Charge Decay Rate Research Articles

Effects of ambient temperature on surface charge and flashover of heat-shrinkable polymer under polarity reversal voltage

DC transmission helps to solve the decentralization of distributed wind power generation and other renewable power sources to enhance system performance. But the existence of surface charges by the corona makes earlier insulation failure and plays an important role during the development of the surface flashover. The influences of the ambient temperature and the polarity reversal voltage on the surface charge and the flashover of the heat-shrinkable polymer are not completely clear. In this paper, the carrier mobility and the volume conductivity were employed to explain the temperature dependent surface charge decay results. The initial surface charge density and decay rates served for analyzing the effects of polarity reversal voltage. Furthermore, the flashover experiments of the samples charged by the polarity reversal voltage at different ambient temperatures were conducted. Obtained results show that the descending speed of the surface charge becomes faster at higher temperature. An obvious temperature dependence of the carrier mobility and the volume conductivity is observed. Moreover, the surface charges of the samples charged by the voltage with shorter reversal time decay more rapidly. The flashover voltage increases with the increasing ambient temperature because of less accumulated surface charges in this condition. Considering the accelerated surface charge decay by the increasing temperature and easier charge accumulation during the steady negative period, attentions should be paid to the design of DC insulation and the security of operation.

Charge retention analysis of Si implanted and wet oxidized SONOS structures

In this work we examine the high temperature charge retention characteristics of modified SONOS (polySi–oxide–nitride–oxide–Si) capacitors. The modified SONOS structures were synthesized by Si low-energy implantation (1keV) into oxide–nitride (ON) stacks, followed by a wet oxidation step. The retention studies were conducted within the temperature range of 50 to 180°C after setting the capacitor to an excess electron state of ΔVFB of 3V. The reference ONO capacitor exhibits a complex behavior which consists of an initial fast discharge rate of 0.1V/decade which switches to a lower and temperature independent rate of 0.06V/decade when the ΔVFB reaches 2.86V. In turn, the implanted and wet oxidized ONO shows a temperature dependent charge decay rate which varies from 0.07V/decade at 30°C, to 0.18V/decade at 180°C. The retention data have been analytically solved using the Wang–White model. The results showed that the nitride trap distribution of the implanted and wet oxidized sample differs clearly from that of the standard stoichiometric nitride. This is attributed to ion induced structural damage in combination with the wet oxidation which increases the distribution profile at deeper trap energies.

Understanding the surface discharge characteristics of thermally aged copper sulphide diffused oil impregnated pressboard material

An attempt has been made to understand the impact of thermal aging with copper sulphide diffused oil impregnated pressboard (OIP) material for surface discharge inception voltage (SDIV) variation. The SDIV of Copper sulphide diffused OIP material reduces with increase in thermal aging. The UHF signals generated due to surface discharges with copper sulphide diffused OIP at the point of inception have frequency content in the range 0.7-1.5 GHz with its dominant frequency at 0.9GHz. HFCT measurement indicated that the rise time of injected current pulse due to surface discharge activity in the negative and positive half cycle of the AC voltage are about 0.8ns and 1ns respectively. It is also found that increase in thermal aging of copper sulphide diffused OIP, the amplitude and width of the current pulse increases. The magnitude of surface charge and its mean life is high with thermal aging temperature of copper sulphide diffused OIP material. Polarity of surface charge acquired by OIP due to AC corona charging depends on the surface condition of the pressboard material and its charge decay rate is lower than under DC voltage. Atomic Absorption Spectroscopy (AAS) and Energy Dispersive Spectrometry (EDS) study confirms the presence of copper sulphide on the surface of OIP and is found to be increased for copper sulfide diffused OIP material compare to unused OIP material. Scanning Electron Microscope (SEM) analysis indicates formation of cracks with thermally aged OIP material. Phase Resolved Partial Discharge (PRPD) study indicates that the surface discharge activity occurs near the peaks of the applied AC voltage at inception and at the rising portion of the applied AC voltage at higher voltages. It is found that the tensile and flexural strength reduces drastically for thermally aged copper sulphide diffused OIP material compare to unused specimen.

