully characterized using x-ray photoelectron spectrometry, grazing incident x-ray diffraction, atomic force microscopy, scanning electron microscope, colorimeter, nanoindentation, and electrochemical corrosion meter, respectively. To evaluate the long-term corrosion resistance, the uncoated, AlN/Si/Al-coated, and AlN/Si/SiN/AlSiN/AlN/Al-coated AZ31B Mg alloys are immersed in salt solution for different durations, followed by characterization of morphology and composition. The results show that the SiN/AlSiN/AlN interlayer is of a gradient structure in both composition and hardness. The AlN crystals grow continuously from the Al bonding layer into the AlSiN layer, resulting in internal longitudinal grain boundaries. The coating surface becomes smoother with a roughness (Rq) of 12.6 nm. The color of the coating is controlled by the AlN surface layer thickness. The coating hardness increases from 6.5 to 20.6 GPa. The corrosion current density of the coating decreases from 2.02 × 10−6 to 1.99 × 10−8 A/cm2. The coating could withstand corrosion in salt solution for at least 192h. The gradient structure of the interlayer effectively alleviates the hardness difference between the Si layer and the Al layer and inhibits the penetration of the corrosive medium from the surface. The mechanism for the enhanced corrosion resistance is explained through a model.

High-performance cabbage-like FeNi3/CoP2@C electrode with 3D porous structure for supercapacitors

The development of supercapacitors relies heavily on the design and manufacture of innovative electrode materials. FeNi3 alloy-based electrodes show good chemical stability and corrosion resistance as positive electrodes. However, their high internal resistance and low electronic conductivity limit the large-scale application. In this work, the CoP2 particles with high electrical conductivity is integrated with FeNi3 nanoalloys to construct FeNi3/CoP2 heterostructure loaded on biomass-derived cabbage-like porous carbon. Combined with the experimental result and density functional theory, the introduction of CoP2 nanoparticles greatly improves the electrochemical properties of the prepared FeNi3/CoP2@C composite. By adjusting the annealing temperature, the FeNi3/CoP2@C-800 electrode displays a specific capacitance of 1135.5 C g−1 at 1 A g−1 with a surface area of 259.45 m2 g−1. In addition, the assembled FeNi3/CoP2@C-800//AC (activated carbon) asymmetric supercapacitor provides a high energy density of 52.2 Wh kg−1 at 525.0 W kg−1 and good electrochemical cycling stability with a capacitance retention rate of 84.23 % after 10,000 cycles. The study offers a feasible idea for making high-performance pseudocapacitive electrode material.

Analytical study on the dynamic mechanical behaviours of foam-core sandwich plate under repeated impacts

The foam-core sandwich structures are probably subjected to repeated impact loadings in engineering applications, resulting in structural plastic deformation and accumulative damage. A valuable analytical approach is needed to predict the accumulative plastic deformation of foam-core sandwich structures under repeated impacts. In this paper, an analytical model of the dynamic responses of foam-core sandwich plates under repeated impacts is proposed using the circumscribing yield locus and the inscribing yield locus based on the rigid-perfectly plastic theory. By employing the principle of energy dissipation rate balance, the analytical expressions of structure permanent deformation and peak force are obtained from the iteration of initial conditions. In addition, polyvinyl chloride (PVC) foam has steady chemical properties and corrosion resistance, which can better adapt to the practical environment and meet the needs of structural protection. To validate the proposed analytical model, the repeated impact dynamic mechanical behaviours of PVC foam-core sandwich plates were experimentally and numerically studied. Results show that theoretical results such as the permanent deformation, peak force, and deformation modes of foam-core sandwich plates under repeated impacts are in good agreement with experimental and numerical results. With the increase in impact numbers, the global bending deformation and local indentation deformation of facesheets increase, the PVC foam core layer is constantly being compressed, and the bottom facesheet plays an increasingly important part in the repeated impact energy absorption with a maximum value of 29.20 %.

