Phase Transformation Characteristics Research Articles

A regenerated cellulose fiber with high mechanical properties for temperature-adaptive thermal management

The escalating global population has led to a surge in waste textiles, posing a significant challenge in landfill management worldwide. In this work, ionic liquid 1-butyl-3-methylimidazole acetate ([Bmim]OAc) and DMF (N, n-dimethylformamide) were used as solvents to dissolve waste denim fabric, then vanadium dioxide (VO2) nanoparticles were introduced into the spinning solution, and cellulose fibers were regenerated by dry-wet spinning process, to promote the recycling of waste cotton fabric. Finally, regenerated cellulose fibers with high added value were prepared by dry-wet spinning. Through this innovative strategy, on the one hand, because VO2 can form a large number of hydrogen bonds between the regenerated cellulose molecules, and realize the cross-networking structure of the molecular chains inside the fiber, the mechanical properties of the regenerated cellulose fibers are enhanced. On the other hand, due to the thermal phase transformation characteristics of VO2, it also endows the regenerated cellulose fiber unique intelligent temperature control function. Compared with the pristine regenerated fiber, the tensile stress of the regenerated fiber after adding VO2 nanoparticles (F-VO2) increased by 25.6 %, reaching 158.68 MPa. In addition, the F-VO2 fibric provides excellent intelligent temperature control, reducing temperatures by up to 6.7 °C.

Effect of heat treatment conditions on the phase transformation characteristics of nitinol

Nitinol is the most widely used shape memory alloy in medical applications. In this study, the effect of different heat treatment conditions on the phase transformation characteristics of medical-grade nitinol was investigated. Nickel-rich nitinol wires containing 50.6% nickel with a diameter of 120 μm were used in the experimental studies. The nitinol wires were heat treated for 10 minutes at heat treatment temperatures between 540 and 570 °C. Then, nitinol wires were heat treated at a heat treatment temperature of 550 °C between 8 and 14 minutes. The austenitic and martensitic transition temperatures of these samples were measured using differential scanning calorimetry (DSC). In the experiments with 10 minutes of heat treatment time, transition temperatures decreased, and hysteresis increased with the increase in heat treatment temperature. This is related to the amount of precipitates in the structure. In the experiments carried out at 550 °C, transition temperatures decreased, and hysteresis increased with increasing heat treatment time. Experimental studies showed that the austenite finish (Af) temperature of all nitinol wire samples was below 37 °C, and they will exhibit superelasticity in the human body.

Study of titanium alloy Ti–Al–Zr–Nb–V during heating under deformation and its phase transformation features

An alloy based on Ti–Al–Zr–Nb–V was prepared and its deformation behavior at elevated temperatures was studied. The microstructure and phase of the alloys were characterized by optical microscopy, scanning electron microscopy, thermal analysis, and mechanical testing. The results showed that the Ti–Al–Zr–Nb–V alloy, when stretched, exhibits a superplasticity effect in the range of 975℃ to 1100℃, with an elongation of up to 400%. It was found that superplasticity develops in the temperature region of the α+β→β transition and is accompanied by a change in grain size and redistribution of alloying elements among phases.

Mechanical response and phase transformation characteristics of R-phase NiTi shape memory alloy under high strain rate compression

R-phase NiTi shape memory alloy (R-NiTi SMA) has many excellent properties, but there are application problems such as simple structure and high price. High velocity impact welding can effectively solve these problems, but the research on the mechanical response and phase transformation (PT) characteristics of R-NiTi SMA under dynamic deformation is lacking. Therefore, the quasi-static (0.001 s-1) and dynamic (500 s-1, 1000 s-1, 1500 s-1, 2000 s-1) compression experiments were conducted on R-NiTi SMA in this research. The results showed that the true stress-strain curves of R-NiTi SMA during deformation were characterized by three stages, including the superelastic, elastic, and plastic segments. The critical stress of austenite to R (A-R) and R to martensite (R-M) phase transformation increased with the increase of strain rate, and the phase transformation process gradually disappeared when the strain rate exceeded 1000 s-1, which was related to the velocities of A-R and R-M phase transformation. With the increase of strain rate, defects such as dislocations increased and hindered the phase transformation process during unloading, resulting in the increase of A-phase content. In addition, the enthalpy of the deformed samples decreased significantly and the temperature ranges of phase transformation increased slightly. This work deepens the understanding of the dynamic response of R-NiTi SMA and helps to expand the application of high strain rate processing technology in R-NiTi SMA.

