Characterization Of Natural Cellulosic Fiber Research Articles

Characterization of natural cellulosic fiber extracted from Grewia ferruginea plant stem

The use of natural fibers as reinforcement in polymer composites has gained significant attention due to their eco-friendly, and biodegradability. This study aims to extract and characterize the natural cellulosic fibers from the Grewia ferruginea stem. The fibers were extracted from plant stems using sodium hydroxide and analyzed using Fourier Transform infrared spectroscopy (FTIR) to determine chemical bonds on the fiber and functional group and Thermos-gravimetric analysis (TGA) was used to determine the thermal stability and degradation temperature of the fiber. The crystalline properties of extracted fibers were characterized by x-ray diffraction and surface morphology was characterized by Scanning electron microscopy. The chemical composition of the fibers, including cellulose, hemicellulose, lignin, moisture, extractive content, and fiber linear density, was evaluated. Tensile, thermal, and FTIR studies were conducted to assess the performance properties of the extracted fiber. The analysis revealed that the Grewia ferruginea fibers contain cellulose (60.4–72.6 wt%), hemicellulose (18.5 ± 3.1 %), and lignin (13.55 ± 2.75 %). The extracted fibers have a crystallinity index of 48.76 % and crystallite size of 5.14 nm. The fiber exhibited tenacity, breaking elongation, and Young's modulus values of (52.3 ± 6.5 cN/tex), (3.6 ± 1.8 %), and 43.5 ± 2.3 GPa, respectively. FTIR studies confirmed the presence of biopolymers in the Grewia ferruginea fiber. Additionally, the fibers demonstrated thermal stability up to 275 °C based on thermogravimetric analysis. These findings suggest that the extracted natural cellulosic Grewia ferruginea fiber has the potential to be used as a sustainable reinforcement material in polymeric composites.

Extraction and characterization of natural cellulosic fiber from Mariscus ligularis plant as potential reinforcement in composites

In this paper, fiber from the Mariscus ligularis (ML) plant was extracted and investigated as a naturally derived fiber for its potential as a reinforcement material for composite applications. Physical, morphological, chemical, thermal, and mechanical property analyses of the Mariscus ligularis fiber (MLF) were performed to evaluate its suitability as a reinforcement material while also generating useful data to serve as the basis for its selection in the development of new composite materials. Physical and morphological analysis results showed MLF as a lightweight fiber of diameter 243.6 μm and density 768.59 kg/m3 with a very rough surface that provides excellent interfacial bonding performance. Chemical and thermal results show MLF has mainly cellulose as its crystallized phase, with cellulose and wax contents of 58.32 % and 0.73 %, respectively, and possesses a 72.23 % crystallinity index and a 3.15 nm crystallite size with thermal stability up to 258 °C. The mechanical results show that the tensile strength, elastic modulus, strain to failure, and microfibril angle were in the ranges of 109–134 MPa, 3.27–5.06 GPa, 3.32–9.13 %, and 13.35–20.33°, respectively. These findings show MLF as a potential reinforcement material.

Extraction, Characterization and Suitability Examination of Tinospora Cordifolia (TC) Fibers for Their Applicability as Reinforcement in Composite Materials

The study focused on extracting and characterizing natural cellulose fibers from Tinospora Cordifolia (TC) for use as reinforcement in composite materials. The extraction process involved several steps including plant material selection, fiber separation, and purification. The resulting fibers were characterized using various techniques such as Fourier Transform Infrared spectroscopy, X-ray diffraction, and scanning electron microscopy. This research showed that the extracted cellulose fibers had high crystallinity and a uniform diameter, making them suitable for use as reinforcement in composites as experimented two samples with 22.6 and 25.7% of Hemicellulose, 41.26 and 41.96% of Cellulose and 23.66 and 22.7% of Lignin. The study concludes that TC is a promising source of natural cellulose fibers for composite reinforcement. The mechanical properties of the composites reinforced with TC cellulose fibers were evaluated and compared with those of conventional synthetic fibers. It was found that the composites reinforced with TC cellulose fibers exhibited superior mechanical properties, such as higher tensile strength and improved flexibility. This highlights the potential of natural cellulose fibers as a sustainable alternative to synthetic fibers in the composite industry. The extraction and characterization of natural cellulose fibers from TC demonstrate their potential as reinforcement in composite materials. The study provides valuable information for future research and development in the area of natural fibers for composite reinforcement. The utilization of TC cellulose fibers in composites not only improves their mechanical properties, but also provides a sustainable and eco-friendly solution to traditional synthetic fibers.