Influence of thermal degradation on surface discharge characteristics for oil-polypropylene insulation

Oil-polypropylene (PP) composite insulation has been widely used in power capacitors, and also being extended to other equipment such as specific transformers, etc. As discharge can readily creep along PP surface, the interface between oil and PP is a weak point in the insulation structure. The oil-PP insulation degrades under the impact of thermal and electrical stress during normal operation. In this study, the influence of thermal degradation on surface discharge characteristics for oil-PP insulation is investigated. Degraded samples are obtained by thermally accelerated aging of virgin oil-PP samples. The microscopic morphology of PP samples are observed with SEM, and the physical and electrical properties of degraded oil are measured. In addition, the isothermal surface potential decay (ISPD) measurement is employed to investigate the charge keeping capability of PP samples. After that, surface discharge detection experiments under AC voltage are performed for the virgin and degraded samples. The ISPD results indicate that charge decay rate of degraded PP sample is faster than virgin sample, which imply that space charge memory effect of virgin PP samples is more remarkable. For this reason, the PD inception phase of virgin sample is smaller than those of degraded samples. It is found that thermal degradation of oil-PP insulation enhances the surface discharge activity. It is considered that rough surface profile and higher bubble conservation capability of degraded PP sample, and impurities in degraded oil are responsible for the enhancement effect of thermal degradation on surface discharge.

Space Charge Behavior in Paper Insulation Induced by Copper Sulfide in High-Voltage Direct Current Power Transformers

The main insulation system in high-voltage direct current (HVDC) transformer consists of oil-paper insulation. The formation of space charge in insulation paper is crucial for the dielectric strength. Unfortunately, space charge behavior changes because of the corrosive sulfur substance in oil. This paper presents the space charge behavior in insulation paper induced by copper sulfide generated by corrosive sulfur in insulation oil. Thermal aging tests of paper-wrapped copper strip called the pigtail model were conducted at 130 °C in laboratory. Scanning electron microscopy (SEM) was used to observe the surface of copper and paper. Pulse electroacoustic (PEA) and thermally stimulated current (TSC) methods were used to obtain the space charge behavior in paper. Results showed that both maximum and total amount of space charge increased for the insulation paper contaminated by semi-conductor chemical substance copper sulfide. The space charge decay rate of contaminated paper was significantly enhanced after the polarization voltage was removed. The TSC results revealed that copper sulfide increased the trap density and lowered the shallow trap energy levels. These results contributed to charge transportation by de-trapping and trapping processes. This improved charge transportation could be the main reason for the decreased breakdown voltage of paper insulation material.

Multimode charge transport in electron implanted PMMA

Energetic electrons directed toward an insulating target material penetrate to the interior where they progressively loose their energy through multiple atomic collisions and eventually come to rest. They therefore cause an internal charge deposition with spatial distribution largely associated with their entrance energy. An investigation of the charge deposition caused by 2 MeV incident energy electrons implanted into polymethylmethacrylate (PMMA) in air at room temperature was made by measurement of the internal charges accumulated according to the applied implantation doses, up to 500 Gy. The internal charges were measured using the electrically stimulated acoustic wave (ESAW) method and initial volume charges were 90% of the applied charge implant, and were very persistent in some cases taking months to decay. Charge transport models were compared to measured charge decay and two processes, conduction and charge drift, appear to be active simultaneously. However implantation also caused changes in the material conductivity as observed by an increase in net charge decay rates according to increased implantation levels. Because of the well-defined charge deposition process in PMMA and slow decay rates, charge accumulation can be used as a diagnostic for electron radiation exposure.

Surface charge and dc flashover characteristics of direct-fluorinated SiR/SiO<sub>2</sub> nanocomposites

Silicone rubber (SiR), as a basic insulating material, is widely used in insulators for HVDC transmission lines. Incorporation of nanoparticles could not only improve the insulating properties, but also alter surface charge behavior as a consequence. In HVDC transmission lines, corona discharge could even occur on well-designed insulators, which can inject charge into the insulator surface and influence dc flashover voltage. Direct fluorination is a method to change the surface chemical component of polymers, which could induce the corresponding changes in electrical properties of the surface layer, thus influencing surface charge behavior and dc flashover voltage. This paper tries to study the effects of fluorination time and mass fraction of nanoparticles on surface charge behavior and dc flashover voltage of SiR/SiO <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> nanocomposites. Samples were prepared by dispersing nano-SiO <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> into SiR matrix with the fraction of 0, 1, 3 and 5 wt% respectively. Then the direct fluorination of the samples were conducted in a stainless reaction vessel at 25 °C using a F <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> /N <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> mixture gas with 12% F <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> by volume at 0.05 MPa for 5, 10, 15 and 20 minutes. After corona discharge tests performed at room temperature with a relative humidity of ~ 40%, the decay curves of the surface potential were measured using an electrostatic voltmeter, and flashover tests were carried out under dc stress, of which the polarity was identical with the corona discharge. Obtained results show that the dc flashover voltage is affected by the surface charge, which varies with the fluorination time and mass fraction of nanoparticles. It is indicated that the direct fluorination can markedly improve the decay rate of surface charge, and raise the dc flashover voltage of SiR/SiO <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> nanocomposites.