Phase Transformation of Arsenic, Antimony and Lead in High-Grade Copper Matte Converting

The duration of the high-grade matte converting process is short, the amount of slag is small, and it is difficult for the original impurity removal operation in the low-grade matte converting process to meet the current production demand. Because the removal method for impurity elements during high-grade matte converting is unclear, the phase transformation of impurity elements during this process is investigated in this study. The results show that arsenic exists mainly in the form of FeAsO4 and As2O5, antimony in the form of Sb and Sb2O5, and lead in the form of PbS and PbO in high-grade matte. During the converting process, arsenic and antimony mainly exist in the melt in the form of oxides and gradually aggregate into large particles with increasing copper content in the melt. Lead exists in matte in the form of PbS until the end of the converting process, and PbS is not completely oxidized until the matte converted to blister copper phase. The phase transformation characteristics of copper, iron, sulfur and impurity elements in the process of high-grade matte converting were revealed. This study provides a theoretical reference for the formulation of an efficient impurity removal scheme for the converting process.

Studying the features of complex beryllium-containing silicate phases co-crystallization in zonal samples using the x-ray electron probe microanalysis method

Research subject. Silicate ingots containing four species-forming components Be, Mg, Al, and Si and belonging to the crystallization region of beryllium indialite (with the formula of Mg2BeAl2Si6O18 and a beryl-type structure). Aim. To investigate the fundamental problem of identifying the patterns of matter differentiation and the stable and metastable phase formation in silicate matrices. Methods. The evolution of the phase composition of silicate melts was registered using a temperature gradient method. Results. New data on the features of phase transformations in silicate melts belonging to the region of beryllium indialite were obtained by electron probe microanalysis (EPMA). Co-existing metastable and stable mineral phases were identified, and the similarity of their compositions with different structures was shown. The nature of impurity phases at each stage of crystallization was established. Conclusions. The evolutionary sequence of phase associations ensuring the crystallization of beryllium indialite and metastable phases of a similar composition, the nature of which is determined by the initial ratio of components, was experimentally recorded. The range of possible phase associations that co-crystallize or replace a stable phase with a beryl structure in melts from the region of existence of beryllium indialite in the BeO–MgO–Al2O3–SiO2 system was extended. The selectivity of the coloring element chromium entry into various phases of the studied system is shown depending on the capabilities of their structure. The addition of a chromophore is a reliable criterion for visualizing successive layers, zones, and areas of changing phase associations in the final ingot.

Trends in GeTe Thermoelectrics: From Fundamentals to Applications

AbstractGermanium telluride (GeTe) with ultrafast ferroelectric transition, Rashba‐like electronic transport, and anomalous phonon anharmonicity are historically studied for potential memorizing and thermoelectric applications. Due to recent breakthroughs in spintronics, valleytronics, orbitronics, pre‐eminent GeTe thermoelectrics have re‐attracted enormous interest from both academia and industries, with increasing reports of significant figure‐of‐merit over 2.7 and the maximum efficiency of up to 17.0%. Here, the emerging trends in advancing GeTe thermoelectrics, starting from fundamentals of phase transformation, crystal structure, bonding mechanisms, and transport characteristics, with a highlight on the roles of Ge_4s2 lone pairs, are timely overviewed. Technical insights in synthesis, characterization, property measurement, and computation are then summarized. After that, several innovative strategies for increasing the figure‐of‐merit, including entropy engineering, nanostructuring, and hybridization, which will further benefit near‐room‐temperature and n‐type performance, are examined. Moreover, high‐density and high‐efficiency devices with broad working temperatures are discussed as a result of rational configurational and interfacial design. In the end, perspective remarks on the challenges and outlook envisaging for next‐generation GeTe thermoelectrics, which will play a prominent role in future energy and environmental landscapes, are provided.