Characterization of Natural Cellulosic Fiber Obtained from the Flower Heads of Milk Thistle (Silybum marianum) as a Potential Polymer Reinforcement Material

ABSTRACT Natural fibers are being investigated as alternatives to synthetic fibers in composite materials. In this paper, the physical, chemical, thermal, and morphological characteristics of fibers derived from milk thistle flower heads were characterized as potential polymer reinforcement material using Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD), thermogravimetric analysis (TGA), and scanning electron microscopy (SEM). The fibers were found to contain 42.9% cellulose, 21.2% hemicellulose, and a negligible lignin content. The fiber constituent functional groups were similar to those observed for other natural fibers. The crystallite size and the crystallinity index were found to be 2.23 nm and 84 ± 3%, respectively. The thermal stability of the fibers was found to be 220°C. The fibers start rapidly degrading above 290°C. Morphologically, the fibers appeared to have a nonporous surface with well-structured longitudinal parallel grooves. Cross sectionally, the fibers consisted of multiple hollow lumens interconnected with cell walls. The hollowed nature of the fibers explains the low value (0.33 ± 0.04 g mL−1) of their density. The tensile strength of the fibers was determined to be 22 ± 1 MPa. In conclusion, the fibers of the flower heads of milk thistle can be used as effective reinforcements in polymer matrices.

Characterization of Natural Cellulose Fibers from the Barks of Ziziphus nummularia as a Reinforcement for Lightweight Composite Applications

ABSTRACT This study deals with the extraction and testing of natural cellulose fibers obtained from the barks of Ziziphus nummularia (Burm. f.) Wight & Arn. plants. The extraction of Z. nummularia fibers from its plant barks was done by water retting. The extracted fibers were analyzed for their chemical, crystalline, thermal, mechanical, and physical properties. Surface characteristics of the fibers were examined using a scanning electron microscope and an atomic force microscope. The test results showed that cellulose content was 52.34%. The crystalline index was 45.77% whereas the crystallite size was 2.01 nm. Thermogravimetric analysis showed a maximum degradation temperature of 348°C. The morphological properties showed that Z. nummularia fibers had a good surface roughness that helps in forming interlocks with the matrix on its usage in polymer matrix composites.

Extraction and Characterization of Natural Cellulose Fibers from the Buxus sempervirens for Composite Reinforcement

ABSTRACT The ecological conservation in the current global scenario has led scholars to use natural fibers as a reinforcement in composites that resulted in the exploration of new natural cellulose fibers. This research investigates the extraction and characterization of natural cellulose fibers from the stems of Buxus sempervirens (BS) plants, which are used to produce various products. Manual retting of stems resulted in Buxus sempervirens fibers production, which was then evaluated for their physical, chemical, thermal, crystallographic, and morphological characteristics. The results elucidated that BS fibers had a cellulose percentage of 51.78%, 18.42% hemicellulose, and 17.36% lignin. The Fourier Transform Infrared Spectroscopy results validated the chemical constituents. Crystallographic investigations utilizing X-Ray diffraction revealed a crystalline index of 18.05%. The thermogravimetric analysis of BS fibers showed char residue of 33% and a maximum degradation temperature of 263°C. The BS fibers revealed good surface interlocks that can be inferred from Scanning Electron Microscope. Thus, from the results compared with other natural fibers, we demonstrate that Buxus sempervirens fibers can be effectively used as reinforcement in polymeric composites.

