Characterization Of Composites Research Articles

A Comprehensive Study of Cellulignin Production from Sugarcane Bagasse, Sugarcane Straw, and Energy Cane for Advanced Biofuels: Liquor Composition and Cellulignin Characterizations

A Comprehensive Study of Cellulignin Production from Sugarcane Bagasse, Sugarcane Straw, and Energy Cane for Advanced Biofuels: Liquor Composition and Cellulignin Characterizations

Mechanical characterization of natural fiber composites prepared with untreated and treated ficus religiosa root fibers

Surface modification techniques are used to modify the surface of the natural fibers in order to improve the surface characteristics; in turn other relevant significant properties of the fiber and its composites. In the present work, epoxy composites have been prepared with the untreated and treated F. religiosa root fiber samples at 5, 10, 15, 20, and 25 wt.% fiber loading. Mechanical properties such as tensile, flexural and impact strength of the prepared composite specimens have been tested as per the ASTM standards. From the results, it has been identified that the strength of the proposed composites increases with the increase in fiber loading, and the composites made up of 20 wt.% of the NaOH solution treated fiber sample exhibits better properties under mechanical characterization study. Alkalization filled the holes, cracks, and pores on the outer layer of fibers and significantly improved the surface roughness, which was reflected in the improvement of the proposed composites.

Fabrication and mechanical characterization of AlSi10Mg-reinforced hybrid composites using bottom pouring top-loaded stir-casting method

Fabrication and mechanical characterization of AlSi10Mg-reinforced hybrid composites using bottom pouring top-loaded stir-casting method

Sonochemical synthesis characterization and biocompatibility studies of polymeric composites for biomedical applications

In this work the in situ synthesis of mixtures of Polymethylmethacrylate (PMMA), High Density Polyethylene (HDPE) and Polypropylene (PP) with biocompatible ceramics was carried out, using high frequency ultrasound as an energy source. Starting from calcium hydroxide and ammonium hydrogen phosphate, two different crystalline phases were obtained: hydroxyapatite (HA) and calcite (CaCO3). FTIR and XRD studies showed that for the materials prepared with HDPE, only CaCO3 was formed during the synthesis process. When Polypropylene used, mixtures of HA with CaCO3 were obtained, while for the materials synthesized with Polymethylmethacrylate, only pure HA was obtained. DSC analyses did not reveal any significant changes in the melting temperatures of HDPE and PP, nor in the glass transition temperature of PMMA with the incorporation of HA and CaCO3, in the polymeric matrices. TGA, showed that the decomposition temperatures of these materials increased with respect to those of the polymers alone, indicating a significant thermal stability. Biocompatibility tests with osteoblastic cells and Scanning Electron Microscopy (SEM) studies showed that the composites of PMMA with HA, PP with HA/CaCO3 and HDPE with CaCO3, are capable of promoting cell adhesion and proliferation mechanisms, revealing potential applications as biomaterials for bone replacement.

Effect of curing temperature, silica fume, and waste tire rubber aggregate on material characterization of lightweight geopolymer composite

This study investigates the potential effect of curing temperature (80 °C and 100 °C), the effect of using waste tire rubber aggregates (WTRA), and silica fume (SF) on the properties of lightweight geopolymer (LG) composite. In LG, SF replaced 20 % of the ground granulated blast furnace slag (GGBS), and WTRA replaced pumice aggregate to varying degrees (15 %, 30 %, and 45 % by volume). The physical properties of the LG composite were assessed through apparent porosity, water absorption, and hardened density. The mechanical properties were examined by testing compressive strength (CS) and flexural strength (FS). The effect of high temperature (300 °C and 600 °C) was examined on CS and mass loss of LG composite. The durability of the LG composite was analyzed using mercury intrusion porosimetry (MIP), capillary water absorption, freeze-thaw, and thermal conductivity. The material characterization of the composite was done using scanning electron microscopy (SEM), X-ray diffraction (XRD), thermogravimetric analysis (TGA), and differential thermogravimetry (DTG) curves. After 28 days, LG composites showed increased porosity and water absorption with the increased WTRA and SF, with higher values at 100 °C. Compressive and flexural strengths decreased with the increased WTRA and SF, especially at higher temperatures. The TGA-DTG curves show that the LG-0–80 mix had the lowest mass loss (15.25 % at 400°C and 19.36 % at 600 °C), while the LG-SF-45–100 mix had the highest mass loss (22.22 % and 24.53 %, respectively). XRD and TGA-DTG analyses reveal that using SF increases Ca(OH)₂ peaks and alters the geopolymer composition, improving the mechanical performance of the LG-SF-0–80 mix and enhancing the thermal stability of the composites.

