In this study, we aimed to demolish irregular constructions that are usually composed of convex, concave, and straight structures based on the shaped charge jet. Accordingly, the penetration behaviour of convergent, divergent, and straight linear shaped charges (LSCs) have been detected with numerical and physical methods. For comparison purposes, numerical models for all three types of LSCs with identical cross-sections have been established to investigate the impacts of structural features. It is found that the shaped charge structure not only determines the kinematic consumption during the penetration process but also influences the initial value of the jet velocity. Additionally, because of the interactions between the previous and subsequent jets, the jet velocity of the convergent LSC shows an obvious undulation during the penetration process. Furthermore, quantitative analyses of the kinematic consumption and initial velocity differences for three types of LSCs are conducted with physical models. A kinematic consumption difference is revealed, and the mass of the charge that determines the initial jet velocity as a function of the geometric parameters in three types of LSCs is deduced. Finally, we combined the numerical and physical models and conducted integral analyses to assess the penetration behaviours of the three LSC types.