Charge Oscillations Research Articles

Fundamental Laws and Quantum Dynamics

Background: Recently, we obtained a unitary theory of quantum mechanics and general relativity, where a quantum particle is a continuous distribution of matter in the two conjugate spaces of the coordinates and momentum, quantized by the equality of the mass parameter describing the relativistic dynamics of the matter, with the mass as an integral of the matter density. However, in this framework, we have not explicitly revealed the connection between our new theory and the fundamental laws of quantum mechanics. Methods: We analyzed in detail the three fundamental laws of quantum mechanics, explicitly describing experimental data: 1) Planck’s law of the blackbody electromagnetic radiation of a system of electrically charged harmonic oscillators, 2) Einstein’s law of the photon energy proportionality with the photon frequency, and 3) de Broglie’s law of the quantum particle as an oscillator in space. Results: We reobtained the two dynamical equations, in the conjugate spaces of the coordinates and momentum, as functions of the Lagrangian system, unlike the Schrödinger equation, depending on the Hamiltonian. Conclusion: According to the fundamental laws of quantum mechanics, a quantum particle is a continuous distribution of matter with an intrinsic mass, unlike the conventional quantum mechanics for the state occupation probabilities of punctual entities moving with the light velocity and getting an apparent mass only by collisions with some bosons pervading the whole universe. According to these laws, we obtained a quantum theory in agreement with common sense, classical logic, and general relativity.

Induced magnetization in anisotropic environment

The non-Markovian dynamics of a two-dimensional charged harmonic oscillator linearly coupled to a neutral bosonic heat bath is investigated in a linear-polarized electric field. The analytical expressions for the time-dependent and asymptotic magnetic moment are derived for the Markovian and non-Markovian dynamics. It is predicted that the liner-polarized electric field generates strong orbital currents and magnetization in a symmetric harmonic oscillator embedded into anisotropic heat bath. The role of the mixed dissipative kernel in magnetization is analyzed.

Redox potentials in ionic liquids: Anomalous behavior?

Redox potentials depend on the nature of the solvent/electrolyte through the solvation energies of the ionic solute species. For concentrated electrolytes, ion solvation may deviate significantly from the Born model predictions due to ion pairing and correlation effects. Recently, Ghorai and Matyushov [J. Phys. Chem. B 124, 3754-3769 (2020)] predicted, on the basis of linear response theory, an anomalous trend in the solvation energies of room temperature ionic liquids, with deviations of hundreds of kJ/mol from the Born model for certain size solutes/ions. In this work, we computationally evaluate ionic solvation energies in the prototypical ionic liquid, 1-butyl-3-methylimidazolium tetrafluoroborate (BMIM/BF4), to further explore this behavior and benchmark several of the approximations utilized in the solvation energy predictions. For comparison, we additionally compute solvation energies within acetonitrile and molten NaCl salt to illustrate the limiting behavior of purely dipolar and ionic solvents. We find that the overscreening effect, which results from the inherent charge oscillations of the ionic liquid, is substantially reduced in magnitude due to screening from the dipoles of the molecular ions. Therefore, for the molten NaCl salt, for which the ions do not have permanent dipoles, modulation of ionic solvation energies from the overscreening effect is most significant. The conclusion is that ionic liquids do indeed exhibit unique solvation behavior due to peak(s) in the electrical susceptibility caused by the ion shell structure; redox potential shifts for BMIM/BF4 are of more modest order ∼0.1V, but may be larger for other ionic liquids that approach molten salt behavior.

Control of the oscillation frequency of a vortex cluster in the trapped polariton condensate

An optically trapped exciton–polariton condensate forms states corresponding to excited energy levels of the confining potential. Recently, it was shown that non-uniformity of the ring-shaped trapping potential leads to the simultaneous occupation of two split energy levels. This results in the formation of an oscillating vortex cluster with periodically changing signs of topological charges. Here, we experimentally demonstrate the control of the topological charge oscillation frequency by tuning the ellipticity of the excitation profile. Our observations are corroborated using the linear Schrödinger equation for a two-dimensional quantum harmonic oscillator. Our findings open a promising avenue for the investigation of optical vorticity properties and their applications in controllable settings.

Van der Waals Engineering of Charge Density Waves in One-Dimensional Nb6Te6 Nanowires.