Unveiling the effect of bovine serum albumin on the corrosion resistance of high nitrogen stainless steel for cardiac stents

Herein, the effect of bovine serum albumin (BSA) on the corrosion resistance of high nitrogen stainless steel (HNS) is systematically investigated based on experimental characterizations and first-principle calculations. Electrochemical measurements firstly prove that the anodic dissolution rate of HNS has significantly increased due to BSA adsorption and the potential deterioration of the passive film. By subsequent morphology and composition characterizations, it is demonstrated that BSA forms a 1.9 μm porous adsorption layer on HNS surface via the peptide bond mostly in -helix and -turn structure. Furthermore, Mott-Schottky tests confirm that the carrier (cation vacancy) density in the passive film has dramatically risen from 6.29×1021 cm-3 to 1.97×1022 cm-3 after BSA adsorption, which could be ascribed to the detachment of Cr atom from its original lattice due to the preference interaction between BSA molecule and Cr atom. Most importantly, such an increased defects will further promote the dissolution process of both the passive film and HNS matrix according to point defect model (PDM), which will definitely undermine the protective ability of the passive film and eventually result in the declined corrosion resistance of HNS in BSA-contained solution.

Investigation and Characterization of Novel Aluminium Matrix Composites Enhanced by Recycled Borosilicate Glass

Investigation and Characterization of Novel Aluminium Matrix Composites Enhanced by Recycled Borosilicate Glass

Manufacturing and Characterization of Polypropylene-Paper Composites for Automotive Applications

The automotive industry is under significant pressure to curb greenhouse gas emissions from their products as the negative impacts on the environment are increasingly apparent. As such, there is significant interest within the industry to develop low-carbon footprint materials. Natural fiber composites are therefore appealing due to both their decreased carbon footprint, as well as their relatively low cost, low density, and beneficial acoustic properties. This research specifically focuses on the use of paper fibers as composite reinforcements. Paper offers additional benefits over other natural fiber types in that it is globally available, does not compete with food resources, and has well-established quality control techniques. The goal of this work was to study the manufacturing of polypropylene (PP)-paper fiber composites using a hybrid wet-lay/compression molding processing. The processing parameters studied included molding temperature, molding duration, and molding pressure. Paper composites were characterized for properties including flexural strength, impact strength, and water uptake rate. An optimal set of processing parameters was identified in which cycle time and energy inputs (e.g. temperature and pressure) were minimized while retaining desired material properties.

Hygrothermal and mechanical characterization of novel hemp-lime composites with enhanced consistency

Hemp-lime composites have captured attention in the construction industry due to their sustainability and excellent hygrothermal performance. However, variability and inconsistent performance have hindered their widespread adoption. This research introduces a novel approach to improve the uniformity and hygrothermal characteristics, aiming for reproducibility and consistency comparable to traditional insulation materials. This method included (1) reducing hemp particle size to coarse (1.33 mm), medium (0.92 mm), and fine (0.72 mm) particles; (2) maximizing the hemp proportion to 70 % by weight; and (3) standardizing dry density using vibration techniques. The findings indicate dry density variability reduction in all samples, with a coefficient of variation ranging from 0.16 % to 2.36 %. The hygrothermal analysis demonstrates enhanced insulation and moisture-buffering properties, along with reduced directional disparity in thermal conductivity (1.2–6.8 %) compared to the control sample, particularly in samples with fine particle sizes. Thermal conductivity was within the range of 0.0535–0.0667 W/m K, considerably lower than previously reported values. Also, a positive correlation is observed between moisture-buffering and hemp ratio, indicating that higher hemp ratios in the composite lead to increased moisture capacity, with moisture buffer values of 2.47, 2.28, and 2.12 g/m² RH corresponding to the binder-to-hemp ratio of 30:70, 40:60, and 50:50 by weight, respectively.

Synthesis and Characterization of Submicron Spherical Core-Shell High-Energy Composites via Electrospray Method

In this study, submicron spherical core-shell high-energy composites of RDX/F2311@CuO/Al were synthesized using the electrospray method. The results demonstrate that the combustion time of composite high-energy microspheres, prepared via electrospraying, was significantly reduced to 460.0 ms from an original 2296.0 ms observed in samples prepared by physical mixing. Additionally, the flame burning was more concentrated, and the combustion process exhibited greater stability. Additionally, the flame combustion exhibited greater concentration and the overall combustion process was more stable. Furthermore, by manipulating the proportion of non-energy-containing components, it is possible to obtain composites with adjustable combustion rates. By manipulating the ratio of aluminium thermal agent, it is possible to procure a composite material with a more vigorous combustion process, thereby enabling the functional modulation of said composite material. Compared to the raw material RDX, the H50 value of the composite microspheres has increased from 14.49cm to 25.16cm, indicating a significant enhancement in impact resistance along with a remarkable desensitization effect. Additionally, the explosion percentage of the composite microspheres has been reduced from 84% to 68%. These significant desensitization effects highlight the morphological advantages of the core-shell structure and the synergistic reaction energy benefits of the components involved.