The driving characteristics of bidirectional SMA wire actuators - Theoretical modeling and experimental testing

Bidirectional shape memory alloy (SMA) wire actuators play a critical role in driving applications thanks to their characteristics in memory shaping and good overall performance. SMA wire actuators were often studied at a single load type, and there is no comprehensive comparison investigation of different SMA wire actuators in the literature. In this paper, the driving characteristics of four available types of SMA wire actuators, namely, dead-load, biased spring, differential type, and biased superelastic SMA wire actuators are modelled mathematically and then tested in laboratory settings. The characteristics of SMA wire actuators are quantitatively measured and then compared under a range of application scenarios. The output displacement and thermal-electric models of NiTi SMA wires are derived based on the Brinson constitutive model with stress effects in consideration. A customized SMA wire actuator test device is developed to evaluate the theocratical models and benchmark testing four types of SMA wires and their driving characteristics, including structure, design, displacement, response and recovery time, energy efficiency and hysteresis properties. The SMA wire phase transformation characteristics of the four actuators are tested under different activation currents, and then quantitatively compared. In conclusion, this paper adds theoretical and experimental significance to the literature on SMA wire actuators. The reference value on the phase transformation characteristics of SMA wires can be used to guide SMA application in industrial designs and enable theoretical studies in complementary research areas.

Influence of applied stress on shape memory characteristics of Ni50Ti45Cu5 (at.%) alloy subjected to thermomechanical cycling

Shape memory alloys have made rapid progress in many domains, primarily biomedical (endovascular stents, orthodontic archwires), and engineering (smart actuators, robotics, hydraulic couplings). The selection of a shape memory alloy for the indented application is based on its characteristic phase transformation temperatures. These characteristic temperatures are influenced by myriad parameters, such as composition, microstructure of the alloy, defect density, etc. When an shape memory alloy under an external load is subjected to cyclic operations to perform useful work, for example, actuators, these characteristic temperatures are modified. This study, therefore, aims to understand the influence of external loading on the shape memory characteristics of a Ni50Ti45Cu5 (at.%) alloy. A wire of 1.43 mm diameter and length of 100 mm was subjected to heating and cooling between its phase transformation temperatures in a cyclic manner under constant stress (of up to 60 MPa). The maximum recovery strain, actuation/retraction rate, and the stress influence coefficient were determined and compared with those of the other Ni-Ti and Cu-based shape memory alloys. The results show that raising the load level causes an increase in the transition temperatures, especially the Ms (martensite start temperature) rather than the other phase transformation temperatures (martensite finish (Mf), austenite start (As), austenite finish (Af)). It also significantly affects the recovery strain and the rate of retraction during forward transformation and the symmetry of operation.

Effect of Surface Roughness and Chemical Composition of Metastable Austenitic Stainless Steels on Electrochemical Polishing-Induced Martensitic Transformation

Herein, we analyzed the martensitic transformation kinetics during electrochemical polishing (EP) for stainless steel specimens with varying surface roughness and austenite stability. Martensite fraction measurement demonstrated that specimens with higher surface roughness and lower austenite stability exhibited relatively higher levels of martensitic transformation. To understand these phase transformation characteristics, the amount of charge build-up on the specimen surface during EP was calculated using COMSOL Multiphysics simulations for specimens with different surface roughness. The effect of charge build-up-induced stress was analyzed using previously published first-principles calculations. We found that specimens with higher surface roughness accumulated more charge build-up, resulting in greater stress and a martensitic transformation driving force. Furthermore, the critical energy required for the martensitic transformation was calculated using Thermo-Calc for specimens with different austenite stabilities. We demonstrated that the martensitic transformation kinetics during EP could be explained in terms of austenite stability, similar to the stress-induced martensitic transformation.Graphical