One-dimensional (1D) systems have played a crucial role in the development of fundamental physics and practical applications. Recently, transition metal monochalcogenide (TMM) wires based on molybdenum (Mo) and tungsten (W) have emerged as promising platforms for investigating 1D physics in pure van der Waals (vdW) platforms. Here, we report on the bottom-up fabrication of Nb6Te6 wires down to the single-wire limit. The unique properties of Nb6Te6 single wire enable the realization of 1D charge density wave (CDW) phases in an isolated single TMM wire. Moreover, we revealed the appealing regulation of 1D CDW orders by van der Waals interactions at either the 1D-2D interface (i.e., rotation of a single wire along its wire axis) or the 1D-1D interface. Two rotation angles (30° and 0°) give rise to 3 × 1 and zigzag chain CDW morphologies, respectively, which exhibit pronounced differences in atomic displacement by a factor of 2. The interwire vdW coupling overwhelms its counterpart at the 1D-2D interface, thus locking the rotation angle (at 0°) as well as the interwire atomic registries. In contrast, interestingly, the phases of the charge oscillations are independent of the adjacent wires. The ability to tailor 1D charge orders provides a crucial addition to the toll set of vdW integrations beyond two-dimensional materials.

Energetics of the dissipative quantum oscillator

In this paper, we discuss some aspects of the energetics of a quantum Brownian particle placed in a harmonic trap, also known as the dissipative quantum oscillator. Based on the fluctuation–dissipation theorem, we analyze two distinct notions of thermally-averaged energy that can be ascribed to the oscillator. These energy functions, respectively dubbed hereafter as the mean energy and the internal energy, are found to be inequivalent for arbitrary system–bath coupling strength when the dissipation kernel has a non-zero memory timescale, as in the case of a Drude bath. Remarkably, both the energy functions satisfy the quantum counterpart of energy equipartition theorem, but with different probability distributions on the frequency domain of the heat bath. Moreover, the Gibbs approach to thermodynamics provides us with yet another thermally-averaged energy function. In the weak-coupling limit, all the above-mentioned energy expressions reduce to ϵ=ħω02coth(ħω02kBT), which is the familiar result. We generalize our analysis to the case of the three-dimensional dissipative charged oscillator placed in a spatially-uniform magnetic field.

Derivation of Miller’s rule for the nonlinear optical susceptibility of a quantum anharmonic oscillator

Miller’s rule is an empirical relation between the nonlinear and linear optical coefficients that applies to a large class of materials but has only been rigorously derived for the classical Lorentz model with a weak anharmonic perturbation. In this work, we extend the proof and present a detailed derivation of Miller’s rule for an equivalent quantum-mechanical anharmonic oscillator. For this purpose, the classical concept of velocity-dependent damping inherent to the Lorentz model is replaced by an adiabatic switch-on of the external electric field, which allows a unified treatment of the classical and quantum-mechanical systems using identical potentials and fields. Although the dynamics of the resulting charge oscillations, and hence the induced polarizations, deviate due to the finite zero-point motion in the quantum-mechanical framework, we find that Miller’s rule is nevertheless identical in both cases up to terms of first order in the anharmonicity. With a view to practical applications, especially in the context of ab initio calculations for the optical response where adiabatically switched-on fields are widely assumed, we demonstrate that a correct treatment of finite broadening parameters is essential to avoid spurious errors that may falsely suggest a violation of Miller’s rule, and we illustrate this point by means of a numerical example.

Soliton dynamics and stability in the ABS spinor model with a PT -symmetric periodic complex potential

We investigate the effects on solitons dynamics of introducing a PT -symmetric complex potential in a specific family of the cubic Dirac equation in (1+1)-dimensions, called the Alexeeva–Barashenkov–Saxena model. The potential is introduced taking advantage of the fact that the nonlinear Dirac equation admits a Lagrangian formalism. As a consequence, the imaginary part of the potential, associated with gains and losses, behaves as a spatially periodic damping (changing from positive to negative, and back) that acts at the same time on the two spinor components. A collective coordinates (CCs) theory is developed by making an ansatz for a moving soliton where the position, rapidity, momentum, frequency, and phase are all functions of time. We consider the complex potential as a perturbation and verify that numerical solutions of the equation of motions for the CCs are in agreement with simulations of the nonlinear Dirac equation. The main effect of the imaginary part of the potential is to induce oscillations in the charge and energy (they are conserved for real potentials) with the same frequency and phase as the momentum. We find long-lived solitons even with very large charge and energy oscillations. Additionally, we extend to the nonlinear Dirac equation an empirical stability criterion, previously employed successfully in the nonlinear Schrödinger equation.

