Simultaneous measurements of the brightness temperature and short-period electric field fluctuations were carried out to reveal possible connections between the electrification rate and turbulence intensity in clouds. The measurements were conducted in Nizhny Novgorod, Russia (56°19′37″N 44°00′27″E) in 2013 and 2018. The 8 mm radiometer was used to measure the brightness temperature of thermal radiation, and the vertical component of the atmospheric electric field were carried out using an electrostatic fluxmeter. With the use of meteorological data and electric field measurements the state of analyzed events has been classified into 4 types: cloudless atmosphere and high-level clouds (Cs), cumulus clouds (Cu), cumulonimbus clouds without lightning that cause strong electrical field disturbances near the ground surface (Cb), cumulonimbus thunderstorm clouds with lightning discharges (Cb+). Detailed statistical characteristics of brightness temperature fluctuations and short-period electric field fluctuations are obtained for the first time for the indicated types of events.It is shown that measured spectral densities of the atmosphere brightness temperature and electric field fluctuations correspond well enough in the considered frequency range to the results of presented theoretical consideration. Precipitation particles in clouds can be considered herewith as passive scalar, and the movement of inhomogeneities in the particle density can be described by Kolmogorov theory. Since electric charges are located on the precipitation with small droplet and ice particles, an increase in the inhomogeneities of the water content means likely an increase in the inhomogeneities of the electric charge. For thunderclouds the estimates of the relative fluctuations of liquid water content give values of the order of tens of percent. There is a tendency towards a relative increase in brightness temperature fluctuations at high frequencies in the band around f ≈ 10−2 Hz (and possibly higher than fmax ≈ 0.05 Hz) for the sequence of cloud types Cu, Cb, Cb+.