A polyphenol‐induced hydroxyapatite coating modulates corrosion resistance and biocompatibility of magnesium alloys

AbstractIn order to solve the problem of excessive degradation rate and insufficient biocompatibility of magnesium‐based bone implants, a polyphenol (EGCG) induced hydroxyapatite (HA) coating was prepared on the surface of AZ31 alloy. The physical and chemical properties and corrosion resistance of the coating were analysed in depth, and its biocompatibility was preliminarily explored in vitro. The results showed that the polyphenol (EGCG) conversion coating constructed on the AZ31 could successfully induce the formation of HA by complexing the phenolic hydroxyl group with calcium ions. The electrochemical and long‐term immersion experiments showed that the corrosion resistance of EGCG/HA composite coating was significantly improved. The self‐corrosion current density, hydrogen evolution and the increase of pH value of AZ31‐EGCG/HA were significantly lower than those of AZ31. On the basis of inhibiting the excessive corrosion of the substrate, the composite coating significantly improves the compatibility of pre‐osteoblasts, supports the adhesion and spreading and effectively reduces the haemolysis rate to less than 5%. The preparation method of the coating is simple, low cost and suitable for complex shape surfaces, which can significantly improve the corrosion resistance and biocompatibility of the AZ31 substrate. It is expected to provide a solution for the surface modification of magnesium‐based bone implants.

Effect of Al content on chemical corrosion resistance of Al/SiC composites

Al/SiC composites with different Al contents were prepared by high-energy ball milling with Al powder and SiC powder as raw materials at a temperature of 1800 °C, a pressure of 50 MPa, and heat preservation for 5 min. The microstructures and phase compositions of the Al/SiC composites were observed using scanning electron microscopy and X-ray diffraction. The results showed that the Al/SiC composites prepared by adding 10 vol% aluminum had the best properties: the strength was 310 MPa, the apparent porosity was 6.50%, and the density was 2.9192 g/cm3. Furthermore, the corrosion rate of the Al/SiC composites gradually decreased with increasing corrosion time when the Al/SiC composites were placed in a 3.5 wt% NaCl solution at room temperature. However, the corrosion rate differed for varying Al contents. The experimental results showed that the Al/SiC composites with 10 vol% Al have the best properties, including the smallest porosity, the largest density, and the highest corrosion resistance.

Mesoscopic Simulation of Centrifugal Melt Electrospinning of PPESK

AbstractPoly(aryl ether sulfone ketone) (PPESK) is an engineering plastic with high strength, good heat resistance, insulation, and chemical corrosion resistance. The properties of PPESK fiber prepared by centrifugal melt electrospinning can be improved, and the method is efficient and environmentally friendly. This article employs a systematic analysis to investigate the impact of process parameters on the jet formation process, jet motion, fiber diameter, fiber yield, and changes in molecular chain orientation of PPESK. The analysis uses dissipative particle dynamics simulation to reveal that PPESK fibers can attain a certain degree of refinement, and fiber yield can be increased with an appropriate increase in rotational speed, temperature, and electric field force. Moreover, for PPESK with different chain lengths, longer molecular chains impede the untwisting of the molecular chains within the fiber, weakening the fiber orientation, increasing fiber diameter, and resulting in a slower fiber yield increase. These simulation results provide theoretical guidance for preparing PPESK ultrafine fibers with the required performance, shortening the exploration process of actual spinning, and saving time and labor.

In situ aluminide armored polyimide nanofiber separators with ultrahigh strength and high wettability for advanced lithium-ion batteries

Polyimide (PI) has been widely used in aerospace, electronic information, novel energy, and other industries due to its excellent high- and low-temperature, radiation, and chemical corrosion resistance. However, the use of electrospun PI separators in lithium-ion batteries (LIBs) is limited due to their poor electrolyte wettability and insufficient mechanical strength. Inorganic materials such as aluminide have typically been used in the coating composition of PI separators. To investigate the effects of different aluminide components, in this work, PI materials were prepared by the complexation–hydrolysis method and used as separators for LIBs. The physicochemical and electrochemical properties of the different nanofiber membranes were studied by adjusting the calcination temperature. The results showed that the sample with the highest tensile strength was 107.6 MPa, which is close to the commercial polyolefin separator. When the calcination temperature increased to 300 °C and then exceeded 400 °C, the aluminide shell initially transformed into thin boehmite and then into γ-Al2O3 phases. The mechanical properties of the nanofiber membranes were enhanced, and the wettability and electrochemical characteristics also improved to some extent. Furthermore, the nanofiber structure was destroyed at 500 °C and could not meet the long-term battery cycles. Therefore, when the calcination temperature was controlled between 300 °C and 400 °C, the aluminide-armored PI nanofiber membranes exhibited better comprehensive performance and were suitable for use as separators in LIBs, which was of great significance for improving the safety and stability of LIBs, especially power batteries.