Coupled Electron-Nuclear Dynamics Induced and Monitored with Femtosecond Soft X-ray Pulses in the Amino Acid Glycine.

The coupling of electronic and nuclear motion in polyatomic molecules is at the heart of attochemistry. The molecular properties, transient structures, and reaction mechanism of these many-body quantum objects are defined on the level of electrons and ions by molecular wave functions and their coherent superposition, respectively. In the present contribution, we monitor nonadiabatic quantum wave packet dynamics during molecular charge motion by reconstructing both the oscillatory charge density distribution and the characteristic time-dependent nuclear configuration coordinate from time-resolved Auger electron spectroscopic data recorded in previous studies on glycine molecules [Schwickert et al. Sci. Adv. 2022, 8, eabn6848]. The electronic and nuclear motion on the femtosecond time scale was induced and probed in kinematically complete soft X-ray experiments at the FLASH free-electron laser facility. The detailed analysis of amplitude, instantaneous phase, and instantaneous frequency of the propagating many-body wave packet during its lifecycle provides unprecedented insight into dynamical processes beyond the Born-Oppenheimer approximation. We are confident that the refined experimental data evaluation helps to develop new theoretical tools to describe time-dependent molecular wave functions in complicated but ubiquitous non-Born-Oppenheimer photochemical conditions.

PHASE SYNCHRONIZATION OF PARTICLES AT CYCLOTRON RESONANCES

Subject and Purpose. The effects considered concern phase synchronization of electrons in an ideal plasma subjected to the action of an external uniform, d. c. magnetic field. Two modes of the synchronization are discussed, specifically one by an external electromagnetic field and the other by the cyclotron radiation emitted by the electrons. The purpose is to compare these forms of synchronization and their effects on plasma stability. Methods and Methodology. The plasma is represented as a set of coupled oscillators whose dynamics is described via coupled differential equations. Assuming the coupling between the oscillators to be weak we find analytical solutions to the equation, further performing a stability analysis which exploits standard approaches of the dynamical systems theory. The solutions found are validated through corresponding numerical simulations. Results. As has been found, an external electromagnetic wave may be capable of guiding the particles toward phase synchronization, which can lead to formation of phased bunches. This mechanism of particle grouping may prove to be more efficient, in terms of scale times of synchronization, if compared with known mechanisms exploiting relativistic effects. Additionally, we show that the cyclotron radiation emitted by the charged particles (which is often disregarded because of its smallness) can lead to self-phase synchronization of the electrons. Moreover, should the density of charged particles in the ensemble be sufficiently high, an instability can arise, potentially disrupting the ensemble. Estimates have been provided of the level of random fluctuations capable of undermining the synchronization process and plasma dynamics stabilization. Conclusions. The most significant finding of this analysis is the emergence of low-frequency oscillations in the charged oscillators set, followed by an onset of the plasma instability when the plasma density exceeds a certain critical value. Within that scenario, the ensemble of oscillators sitting in the external magnetic field is no longer held together by the field. The effect should be taken into account in applications related to plasmas of a relatively high density.

High-precision realization for sensing charged particles based on optomechanically induced two-color second-order sidebands

We propose an effective scheme to sense charged particles by employing two-color second-order sidebands (TSSs) in a hybrid optomechanical system. This is realized in an optomechanical cavity with a double-oscillator structure, where the Coulomb force acting on two charged oscillators participates in nonlinear optomechanical interaction. With the aid of mechanical mode splitting induced by the Coulomb force, we report that the TSS spectrum can be generated and enhanced when the strong absorption in the transmission spectrum allows the TSS generated pathways to be readily accessed. More importantly, after seeking two correlations between the TSS spectra and the charged particles deposited on the oscillator, we design a dual-parameter sensor to measure the mass and the charge of the external particles simultaneously. Through evaluating the influence of the thermomechanical noise on the optomechanical sensing device, the resolution for detecting the mass and the charge of the measured particles can be identified as δm≈1.7×10−18g and δQ≈1.6×10−18C, respectively.