Berkovich indentation and the Oliver-Pharr method for shape memory alloys

Advances in instrumentation and interpretation of nanoindentation data with the Oliver-Pharr (O-P) method have fueled the reliable assessment of hardness and elastic modulus. However, shape memory alloys (SMAs) undergo a reversible phase transformation that complicates and challenges the conventional practice. This paper examines through finite element simulations the variation in nanoindentation response with SMA constitutive properties and the deformation regimes underneath a Berkovich indenter. Unique features of phase transformations – including tension-compression asymmetry, limited magnitude of transformation strain compared to plastic strain, and pressure-dependent transformation stress – inject fundamentally different patterns of elastic and inelastic deformation, compared to conventional elastic-plastic indentation. This can generate errors of up to 16% and 40% in hardness and modulus, respectively, when a conventional O-P approach for elastic-plastic materials is used. These errors are decreased if (1) contact stiffness is measured over a reduced (2% or less) portion of the initial unloading response and (2) new material-dependent expressions are used for geometric and correction factors in the O-P nanoindentation analysis. Approximate analytic expressions are obtained for the effective elastic modulus and martensite volume fraction in the inhomogeneous medium created by indentation. This new method is applied to Ni50.5Ti49.5 (at%) wire and for other SMAs, general guidance for selection of geometric and correction factors is provided.

Structural-phase transformations of 12% chromium ferritic-martensitic steel EP-823

The features of phase transformations of 12 % chromium ferritic-martensitic steel EP-823 under heating and cooling conditions in the temperature range from 30 to 1100 ℃ were studied by the methods of high-temperature X-ray diffraction analysis (XRD) in situ and differential scanning calorimetry (DSC). According to XRD in situ data, upon heating, the temperatures of the beginning and end of the (α → γ) transformation of ferrite (martensite – austenite) are Ac1 ≈ 880 °C, Ac3 ≈ 1000 °C, respectively. Upon cooling, a diffusion (γ → α) transformation occurs with critical points – Аr1 ≈ 860°С (beginning temperature) and Аr3 ≈ 840 °С (end temperature). According to DSC data, during heating, the critical points of the (α → γ) transformation are Ac1 ≈ 840 °C and Ac3 ≈ 900 °C. During cooling, a martensitic (γ → α) transformation is realized with critical points of the beginning of Ms = 344 ℃ and the end of Mf = 212 ℃ of this transformation. The XRD in situ analysis revealed no precipitation of carbide phases under heating and cooling conditions of steel EP-823. Position of the critical points of phase transformations depends on the research method (XRD in situ or DSC), which is determined by the difference in effective (taking into account the time for shooting in the XRD method) heating-cooling rate. The effect of elemental composition on the position of critical points of phase transformations and the formation of structural-phase states of ferritic-martensitic steels is discussed. It is shown that the increased content of ferrite-stabilizing elements (Cr, Mo, Nb) in composition of EP-823 steel, compared with other steels of the same class, expands the region of existence of the ferrite phase, which can contribute to an increase in the temperature of Ac1 .