Fabrication and characterization of SiC-reinforced magnesium-matrix composites with honeycomb structures and anisotropic properties

This study presents a novel approach for fabricating SiC-reinforced magnesium matrix composites by combining digital light processing (DLP) with pressureless infiltration. Pre-oxidation of SiC powder enhanced its wettability with the magnesium alloy, enabling the near-net-shape fabrication of honeycomb Mg-based composites with precisely controlled SiC and Al2O3 powder ratios. The influence of varying ceramic content on the microstructure and compressive properties of the composites was investigated, revealing significant mechanical anisotropy. A combined approach utilizing fracture morphology analysis and finite element simulations elucidated the compressive behavior and failure mechanisms of the composites under different loading directions. This work not only offers a promising route for on-demand design and fabrication of Mg-based composites but also provides valuable insights into understanding the mechanical behavior of architected composites.

Characterization and machinability analysis of aluminium-based metal matrix composites (MMC): A critical review

Hybrid nanocomposite has progressively attracted advanced industrial and automotive sectors in recent years. Hybrid nanocomposites have emerged as a viable material for a wide variety of engineering uses because of their excellent thermal, mechanical, and environmental characteristics. This article introduces reviews on the turning process of metal matrix composites (MMC) and its examination of the improvement of the machining indicators of MMCs. Furthermore, this review reviews the latest research progress in sustainable turning of aluminium based composite particularly hybrid nanocomposite. Moreover, a summary regarding the impact of machining variables on measured outputs is also discussed. Machinability evaluations, along with other factors, are considered critical analyses that directly determine the cost of machining processes. The point of this review is to focus on the impact of essential cutting variables on hybrid turning processes. Furthermore, this paper draws extensive conclusions based on experimental findings. This research also identifies potential future topics that need to be solved to improve the development and characterization of hybrid nanocomposites. In brief, the paper presents a comprehensive review for developing a sustainable machining approach for these fabricated hybrid metal matrix composites.

Development of sustainable aluminum alloy‑tungsten carbide hybrid composites using industrial waste - An experimental analysis

The research article focuses on the development of aluminum alloy 6061 sustainable composites with the utilization of industrial waste through the use of the stir casting process. Recycling industrial waste is essential for reducing environmental impact. Thus, the red mud waste came from the aluminum production process, which was considered for producing sustainable metal matrix composites (MMCs). Also, tungsten carbide (WC) microparticles have been used to develop hybrid aluminum composite materials. The concentrations of red mud and tungsten carbide were 2 wt%, 4 wt%, and 6 wt%, respectively, and were used to achieve the desired strength performance of aluminum metal matrix composites. The elemental and bonding analyses of hybrid composites were analyzed using X-ray Diffraction (XRD) and Fourier Transform Infrared Spectroscopy (FTIR) analysis. Mechanical characterizations of aluminum hybrid sustainable composites were also investigated, including tensile, compression, and microhardness testing. The results show that increasing reinforcement by up to 4 wt% increases the mechanical strength of aluminum alloy composites. The tensile, compression, and microhardness of metal matrix composites are increased by 25.24 %, 40.2 %, and 20.6 %, respectively, as compared to the aluminum alloy 6061 alloy. The surface morphology of metal matrix composites was analyzed by utilizing Field emission scanning electron microscopy. The proposed sustainable aluminum composites have the potential to develop structural and automotive components due to their higher strength-to-weight ratio.