Coherent charge oscillations in a bilayer graphene double quantum dot

The coherent dynamics of a quantum mechanical two-level system passing through an anti-crossing of two energy levels can give rise to Landau-Zener-Stückelberg-Majorana (LZSM) interference. LZSM interference spectroscopy has proven to be a fruitful tool to investigate charge noise and charge decoherence in semiconductor quantum dots (QDs). Recently, bilayer graphene has developed as a promising platform to host highly tunable QDs potentially useful for hosting spin and valley qubits. So far, in this system no coherent oscillations have been observed and little is known about charge noise in this material. Here, we report coherent charge oscillations and T2*\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$${T}_{2}^{*}$$\\end{document} charge decoherence times in a bilayer graphene double QD. The charge decoherence times are measured independently using LZSM interference and photon assisted tunneling. Both techniques yield T2*\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$${T}_{2}^{*}$$\\end{document} average values in the range of 400–500 ps. The observation of charge coherence allows to study the origin and spectral distribution of charge noise in future experiments.

Charge Oscillations in Bilayer Graphene Quantum Confinement Devices.

Quantum confinement structures are building blocks of quantum devices in fundamental physics exploration and technological applications. In this work, we fabricate dual-gated bilayer graphene Fabry-Pérot quantum Hall interferometers employing two different gating strategies and conduct finite element simulations to understand the electrostatics of the confinement structures and to guide device design and fabrication. We observe two types of resistance oscillations arising from the charging of quantum dots formed inside the interferometers. We obtain the size, location, and charging energy of the dots by measuring the dependence of the oscillations on the magnetic field, gate voltages, and dc bias. We analyze and discuss the origin of the quantum dots and their impact on quantum Hall edge state backscattering and interference. Insights gained in these studies shed light on the construction of van der Waals quantum confinement devices.

Numerical simulations unveil superradiant coherence in a lattice of charged quantum oscillators

A system of Nosc charged oscillators interacting with the electromagnetic field, spatially confined in a 3D lattice of sub-wavelength dimension, can condense into a superradiant coherent state if appropriate density and frequency conditions are met. In this state, the common frequency ω of the oscillators and the plasma frequency ωp of the charges are combined into a frequency ω′=ω2+ωp2 that is off-shell with respect to the wavelength of the photon modes involved, preventing them from propagating outside the material. Unlike other atomic cavity systems, the frequency ω in this case is not determined by the cavity itself but is defined by the periodic electrostatic potential that confines the charged particles in the lattice. Additionally, the electromagnetic modes involved have wave vectors distributed in all spatial directions, resulting in a significant increase in coupling. The analytical study of this system can be carried out in the limit of large Nosc by searching for an approximation of the ground state via suitable coherent trial states. Alternatively, numerical simulations can be employed for smaller Nosc. In the numerical approach, it is possible to go beyond the Rotating Wave Approximation (RWA) and introduce a dissipation term for the photon modes. This dissipation term can account for the ohmic quench in a metal and also consider photon losses at the boundary of the material. By utilizing numerical solutions and Monte Carlo simulations, the presence of condensation has been confirmed, and an energy gap of a few electron volts (eV) per particle has been observed in typical metal crystals with protons bound to tetrahedral or octahedral sites.

Nonlocal Soft Plasmonics in Planar Homogeneous Multilayers

Plasmonics is the study of resonant oscillations of free electrons in metals caused by incident electromagnetic radiation. Surface plasmons can focus and steer light on the subwavelength scale. Apart from metals, plasmonic phenomena can be observed in soft matter systems such as electrolytes which we study here. Resonant charge oscillations can be induced for ions in solution, however, due to their larger mass, they are plasmon-active in a lower frequency regime and on a larger wavelength scale. Our investigation focuses on spatial confinement which allows increasingly strong charge interactions and gives rise to nonlocality or spatial dispersion effects. We derive and discuss the nonlocal optical response of ionic plasmons using a hydrodynamic two-fluid model in a planar homogeneous three-layer system with electrolyte-dielectric interfaces. As in metals, we observe the emergence of additional longitudinal propagation modes in electrolytes which causes plasmonic broadening. Studying such systems enables us to identify and understand plasmonic phenomena in biological and chemical systems.