From mechanical behavior and elastocaloric effect to microscopic mechanisms of gradient-structured NiTi alloy: A phase-field study

The introduction of gradient structure has been recently reported as a practical way to tailor the mechanical behavior of NiTi alloy while improving its elastocaloric effect simultaneously. In this research, a thermo-mechanically weakly coupled phase-field model considering crystal plasticity is employed to investigate the microscopic mechanisms of the elastocaloric effect related to the gradient structure, especially from the point of view of the two-way interaction between stress and martensite variants. A set of polycrystalline systems are established to accomplish the gradual transition from a fine-grained specimen to a coarse-grained one by the grain-size gradient. The gradually changed mechanical response and phase transformation characteristics during the superelastic simulations embody the effectiveness of the grain structure as a regulator of the material properties. The Brayton cycle simulations conducted next revolve around further validation of the proposed model and variant-related interpretation of the effects of the grain structure. Predictions relevant to histories of stress and temperature agree well with the experimental results, and more remarkably, the linear stress-temperature relationship observed during the stress drop of the first hold in the Brayton cycle conforms perfectly to the classical Clausius–Clapeyron relation. Together with martensite reorientation, the propagating martensite phases, where the increasing non-major variants are necessary complements to the major one preferentially aligned with the external stress, are largely responsible for this stress drop. Regarding the elastocaloric effect, the gradient structures achieve very similar cooling capacity but higher cooling efficiency compared to the coarse-grain one, taking advantage of more martensite, particularly the major variant, produced if provided with the same transformable area (excluding the grain boundaries). Besides, a steeper gradient in structures is prone to alter the composition of martensite variants and more non-major variants are demanded to alleviate the developing deformation mismatch among layers with different grain sizes.

Influence of high temperature ternary and quaternary additions on the phase transformation and actuation fatigue characteristics of NiTi shape memory alloys

Influence of high temperature ternary and quaternary additions on the phase transformation and actuation fatigue characteristics of NiTi shape memory alloys

Spin exchange between paramagnetic probes inside graphite oxide

Heisenberg spin exchange among paramagnetic species in acetonitrile intercalated into graphite oxide was studied. It was found that spin exchange in between the oxidized graphene planes is strongly hindered, and spin-exchange broadening of EPR spectra has not been observed both for particles of the same nature (TEMPO-TEMPO) and for particles of different types (TEMPO-Ni2+). The addition of nickel ions into the “graphite oxide – CH3CN” system led to the absence of the characteristic phase transformation of the high-temperature swelled graphite oxide to the low-temperature one.

Study of the effects of laser power and scanning speed on the microstructural morphologies and physical properties of L-PBF produced Ni52.39Ti47.61

This study examined the effect of variations in the laser power and scan speed for 52.39 at.%Ni-47.61 at.%Ti samples produced via laser powder bed fusion (L-PBF). The laser power was varied between 150W and 180 W, the scanning speeds were varied between 500 mm/s and 1000 mm/s, and other process parameters were kept constant. The resulting microstructures and physical properties of the produced samples were evaluated. In particular, the phase type and phase transformation characteristics, composition, Vickers microhardness, and microstructures were examined. It was observed that variation in the mean microhardness and relative density were not significant at a constant scan speed of 1000 mm/s, regardless of the laser power value. Samples processed at a laser power of 180W (with all other parameters kept constant) exhibited a bimodal micro- and nano structures. It was found that the samples with bimodal microstructure had a higher lattice strain, extent of B2 phase, and higher phase transformation temperatures.

Magnetic Shape-Memory Heuslers Turn to Bio: Cytocompatibility of Ni-Mn-Ga Films and Biomedical Perspective.

Magnetic shape-memory (MSM) Heuslers have attracted great attention in recent years for both caloric and magnetomechanical applications. Thanks to their multifunctional properties, they are also promising for a vast variety of biomedical applications. However, this topic has been rarely investigated so far. In this communication, we present the first report on the absence of cytotoxicity of MSM Heuslers in Ni-Mn-Ga epitaxial thin films and the perspective toward bioapplications. Qualitative and quantitative biological characterizations reveal that Ni-Mn-Ga films can promote the adhesion and proliferation of human fibroblasts without eliciting any cytotoxic effect. Additionally, our findings show that the morphology, composition, microstructure, phase transformation, and magnetic characteristics of the films are well preserved after the biological treatments, making the material a promising candidate for further investigations.