Black powder and mineral deposits in the LPG production and processing line: Analytical study and formation mechanisms

The accumulation of mineral deposits such as black powder causes severe impacts throughout the gas production and transport process. The phenomenon takes place from gas wells to LNG/LPG treatment plants and terminals. The complexity lies in understanding the mechanisms by which these materials are formed in random quantities, as well as their varied nature. The aim of this study is to monitor black powder and other mineral deposits formation in a chain of gas production and processing situated in the south of Algeria and unravel their root causes. To that extent, an analytical study was carried out on four samples of both mineral deposits and black powder taken from an LPG processing and production unit. The adopted analytical approach included an exploration of the textural and structural properties. It also involves a composition characterizations related to the content of metallic elements, moisture, organic and mineral matter. The particle distribution is also determined. The analytical study was conducted using gravimetric determination, XRD, XRF, SEM/EDX and Raman spectroscopy. Particle distribution was given by Laser granulometry technique. The results of the DRX/FRX and EDX characterization primarily revealed that the samples contain a variety of mineral components such as iron oxides; magnetite Fe3O4 and hematite Fe2O3, iron oxy-hydroxide FeO(OH), iron sulphide FeS2, calcite CaCO3, SiO2 and halite NaCl. The presence distribution of these components depends on the location of the sample in gas line. Granulometry study shows that black powder contamination can be spread over a wide spectrum of particle sizes ranging from 1.51 µm to 678.50 µm. This study has allowed to elucidate the nature and distribution of particles deposited at different positions in the LPG production chain and to propose probable mechanisms for their formation.

Development and characterization of sustainable epoxy resin composites reinforced with palm kernel shell particulate and sisal fiber

This study explores the development and characterization of epoxy resin composites reinforced with palm kernel shell (PKS) particulate and sisal fibers, aiming to create sustainable and high-performance materials. Elemental composition analysis using energy dispersive X-ray revealed significant increases in carbon and oxygen content with higher PKS particulate content, indicating successful reinforcement integration. The mechanical properties were evaluated through Brinell hardness, impact energy, impact strength, tensile stress, and wear resistance tests. The Brinell hardness increased from 31.8 kg/mm2 in the control sample to a peak of 60.6 kg/mm2 in sample SP4, demonstrating enhanced hardness with PKS particulate addition. Impact tests identified an optimal reinforcement level in sample SP3, which achieved the highest impact energy (83 J) and impact strength (47.43 kJ/m2). Tensile stress analysis showed a maximum tensile stress of 28.7991 MPa for SP3, while excessive PKS content in SP4 reduced this to 20.4612 MPa. Wear tests indicated a trade-off between mechanical reinforcement and wear resistance, with the control sample exhibiting the lowest wear rates and SP4 the highest having a 91.9% increase. Based on the obtained results, SP3 with 0.8 g PKS particulate, 0.2 g sisal fiber in epoxy resin matrix seems the optimized composite with enhance mechanical properties without compromising wear resistance.

Physics-based prediction of moisture-capture properties of hydrogels

Moisture-capturing materials can enable potentially game-changing energy-water technologies such as atmospheric water production, heat storage, and passive cooling. Hydrogel composites recently emerged as outstanding moisture-capturing materials due to their low cost, high affinity for humidity, and design versatility. Despite extensive efforts to experimentally explore the large design space of hydrogels for high-performance moisture capture, there is a critical knowledge gap on our understanding behind the moisture-capture properties of these materials. This missing understanding hinders the fast development of novel hydrogels, material performance enhancements, and device-level optimization. In this work, we combine synthesis and characterization of hydrogel-salt composites to develop and validate a theoretical description that bridges this knowledge gap. Starting from a thermodynamic description of hydrogel-salt composites, we develop models that accurately capture experimentally measured moisture uptakes and sorption enthalpies. We also develop mass transport models that precisely reproduce the dynamic absorption and desorption of moisture into hydrogel-salt composites. Altogether, these results demonstrate the main variables that dominate moisture-capturing properties, showing a negligible role of the polymer in the material performance under all considered cases. Our insights guide the synthesis of next-generation humidity-capturing hydrogels and enable their system-level optimization in ways previously unattainable for critical water-energy applications.

Thermal performance and characterization of phase change material composites reinforced with nano-particles in thermal energy storage systems: a review

Abstract The energy storage now a days is a cumbersome process to exploit its best use. This review paper discusses the challenges of efficiently utilizing energy storage and proposes phase-change materials (PCMs) with Nano-particle
reinforcement as a solution, particularly for storing solar thermal energy. Various synthesis methods for PCM, including impregnation and encapsulation, are examined, with emphasis on factors like particle size, shape, and solid content. Carbon-based materials, including carbon nanotubes and graphene oxide, emerge as superior options due to their reliability, cost-effectiveness, lightweight nature, and high heat transfer efficiency, with minimal environmental impact. This review highlights the enhanced thermal conductivity of Nano-particle-reinforced PCM composites, emphasizing their thermally stable, durable, and conductive properties. Additionally, it discusses thermal performance through techniques like DSC, TGA, and DTG, along with material characterization methods such as FTIR, SEM, XRD, EDX, and XPS analysis. Overall, the research underscores the promising potential of Nano-particle-reinforced PCM composites for efficient energy storage and thermal management applications.

