The probability of ejecting two or more electrons by the interaction of an x ray with the outermost shell of He, Ne, and Ar has been investigated. The relative abundances of doubly charged to singly charged ions following x irradiation have been measured with a charge spectrometer. These ratios are essentially constant over the range of x-ray energies from 3 to 8 times the threshold for double ionization. They are, respectively, 0.035, 0.14, and 0.17 for He, Ne, and Ar. Energy spectra for electrons ejected in photo-ionization have been measured with an electron spectrometer. In addition to characteristic photolines, continuum spectra are found, which are related to double electron ejection. The probabilities for double electron ejection as determined from these spectra are in agreement with those obtained by charge spectrometry. The shapes of the continuum spectra are qualitatively similar to those expected for electron shake-off. However, the probabilities for electron shake-off as calculated from single-electron wave functions are much smaller than found experimentally. It is suggested that a many-body solution which explicitly includes electron correlations may be necessary. For example, such a calculation by Salpeter and Zaidi, for the case where one electron goes to the continuum while the other goes to the $2s$ state in the photo-ionization of He, is shown to be in good agreement with experiment. Some results are also presented on the differential cross sections of Ne and Ar for C $K\ensuremath{\alpha}$ x rays.