Test and DEM study on cyclic hysteresis characteristics of stereoscopic geogrid–soil interface

The bearing resistance provided by the geogrid's transverse ribs is a non-negligible aspect of the strength mechanism in mobilizing the geogrid–soil interface. Therefore, studying its influence on the response mechanism of geosynthetic-reinforced soil structures under cyclic loading is crucial. The stereoscopic geogrids were manufactured using 3D printing technology by quantitatively thickening the transverse ribs of planar geogrids. To investigate the cyclic hysteresis relationship and stress–dilatancy phase-transformation characteristics of the stereoscopic geogrid–coarse particle interface, cyclic direct shear tests were conducted. Additionally, a discrete element method (DEM) was employed to study the evolution of shear bands and fabric anisotropy at the interface under cyclic loading. The results of the study indicate that the stress–displacement phase angle of the stereoscopic geogrid in the horizontal direction of cyclic shear is smaller compared to the planar geogrid. Furthermore, thickening the transverse ribs decreases the stress–dilatancy phase-transformation angle of the interface. The thickness of the interface shear band in the stereoscopic geogrid is greater than that of the planar geogrid. Moreover, as the transverse-rib thickness increases, the principal direction of the average normal contact force and average tangential contact force under cyclic loading also increases.

Unlocking the Origins of Highly Reversible Lithium Storage and Stable Cycling in a Spinel High‐Entropy Oxide Anode for Lithium‐Ion Batteries

AbstractDeveloping high‐capacity conversion‐type anodes with superior durability substituting conventional graphite anodes is urgently desired to improve the energy density of lithium‐ion batteries (LIBs). However, fatal capacity decay during cycling of the conversion‐type anodes, which is primarily due to their inevitable structural degradation and continuous solid‐electrolyte interphase reformation induced by drastic volume change, has highly restricted their commercialization. And, the interrelated effects of phase transformation, structural evolution, and electrochemical characteristics of the conversion‐type anodes during cycling remain poorly understood. Herein, the findings on the fabrication and understanding of a previously unexplored entropy‐stabilized spinel oxide, (Co0.2Mn0.2V0.2Fe0.2Zn0.2)3O4 as a promising conversion anode for LIBs, exhibiting not only moderate volume change character but also highly reversible capacities of ≈900 mAh g−1 for 500 cycles at 0.2 A g−1 and ≈500 mAh g−1 for 2000 cycles at 3 A g−1, respectively, are reported. Evidenced by in situ transmission electron microscopy coupled with theoretical calculations, its underlying mechanism underpinning highly reversible Li storage is explicitly revealed, which originates from reversible phase transformation and domain reconstruction during cycling. Moreover, the origin of small volume change is also clearly clarified. This work provides renewed mechanistic insights into designing high‐capacity and durable conversion‐type electrode materials for high‐performance LIBs.

Achieving high-damping NiTip/7075Al composites with controllable phase transformation behavior fabricated by friction stir processing

To achieve controllable damping temperature zones in aluminum matrix composites, the NiTip/7075Al composites with controllable phase transformation characteristics were prepared through friction stir processing (FSP) and heat treatment. Aging of NiTi particles led to a downward shift in the phase-transition peak temperature of the composite, accompanied by a sharper peak. During the cooling process, the as-NiTip/7075Al + T6 composites underwent a B2 → R transformation and an R → B19′ transformation. Furthermore, the T6 treatment effectively enhanced the tensile strength of the composites. The damping properties of NiTip/7075Al composites at low-temperatures (<90 °C) were significantly superior to those of FSP-7075Al alloy. The as-NiTip/7075Al + T6 composites exhibited two internal friction peaks during cooling, which were 153 % and 211 % higher, respectively, than those observed in the FSP-7075Al alloy at corresponding temperatures. The damping temperature range of the composites can be effectively controlled through T6 treatment and NiTi particle pre-aging.