Clay Minerals/TiO2 Composites—Characterization and Application in Photocatalytic Degradation of Water Pollutants

TiO2 used for photocatalytic water purification is most active in the form of nanoparticles (NP), but their use is fraught with difficulties in separation from solution or/and a tendency to agglomerate. The novel materials designed in this work circumvent these problems by immobilizing TiO2 NPs on the surface of exfoliated clay minerals. A series of TiO2/clay mineral composites were obtained using five different clay components: the Na-, CTA-, or H-form of montmorillonite (Mt) and Na- or CTA-form of laponite (Lap). The TiO2 component was prepared using the inverse microemulsion method. The composites were characterized with X-ray diffraction, scanning/transmission electron microscopy/energy dispersive X-ray spectroscopy, FTIR spectroscopy, thermal analysis, and N2 adsorption–desorption isotherms. It was shown that upon composite synthesis, the Mt interlayer became filled by a mixture of CTA+ and hydronium ions, regardless of the nature of the parent clay, while the structure of Lap underwent partial destruction. The composites displayed high specific surface area and uniform mesoporosity determined by the size of the TiO2 nanoparticles. The best textural parameters were shown by composites containing clay components whose structure was partially destroyed; for instance, Ti/CTA-Lap had a specific surface area of 420 m2g−1 and a pore volume of 0.653 cm3g−1. The materials were tested in the photodegradation of methyl orange and humic acid upon UV irradiation. The photocatalytic activity could be correlated with the development of textural properties. In both reactions, the performance of the most photoactive composites surpassed that of the reference commercial P25 titania.

Development and characterisation of myristic acid-paraffin wax, silica fume and zinc oxide cementitious composites for thermal control in buildings

This study focuses on the development of a cement-based phase change material (CBPCM) to improve thermal performance in construction applications. The CBPCM was synthesised by blending 90 wt% of myristic acid with 10 wt% of paraffin wax, absorbed into 10 wt% of silica fume to prevent leakage. Additionally, 5 wt% of zinc oxide was added to improve thermal conductivity. A leakage test conducted with 10 wt% of SF exhibited no signs of leakage during thermal cycling. Scanning electron microscopy (SEM) established the uniform dispersion of the nano-enhanced phase change material (NEPCM) within the cement. Fourier transform infrared spectroscopy (FTIR) analysis revealed no chemical structure changes after 100 thermal cycles. Thermogravimetric analysis (TGA) confirmed thermal stability in the temperature range of 74.8–236.64 °C with a mass loss of 6.3 wt%. The material demonstrated minimal variation in phase change temperatures and latent heats after 100 cycles. The latent heat of the CBPCM was 1.09 J/g during melting and 1.887 J/g during solidification. Incorporating NEPCM into the cement increased the thermal conductivity of the cement matrix to 0.559 W/m K. These findings underline the potential of the CBPCM for energy-efficient construction, offering enhanced thermal storage, stability, and conductivity.

Mechanical characterization and performance evaluation of twisted Jute-Kevlar hybrid composites with varied fiber orientations

Abstract Composite materials play a vital role in developing new materials in engineering and technology. Composites show how the properties of the matrix and reinforcement work together to create more robust, more rigid materials than would be possible from the individual components working alone. They consist of two or more component materials combined with notably dissimilar physical or chemical characteristics. Two categories of composite coupons have been developed in this research work: the first category (C1) is made up of jute twisted-Kevlar twisted jute fiber (0/90 degree), and the second category (C2) is made up of jute twisted-Kevlar twisted jute fiber (0/45 degree). The nano-silica is reinforced with the matrix with a weight percentage of 0%,5%,10% and 15%. The necessary interfacial adhesion and bonding between fiber layers have been accomplished using a 10:1 mixture of epoxy resin (LY556) and hardener (HY951). According to ASTM guidelines, the tensile, flexural, impact, double shear, wear, and hardness tests were carried out. This study uses two natural and synthetic fibers—twisted Jute and Kevlar fibers—as reinforcement. The Jute fibers have a high strength since they are high in cellulose. Efforts have been made to create a composite material with completely different twisted fiber orientations and to assess the mechanical properties of the composites. This involved various mechanical tests, analysis of wear surfaces, as well as DMA, DSC, FEA testing, and ultimately, the machining of the composites studied. The machining parameters used in waterjet machining have been carefully analyzed.