Corrosion Performance of Ti6Al7Nb Alloy in Simulated Body Fluid for Implant Application Characterized Using Macro- and Microelectrochemical Techniques

In this paper, the applicability of Ti6Al7Nb as a more biocompatible alternative for bone and dental implants than Ti6Al4V and pure titanium in terms of corrosion resistance and electrochemical inertness is investigated. The chemical inertness and corrosion resistance of the Ti6Al7Nb biomaterial were characterized by a multi-scale electrochemical approach during immersion in simulated physiological environments at 37 °C comparing its behavior to that of c.p. Ti, Ti6Al4V, and stainless steel. The establishment of a passive regime for Ti6Al7Nb results from the formation of a thin layer of metal oxide on the surface of the material which prevents the action of aggressive species in the physiological medium from direct reaction with the bulk of the alloy. Conventional electrochemical methods such as potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) provide quantified information on the surface film resistance and its stability domain that encompasses the potential range experienced in the human body; unfortunately, these methods only provide an average estimate of the exposed surface because they lack spatial resolution. Although local physiological environments of the human body are usually simulated using different artificial physiological solutions, and changes in the electrochemical response of a metallic material are observed in each case, similar corrosion resistances have been obtained for Ti6Al7Nb in Hank’s and Ringer’s solutions after one week of immersion (with a corrosion resistance of the order of MΩ cm2). Additionally, scanning electrochemical microscopy (SECM) provides in situ chemical images of reactive metal and passive dielectric surfaces to assess localized corrosion phenomena. In this way, it was observed that Ti6Al7Nb exhibits a high corrosion resistance consistent with a fairly stable passive regime that prevents the electron transfer reactions necessary to sustain the metal dissolution of the bulk biomaterial. Our results support the proposition of this alloy as an efficient alternative to Ti6Al4V for biomaterial applications.

Sol–Gel Silica Coatings for Corrosion Protection of Aluminum Parts Manufactured by Selective Laser Melting (SLM) Technology

Metal additive manufacturing is a rapidly growing field based on the fabrication of complex parts with improved performance. The advantages of using this technology include the production of shapes that cannot be produced by traditional machining technologies, the possibility of using trabecular reinforcing structures, and the ability to make parts with topological optimization that allow for increased performance and decreased mass of the parts produced. Metal parts produced by selective laser melting technology exhibit high surface roughness, which limits their direct implementation. Corrosion protection of these surfaces is difficult, especially for galvanic processes. This paper analyzes the possibility of using sol–gel silica (silicon oxide) coatings to effectively protect various surfaces of aluminum alloys produced by selective laser melting technology. Silicon oxide sol–gel protective coatings have demonstrated excellent chemical stability and corrosion resistance, being able to be applied in very thin layers. These properties make them excellent candidates for protecting additive-manufactured metal parts, especially as-built surfaces with a high surface roughness. Nanostructured silica sol–gel protective coatings have demonstrated excellent corrosion resistance and have the potential to replace the highly toxic chromium-based galvanic treatments. Using nanostructured silica sol–gel coatings, aluminum parts can be seamlessly integrated into circular-economy cycles.

Potential utilization of oil sludge incineration bottom ash for glass-ceramics: Crystallization kinetics, properties and toxicological evaluation

The bottom ash (OIBA) generated from the incineration of hazardous oil sludge is classified as a hazardous waste. In this work, the OIBA was applied as raw material to prepare SiO2-Al2O3-CaO system glass-ceramics by melt-sintering with the addition of waste glass wool (GW). The effects of basicity (CaO/SiO2 ratio, 0.52-1.05) and sintering temperature (900–1050 °C) on the crystallization kinetics, properties, microstructure, leaching concentrations of heavy metals and potential toxicity of glass-ceramics were investigated. The results showed that the crystallization pattern was two-dimensional crystallization, and with the decrease of basicity, the main crystalline phase evolved from gehlenite to diopside. And the glass-ceramics with basicity of 0.88 and sintering temperature of 950 °C exhibited the best comprehensive properties, including density (2.72 g/cm3), water absorption (0.06%), compressive strength (452.45 MPa) and chemical corrosion resistance. In addition, the reduction of heavy metal leaching concentration indicates that produced glass-ceramics showed excellent solidification effect on heavy metals, the low toxicity of glass-ceramics leaching solution to the wheat seeds and Artemia suggests the environmental protection characteristics of OIBA-based glass-ceramics. These findings proved that the glass-ceramics produced by OIBA and GW could be a promising method to dispose hazardous waste with preparing high value-added construction materials.