Quantum correlation in a nano-electro-optomechanical system enhanced by an optical parametric amplifier and Coulomb-type interaction

In this paper, we investigated the quantum correlation of nano-electro-optomechanical system enhanced by an optical parametric amplifier (OPA) and Coulomb-type interaction. In particular, we consider a hybrid system consisting of a cavity and two charged mechanical oscillators with an OPA, where the optical cavity mode is coupled with a charged mechanical oscillator via radiation pressure, and the two charged mechanical oscillators are coupled through a Coulomb interaction. We use logarithmic negativity to quantify quantum entanglement, and quantum discord to measure the quantumness correlation between the two mechanical oscillators. We characterize quantum steering using the steerability between the two mechanical oscillators. Our results show that the presence of OPA and strong Coulomb coupling enhances the quantum correlations between the two mechanical oscillators. In addition, Coulomb interactions are more prominent in quantum correlations. Besides, in the presence of OPA, the maximum amount of quantum entanglement, quantum steering, and quantum discord were achieved between the two mechanical oscillators is greater than in the absence of OPA. Moreover, a proper phase choice of the optical field driving the OPA enhances quantum correlations under suitable conditions. We obtain quantum entanglement confines quantum steering and quantum discord beyond entanglement. Furthermore, quantum entanglement, quantum steering, and quantum discord decrease rapidly with increasing temperature as a result of decoherence. In addition, quantum discord persists at higher temperature values, although the quantum entanglement between the systems also vanishes completely. Our proposed scheme enhances quantum correlation and proves robust against fluctuations in the bath environment. We believe that the present scheme of quantum correlation provides a promising platform for the realization of continuous variable quantum information processing.

Periodic charge oscillations in the Proca theory

We consider the Proca theory of the real massive vector field. There is a locally conserved 4-current operator in such a theory, which one may use to define the charge operator. Accordingly, there are charged states in which the expectation value of the charge operator is non-zero. We take a close look at the charge operator and study the dynamics of the certain class of charged states. For this purpose, we discuss the mean electric field and 4-current in such states. The mean electric field has the periodically oscillating Coulomb component, whose presence explains the periodic charge oscillations. A complementary insight at such a phenomenon is provided by the mean 4-current, whose discussion leads to the identification of a certain paradox. Last but not least, we show that there is a shock wave propagating in the studied system, which affects analyticity of the mean electric field and 4-current.

A novel approach for an approximate solution of a nonlinear equation of charged damped oscillator with one degree of freedom

A novel technique is proposed for finding an approximate solution of the strongly nonlinear ordinary differential equation for the charged damped pendulum with one degree of freedom. The method relies on a transformation of the governing nonlinear differential equation that keeps unchanged the order of the highest derivative, in conjunction with a modified homotopy perturbation technique (MHPM). Only quadratic damping is considered for the numerical computations. To validate the used technique, the obtained results are compared to those arising from a numerical solution by Runge–Kutta of the fourth order (RK4) and by finite differences (FD). Good agreement between the two solutions is reached when quadratic damping is suppressed. In the presence of damping, agreement takes place only for a rather limited range of times. Plots of the analytical solutions are provided for both cases. The proposed method may be used to analyze a wide class of nonlinear differential equations.

Generation and optimization of electron bunch trains from nonlinear longitudinal space charge oscillation

Generation and optimization of electron bunch trains from nonlinear longitudinal space charge oscillation

Radiative volume plasmon and phonon-polariton resonances in TiN-based plasmonic/polar-dielectric hyperbolic optical metamaterials

Ferrell and Berreman modes are absorption resonances in thin metal films and polar-dielectric media that arise from radiative bulk plasmon-polariton and phonon-polariton excitations. Compared to surface polaritons, Ferrell and Berreman modes occur due to volume charge oscillations across the medium and provide a unique pathway for light–matter interactions. Though the resonances are studied individually, stringent polarization and material requirements have prevented their observation in one host medium. Here, we show simultaneous excitation of Ferrell and Berreman absorption resonances in refractory epitaxial TiN/Al0.72Sc0.28N plasmonic metal/polar-dielectric hyperbolic metamaterials in the visible and far-infrared spectral ranges. The nanoscale periodicity of the superlattices enables the coupling of bulk plasmons (and longitudinal optical phonons) across different TiN (and Al0.72Sc0.28N) layers and allows polarization matching with free-space light that results in Ferrell (and Berreman) mode excitations. Ferrell and Berreman absorption resonances can be used for strong light confinement in radiative cooling, thermophotovoltaics, and other dual-band applications.