Fabrication of a flexible Ag-grid transparent electrode using ac based electrohydrodynamic Jet printing

In the dc voltage-applied electrohydrodynamic (EHD) jet printing of metal nanoparticles, the residual charge of droplets deposited on a substrate changes the electrostatic field distribution and interrupts the subsequent printing behaviour, especially for insulating substrates that have slow charge decay rates. In this paper, a sinusoidal ac voltage was used in the EHD jet printing process to switch the charge polarity of droplets containing Ag nanoparticles, thereby neutralizing the charge on a polyethylene terephthalate (PET) substrate. Printed Ag lines with a width of 10 µm were invisible to the naked eye. After sintering lines with 500 µm of line pitch at 180 °C, a grid-type transparent electrode (TE) with a sheet resistance of ∼7 Ω sq−1 and a dc to optical conductivity ratio of ∼300 at ∼84.2% optical transmittance was obtained, values that were superior to previously reported results. In order to evaluate the durability of the TE under bending stresses, the sheet resistance was measured as the number of bending cycles was increased. The sheet resistance of the Ag grid electrode increased only slightly, by less than 20% from its original value, even after 500 cycles. To the best of our knowledge, this is the first time that Ag (invisible) grid TEs have been fabricated on PET substrates by ac voltage applied EHD jet printing.

Drop-on-demand E-jet printing of continuous interconnects with AC-pulse modulation on highly insulating substrates

In this paper, we present a novel AC-pulse modulated electrohydrodynamic (EHD) jet printing technology that enables high resolution fabrication of electrical features and interconnects using the silver nanoink on highly insulating substrates. In traditional EHD jet printing, the remained charge of the printed droplets changes the electrostatic field distribution and interrupts the follow-on printing behavior, especially for highly insulating substrates having a slow charge decay rate. In this paper, a modulated AC-pulsed voltage was used for the EHD jet printing process that can alternate the charge polarity of the consequent droplets to neutralize the residue charge on the substrate. The effect of the residue charge is minimized, which enables high resolution printing of continuous patterns. With three printing parameters (e.g. pulse frequency, voltage, and duration), the EHD jet printing speed and droplet size can be controlled independently. We demonstrated that AC-pulse modulated EHD jet printing can overcome the charge accumulation challenge on highly insulating substrates, and investigated the variables of fabrication process to achieve reliable jet printing of conductive silver tracks.

High-resolution ac-pulse modulated electrohydrodynamic jet printing on highly insulating substrates

This paper presents a new high-resolution ac-pulse modulated electrohydrodynamic (EHD)-jet printing technology on highly insulating substrates for drop-on-demand fabrication of electrical features and interconnects using silver nanoink. In traditional EHD-jet printing, the remained charge of the printed droplets changes the electrostatic field distribution and interrupts the follow-on printing behavior, especially for highly insulating substrates which have slow charge decay rates. The residue charge makes the control of EHD-jet printing very challenging for high-resolution continuous features. In this paper, by using modulated ac-pulsed voltage, the EHD-jet printing process switches the charge polarity of the consequent droplets to neutralize the charge on the substrate. The effect of the residue charge is minimized, which enables high-resolution printing of continuous patterns. Moreover, by modulating the pulse frequency, voltage, and duration, the EHD-jet printing behavior can be controlled with respect to printing speed/frequency and droplet size. Printing frequency is directly controlled by the pulse frequency, and the droplet dimension is controlled by the voltage and the duration of the pulse. We demonstrated that ac-pulse modulated EHD-jet printing can overcome the long-predicated charge accumulation problem on highly insulating substrates, and potentially be applied to many flexible electronics applications.

Warm dust-acoustic shocks

We investigate the formation of shock waves in a warm dusty plasma with equilibrium drift. We show that the natural decay rate of dust charge plays an important role in determining the properties of the shock front in such a plasma.