Extraction and Characterization of Natural Cellulosic Fiber from Taraxacum Sect. Ruderalia

ABSTRACT The aim is to explore the utilization of cellulosic fibers extracted from the Taraxacum Sect. Ruderalia, which is also known as dandelion, introduces a potential reinforcement for the green composite industry. This research is focused on the analysis of chemical, physical, thermal, and morphological properties of the Taraxacum Sect. Ruderalia fibers. Its lightweight (1.397 g/cm3) with the presence of an acceptable cellulose ratio (52.7%) and high crystallinity (69.59%) provide comparable tensile strength (57.36 MPa) and Young’s modulus (2.96 GPa) for Taraxacum Sect. Ruderalia fibers. The fibers are experimentally thermal resistant to 272°C according to TGA that may be profitable in extrusion processes in polymeric composite manufacturing. The average fiber diameter and wall thickness were optically 233 µm and 1.5 µm, respectively. Taraxacum Sect. Ruderalia fibers have a rough surface character with some irregularities such as porosities, particles, indentations, protrusions, and also the microfibrillar structure which can support mechanical interlocking with polymer in a composite system. With all these encouraging properties, Taraxacum Sect. Ruderalia fibers can be good alternative reinforcement for common cellulosic bast fibers in the development of ecologically friendly and sustainable polymeric-based materials.

Extraction and Characterization of Natural Cellulosic Fiber from Pandanus amaryllifolius Leaves.

Pandanus amaryllifolius is a member of Pandanaceae family and is abundant in south-east Asian countries including Malaysia, Thailand, Indonesia and India. In this study, Pandanus amaryllifolius fibres were extracted via a water retting extraction process and were investigated as potential fibre reinforcement in polymer composite. Several tests were carried out to investigate the characterization of Pandanus amaryllifolius fibre such as chemical composition analysis which revealed Pandanus amaryllifolius fibre’s cellulose, hemicellulose and lignin content of 48.79%, 19.95% and 18.64% respectively. Material functional groups were analysed by using Fourier transform infrared (FTIR) spectroscopy and X-ray diffraction analysis confirming the presence of cellulose and amorphous substances in the fibre. The morphology of extracted Pandanus amaryllifolius fibre was studied using a scanning electron microscope (SEM). Further mechanical behaviour of fibre was investigated using a single fibre test with 5 kN cell load and tensile strength was found to be 45.61 ± 16.09 MPa for an average fibre diameter of 368.57 ± 50.47 μm. Meanwhile, moisture content analysis indicated a 6.00% moisture absorption rate of Pandanus amaryllifolius fibre. The thermogravimetric analysis justified the thermal stability of Pandanus amaryllifolius fibre up to 210 °C, which is within polymerization process temperature conditions. Overall, the finding shows that Pandanus amaryllifolius fibre may be used as alternative reinforcement particularly for a bio-based polymer matrix.

Extraction and characterization of natural cellulosic fiber from fragrant screw pine prop roots as potential reinforcement for polymer composites

AbstractBiodegradable natural plant fiber isolated from the prop roots of fragrant screwpine (FSP) plant has been thoroughly studied as a potential replacement for artificial fiber in light weight bio‐based composite applications. Chemical, physical, Fourier transform infrared spectroscopy, X‐ray diffraction, scanning electron microscopy, differential scanning calorimetry, and thermo gravimetric studies were used to determine the appropriateness of FSP fiber for use as a novel reinforcement. FSP fibers were determined to have a density of 1.3852 g/cm3 and a diameter of 27–280 μm respectively. Good specific strength and bonding qualities are provided by a high cellulose content (73.10 wt%) and a low wax content (0.35 wt%). The tensile strength of raw FSP fiber was 915 ± 195 MPa, the young's modulus was 33 ± 12 GPa, and the average strain to failure rate was 4.59 ± 2.17%. Thermal analysis (TG and DTG) confirmed FSP fiber's thermal stability up to 235°C. The findings revealed that FSP fiber (FSPF) is an excellent alternative for constructing polymer‐based bio‐composites and other high‐value products with both technical and environmental requirements.

Characterization of natural cellulosic fiber isolated from Malaysian Cymbopogan citratus leaves

A novel natural fiber derived from the Cymbopogan citratus plant was investigated for the first time. The characterization of the C. citratus fibers was conducted, and the chemical composition and physical, thermal, mechanical, crystallinity, and morphological characteristics were studied. The chemical composition analysis of Cymbopogan citratus fiber revealed that the suggested fiber was rich in cellulose contents (37.6%). The tensile test of C. citratus fiber demonstrated the fiber’s average tensile strength of 43.81 ± 15.27 MPa and modulus of elasticity of 1.046 ± 0.33 GPa. Further analysis with X-ray diffraction (XRD) confirmed that the crystallinity index of Cymbopogan citratus fiber was 35.2%, and the crystalline size was estimated as 4.28 nm. The Cymbopogan citratus fiber’s thermal stability was investigated via thermogravimetric analysis (TGA) and observed to be thermally stable (230 °C). A morphological investigation was employed on the fiber via a scanning electron microscope (SEM). The morphological study result exhibited that the fiber had a perforated and rough surface with the lumen in the center. Thus, the findings revealed that the Cymbopogan citratus fiber was a promising potential reinforcement for thermoplastic green composite applications.

