The synthesis of a highly active zeolite beta catalyst for acetyl functionalization of anisole by utilizing the silica precursor obtained from Rice husk is a promising approach for mitigation of agricultural waste. The influence of combustion temperature(CT) (300, 500, 700, and 900 °C) on the characteristics of Rice husk ash was investigated. The C52H obtained at a medium CT (500 °C) has a high surface area compared to the C72H indicates that, merging of smaller crystallites of amorphous silica to form crystalline silica with larger crystallites by applying more thermal energy when CT ≥ 700 °C. The PS-5 catalyst derived from C52H possess high surface area (332 m2/g) and smaller crystallite size (14.8 nm) compared to the PS-7 obtained from C72H, which shows the lower surface area (131.5 m2/g) with a larger crystallite size (25.6 nm). Solid-state NMR studies and NH3-TPD analysis reveals that PS-5 catalyst possessing higher acidity compare to both PS and PS-7. The activity studies confirm that the PS-5 catalyst exhibited superior catalytic activity (>98.0%) compared to PS (conventional) and PS-7 catalysts, making it a potential candidate for continuous production of aromatic ketones acylation reactions.