Effects of Fluorination on Surface Charge Accumulation and Decay of Polyimide Film

In this paper, we present a study aimed at clarifying the effects of fluorination time on surface charge accumulation and decay behaviors of fluorinated polyimide films. The samples were surface-fluorinated in a laboratory vessel at about 328 K using a F2/N2 mixture with 20% F2 by volume at 0.05 MPa for 15, 30, 45, and 60 min. Corona charging tests were performed at room temperature with a relative humidity of ∼40%. The chemical composition of the fluorinated layer of the samples was observed. The results indicate that charge density and charge decay rate are markedly affected by fluorination and that the degree of fluorination is affected by treatment duration.

Surface charge accumulation and decay on directfluorinated polyimide/Al2O3 nanocomposites

Polyimide film, as a special type of engineering plastic film, is a basic insulating material and is widely applied in the electrical and electronic industry. Addition of nanoparticles into polyimide can improve the insulating properties compared with undoped material. However, due to the change of the material structure, the trap characteristics and charge behavior are altered as a consequence. The existence of surface charge has a great effect on the breakdown characteristic and is the main reason leading to dielectric breakdown. Fluorination as change the chemical component in surface layer of polymers should give rise to the corresponding change in electrical properties of the surface layer thus influence the charge injection from electrodes when they are used as an insulator. This paper presents a study aimed at clarifying the effect of fluorination and nanoparticles on the surface charge accumulation and decay behaviors of fluorinated polyimide nanocomposite film. Samples were prepared by dispersing nano-scale Al <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> O <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">3</sub> into polyimides with weight percentages of 0, 1, 3, 5 and 7 respectively. Then the samples were surface fluorinated in a laboratory vessel at about 328 K (55 °) using a F <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> /N <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> > mixture with 20% F <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> by volume and 0.05 MPa (500 mbar) for 30 minutes. Corona charging tests were performed at room temperature with a relative humidity of 40%. The charge distribution was measured by means of an electrostatic voltmeter. The results show the dependence of the charge density as well as the charge decay rate upon the fluorination and nanoparticle concentration, varying as a function of the charge polarity and charging time. It is suggested that the fluorination can significantly improve the decay rate of the surface charge in polyimide films.

Dynamic behavior of surface charge on direct- fluorinated polyimide films

Polyimide film, as a special type of engineering plastic film, is a kind of basic insulating material and is widely applied in the aerial, nuclear, microelectronic industry, turn to turn insulation and turn to ground insulation of inverter-fed motors. However, premature insulation failures occur frequently in motors with the disadvantage of pure PI inherent in all organic materials. The existence of surface charge has a great effect on breakdown characteristic and is the main reason leading to dielectric breakdown. Fluorination as change the chemical component in surface layer of polymers should give rise to the corresponding change in electrical properties of the surface layer thus influence the charge injection from electrodes when they are used as an insulator. This paper presents a study aimed at clarifying the effect of fluorination time on surface charge accumulation and decay behaviors of fluorinated polyimide film. Samples were surface fluorinated in a laboratory vessel at about 328 K (55 °C) using a F2/N2 mixture with 20% F2 by volume and 0.05 MPa (500 mbar) for respectively 15, 30, 45 and 60 minutes. Corona charging tests were performed at room temperature with a relative humidity of ~ 40%. The charge distribution was measured by means of an electrostatic voltmeter. Obtained results show the dependence of the charge density as well as the charge decay rate upon the fluorination time of samples, varying as a function of the charge polarity and charging time. It is suggested that the fluorination can significantly improve the decay rate of the surface charge in polyimide films.

TiO2 nanoparticle induced space charge decay in thermal aged transformer oil

TiO2 nanoparticle with good dispersibility and stability in transformer oil was prepared and used to modify insulating property of aged oil. It was found that space charge decay rate in the modified aged oil can be significantly enhanced to 1.57 times of that in the aged oil at first 8 s after polarization voltage was removed. The results of trap characteristics reveal that the modification of nanoparticle can not only greatly lower the shallow trap energy level in the aged oil but also increase the trap density, resulting in improved charge transportation via trapping and de-trapping process in shallower traps.