Extraction and Characterization Chemical Treated and Untreated Lycium ferocissimum Fiber for Epoxy Composites

ABSTRACT The current study deals with the extraction and characterization of natural cellulose fibers from Lycium ferocissimum plant stems. The fibers were retted using a manual retting process and were subjected to benzoylation treatment. The properties namely physio-chemical, thermal, crystalline, and morphological were measured for both untreated and chemical treated Lycium ferocissimum fibers. Then, the epoxy composites were fabricated using chemical treated and untreated Lycium ferocissimum fibers and analyzed for their mechanical performance. The cellulose content was 67.19%, with the crystalline index of 47.7% for the benzoyl chloride treated Lycium ferocissimum fibers, which were substantially higher than untreated Lycium ferocissimum fibers. While the epoxy composites containing benzoyl chloride treated Lycium ferocissimum fibers showed an increase in the ultimate flexural strength of 51.3 MPa, while it was 42 MPa for untreated Lycium ferocissimum fiber-based composite. Thus, the test results elucidated that benzoyl chloride treatment reduced Lycium ferocissimum fibers hydrophilicity that induced fiber wettability with the matrix to better mechanical properties compared to untreated Lycium ferocissimum fiber-based composites.

Characterization of natural cellulosic fiber from treated acacia arabica and pencil cactus fiber

The natural fiber composites are accepted as the major resources in industrial relevance because of their properties like lightweight, good strength and biodegradability. Acacia and cactus fibers are available in abundance and have high cellulose which is reasonable for polymer matrix composite. The Acacia and cactus fibers are extracted and experimentally determined the density, diameter, cellulose, hemicelluloses, wax, lignin and tensile strength. Acacia and Cactus fibers were treated with 6% NaOH and explored their properties. In this study the 6% NaOH treated Acacia and Cactus fibers achieved better tensile strength 202.82 MPa and 334.35 MPa respectively when compared with untreated fibers. The Fourier Transform Infrared Spectroscopy (FTIR) was made and observed that the functional groups were present in both treated and untreated fibers. The morphological study was made by Scanning Electron Microscope (SEM) to identify the impurities on the untreated fiber surface and surface modification in treated fibers.

Characterization of Natural Cellulose Fibers from the Stem of Albizia Julibrissin as Reinforcement for Polymer Composites

ABSTRACT This current study focuses on the suitability evaluation of cellulose fibers from the stem of Albizia julibrissin (AJ) plant. Density, Diameter, chemical constitutions, thermal degradation nature, crystallinity and topographical properties of AJF was evaluated. The results concluded that the cellulose percentage was higher with 55.83 wt. % with a lower percentage of lignin (16.03 wt. %) and hemicellulose (10.74 wt. %) for AJ fibers. The X-Ray diffraction analysis revealed that the crystallinity index value of the proposed fiber is 27.77% and the crystalline size is 6.79 nm. The thermo gravimetric analysis showed excellent stability with a char residue of 25.23% and a maximum degradation temperature of 330°C. Based on the outcomes in comparison with other cellulose fibers, it is proved that AJ fibers could be effectively used as reinforcement in the manufacturing of lightweight composites.

Characterization of natural cellulosic fiber extracted from Grewia damine flowering plant's stem

Grewia damine is a flowering plant found in India and Sri Lanka. The fiber taken out from the stem bark of G. damine is found to be novel and selected for characterization study. The G. damine stem bark fiber (GDSF) has rich in cellulose contents (57.78 ± 3.56%). Its lower density (1.378 ± 0.036 g/cm3) makes it fit for use in lightweight applications. The weight percentage values of the chemical constituents confirm the use of GDSF for structural applications. Crystallinity index of GDSF was noted as 30.35%. The mechanical properties of GDSF were predicted as 375.6 ± 16.58 MPa tensile strength and 126.2 ± 11.93 GPa modulus of elasticity. The morphological and atomic force microscopy study results revealed that the fiber has rough surface even in its raw form. Hence it can be used to prepare composite specimens with better bonding strength between fiber and polymer. The thermal stability of GDSF was noted as 326 °C. Weibull distribution plots were drawn for validating the physical and tensile property values of GDSF.

Extraction and Characterization of Natural Cellulose Fibers from Sanseveria Trifasciata Plant

The Egyptian Civilization period provided a rich treasure of different types of textiles. Some of these textiles especially in uncontrolled Museums storage are exposed to many challenges such as oscillate Relative Humidity

Characterization of natural cellulosic fiber from bark of Albizia amara

ABSTRACTThe present investigation aimed to understand the physicochemical properties of new natural fiber extracted from Albizia amara (AA) bark. The chemical composition and structural, thermal, and tensile properties of AA fibers (AAFs) were investigated. The results indicated that AAF had crystallinity index of 63.78%, cellulose of 64.54 wt%, hemicellulose of 14.32 wt%, lignin of 15.61 wt%, and low density of 1043 kg/m3. Thermogravimetric analysis shows that AAFs were thermally stable up to 330.6°C and the functional groups of the AAFs were identified by Fourier transform infrared analysis. The AAFs exhibited tensile strength of 640 ± 13.4 MPa with strain rate of 1.57 ± 0.04%. This investigation reveals that AAFs could be a suitable material as reinforce agent in natural fiber–polymer composites for different applications.

Extraction and characterization of natural cellulosic fiber from Passiflora foetida stem

ABSTRACTThis article presents a comprehensive characterization study of natural cellulosic fiber extracted from Passiflora foetida vine stem. The chemical composition of the obtained P. foetida fibers (PFFs) comprised high cellulose (77.9 wt%) and low lignin (10.47 wt%) content and had distinctly higher crystallinity (67.36%) of cellulose, which was determined by an X-ray diffractometer. The PFFs exhibited good tensile strength of 248−942 MPa associated with elongation (1.38−4.67%) during tensile testing. Thermogravimetric analysis revealed that the PFFs are thermally stable up to 320°C with kinetic activation energy of 85.46 kJ mol−1; hence they ensure their suitability as a reinforcing phase in composites for potential applications.

Extraction and Characterization of Natural Cellulose Fibers from Maize Tassel

This article reports on the extraction and characterization of novel natural cellulose fibers obtained from the maize (tassel) plant. Cellulose was extracted from the agricultural residue (waste biomaterial) of maize tassel. The maize tassel fibers were obtained after treatment with NaOH and were carefully characterized while the chemical composition was determined. The chemical composition of the maize tassel fibers showed that the cellulose content increased from 41% to 56%, following alkali treatment. FT-IR spectroscopic analysis of maize tassel fibers confirmed that this chemical treatment also shows the way to partial elimination of hemicelluloses and lignin from the structure of the maize tassel fibers. X-ray diffraction results indicated that this process resulted in enhanced crystallinity of the maize tassel fibers. The thermal properties of the maize tassel fibers were studied by the TGA technique and were found to have improved significantly. The degradation temperature of the alkali-treated maize tassel fiber is higher than that of the untreated maize tassel fibers. This value convincingly showed the potential of maize tassel fibers for use in reinforced biocomposites and waste water treatment.

Extraction and characterization of natural cellulose fibers from common milkweed stems

AbstractNatural cellulose fibers with cellulose content, strength, and elongation higher than that of milkweed floss and between that of cotton and linen have been obtained from the stems of common milkweed plants. Although milkweed floss is a unique natural cellulose fiber with low density, the short length and low elongation make milkweed floss unsuitable as a textile fiber. The possibility of using the stems of milkweed plant as a source for natural cellulose fibers was explored in this research. Natural cellulose fibers extracted from milkweed stems have been characterized for their composition, structure, and properties. Fibers obtained from milkweed stems have about 75% cellulose, higher than the cellulose in milkweed floss but lower than that in cotton and linen. Milkweed stem fibers have low % crystallinity when compared with cotton and linen but the strength of the fibers is similar to cotton and elongation is higher than that of linen fibers. POLYM. ENG. SCI., 2009. © 2009 Society of Plastics Engineers