Effect of nanosecond rise time of pulse voltage on the surface charge of Epoxy/TiO2nanocomposites

Polymeric insulating materials exposed to pulse voltage with a nanosecond rise time in pulsed power have drawn increasing attention. Surface charge accumulation and decay on the charged polymers are very important parameters related to discharge. Nanocomposite technology has been used to improve the electrical properties of polymeric insulating materials. Therefore, it must be confirmed whether the nanosecond rise time of pulse voltage on the dynamic behaviour of surface charge on polymeric nanocomposites is different from that without nanoparticles. In this paper, we attempted to clarify the effect of the rise time on the electrical properties of epoxy/TiO <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> nanocomposites focusing on surface charge accumulation and decay. Samples were prepared by dispersing nano-scale TiO <sub xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">2</sub> particles into epoxy (EX) by mixing with shear force. Corona charging tests were performed at room temperature with a relative humidity of ~40%. The charge distribution was measured by means of an electrostatic voltmeter. The results show that the rise time plays an important role in the accumulating charge as well as the charge decay rate and varies with the concentration of nanoparticles and charge polarity. It is suggested that charge dynamics are dependent upon the rise time.

Surface charge decay on HTV silicone rubber: effect of material treatment by corona discharges

Surface charge decay on thick flat samples of high temperature vulcanized silicone rubber is studied prior and after ac and dc corona pre-treatments. It is found that the charge decay rate on the material exposed to ac corona becomes much higher and sensitive to moisture content in the surrounding air. These features are associated with an increased surface conductivity and formation of a silica-like layer on the polymeric surface, both resulting from ac corona treatment. In contrast, characteristics of the charge decay on the material exposed to dc corona are found to be similar to that measured on untreated samples.

Effects of paper-aged state on space charge characteristics in oil-impregnated paper insulation

Oil-paper compound insulation has been widely used in power transformers for quite a long time because of its good performance. The paper insulation degrades under the combined stresses of thermal, electrical and chemical stresses during routine operations, resulting in the reduction of its degree of polymerization (DP) and hence its mechanical and electrical strength. Space charges in a dielectric material have a close relation to its electrical performance. Therefore, in this work, the effect of paper-aged states (with different DP values) on the space charge behavior in oil-impregnated paper insulation is investigated, and the pulsed electro-acoustic (PEA) method is used for the space charge distribution measurement. In order to achieve this purpose, new oil-impregnated paper samples are thermally-accelerated aged for different time interval to obtain different DP values, and then the residual oil in each sample is removed, and the Kraft paper samples are dried in a vacuum dry oven. After that, all paper samples are impregnated with new oil, and PEA measurements are performed at room temperature. The experimental results show that, when the external dc voltage is applied on the oil-paper sample, homo-charge injection occurs for all samples. The samples with different aging states exhibit quite different space charge characteristics for both voltage-on and voltage-off conditions. When the aged states are worse, for voltage-on condition, more charges are induced at cathode and anode, as well as more space charges are accumulated in the bulk. For voltage-off condition, the space charge decay rate shows no obvious change for different aged samples.

Effect of water adsorption at nanoparticle–oil interface on charge transport in high humidity transformer oil-based nanofluid

Transformer oil-based nanofluids (NFs) with TiO2 semiconductive nanoparticles (SNFs) exhibit substantially higher AC breakdown voltage than that of pure transformer oils at variable relative humidity from 20% to 80%. Charge accumulation and decay characteristics of pure oils and SNFs were measured by the pulse electroacoustic technique (PEA). It reveals that SNFs have more uniform internal electric fields and higher charge decay rate compared to pure oils under high relative humidity. It is confirmed by the test results of electrophoresis and thermally stimulated current (TSC) that the nanoparticles adsorb water molecules at the nanoparticle–oil interface, giving rise to the higher shallow trap density and resulting in better charge transport in SNFs.

Effect of nanoparticles on charge transport in nanofluid-impregnated pressboard

Transformer pressboard impregnated in mineral oil modified by nanoparticles (nanofluid) exhibits substantially higher AC and DC breakdown voltage than that of the pure oil-impregnated pressboard (OP). Charge transport and decay characteristics of both pressboards were measured by pulse electroacoustic technique. It reveals that nanofluid-impregnated pressboard (NP) has a more uniform internal electric field and a higher charge decay rate compared to OP, which is caused by an increase of shallow trap density in NP related to the difference of internal structures, based on the test results of thermally stimulated current and Fourier transformed infra-red spectroscopy.